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    • 6. 发明专利
    • Hydrogen storage material
    • 氢储存材料
    • JP2004176089A
    • 2004-06-24
    • JP2002341123
    • 2002-11-25
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • OBA NOBUKOAOKI MASAKAZUTOWATA SHINICHI
    • C22C28/00C22C19/00
    • PROBLEM TO BE SOLVED: To provide a low-cost hydrogen storage material capable of absorbing/desorbing hydrogen at a temperature in the vicinity of room temperature.
      SOLUTION: The hydrogen storage material is represented by composition formula (Ca
      1-x A
      x )(Si
      1-y B
      y ) (wherein, A is at least one element selected from the group consisting of alkali elements, alkaline-earth elements, rare-earth elements, elements in groups III to VI, Ni, Au, In, Tl, Sn, Fe, Co, Cu and Ag; B is at least one element selected from the group consisting of elements in groups VII to XVII, rare-earth elements, Hf and Be; and 0≤x
    • 要解决的问题:提供能够在室温附近的温度下吸收/解吸氢的低成本储氢材料。 解决方案:储氢材料由组成式(Ca 1-x A x )(Si 1-y SB> y )(其中,A为选自碱金属元素,碱土金属元素,稀土元素,III〜VI族元素,Ni,Au,In,Tl中的至少一种元素 ,Sn,Fe,Co,Cu和Ag中的至少一种元素; B是选自VII〜XVII族元素,稀土元素,Hf和Be中的至少一种元素;0≤x<1且0≤y< 1)。 这种储氢材料可以在室温附近的温度下可逆地吸收/解吸氢,因为氢化物形成的热量(ΔH)取规定范围内的值。 此外,由于使用Ca和Si作为主要组成元素,所以这种储氢材料便宜。 版权所有(C)2004,JPO
    • 9. 发明专利
    • Magnesium type hydrogen storage material and production method therefor
    • 镁型储氢材料及其生产方法
    • JP2005279438A
    • 2005-10-13
    • JP2004097008
    • 2004-03-29
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • TOWATA SHINICHINORITAKE TATSUOMIWA KAZUTOSHIOBA NOBUKOORIMO SHINICHINAKAMORI HIROKO
    • C01B21/092B01J20/04C01B3/00
    • Y02E60/324
    • PROBLEM TO BE SOLVED: To provide a magnesium type hydrogen storage material which has a large hydrogen storage amount and is capable of taking out stored hydrogen in a low temperature region, and to provide a method for conveniently producing the magnesium type hydrogen storage material with high purity. SOLUTION: The magnesium type hydrogen storage material is represented by the formula: (Mg 1-x M x )(NH 2 ) 2±y , wherein M is one or more kinds selected from alkali elements and alkali earth elements, 0≤x≤0.75 and 0≤y≤0.75. Or, it is represented by the formula: (Mg 1-x M x )(NH) 1±y , wherein M is one or more kinds selected from alkali elements and alkali earth elements, 0≤x≤0.75 and 0≤y≤0.75. The magnesium type hydrogen storage materials are produced, for example, by allowing reaction gas to react with a magnesium type hydride raw material as a nitrogen source to prepare NH bonds while adding at least one of heat and mechanical energy. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有大的储氢量并能够在低温区域中取出储存的氢的镁型储氢材料,并提供方便地制备镁型氢存储器的方法 高纯度材料 解决方案:镁型储氢材料由下式表示:(Mg 1-x M x )(NH SB 2) 其中M是选自碱金属元素和碱土金属元素中的一种或多种,​​0≤x≤0.75和0≤y≤0.75。 或者,它由下式表示:其中M是一个或多个,其中M是1或Y 选自碱元素和碱土元素的更多种类,0≤x≤0.75和0≤y≤0.75。 镁型储氢材料例如通过使反应气体与镁型氢化物原料作为氮源反应来制备,以在添加热和机械能中的至少一种的同时制备NH键。 版权所有(C)2006,JPO&NCIPI