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1. 发明授权

US5475158A Preparation of cycloalkanols 失效
标题翻译：环烷醇的制备
公开(公告)号：US5475158A
公开(公告)日：1995-12-12
申请号：US159706
申请日：1993-12-01
申请人： Thomas Krug , Rolf Fischer , Rolf Pinkos
发明人： Thomas Krug , Rolf Fischer , Rolf Pinkos
IPC分类号： C07C27/02 , C07C29/09 , C07C35/08 , C07C29/20 , C07C53/10
CPC分类号： C07C29/095 , C07C2101/14
摘要： A process for the preparation of cycloalkanols by the hydrolysis of cycloalkyl C.sub.1 -C.sub.4 fatty acid esters, which comprises the following steps:a) reaction of cycloalkyl C.sub.1 -C.sub.4 fatty acid esters with water at a temperature of from 30.degree. to 250.degree. in the liquid phase yielding a reaction mixture consisting of cycloalkyl C.sub.1 -C.sub.4 fatty acid esters, cycloalkanol, C.sub.1 -C.sub.4 fatty acids, and water.b) separation of the reaction mixture obtained in stage a) at a temperature of from 0.degree. to 200.degree. C. into a top phase consisting substantially of cycloalkanol and cycloalkyl C.sub.1 -C.sub.4 fatty acid esters and a bottom phase consisting substantially of water and C.sub.1 -C.sub.4 fatty acids.c) separation of cycloalkanol from the top phase obtained in stage b) by distillation and recycling unconverted cycloalkyl C.sub.1 -C.sub.4 fatty acid esters to stage a).
摘要翻译：通过环烷基C1-C4脂肪酸酯的水解制备环烷醇的方法，其包括以下步骤：a）环烷基C1-C4脂肪酸酯与水在30℃至250℃的温度下反应产生由环烷基C1-C4脂肪酸酯，环烷醇，C1-C4脂肪酸和水组成的反应混合物。 b）将步骤a）中获得的反应混合物在0℃至200℃的温度下分离成基本上由环烷基醇和环烷基C1-C4脂肪酸酯组成的顶相和基本上由水和C1组成的底部相 -C4脂肪酸。 c）通过蒸馏并将未转化的环烷基C1-C4脂肪酸酯再循环到步骤a）中，从步骤b）中获得的顶部相分离环烷醇。

2. 发明授权

US08217186B2 Process for preparing epsilon-caprolactone 失效
标题翻译：制备ε-己内酯的方法
公开(公告)号：US08217186B2
公开(公告)日：2012-07-10
申请号：US12746680
申请日：2008-12-10
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
IPC分类号： C07D313/00
CPC分类号： C07D313/04
摘要： The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要翻译：本发明涉及一种在活性炭作为催化剂存在下随后蒸馏的在气相中由6-羟基己酸酯制备ε-己内酯的方法。

3. 发明授权

US07449609B2 Method for production of 1,6-hexanediol with a purity in excess of 99.5% 失效
标题翻译：制备纯度超过99.5％的1,6-己二醇的方法
公开(公告)号：US07449609B2
公开(公告)日：2008-11-11
申请号：US10569980
申请日：2005-07-07
申请人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
发明人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
IPC分类号： C07C29/149
CPC分类号： C07C29/145 , C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要翻译：本发明提供了一种通过以下方式制备1,6-己二醇的方法：通过以下方法将氢化己二酸二烷基酯，6-羟基己酸烷基酯，1,4-环己二酮和4-羟基环己烷-1-酮作为包含杂质的酯混合物，在第一蒸馏阶段（醇去除）中的过量醇和低锅炉的b），b）在第二蒸馏阶段中将底部产物分离成基本上不含1,4-环己烷二醇的酯馏分和至少包含大部分1,4-环己烷二醇，c）催化氢化基本上不含1,4-环己二醇的酯馏分（酯氢化）和d）在纯化蒸馏阶段，以一种方式从氢化流出物中获得1,6-己二醇本身已知，其包括在阶段a）和/或阶段b）之前选择性地氢化酯混合物（纯化氢化）。

4. 发明授权

US08247580B2 Process for preparing ε-caprolactone 有权
标题翻译：己内酯的制备方法
公开(公告)号：US08247580B2
公开(公告)日：2012-08-21
申请号：US12741383
申请日：2008-10-28
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
IPC分类号： C07D313/00
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要翻译：本发明提供了通过在150至400℃和1至1020hPa绝对压力下使液相中的6-羟基己酸酯环化来制备纯度大于99％的己内酯的方法，冷凝在环化条件下挥发的化合物，其包括在至少一个另外的反应器中热处理剩余的环化的底部产物，除去和冷凝挥发性化合物，并通过从冷凝物蒸馏获得ε-己内酯。

