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1. 发明授权

US4221654A Hydroprocessing coal liquids 失效
标题翻译：加氢处理煤液
公开(公告)号：US4221654A
公开(公告)日：1980-09-09
申请号：US913477
申请日：1978-06-07
申请人： Thomas R. Stein , Roland H. Heck , Albert V. Cabal
发明人： Thomas R. Stein , Roland H. Heck , Albert V. Cabal
IPC分类号： C10G1/00 , C10G1/06 , C10G45/02 , C10L1/04 , C10G1/04
CPC分类号： C10L1/04 , C10G1/002 , C10G2300/107
摘要： Compatibility of solvent refined coal and other coal liquids with conventional petroleum fuels is improved by moderate catalytic hydrogenation of the solvent refined coal liquid to a hydrogen to carbon atomic ratio less than that of corresponding petroleum fractions. As degree of hydrogenation of solvent refined coal is increased, compatibility with petroleum fractions of like boiling range increases to a maximum measured by precipitation of sediment from the blend of equal parts of the two fuels. That maximum is achieved at a hydrogen/carbon ratio below that of the corresponding petroleum fractions. As that ratio is increased toward the ratio characteristic of a like petroleum fraction, compatibility is impaired.
摘要翻译：溶剂精炼煤和其他煤液与常规石油燃料的相容性通过溶剂精炼煤液体的适度催化氢化至低于相应石油馏分的氢碳原子比来提高。随着溶剂精炼煤的氢化程度的增加，与沸点范围内的石油馏分的相容性通过两种燃料的相等部分的混合物的沉淀物沉淀测得的最大值。在氢/碳比低于相应的石油馏分的情况下达到最大值。当该比率朝向类似石油馏分的比率特性增加时，相容性受损。

2. 发明授权

US4200521A Catalytic hydroprocessing of solvent refined coal to provide a liquid and a solid fuel 失效
标题翻译：溶剂精炼煤的催化加氢处理提供液体和固体燃料
公开(公告)号：US4200521A
公开(公告)日：1980-04-29
申请号：US913478
申请日：1978-06-07
申请人： Thomas R. Stein , Roland H. Heck , Michael J. Dabkowski
发明人： Thomas R. Stein , Roland H. Heck , Michael J. Dabkowski
IPC分类号： C10L9/04 , C10G1/00 , C10G1/06 , C10G1/08 , C10G23/02
CPC分类号： C10G1/086 , C10G1/006 , C10G1/083
摘要： In the hydroprocessing of blends of solvent refined coal and recycle solvent, small pore hydrotreating catalysts cause separation of a solid phase from treating blends containing high concentration of solvent refined coal.
摘要翻译：在溶剂精炼煤和再循环溶剂的共混物的加氢处理中，小孔加氢处理催化剂使固相与处理含高浓度溶剂精炼煤的共混物分离。

3. 发明授权

US4071574A Conversion of Fischer-Tropsch heavy product to high quality jet fuel 失效
标题翻译：费托重产品转化为高品质喷气燃料
公开(公告)号：US4071574A
公开(公告)日：1978-01-31
申请号：US671451
申请日：1976-03-29
申请人： Donald Milstein , Thomas R. Stein
发明人： Donald Milstein , Thomas R. Stein
IPC分类号： C10G65/04 , C10L1/04 , C07C1/04 , C10G34/00
CPC分类号： C10L1/04 , C10G2400/08 , Y10S208/95 , Y10S585/943
摘要： Upgrading a Fischer-Tropsch synthesis product by separating a 350.degree. to 850.degree. F product fraction thereof into a 650.degree. F minus fraction and a 650.degree. F plus fraction; separating the 650.degree. F minus fraction to provide a more narrow 350.degree. to 650.degree. F fraction; combining the 650.degree. F plus fraction with a portion of the 350.degree. to 650.degree. F fraction to form a wide boiling range feed material; contacting this formed wide boiling range feed material, together with hydrogen, with a special catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12, at a temperature of about 500.degree. to 800.degree. F, a hydrogen partial pressure of about 100 to 800 psia and a space velocity of about 0.5 to 5 LHSV to produce a converted product thereof separating the zeolite conversion product to recover a 350.degree. F minus fraction from a 350.degree. F plus fractions; and separating the 350.degree. F plus fraction to recover a 350.degree. to 450.degree. F jet fuel fraction having a freeze point of less than about -58.degree. F.
摘要翻译：通过将350至850°F的产物馏分分离成650°F馏分和650°F加馏分来升级费 - 托合成产物; 分离650°F负分数以提供更窄的350°至650°F馏分; 将650°F加成分与350°至650°F馏分的一部分结合形成宽沸程饲料; 使该形成的大沸点范围的原料与氢一起使用包含二氧化硅与氧化铝比至少为12且约束指数为1至12的结晶硅铝酸盐沸石的特殊催化剂在约500至800℃的温度下接触 DEG F，约100至800psia的氢分压和约0.5至5LHSV的空速，以产生其转化产物，分离沸石转化产物以从350°F加馏分回收350°F的负分馏; 并分离350°F加馏分以回收冷冻点小于约-58°F的350°至450°F喷射燃料馏分。

