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1. 发明专利

JP2006008446A Hydrogen storage method, hydrogen storage material, and fuel cell system using the same 审中-公开
标题翻译：氢储存方法，储氢材料和使用其的燃料电池系统
公开(公告)号：JP2006008446A
公开(公告)日：2006-01-12
申请号：JP2004187342
申请日：2004-06-25
申请人： Tohoku Univ , Toyota Central Res & Dev Lab Inc , 国立大学法人東北大学 , 株式会社豊田中央研究所
发明人： TOWATA SHINICHI , NORITAKE TATSUO , AOKI MASAKAZU , KOJIMA YOSHITSUGU , MIWA KAZUTOSHI , OBA NOBUKO , ORIMO SHINICHI , NAKAMORI HIROKO , KITAHARA MANABU
IPC分类号： C01B3/00 , B01J20/04 , C01B6/00 , C01B6/04 , C01B6/21 , C01B6/24 , C01B21/06 , C01B21/092 , F17C11/00 , H01M8/04 , H01M8/06
CPC分类号： Y02E60/321 , Y02E60/327
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen storage method, by which a large amount of hydrogen can be stored and the stored hydrogen can be easily taken out; and to provide a hydrogen storage material. SOLUTION: A first hydrogen storage method includes a raw material mixture preparation process for preparing a raw material mixture by mixing two or more kinds of compounds selected from nitrides and complex hydrides and a hydrogen storage process for storing hydrogen by forming a hydride comprising at least one kind of constitutive elements of the compounds and hydrogen by reacting the raw material mixture with hydrogen. Further, a second hydrogen storage method comprises storing hydrogen by forming two or more kinds of hydrides comprising at least one kind of constitutive elements of the raw material compounds and hydrogen by reacting a raw material compound containing at least one element selected from alkali metal elements and alkaline earth metal elements, and aluminum or boron with hydrogen. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种氢存储方法，通过该方法可以储存大量氢气，并且可以容易地取出储存的氢气; 并提供储氢材料。解决方案：第一种氢存储方法包括通过混合选自氮化物和络合氢化物的两种或更多种化合物制备原料混合物的原料混合物制备方法和通过形成氢化物的氢存储方法，通过使原料混合物与氢气反应，化合物和氢的至少一种组成元素。此外，第二氢存储方法包括通过将包含至少一种原料化合物的组成元素和氢的组成的两种或更多种氢化物储存在氢气中，使含有至少一种选自碱金属元素的元素和碱土金属元素，铝或硼与氢。版权所有（C）2006，JPO＆NCIPI

