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    • 4. 发明授权
    • Photographic elements containing 3-alkyl group substituted
2-hydroxyphenylbenzotriazole UV absorbing polymers
    • 含有3-烷基取代的2-羟基苯基苯并三唑紫外线吸收聚合物的摄影元件
    • US5858633A
    • 1999-01-12
    • US857375
    • 1997-05-16
    • Tienteh ChenHwei-Ling Yau
    • Tienteh ChenHwei-Ling Yau
    • G03C1/815
    • G03C1/8155Y10S430/132
    • Photographic elements containing 3-tertiary alkyl group substituted 2-hydroxyphenylbenzotriazole UV absorbing polymers. In particular, a photographic element having at least one layer containing a light sensitive silver halide emulsion and at least one layer which is not light sensitive, the element having in at least one of the layers an ultraviolet absorbing polymer which includes units formed from monomers of the structure of formula (I): ##STR1## wherein: n is an integer of 1 to 6;p and m are, independently, 0 or 1;tert-Alk is a 4 to 10 carbon atom tertiary alkyl group;G is --CO--, --C(O)--, --C(O)NH--, or --SO.sub.2 --;R.sub.2 and R.sub.3 are, independently, H, halogen, alkyl group or alkoxy group, and if n is more than 1 all of the R.sub.2 may be the same or different and all of the R.sub.3 may be the same or different; the benzene ring of the benzotriazole and the phenyl ring phenol group each may be further substituted or unsubstituted;z is an arylene group, alkylene group, or alkylene group which is interrupted by O, N or a group of the type which G can represent; andY is an ethylenically unsaturated polymerizable group.
    • 含有3-叔烷基取代的2-羟基苯基苯并三唑紫外线吸收聚合物的摄影元件。 特别地,具有至少一层含有感光卤化银乳剂和至少一层不敏感的照相元件,该元件在至少一层中具有紫外线吸收聚合物,该聚合物包括由单体形成的单元 式(I)的结构:其中:n为1至6的整数; p和m独立地为0或1; 叔烷醇是4至10个碳原子的叔烷基; G是-CO - , - C(O) - , - C(O)NH-或-SO 2 - ; R2和R3独立地为H,卤素,烷基或烷氧基,如果n大于1,则所有的R 2可以相同或不同,并且所有的R 3可以相同或不同; 苯并三唑和苯环酚基的苯环各自可以是进一步取代或未取代的; z是被O,N间隔的亚芳基,亚烷基或亚烷基,G可以表示的基团; Y是烯属不饱和可聚合基团。
    • 10. 发明授权
    • Protective layer for gelatin based AGX photographic products
    • 用于明胶基AGX摄影产品的保护层
    • US5952130A
    • 1999-09-14
    • US136375
    • 1998-08-19
    • Hwei-Ling YauTienteh ChenJeffrey F. TaylorElmer C. FloodDavid E. Decker
    • Hwei-Ling YauTienteh ChenJeffrey F. TaylorElmer C. FloodDavid E. Decker
    • G03C1/76G03C1/85G03C5/14G03C11/08G03C1/775G03C1/795
    • G03C11/08G03C1/85G03C5/14
    • The present invention is an imaged photographic element which includes a support, at least one light sensitive silver halide emulsion layer superposed on the support, and an overcoat layer overlying the light sensitive silver halide emulsion layer. The protective overcoat includes a first water insoluble polymer having a Tg less than 25.degree. C. and a second water insoluble polymer having a Tg greater than 25.degree. C. The first or second polymer is composed of a monomer at a weight percent of 20 to 100 having the following formula ##STR1## wherein: X is selected from the group consisting of --Cl, --F, and --CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n--C.sub.3 H.sub.7, iso--C.sub.3 H.sub.7, n--C.sub.4 H.sub.9, n--C.sub.5 H.sub.11, n--C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, C.sub.2 F.sub.5, n--C.sub.3 F.sub.7, iso--C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, --COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5.
    • 本发明是一种成像的照相元件,其包括载体,叠加在载体上的至少一种感光卤化银乳剂层和覆盖在感光卤化银乳剂层上的外涂层。 保护性外涂层包括Tg小于25℃的第一水不溶性聚合物和Tg大于25℃的第二水不溶性聚合物。第一或第二聚合物由重量百分比为20至 100,其中:X选自-Cl,-F和-CN,Y各自独立地选自H,Cl,F,CN,CF 3,CH 3,C 2 H 5, 正C 3 H 7,异-C 3 H 7,n-C 4 H 9,n -C 5 H 11,n-C 6 H 13,OCH 3,OC 2 H 5,苯基C 6 F 5,C 6 Cl 5,CH 2 Cl,CH 2 F,C 2 F 5,n -C 3 F 7,异-C 3 F 7,OCF 3,OC 2 F 5,OC 3 F 7,C (CF 3)3,CH 2(CF 3),CH(CF 3)2,-COCF 3,COC 2 F 5,COCH 3,COC 2 H 5。