4. 发明授权

US4053532A Method for improving the Fischer-Tropsch Synthesis product distribution 失效
标题翻译：改进FISCHER-TROPSCH合成产品分配的方法
公开(公告)号：US4053532A
公开(公告)日：1977-10-11
申请号：US638217
申请日：1975-12-05
申请人： Henry R. Ireland , Thomas R. Stein
发明人： Henry R. Ireland , Thomas R. Stein
IPC分类号： C10G3/00 , C10G45/64 , C10L1/06 , C07C1/04
CPC分类号： C10L1/06 , C10G3/49 , C10G3/50 , C10G45/64 , C10G2300/1022 , C10G2300/807 , C10G2400/02 , Y02P30/20 , Y10S208/95
摘要： The product of Fischer-Tropsch Synthesis is separated to recover a product boiling above about 400.degree. F which is thereafter processed over a selective crystalline zeolite under hydrodewaxing conditions promoting the formation of fuel oil and gasoline products. Improving start up and operation of the process in the presence of a ZSM5 crystalline zeolite is described.

5. 发明授权

US4192734A Production of high quality fuel oils 失效
标题翻译：生产高品质燃油
公开(公告)号：US4192734A
公开(公告)日：1980-03-11
申请号：US922948
申请日：1978-07-10
申请人： Robert T. Pavlica , Thomas R. Stein , Carl W. Streed
发明人： Robert T. Pavlica , Thomas R. Stein , Carl W. Streed
IPC分类号： C10G69/00 , F02B3/06 , C10G37/04 , C10G39/00
CPC分类号： C10G69/00 , F02B3/06
摘要： A processing arrangement for upgrading crude oil by the combination of hydrodewaxing, and fluid catalytic cracking or hydrocracking to maximize the production of low pour, high quality distillate fuel oil is particularly described. Cracking of atmospheric bottoms of residua, hydrodewaxing atmospheric heavy gas oil and hydrodesulfurizing light gas oil material to produce diesel fuel oil products are primary components of the processing arrangement.
摘要翻译：特别描述了通过加氢脱蜡和流化催化裂化或加氢裂化的组合来提高原油的最大化生产低倾吐，优质馏出燃料油的处理装置。残留物大气底渣，加氢脱蜡大气重质瓦斯油和加氢脱硫轻质油料生产柴油燃料油产品的开裂是加工装置的主要组成部分。

