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    • 3. 发明申请
    • Method for coating metallic surfaces
    • 金属表面涂层方法
    • US20050205166A1
    • 2005-09-22
    • US10519006
    • 2003-07-09
    • Jurgen SpechtPeter SchubachRudiger ReinPeter Claude
    • Jurgen SpechtPeter SchubachRudiger ReinPeter Claude
    • C23C22/36
    • C23C22/365C23C22/362
    • The invention relates to a method for treating or pre-treating parts, profiled-pieces, strips, sheet metals and/or wires having metallic surfaces, in which at least 5% of these surfaces consists of aluminum and/or of at least one aluminum alloy and, optionally, the remaining metallic surfaces can predominantly consist of iron alloys, zinc and/or zinc alloys. The treatment involves the use of an acid aqueous solution, which contains fluoride, zinc and phosphate and which has the following dissolved contents in the phosphatizing solution: sodium virtually none or in a concentration ranging from 0.04 to less than 2 g/L; potassium virtually none or in a concentration ranging from 0.025 to 2.5 g/L; sodium and potassium in a concentration ranging from 0.025 to 2.5 g/L as sodium, whereby the potassium content is converted to sodium on a molar basis; zinc in a concentration ranging from 0.2 to 4 g/L; phosphate in a concentration ranging from 4 to 65 g/L and calculated as PO4; free fluoride in a concentration ranging from 0.03 to 0.5 g/L, and; total fluoride in a concentration ranging from 0.1 to 5 g/L. A zinc-containing phosphate layer is thereby deposited onto the metallic surfaces with a layer weight ranging from 0.5 to 10 g/m2.
    • 本发明涉及一种用于处理或预处理具有金属表面的部件,成型件,带材,钣金和/或金属表面的方法,其中至少5%的这些表面由铝和/或至少一种铝 合金和任选的其余金属表面可主要由铁合金,锌和/或锌合金组成。 该处理包括使用含有氟化物,锌和磷酸盐的酸性水溶液,并且在磷酸盐化溶液中具有以下溶解的含量:钠实际上没有或浓度为0.04至小于2g / L; 实际上无钾或浓度范围为0.025至2.5g / L的钾; 钠和钾的浓度范围为0.025至2.5g / L,钠的含量以摩尔计转换为钠; 浓度范围为0.2〜4g / L的锌; 磷酸盐,浓度范围为4至65g / L,计算为PO; 4; 浓度范围为0.03〜0.5g / L的游离氟化物, 总氟化物浓度范围为0.1至5g / L。 因此,含锌磷酸盐层以0.5至10g / m 2的层重量沉积在金属表面上。
    • 4. 发明授权
    • Activator for use in phosphating processes
    • 激光器用于磷化过程
    • US5160551A
    • 1992-11-03
    • US686825
    • 1991-04-17
    • Rudiger ReinDieter JentschKalus-Werner Wittel
    • Rudiger ReinDieter JentschKalus-Werner Wittel
    • C23C22/80C23C22/18C23C22/36F16L37/084F16L37/098F16L37/12
    • C23C22/80
    • The activating agent which is based on titanium(IV) phosphate and intended for use in the activation of metal surfaces before a zinc phosphating treatment contains one or more copper compounds and has a Ti:Cu weight ratio of 1:100 to 60:1 and optionally contains in addition at least one of the components consisting of condensed phosphate, silicate, complexing agent, water-soluble organic polymer, thickening agent, and surfactant. It is used to prepare aqueous activating baths for activating iron, steel, galvanized steel, zinc alloy-plated steel, aluminum-plated steel and aluminum before a zinc phosphating treatment, which baths contain 0.001 to 0.060 g/l Ti, 0.020 to 1.2 g/l orthophosphate (calculated as P.sub.2 O.sub.5), and 0.001 to 0.1 g/l Cu and so much alkali that the bath has a pH value of 7 to 11, preferably of 7.5 to 10.
    • 基于磷酸钛(IV)的活化剂,用于在磷化锌处理之前活化金属表面时含有一种或多种铜化合物,并且具有1:100至60:1的Ti:Cu重量比和 另外还含有由缩合磷酸盐,硅酸盐,络合剂,水溶性有机聚合物,增稠剂和表面活性剂组成的组分中的至少一种。 在锌磷化处理之前,用于制备用于活化铁,钢,镀锌钢,镀锌钢,镀铝钢和铝的水性活化浴,该浴含有0.001至0.060g / l Ti,0.020至1.2g /正磷酸盐(以P 2 O 5计)和0.001〜0.1g / l的Cu以及碱溶液的pH值为7〜11,优选为7.5〜10。