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    • 1. 发明授权
    • Imaging member with partially conductive overcoating
    • 具有部分导电涂层的成像构件
    • US06139999A
    • 2000-10-31
    • US429387
    • 1999-10-28
    • Timothy J. FullerDamodar M. PaiJohn F. YanusPaul J. DeFeoAnthony T. WardDale S. RenferHarold F. HammondMerlin E. ScharfeMarkus R. SilvestriWilliam W. Limburg
    • Timothy J. FullerDamodar M. PaiJohn F. YanusPaul J. DeFeoAnthony T. WardDale S. RenferHarold F. HammondMerlin E. ScharfeMarkus R. SilvestriWilliam W. Limburg
    • G03G5/05G03G5/147
    • G03G5/0592G03G5/0571G03G5/14765G03G5/14791
    • An electrophotographic imaging member includingat least one photographic imaging layer anda partially electrically conductive overcoat layer includingfinely divided charge injection enabling particles dispersed ina charge transporting continuous matrix including a cross linked polyamide, charge transport molecules and oxidized charge transport molecules, the continuous matrix being formed from a solution selected from the group includinga first solution includingcrosslinkable alcohol soluble polyamide containing methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.a of less than about 3,a cross linking agent selected from the group comprising a formaldehyde generating cross linking agent, an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof,a dihydroxy arylamine, anda liquid selected from the group including alcohol solvents, diluent and mixtures thereof,a second solution includingcrosslinkable alcohol soluble polyamide free of methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.a of less than about 3,an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof,a dihydroxy arylamine, anda liquid selected from the group including alcohol solvents, diluent and mixtures thereof.The electrophotographic imaging process is also disclosed.
    • 一种电子照相成像构件,包括至少一个照相成像层和部分导电的外涂层,其包括分散在包含交联聚酰胺,电荷传输分子和氧化电荷传输分子的电荷传输连续基质中的细碎电荷注入使颗粒,连续基质 由选自包含第一溶液的溶液形成,所述溶液包括含有与酰胺氮原子连接的甲氧基甲基的可交联醇可溶性聚酰胺,pKa小于约3的酸,选自甲醛的交联剂 产生交联剂,烷氧基化交联剂,羟甲基胺交联剂及其混合物,二羟基芳基胺和选自醇溶剂,稀释剂及其混合物的液体;第二溶液,包括可交联醇可溶性聚 不含与酰胺氮原子连接的甲氧基甲基,pKa小于约3的酸,烷氧基化交联剂,羟甲基胺交联剂及其混合物,二羟基芳基胺和选自以下的液体: 醇溶剂,稀释剂及其混合物。 还公开了电子照相成像方法。
    • 2. 发明授权
    • Electrophotographic imaging member
    • 电子照相成像部件
    • US6025102A
    • 2000-02-15
    • US914643
    • 1997-08-19
    • Damodar M. PaiJohn F. YanusTimothy J. FullerMerlin E. ScharfePaul J. DeFeoMarkus R. Silvestri
    • Damodar M. PaiJohn F. YanusTimothy J. FullerMerlin E. ScharfePaul J. DeFeoMarkus R. Silvestri
    • G03G5/00G03G5/047G03G5/05G03G5/06
    • G03G5/0618G03G5/047G03G5/0517G03G5/0525G03G5/0614G03G5/0629
    • A flexible electrophotographic imaging member including a supporting substrate coated with at least one imaging layer comprising charge transport material free of long chain alkyl carboxylate groups and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent. Preferably, the flexible electrophotographic imaging member is free of an anticurl backing layer, the imaging member comprising a supporting substrate uncoated on one side and coated on the opposite side with at least a charge generating layer and a charge transport layer containing comprising a first charge transport material and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent.
    • 柔性电子照相成像构件,其包括涂覆有至少一个成像层的支撑基底,该成像层包含不含长链烷基羧酸盐基团的电荷输送材料和少量溶解或分子量的至少两个长链烷基羧酸盐基团的第二空穴传输材料 分散在成膜粘合剂中并由含有低沸点组分和低浓度沸点溶剂的溶剂的混合物涂覆。 优选地,柔性电子照相成像构件没有防反射背衬层,成像构件包括在一侧未涂覆并且在至少一个电荷产生层和包含第一电荷传输的电荷传输层的相对侧上涂覆的支撑衬底 材料和少量不同的第二空穴传输材料,其包含溶解或分子分散在成膜粘合剂中并由含有低沸点组分和低浓度沸点溶剂的溶剂的混合物涂覆的至少两个长链烷基羧酸盐基团。
    • 3. 发明授权
    • Electrophotographic imaging member overcoat fabrication process
    • 电子照相成像构件外套制造工艺
    • US6096470A
    • 2000-08-01
    • US429378
    • 1999-10-28
    • Timothy J. FullerDamodar M. PaiJohn F. YanusAnthony T. WardHarold F. HammondMerlin E. ScharfePaul J. DeFeo
    • Timothy J. FullerDamodar M. PaiJohn F. YanusAnthony T. WardHarold F. HammondMerlin E. ScharfePaul J. DeFeo
    • G03G5/00G03G5/047G03G5/05G03G5/07G03G5/147
    • G03G5/0525G03G5/047
    • A process for fabricating an electrophotographic imaging member includingforming a charge generating layer,forming an undried charge transport layer coating by applying to the charge generating layer a solution selected from either or both the group consisting ofa solution including a charge transport molecule, a first film forming binder and at least a first solvent anda solution including a charge transporting polymer and at least a first solvent,forming an undried overcoat layer coating by applying to the undried charge transport layer coating an overcoat layer coating solution including a second film forming polymer and at least a second solvent, the charge transport molecule and first film forming polymer or either or both a charge transporting polymer being substantially insoluble in the second solvent and the second polymer being substantially insoluble in the first solvent,applying heat to both the undried charge transport layer coating and the undried overcoat layer coating to migrate the first solvent from the charge transport layer coating through the undried overcoat layer coating while maintaining the overcoat layer coating porous to migration of the first solvent through the overcoat layer coating until the charge transport layer is substantially dry,increasing the heat applied to the overcoat layer coating to form a substantially dry overcoat layer.
    • 一种用于制造电子照相成像部件的方法,包括形成电荷产生层,通过向电荷产生层施加选自以下两者或两者的溶液形成未干燥的电荷传输层涂层,所述溶液选自包含电荷传输分子,第一 成膜粘合剂和至少第一溶剂和包含电荷输送聚合物和至少第一溶剂的溶液,通过向未干燥的电荷输送层施加涂覆包含第二成膜聚合物的外涂层涂层溶液形成未干燥的外涂层涂层 和至少第二溶剂,电荷输送分子和第一成膜聚合物,或电荷输送聚合物中的任一种或两者均基本上不溶于第二溶剂,第二聚合物基本上不溶于第一溶剂,向未干燥的电荷 运输层涂层和未干燥的外涂层涂层 将第一溶剂从电荷输送层涂层迁移通过未干燥的外涂层涂层,同时保持外涂层涂层多孔以使第一溶剂迁移通过外涂层涂层,直到电荷输送层基本上干燥,从而将施加到 外涂层涂层以形成基本上干燥的外涂层。