6. 发明授权

US4046829A Method for improving the Fischer-Tropsch synthesis product distribution 失效
标题翻译：改进费 - 托合成产物分布的方法
公开(公告)号：US4046829A
公开(公告)日：1977-09-06
申请号：US601753
申请日：1975-08-04
申请人： Henry R. Ireland , Thomas R. Stein
发明人： Henry R. Ireland , Thomas R. Stein
IPC分类号： C10G3/00 , C10G35/095 , C10G45/08 , C10G45/64 , C10L1/06 , C07C1/04
CPC分类号： C10L1/06 , C10G3/46 , C10G3/49 , C10G35/095 , C10G2300/1022 , C10G2300/107 , C10G2300/301 , C10G2400/02 , Y02P30/20 , Y10S208/95
摘要： The product of Fischer-Tropsch Synthesis is separated to recover a product boiling above and below about 400.degree. F which is thereafter separately process over different beds of ZSM-5 crystalline zeolite under conditions promoting the formation of fuel oil products and gasoline of a higher octane rating.
摘要翻译：分离费 - 托合成的产物以回收高于和低于约400°F的产物，然后在促进形成燃料油产物和较高辛烷值的汽油的条件下，在不同的ZSM-5结晶沸石床上分别处理评分。

7. 发明授权

US4041097A Method for altering the product distribution of Fischer-Tropsch synthesis product 失效
标题翻译：改变费托合成产物分布的方法
公开(公告)号：US4041097A
公开(公告)日：1977-08-09
申请号：US614588
申请日：1975-09-18
申请人： Henry R. Ireland , Thomas R. Stein
发明人： Henry R. Ireland , Thomas R. Stein
IPC分类号： C10G50/00 , C10G59/02 , C10G67/02 , C10L1/06 , C07C1/04
CPC分类号： C10G59/02 , C10G50/00 , C10G67/02 , C10L1/06 , Y10S208/95
摘要： A Fischer-Tropsch synthesis effluent is separated into gaseous, gasoline boiling, light fuel oil and heavy fuel oil products for upgrading to more desirable products by conversion over a special class of crystalline zeolites suitable for the purpose. Water washing of the separated fractions may be practiced to recover oxygenates from any separated fraction before further upgrading of oxygenates and hydrocarbons.
摘要翻译：费 - 托合成流出物被分离成气体，汽油沸点，轻燃料油和重质燃料油产品，通过适用于该目的的特殊类型的结晶沸石转化成升级成更理想的产物。在进一步升级含氧化合物和烃之前，可以对分离的馏分进行水洗以从任何分离的馏分中回收含氧化合物。

8. 发明授权

US4324645A Upgrading residual oil 失效
标题翻译：升级残油
公开(公告)号：US4324645A
公开(公告)日：1982-04-13
申请号：US147033
申请日：1980-05-07
申请人： Philip J. Angevine , Thomas R. Stein
发明人： Philip J. Angevine , Thomas R. Stein
IPC分类号： C10G47/02 , B01J23/28 , B01J23/30 , B01J23/44 , B01J23/652 , B01J23/74 , B01J23/755 , B01J23/85 , B01J23/88 , B01J23/89 , B01J27/04 , B01J27/043 , B01J35/10 , C10G45/06 , C10G45/08 , C10G45/10 , C10G47/10 , C10G69/06 , C10G45/00 , B01J23/16
CPC分类号： B01J23/755 , B01J23/30 , C10G2300/107
摘要： Residual oil fractions are upgraded in that CCR is selectively removed without undue hydrogen consumption by hydroprocessing with a catalyst comprises a single metal such as molybdenum, tungsten, nickel, iron or palladium or multimetallic combination of such metals, excluding, however, active desulfurization compositions such as nickel molybdenum and nickel-tungsten. Said catalyst is characterized as having greater than about 50% of its pore volume contribution in pores having diameters in the range of between about 100 and 200 Angstroms. The product of such hydroprocessing is a particularly preferable feedstock for coking to give more liquid yield and less coke make.
摘要翻译：残余油馏分被升级，其中选择性地除去CCR，而不用过度氢消耗通过用含有钼，钨，镍，铁或钯的单一金属或这种金属的多金属组合的催化剂进行加氢处理而除去活性脱硫组合物如镍钼和镍 - 钨。所述催化剂的特征在于具有在约100和200埃之间的直径的孔中具有大于其孔体积贡献的约50％。这种加氢处理的产物是特别优选的用于焦化以产生更多液体产率和较少焦炭制备的原料。