2. 发明专利

JP2007117989A Hydrogen storage material and its production method 审中-公开
标题翻译：氢储存材料及其生产方法
公开(公告)号：JP2007117989A
公开(公告)日：2007-05-17
申请号：JP2006197495
申请日：2006-07-19
申请人： Tohoku Univ , Toyota Central Res & Dev Lab Inc , 国立大学法人東北大学 , 株式会社豊田中央研究所
发明人： TOWATA SHINICHI , AOKI MASAKAZU , NORITAKE TATSUO , MIWA KAZUTOSHI , OBA NOBUKO , ORIMO SHINICHI , NAKAMORI HIROKO , NINOMIYA AKIHITO
IPC分类号： B01J20/04 , B01J20/02 , B01J20/30 , C01B6/00 , C01B6/15 , C01B6/23 , C01B35/18 , H01M8/04
CPC分类号： Y02P20/129 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To suppress the decomposition of a hydrogen storage material caused by its contact with water and deterioration in its hydrogen storage or discharge properties, and to reduce the discharge starting temperature of hydrogen in the hydrogen storage material. SOLUTION: The hydrogen storage material comprises one or more kinds of first hydrides including an M 1 element(s), boron and hydrogen, and one or more kinds of first chlorides including an M 2 element(s); wherein, the M 1 element(s) and M 2 element(s) are at least one or more kinds of elements selected from Li, Na, K, Ca, Zn, Cu, Mg, Sc, Zr, Mn, Hf, Al, Ti, Cr, V, Ga, Fe, Co, Ni, Y and rare earth elements, respectively. The production method uses the same. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：抑制由于其与水的接触而导致的储氢材料的分解和其储氢或排出性能的劣化，并降低储氢材料中氢的排出开始温度。解决方案：储氢材料包括一种或多种包括M SB 3元素，硼和氢的第一种氢化物和一种或多种包括M 2 元件（多个）; 其中，一个或多个M 元素是至少一种或多种选自Li，Na，K，Ca，Zn的元素，Cu，Mg，Sc，Zr，Mn，Hf，Al，Ti，Cr，V，Ga，Fe，Co，Ni，Y和稀土元素。生产方法使用相同。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2007008738A Composite of hydrides, hydrogen storing material, and manufacturing method thereof 有权
标题翻译：氢化物复合材料，储氢材料及其制造方法
公开(公告)号：JP2007008738A
公开(公告)日：2007-01-18
申请号：JP2005188905
申请日：2005-06-28
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , NORITAKE TATSUO , OBA NOBUKO , MIWA KAZUTOSHI , TOWATA SHINICHI
IPC分类号： C01B6/00 , B01J20/04 , C01B3/00
CPC分类号： Y02E60/327 , Y02P20/129
摘要： PROBLEM TO BE SOLVED: To provide a composite of hydrides and a hydrogen storing material which contain a small amount of rare elements and are light in weight and capable of storing/releasing a large amount of hydrogen at a relatively low temperature, and a manufacturing method thereof. SOLUTION: The composite of hydrides is obtained by compounding in a mechanically mixing process one or more kinds of borohydrides represented by X(BH 4 ) m (wherein m is a valence number of the element X) and one or more kinds of amides represented by Y(NH 2 ) n (wherein n is a valence number of the element Y) and the manufacturing method thereof is provided. The hydrogen storing material is obtained by releasing all or a part of hydrogen contained in the composite of hydrides and the manufacturing method thereof is provided. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供含有少量稀有元素并且重量轻且能够在较低温度下储存/释放大量氢的氢化物和储氢材料的复合物，以及其制造方法。解决方案：氢化物复合物通过在机械混合过程中配混一种或多种由X（BH 4 ）表示的硼氢化物（其中m为元素X的价数）和由Y（NH 2 SBR）表示的一种或多种酰胺（其中n是元素Y的价数）和提供其制造方法。储氢材料是通过释放氢化物复合物中所含的全部或一部分氢而获得的，其制造方法。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2004300561A Hydrogen storage alloy, and its production method 审中-公开
公开(公告)号：JP2004300561A
公开(公告)日：2004-10-28
申请号：JP2003097973
申请日：2003-04-01
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： TOWATA SHINICHI , AOKI MASAKAZU , MORI TOSHIHIRO , SAITO KATSUSHI
IPC分类号： C22C1/00 , C22C23/00
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen storage alloy which has a large hydrogen storage content, and has high hydrogen storing/discharging rates.
SOLUTION: In the hydrogen storage alloy consisting of two or more phases, at least one phase is a stable hydride formation phase comprising one or more kinds of stable hydride formation elements reacted with hydrogen so as to form stable hydride. As for the stable hydride formation phase, in the observed cross-sectional structure, the diameter of minor axis is ≤5 μm and the phase is dispersed at the intervals of ≤1 μm, and the phase is further separated since the one or more stable hydride formation elements form hydride. There are many crystal grain boundaries since the stable hydride formation phase is separated. Thus, the diffusion paths of hydrogen increase, and the diffusion rate of hydrogen is made high.
COPYRIGHT: (C)2005,JPO&NCIPI

5. 发明专利

JP2004066653A Multi-ply structured hydrogen storage body 有权
公开(公告)号：JP2004066653A
公开(公告)日：2004-03-04
申请号：JP2002229674
申请日：2002-08-07
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： TOWATA SHINICHI , AOKI MASAKAZU , HIOKI TATSUMI , ITO AKIO , KOIWAI AKIHIKO , MORI TOSHIHIRO , SAITO KATSUSHI
IPC分类号： B32B15/01 , C01B3/00 , C22C14/00 , C22C23/00 , C22C27/02 , H01M8/06
CPC分类号： B32B15/018 , C01B3/0078 , C22C14/00 , C22C23/00 , C22C27/02 , H01M8/065 , Y02E60/324 , Y10T428/12493 , Y10T428/12729 , Y10T428/12819 , Y10T428/12875
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen absorbing storage body wherein a hydrogen storage amount is large, and a storage speed and an emission speed of hydrogen are quick at a temperature near an ordinary temperature. SOLUTION: The hydrogen storage body is a multi-ply structured hydrogen storage body wherein at least two kinds of hydrogen storage materials are laminated. Then, in the multi-ply structured hydrogen storage body, hydrogen storage materials contacted with each other are laminated so that degrees of strains generated following storage and emission of hydrogen are varied. COPYRIGHT: (C)2004,JPO

