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1. 发明授权

US06139999A Imaging member with partially conductive overcoating 有权
标题翻译：具有部分导电涂层的成像构件
公开(公告)号：US06139999A
公开(公告)日：2000-10-31
申请号：US429387
申请日：1999-10-28
申请人： Timothy J. Fuller , Damodar M. Pai , John F. Yanus , Paul J. DeFeo , Anthony T. Ward , Dale S. Renfer , Harold F. Hammond , Merlin E. Scharfe , Markus R. Silvestri , William W. Limburg
发明人： Timothy J. Fuller , Damodar M. Pai , John F. Yanus , Paul J. DeFeo , Anthony T. Ward , Dale S. Renfer , Harold F. Hammond , Merlin E. Scharfe , Markus R. Silvestri , William W. Limburg
IPC分类号： G03G5/05 , G03G5/147
CPC分类号： G03G5/0592 , G03G5/0571 , G03G5/14765 , G03G5/14791
摘要： An electrophotographic imaging member includingat least one photographic imaging layer anda partially electrically conductive overcoat layer includingfinely divided charge injection enabling particles dispersed ina charge transporting continuous matrix including a cross linked polyamide, charge transport molecules and oxidized charge transport molecules, the continuous matrix being formed from a solution selected from the group includinga first solution includingcrosslinkable alcohol soluble polyamide containing methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.a of less than about 3,a cross linking agent selected from the group comprising a formaldehyde generating cross linking agent, an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof,a dihydroxy arylamine, anda liquid selected from the group including alcohol solvents, diluent and mixtures thereof,a second solution includingcrosslinkable alcohol soluble polyamide free of methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.a of less than about 3,an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof,a dihydroxy arylamine, anda liquid selected from the group including alcohol solvents, diluent and mixtures thereof.The electrophotographic imaging process is also disclosed.
摘要翻译：一种电子照相成像构件，包括至少一个照相成像层和部分导电的外涂层，其包括分散在包含交联聚酰胺，电荷传输分子和氧化电荷传输分子的电荷传输连续基质中的细碎电荷注入使颗粒，连续基质由选自包含第一溶液的溶液形成，所述溶液包括含有与酰胺氮原子连接的甲氧基甲基的可交联醇可溶性聚酰胺，pKa小于约3的酸，选自甲醛的交联剂产生交联剂，烷氧基化交联剂，羟甲基胺交联剂及其混合物，二羟基芳基胺和选自醇溶剂，稀释剂及其混合物的液体;第二溶液，包括可交联醇可溶性聚不含与酰胺氮原子连接的甲氧基甲基，pKa小于约3的酸，烷氧基化交联剂，羟甲基胺交联剂及其混合物，二羟基芳基胺和选自以下的液体：醇溶剂，稀释剂及其混合物。还公开了电子照相成像方法。

2. 发明授权

US6096470A Electrophotographic imaging member overcoat fabrication process 有权
标题翻译：电子照相成像构件外套制造工艺
公开(公告)号：US6096470A
公开(公告)日：2000-08-01
申请号：US429378
申请日：1999-10-28
申请人： Timothy J. Fuller , Damodar M. Pai , John F. Yanus , Anthony T. Ward , Harold F. Hammond , Merlin E. Scharfe , Paul J. DeFeo
发明人： Timothy J. Fuller , Damodar M. Pai , John F. Yanus , Anthony T. Ward , Harold F. Hammond , Merlin E. Scharfe , Paul J. DeFeo
IPC分类号： G03G5/00 , G03G5/047 , G03G5/05 , G03G5/07 , G03G5/147
CPC分类号： G03G5/0525 , G03G5/047
摘要： A process for fabricating an electrophotographic imaging member includingforming a charge generating layer,forming an undried charge transport layer coating by applying to the charge generating layer a solution selected from either or both the group consisting ofa solution including a charge transport molecule, a first film forming binder and at least a first solvent anda solution including a charge transporting polymer and at least a first solvent,forming an undried overcoat layer coating by applying to the undried charge transport layer coating an overcoat layer coating solution including a second film forming polymer and at least a second solvent, the charge transport molecule and first film forming polymer or either or both a charge transporting polymer being substantially insoluble in the second solvent and the second polymer being substantially insoluble in the first solvent,applying heat to both the undried charge transport layer coating and the undried overcoat layer coating to migrate the first solvent from the charge transport layer coating through the undried overcoat layer coating while maintaining the overcoat layer coating porous to migration of the first solvent through the overcoat layer coating until the charge transport layer is substantially dry,increasing the heat applied to the overcoat layer coating to form a substantially dry overcoat layer.
摘要翻译：一种用于制造电子照相成像部件的方法，包括形成电荷产生层，通过向电荷产生层施加选自以下两者或两者的溶液形成未干燥的电荷传输层涂层，所述溶液选自包含电荷传输分子，第一成膜粘合剂和至少第一溶剂和包含电荷输送聚合物和至少第一溶剂的溶液，通过向未干燥的电荷输送层施加涂覆包含第二成膜聚合物的外涂层涂层溶液形成未干燥的外涂层涂层和至少第二溶剂，电荷输送分子和第一成膜聚合物，或电荷输送聚合物中的任一种或两者均基本上不溶于第二溶剂，第二聚合物基本上不溶于第一溶剂，向未干燥的电荷运输层涂层和未干燥的外涂层涂层将第一溶剂从电荷输送层涂层迁移通过未干燥的外涂层涂层，同时保持外涂层涂层多孔以使第一溶剂迁移通过外涂层涂层，直到电荷输送层基本上干燥，从而将施加到外涂层涂层以形成基本上干燥的外涂层。