9. 发明授权

US4044064A Conversion of Fischer-Tropsch heavy product to high quality jet fuel 失效
标题翻译：费托重产品转化为高品质喷气燃料
公开(公告)号：US4044064A
公开(公告)日：1977-08-23
申请号：US671511
申请日：1976-03-29
申请人： Donald Milstein , Thomas R. Stein
发明人： Donald Milstein , Thomas R. Stein
IPC分类号： C10G45/64 , C10G65/04 , F02B3/06 , C07C1/04
CPC分类号： C10G65/043 , C10G45/64 , F02B3/06 , Y10S208/95
摘要： Upgrading a fraction of a heavy Fischer-Tropsch oil to jet fuel by hydropretreating a 350.degree. to 850.degree. F boiling fraction; separating the hydrotreated product into a 650.degree. F minus and a 650.degree. F plus fraction, separating the650.degree. F minus fraction to provide a 350.degree. F minus naphtha boiling range fraction and a 350.degree. to 650.degree. F light distillate fraction; distilling the 350.degree. to 650.degree. F hydrotreated fraction to provide a fraction boiling in the range of 350.degree. F to 550.degree. F separate from a 550.degree. to 650.degree. F fraction processing either of the 650.degree. F plus fraction above separated or the 350.degree. to 550.degree. F boiling fraction above obtained over a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12 with hydrogen, at a temperature of about 500.degree. to 800.degree. F, a hydrogen partial pressure of about 100 to 800 psig and a space velocity in the range of about 0.5 to 5 LHSV to produce a converted product comprising lower boiling hydrocarbons than the feed charged and recovering as a product of the process a reduced pour point diesel oil fraction, a 350.degree. to 550.degree. F jet fuel fraction, and a 350.degree. F minus naphtha product fraction.
摘要翻译：通过加氢分解350至850°F的沸点，将一部分重的费 - 托油升级成喷气燃料; 将加氢处理的产物分离成650°F和650°F加馏分，分离出650°F的馏分，得到350°F的减碳馏分沸点馏分和350至650°F馏分馏分。蒸馏出350°F至650°F的加氢处理馏分，以提供350°F至550°F沸点的馏分，分馏于550°F至650°F馏分，加工分离的650°F加馏分或350 通过包含二氧化硅与氧化铝之比至少为12的结晶硅铝酸盐沸石和氢的约束指数为1至12的催化剂，在约500至800°F的温度下，约100至800psig的氢分压和约0.5至5LHSV范围内的空速，以产生包含低于加入的原料的低沸点烃的转化产物，并将该还原的倾点柴油作为该方法的产物回收馏分，350〜550°F的燃油馏分和350°F的减碳馏出物馏分。

10. 发明授权

US4229282A Catalytic dewaxing of hydrocarbon oils 失效
标题翻译：烃油的催化脱蜡
公开(公告)号：US4229282A
公开(公告)日：1980-10-21
申请号：US33775
申请日：1979-04-27
申请人： Alan W. Peters , Emmerson Bowes , Thomas R. Stein
发明人： Alan W. Peters , Emmerson Bowes , Thomas R. Stein
IPC分类号： C10G73/02 , B01J29/48 , C10G45/64 , C10G71/00 , C10G47/16
CPC分类号： C10G45/64 , B01J29/48
摘要： An improved process for catalytically dewaxing a hydrocarbon oil is disclosed. In this process the waxy oil is contacted in the presence of hydrogen with a dense zeolitic dewaxing catalyst associated with a nickel-tungsten hydrogenation component. The dewaxed oil has unexpectedly good stability and a low bromine number compared with prior-art processed oils. The process may be used to dewax crude oils, fuel oil fractions and lubricating oils.
摘要翻译：公开了一种用于催化脱蜡烃油的改进方法。在该方法中，蜡状油在氢的存在下与与镍 - 钨氢化组分相关的致密的沸石脱蜡催化剂接触。与现有技术的加工油相比，脱蜡的油具有出乎意料的良好的稳定性和低的溴数。该方法可用于脱蜡原油，燃料油馏分和润滑油。

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