6. 发明专利

JP2008013503A Organometallic amide compound and method for preparing the same, amide compound complex and method for preparing the same, and hydrogen storage material 审中-公开
标题翻译：有机酰胺化合物及其制备方法，酰胺化合物复合物及其制备方法和氢储存材料
公开(公告)号：JP2008013503A
公开(公告)日：2008-01-24
申请号：JP2006187276
申请日：2006-07-06
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , TOWATA SHINICHI , NORITAKE TATSUO , MATSUMOTO MITSURU , KITAJIMA SATSUKI , SATO MASAHIRO
IPC分类号： C07F3/02 , B01J20/22
摘要： PROBLEM TO BE SOLVED: To provide a novel and thermally unstable organometallic amide compound from which hydrogen is easily produced, a method for preparing the compound, an amide compound complex made from the amide compound, a method for preparing the amid compound complex, and a hydrogen storage material.
SOLUTION: An organometallic amide compound having a composition represented by the formula (R)
m M
x (NH
y )
n , wherein R represents at least one organic group selected from the group consisting of a 1 to 10C linear alkyl group, a 1 to 10C branched alkyl group and an aromatic group; M represents a metal element; m is a natural number of from 1 to 4; n is a natural number of from 1 to 4, x and y each are a natural number of from 1 to 2, which is prepared by reacting an organometallic compound represented by the formula (R)
p M with ammonia, a method for preparing the organometallic amide compound, an amide compound complex comprising the organometallic amide compound and a method for preparing the amide compound complex, and a hydrogen storage material formed by releasing the hydrogen contained in the amide compound complex are disclosed.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供容易产生氢的新颖且不稳定的有机金属酰胺化合物，制备该化合物的方法，由酰胺化合物制备的酰胺化合物络合物，制备酰胺化合物络合物的方法，和储氢材料。解决方案：具有由式（R）表示的组成的有机金属化合物酰胺化合物（SBB）（SBB）＆lt; SB＆gt; n ，其中R表示选自1至10个直链烷基，1至10个支链烷基和芳族基团中的至少一种有机基团; M表示金属元素; m是1到4的自然数; n是1至4的自然数，x和y各自为1至2的自然数，其通过使由式（R） p M表示的有机金属化合物与氨，制备有机金属酰胺化合物的方法，包含有机金属酰胺化合物的酰胺化合物络合物和制备酰胺化合物络合物的方法，以及通过释放酰胺化合物络合物中所含的氢而形成的储氢材料。版权所有（C）2008，JPO＆INPIT

7. 发明专利

JP2007113111A Hydrogen storage alloy 审中-公开
标题翻译：氢储存合金
公开(公告)号：JP2007113111A
公开(公告)日：2007-05-10
申请号：JP2006190750
申请日：2006-07-11
申请人： Toyota Central Res & Dev Lab Inc , Toyota Industries Corp , 株式会社豊田中央研究所 , 株式会社豊田自動織機
发明人： MIYOSHI MANABU , KINOSHITA KYOICHI , AOKI MASAKAZU , OBA NOBUKO , NORITAKE TATSUO
IPC分类号： C22C24/00 , C01B3/00 , C22C28/00
CPC分类号： C22C24/00 , C01B3/0031 , C22C28/00 , Y02E60/327
摘要： PROBLEM TO BE SOLVED: To provide a new hydrogen storage alloy capable of absorbing or desorbing hydrogen at relatively low temperature. SOLUTION: The hydrogen storage alloy is represented by (Ca 1-n Sr n )Si, in which the Sr atoms substitute for a part of the Ca atoms of CaSi alloy whose atomic ratio of Ca to Si is 1:1 and the symbol "n" satisfies 0 COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供能够在相对低的温度下吸收或解吸氢的新的储氢合金。解决方案：储氢合金由（Ca 1-n Sr n ）Si表示，其中Sr原子代替一部分Ca原子 Ca〜Si原子比为1：1，符号“n”的CaSi合金满足0