3. 发明授权

US6103436A Overcoated photoreceptors and methods of using overcoated photoreceptors 有权
标题翻译：涂覆光感受器和使用外敷光感受器的方法
公开(公告)号：US6103436A
公开(公告)日：2000-08-15
申请号：US182602
申请日：1998-10-29
申请人： John F. Yanus , Damodar M. Pai , Timothy J. Fuller , Paul J. DeFeo , Anthony T. Ward , Dale S. Renfer , William W. Limburg , Markus R. Silvestri , Harold F. Hammond , Robert W. Nolley
发明人： John F. Yanus , Damodar M. Pai , Timothy J. Fuller , Paul J. DeFeo , Anthony T. Ward , Dale S. Renfer , William W. Limburg , Markus R. Silvestri , Harold F. Hammond , Robert W. Nolley
IPC分类号： C08G69/36 , G03G5/05 , G03G5/06 , G03G5/147 , G03G5/047
CPC分类号： G03G5/0571 , C08G69/36 , G03G5/0614 , G03G5/14708 , G03G5/14765
摘要： An electrophotographic imaging member including a supporting substrate coated with at least photoconductive layer, a charge transport layer and an overcoating layer, the overcoating layer includinga hydroxy functionalized aromatic diamine anda hydroxy functionalized triarylamine dissolved or molecularly dispersed ina crosslinked polyamide matrix, the crosslinked polyamide prior to crosslinking being selected from the group consisting of materials represented by the following Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene unit containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are --H, andthe remainder of the R.sub.2 sites are --CH.sub.2 --O--CH.sub.3, and ##STR2## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000,R.sub.1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms, andbetween 1 and 99 percent of the R.sub.3 and R.sub.4 sites are --H, andthe remainder of the R.sub.3 and R.sub.4 sites are --CH.sub.2 --O--CH.sub.3.Coating compositions for the overcoating layer of this invention as well as methods of making and using the overcoated photoreceptor are also disclosed.
摘要翻译：一种电子照相成像构件，其包括涂覆有至少光电导层，电荷传输层和外涂层的支撑基底，所述外涂层包含溶解或分子分散在交联聚酰胺基质中的羟基官能化芳族二胺和羟基官能化三芳基胺，所述交联交联前的聚酰胺选自由以下式I和II表示的材料组成的组：其中：n是足以实现约5000至约100,000的重均分子量的正整数，R是含有 1至10个碳原子，1至99％的R2位点为-H，其余部分为-CH2-O-CH3，其中：m为足以达到重均分子量的正整数在约5000至约100000之间，R 1和R 2独立地选自亚烷基单元co 具有1至10个碳原子，并且1至99％的R 3和R 4位点是-H，并且R 3和R 4位点的其余部分是-CH 2 -O-CH 3。还公开了本发明的外涂层的涂料组合物以及制备和使用外涂感光体的方法。

4. 发明授权

US5976744A Photoreceptor overcoatings containing hydroxy functionalized aromatic diamine, hydroxy functionalized triarylamine and crosslinked acrylated polyamide 有权
公开(公告)号：US5976744A
公开(公告)日：1999-11-02
申请号：US182375
申请日：1998-10-29
申请人： Timothy J. Fuller , John F. Yanus , Damodar M. Pai , William W. Limburg , Markus R. Silvestri , Dale S. Renfer , Anthony T. Ward , Paul J. DeFeo , Harold F. Hammond , Robert W. Nolley
发明人： Timothy J. Fuller , John F. Yanus , Damodar M. Pai , William W. Limburg , Markus R. Silvestri , Dale S. Renfer , Anthony T. Ward , Paul J. DeFeo , Harold F. Hammond , Robert W. Nolley
IPC分类号： G03G5/047 , G03G5/07 , G03G5/147 , G03G13/22
CPC分类号： G03G5/075 , G03G5/047 , G03G5/14765 , G03G5/14791
摘要： An electrophotographic imaging member includinga supporting substrate coated withat least one photoconductive layer, andan overcoating layer, the overcoating layer including aa hydroxy functionalized aromatic diamine anda hydroxy functionalized triarylamine dissolved or molecularly dispersed ina crosslinked acrylated polyamide matrix, the hydroxy functionalized triarylamine being a compound different from the polyhydroxy functionalized aromatic diamine, the crosslinked polyamide prior to crosslinking being selected from the group consisting of materials represented by the following Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene group containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are ##STR2## wherein X is selected from the group consisting of --H (acrylate), --CH.sub.3 (methacrylate), alkyl and aryl, andthe remainder of the R.sub.2 sites are selected from the group consisting of --H, --CH.sub.2 OCH.sub.3, and --CH.sub.2 OH, and ##STR3## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000,R and R.sub.1 are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms;between 1 and 99 percent of R.sub.3 and R.sub.4 are independently selected from the group consisting of ##STR4## wherein X is selected from the group consisting of hydrogen, alkyl, aryl and alkylaryl, wherein the alkyl groups contain 1 to 10 carbon atoms and the aryl groups contain 1 to 3 alkyl groups, y is an integer between 1 and 10, andthe remainder of the R.sub.3 and R.sub.4 groups are selected from the group consisting of --H, --CH.sub.2 OH, --CH.sub.2 OCH.sub.3, and --CH.sub.2 OC(O)--C(X).dbd.CH.sub.2.The overcoating layer is formed by coating. The electrophotographic imaging member may be imaged in a process.

5. 发明授权

US6132913A Photoreceptor overcoatings containing hydroxy functionalized aromatic diamine, hydroxy functionalized triarylamine and crosslinked acrylated polyamide 有权
标题翻译：含有羟基官能化芳族二胺，羟基官能化三芳基胺和交联丙烯酸酯化聚酰胺的光敏剂外涂层
公开(公告)号：US6132913A
公开(公告)日：2000-10-17
申请号：US265187
申请日：1999-03-09
申请人： Timothy J. Fuller , John F. Yanus , Damodar M. Pai , William W. Limburg , Markus R. Silvestri , Dale S. Renfer , Anthony T. Ward , Paul J. DeFeo , Harold F. Hammond , Robert W. Nolley
发明人： Timothy J. Fuller , John F. Yanus , Damodar M. Pai , William W. Limburg , Markus R. Silvestri , Dale S. Renfer , Anthony T. Ward , Paul J. DeFeo , Harold F. Hammond , Robert W. Nolley
IPC分类号： G03G5/047 , G03G5/07 , G03G5/147 , G03G5/47 , G03G13/22
CPC分类号： G03G5/075 , G03G5/047 , G03G5/14765 , G03G5/14791
摘要： A crosslinkable coating composition including an alcohol soluble acrylated polyamide containing alkoxymethyl or alkoxyalkylmethyl groups attached to amide nitrogen atoms, a crosslinking catalyst and a mixture of a hydroxy functionalized aromatic diamine with a hydroxy functionalized triarylamine. A coating is formed from this composition.
摘要翻译：一种可交联涂料组合物，其包含含有与酰胺氮原子连接的烷氧基甲基或烷氧基烷基甲基的醇可溶性丙烯酸酯化聚酰胺，交联催化剂和羟基官能化芳族二胺与羟基官能化三芳基胺的混合物。由该组合物形成涂层。