8. 发明专利

JP2006256888A Hydrogen storage material and its manufacturing method 审中-公开
标题翻译：氢储存材料及其制造方法
公开(公告)号：JP2006256888A
公开(公告)日：2006-09-28
申请号：JP2005074740
申请日：2005-03-16
申请人： Toyota Central Res & Dev Lab Inc , Toyota Industries Corp , 株式会社豊田中央研究所 , 株式会社豊田自動織機
发明人： AOKI MASAKAZU , OBA NOBUKO , NORITAKE TATSUO , MIWA KAZUTOSHI , TOWATA SHINICHI , MIYOSHI MANABU , KINOSHITA KYOICHI
IPC分类号： C01B33/06 , B01J20/02 , B22F1/00 , C01B3/00 , C22C1/04 , C22C28/00
CPC分类号： Y02E60/327 , Y02P20/129
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen storage material which contains a small amount of rare elements, and is lightweight and capable of storing/releasing a large amount of hydrogen at a relatively low temperature. SOLUTION: The hydrogen storage material is represented by composition formula: (Ca 1-x Li x ) 1-z Si z (wherein, 0.25≤x≤0.4 and 0.38≤x≤0.58). The method for manufacturing the hydrogen storage material has a compounding process of blending CaH 2 , LiH and Si so that the ratios of Ca, Li and Si satisfy the composition formula: (Ca 1-x Li x ) 1-z Si z (wherein, 0.25≤x≤0.4 and 0.38≤x≤0.58) and compounding the resulting blend in a mechanical mixing process and a heat treating process of heat treating the composite of the hydrides obtained in the compounding process. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种含有少量稀有元素的储氢材料，重量轻且能够在较低温度下储存/释放大量的氢。
解决方案：储氢材料由组成式表示：（Ca x ）Si SB z （其中，0.25≤x≤0.4和0.38≤x≤0.58）。制备储氢材料的方法具有混合CaH 2 ，LiH和Si的配合方法，使得Ca，Li和Si的比例满足组成式：（Ca 1-x （其中，0.25≤x≤0.4和0.38≤x≤0.58）和复合物（其中，0.25≤x≤0.4和0.38≤x≤0.58）所得到的混合机械混合过程和热处理在复合过程中获得的氢化物的复合物的热处理工艺。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2005324972A Hydrogen occlusion material 审中-公开
标题翻译：氢化物质
公开(公告)号：JP2005324972A
公开(公告)日：2005-11-24
申请号：JP2004142462
申请日：2004-05-12
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , OBA NOBUKO , NORITAKE TATSUO , TOWATA SHINICHI
IPC分类号： C01B3/00 , C22C1/00 , C22C24/00
CPC分类号： Y02E60/327
摘要： PROBLEM TO BE SOLVED: To provide a light and inexpensive hydrogen occlusion material.
SOLUTION: The hydrogen occlusion material is expressed by the composition formula: (Ca
1-x A
x )
1-z (Si
1-y B
y )
z , in which A expresses at least one kind selected from the group consisting of alkali metal elements, alkaline earth metal elements, rare earth elements, group 3-5 elements, group 8-10 elements, and Mn; B expresses at least one kind selected from the group consisting of group 11-15 elements; and 0≤x
摘要翻译：要解决的问题：提供一种轻便且廉价的吸氢材料。解决方案：吸氢材料由以下组成式表示：（Si（SB）1-x SB ）其中A表示选自碱金属元素，碱土金属元素，碱金属元素，碱金属元素，碱金属元素，元素，稀土元素，3-5族元素，第8-10族元素和Mn; B表示从由组11-15组成的组中选出的至少一种; 0≤x<1,0≤y<1，0

10. 发明专利

JP2005257306A X-ray analyzing sample container and sample container housing device 审中-公开
标题翻译： X射线分析样品容器和样品容器装置
公开(公告)号：JP2005257306A
公开(公告)日：2005-09-22
申请号：JP2004065584
申请日：2004-03-09
申请人： Japan Synchrotron Radiation Research Inst , Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所 , 財団法人高輝度光科学研究センター
发明人： NOZAKI HIROSHI , TOWATA SHINICHI , AOKI MASAKAZU , NORITAKE TATSUO , SENOO YOSHIKI , HIROZAWA ICHIRO , SATO MASANAO
IPC分类号： G01N23/20
摘要： PROBLEM TO BE SOLVED: To provide an X-ray analyzing sample container, capable of arbitrarily setting the incident angle of incident X-rays and the emission angle of diffracted X-rays, capable of being adapted even to a high-pressure gas and capable of being reduced in size and cost, and to provide a sample container housing device capable of easily introducing/discharging a desired gas, with respect to the X-ray analyzing sample container. SOLUTION: In the X-ray analyzing sample container 10, a sample 22 is housed in a hermetically closed space 42, formed by a dome partition wall 34 and a placing stand 12. Since the dome partition wall 34 is formed into a semispherical shape by a polyimide film, the incidence angle of the incident X-rays can be arbitrarily set to an angle range of a 0-90° and the diffracted X-rays can be emitted from the dome part 36 at an emission angle range of 0-90° to enable measurement. Further, even when the high-pressure gas is introduced into the hermetically closed space 42, gas pressure is dispersed uniformly to the semispherical inner wall surface of the dome part 36 and the elastic deformation range of the dome part 36 is wide, the sample container can withstand the high pressure gas. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供能够任意设定入射X射线的入射角和衍射X射线的发射角的X射线分析样本容器，能够适应于高压气体并且能够减小尺寸和成本，并且提供相对于X射线分析样品容器能够容易地引入/排出所需气体的样品容器容纳装置。解决方案：在X射线分析样品容器10中，样品22容纳在由圆顶隔壁34和放置台12形成的气密封闭空间42中。由于圆顶隔壁34形成为通过聚酰亚胺膜的半球形状，入射X射线的入射角可以任意设定为0-90°的角度范围，衍射X射线可以从圆顶部36发射，发射角度范围为 0-90°使能测量。此外，即使将高压气体导入密封空间42，气压均匀地分散到圆顶部36的半球形内壁面，并且圆顶部36的弹性变形范围宽，样品容器可承受高压气体。版权所有（C）2005，JPO＆NCIPI

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