6. 发明授权

US6025102A Electrophotographic imaging member 失效
标题翻译：电子照相成像部件
公开(公告)号：US6025102A
公开(公告)日：2000-02-15
申请号：US914643
申请日：1997-08-19
申请人： Damodar M. Pai , John F. Yanus , Timothy J. Fuller , Merlin E. Scharfe , Paul J. DeFeo , Markus R. Silvestri
发明人： Damodar M. Pai , John F. Yanus , Timothy J. Fuller , Merlin E. Scharfe , Paul J. DeFeo , Markus R. Silvestri
IPC分类号： G03G5/00 , G03G5/047 , G03G5/05 , G03G5/06
CPC分类号： G03G5/0618 , G03G5/047 , G03G5/0517 , G03G5/0525 , G03G5/0614 , G03G5/0629
摘要： A flexible electrophotographic imaging member including a supporting substrate coated with at least one imaging layer comprising charge transport material free of long chain alkyl carboxylate groups and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent. Preferably, the flexible electrophotographic imaging member is free of an anticurl backing layer, the imaging member comprising a supporting substrate uncoated on one side and coated on the opposite side with at least a charge generating layer and a charge transport layer containing comprising a first charge transport material and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent.
摘要翻译：柔性电子照相成像构件，其包括涂覆有至少一个成像层的支撑基底，该成像层包含不含长链烷基羧酸盐基团的电荷输送材料和少量溶解或分子量的至少两个长链烷基羧酸盐基团的第二空穴传输材料分散在成膜粘合剂中并由含有低沸点组分和低浓度沸点溶剂的溶剂的混合物涂覆。优选地，柔性电子照相成像构件没有防反射背衬层，成像构件包括在一侧未涂覆并且在至少一个电荷产生层和包含第一电荷传输的电荷传输层的相对侧上涂覆的支撑衬底材料和少量不同的第二空穴传输材料，其包含溶解或分子分散在成膜粘合剂中并由含有低沸点组分和低浓度沸点溶剂的溶剂的混合物涂覆的至少两个长链烷基羧酸盐基团。

7. 发明授权

US6004709A Allyloxymethylatedpolyamide synthesis compositions and devices 有权
公开(公告)号：US6004709A
公开(公告)日：1999-12-21
申请号：US218682
申请日：1998-12-22
申请人： Dale S. Renfer , William W. Limburg , Timothy J. Fuller , John F. Yanus , Damodar M. Pai , Robert W. Nolley , Paul J. DeFeo , Anthony T. Ward
发明人： Dale S. Renfer , William W. Limburg , Timothy J. Fuller , John F. Yanus , Damodar M. Pai , Robert W. Nolley , Paul J. DeFeo , Anthony T. Ward
IPC分类号： C08F299/02 , C08G69/48 , C09D179/04 , G03G5/05 , G03G5/06 , G03G5/147 , G03G5/047
CPC分类号： G03G5/0589 , G03G5/0578 , G03G5/0592 , G03G5/0614 , G03G5/14708 , G03G5/14773 , G03G5/14786 , G03G5/14791
摘要： An allyloxymethylatedpolyamide composition is disclosed, the allyloxymethylatedpolyamide being represented by Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene unit containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are --H, andbetween 1 and 99 percent of the R.sub.2 sites are --H, and the remainder of the R.sub.2 sites is between 25 percent and 99 percent --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2, whereinw is 1, 2 or 3,between 1 and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5, andR.sub.5 is an alkyl unit containing 1 to 4 carbon atoms, and ##STR2## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R.sub.1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.3 and R.sub.4 sites are --H, and between 25 percent and 99 percent of the remainder of the R.sub.3 and R.sub.4 sites are --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2,whereinw is 1, 2 or 3, andbetween 1 percent and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5wherein R.sub.5 is an alkyl unit containing 1 to 4 carbon atoms.The allyloxymethylatedpolyamide may be synthesized by reacting an alcohol soluble polyamide with formaldehyde and an allylalcohol.The allyloxymethylatedpolyamide may be cross linked by a process selected from the group consisting of(a) heating an allyloxymethylatedpolyamide in the presence of a free radical catalyst, and(b) hydrosilation of the double bond of the allyloxy group of the allyloxymethylatedpolyamide with a silicon hydride reactant having at least 2 reactive sites.A preferred article includesa substrate,at least one photoconductive layer, andan overcoat layer comprisinga hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, anda cross linked allyloxymethylatedpolyamide film forming binder.A stabilizer may be added to the overcoat.

8. 发明授权

US06194111B1 Crosslinkable binder for charge transport layer of a photoconductor 有权
标题翻译：光电导体的电荷传输层的可交联粘合剂
公开(公告)号：US06194111B1
公开(公告)日：2001-02-27
申请号：US09487327
申请日：2000-01-19
申请人： Timothy J. Fuller , Markus R. Silvestri , John F. Yanus , Damodar M. Pai , Paul J. De Feo , Dale S. Renfer , Anthony T. Ward , William W. Limburg , Harold F. Hammond , Robert W. Nolley
发明人： Timothy J. Fuller , Markus R. Silvestri , John F. Yanus , Damodar M. Pai , Paul J. De Feo , Dale S. Renfer , Anthony T. Ward , William W. Limburg , Harold F. Hammond , Robert W. Nolley
IPC分类号： G03G5047
CPC分类号： C08G65/38 , C08G8/02 , C08G16/00 , C08G65/48
摘要： A crosslinkable charge transport layer material for a photoconductor includes at least one poly(arylene ether alcohol), at least one polyisocyanate crosslinking agent and at least one charge transport material dispersed in a solvent. The crosslinkable charge transport layer material is crosslinked following application of the coating solution to the photoconductor. The photoconductor including such crosslinked charge transport layer exhibits excellent wear resistance so as to have long life, thereby reducing the cost of electrophotographic printing machines employing such photoconductors therein.
摘要翻译：用于光电导体的可交联电荷传输层材料包括至少一种聚（亚芳基醚醇），至少一种多异氰酸酯交联剂和分散在溶剂中的至少一种电荷输送材料。在将涂布溶液涂布到感光体上之后，可交联电荷输送层材料交联。包含这种交联的电荷输送层的感光体表现出优异的耐磨性，从而具有长的使用寿命，从而降低了在其中使用这种感光体的电子照相印刷机的成本。

9. 发明授权

US07226712B2 Photoconductive imaging members having pyrolyzed polyacrylonitrile hole blocking layer 有权
标题翻译：具有热解聚丙烯腈空穴阻挡层的光导成像构件
公开(公告)号：US07226712B2
公开(公告)日：2007-06-05
申请号：US11302877
申请日：2005-12-14
申请人： Timothy J. Fuller , Helen R. Cherniack , Damodar M. Pai , Markus R. Silvestri , John F. Yanus , Yuhua Tong , Dale S. Renfer , Kenny-Tuan T. Dinh , Merlin E. Scharfe , Steven M. Sterling
发明人： Timothy J. Fuller , Helen R. Cherniack , Damodar M. Pai , Markus R. Silvestri , John F. Yanus , Yuhua Tong , Dale S. Renfer , Kenny-Tuan T. Dinh , Merlin E. Scharfe , Steven M. Sterling
IPC分类号： G03G5/14
CPC分类号： G03G5/142 , G03G5/0542 , G03G5/0546 , G03G5/0614 , G03G5/0644 , G03G5/0646 , G03G5/0651 , G03G5/0657 , G03G5/0659 , G03G5/0696
摘要： A photoconductive imaging member comprised of an optional supporting substrate, a hole blocking layer thereover, a photogenerating layer, and a charge transport layer, and wherein the hole blocking layer is comprised of a pyrolyzed polyacrylonitrile.
摘要翻译：一种感光成像构件，包括任选的支撑衬底，其上的空穴阻挡层，光生代层和电荷传输层，并且其中空穴阻挡层由热解的聚丙烯腈构成。

10. 发明授权

US07049038B2 Photoconductive imaging members having pyrolized polyacrylonitrile hole blocking layer 有权
标题翻译：具有热解聚丙烯腈空穴阻挡层的光导成像构件
公开(公告)号：US07049038B2
公开(公告)日：2006-05-23
申请号：US10774636
申请日：2004-02-09
申请人： Timothy J. Fuller , Helen R. Cherniack , Damodar M. Pai , Markus R. Silvestri , John F. Yanus , Yuhua Tong , Dale S. Renfer , Kenny-Tuan T. Dinh , Merlin E. Scharfe , Steven M. Sterling
发明人： Timothy J. Fuller , Helen R. Cherniack , Damodar M. Pai , Markus R. Silvestri , John F. Yanus , Yuhua Tong , Dale S. Renfer , Kenny-Tuan T. Dinh , Merlin E. Scharfe , Steven M. Sterling
IPC分类号： G03G5/14
CPC分类号： G03G5/142 , G03G5/0542 , G03G5/0546 , G03G5/0614 , G03G5/0644 , G03G5/0646 , G03G5/0651 , G03G5/0657 , G03G5/0659 , G03G5/0696
摘要： A photoconductive imaging member comprised of an optional supporting substrate, a hole blocking layer thereover, a photogenerating layer, and a charge transport layer, and wherein the hole blocking layer is comprised of a pyrolyzed polyacrylonitrile.
摘要翻译：一种感光成像构件，包括任选的支撑衬底，其上的空穴阻挡层，光生代层和电荷输送层，并且其中空穴阻挡层由热解的聚丙烯腈构成。

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