5. 发明申请

US20100240913A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 有权
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100240913A1
公开(公告)日：2010-09-23
申请号：US12741383
申请日：2008-10-28
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C. Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C. Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
IPC分类号： C07D313/02
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要翻译：本发明提供一种制备纯度大于99％的己内酯的方法，其通过在150至400℃和1至1020hPa绝对压力下使液相中的6-羟基己酸酯环化，冷凝在环化条件下挥发的化合物，其包括在至少一个另外的反应器中热处理剩余的环化的底部产物，除去和冷凝挥发性化合物，并通过从冷凝物蒸馏获得ε-己内酯。

6. 发明申请

US20100168445A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 审中-公开
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100168445A1
公开(公告)日：2010-07-01
申请号：US12602837
申请日：2008-06-06
申请人： Rolf Pinkos , Gerd Tebben , Christophe Bauduin , Daniel Breuninger , Maria Guixa Guardia , Tilman Sirch , Thomas Krug
发明人： Rolf Pinkos , Gerd Tebben , Christophe Bauduin , Daniel Breuninger , Maria Guixa Guardia , Tilman Sirch , Thomas Krug
IPC分类号： C07D313/04
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity above 99%, in which 6-hydroxycaproic ester comprising from 0.5 to 40% by weight of adipic diester is cyclized in the gas phase at from 150 to 450° C. in the presence of oxidic catalysts and ε-caprolactone is obtained from the cyclization product by distillation.
摘要翻译：本发明提供了一种制备纯度高于99％的己内酯的方法，其中包含0.5至40重量％的己二酸二酯的6-羟基己酸酯在150至450℃的气相中环化。在氧化催化剂的存在下，通过蒸馏从环化产物得到ε-己内酯。

7. 发明申请

US20100256398A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 失效
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100256398A1
公开(公告)日：2010-10-07
申请号：US12746680
申请日：2008-12-10
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
IPC分类号： C07D313/04
CPC分类号： C07D313/04
摘要： The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要翻译：本发明涉及一种在活性炭作为催化剂存在下随后蒸馏的在气相中由6-羟基己酸酯制备ε-己内酯的方法。

8. 发明申请

US20080207958A1 Method For Production Of 1,6-Hexanediol With A Purity In Excess of 99.5% 失效
标题翻译： 1,6-己二醇生产方法纯度超过99.5％
公开(公告)号：US20080207958A1
公开(公告)日：2008-08-28
申请号：US10569980
申请日：2005-07-07
申请人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
发明人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
IPC分类号： C07C29/143
CPC分类号： C07C29/145 , C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要翻译：本发明提供了一种通过以下方式制备1,6-己二醇的方法：通过以下方法将氢化己二酸二烷基酯，6-羟基己酸烷基酯，1,4-环己二酮和4-羟基环己烷-1-酮作为包含杂质的酯混合物，在第一蒸馏阶段（醇去除）中的过量醇和低锅炉的b），b）在第二蒸馏阶段中将底部产物分离成基本上不含1,4-环己二醇的酯馏分和至少包含大部分1,4-环己烷二醇，c）催化氢化基本上不含1,4-环己二醇的酯馏分（酯氢化）和d）在纯化蒸馏阶段，以一种方式从氢化流出物中获得1,6-己二醇本身已知，其包括在阶段a）和/或阶段b）之前选择性地氢化酯混合物（纯化氢化）。

9. 发明申请

US20120271068A1 REACTION OF GLYCOLALDEHYDE WITH AN AMINATING AGENT 有权
标题翻译：甘氨酸与氨基化剂的反应
公开(公告)号：US20120271068A1
公开(公告)日：2012-10-25
申请号：US13516479
申请日：2010-12-14
申请人： Wolfgang Mägerlein , Johann-Peter Melder , Jörg Pastre , Jan Eberhardt , Thomas Krug , Mirko Kreitschmann
发明人： Wolfgang Mägerlein , Johann-Peter Melder , Jörg Pastre , Jan Eberhardt , Thomas Krug , Mirko Kreitschmann
IPC分类号： C07C213/02
CPC分类号： C07C209/26 , C07C213/00 , C07C215/08 , C07C211/10
摘要： The present invention relates to a process for reacting glycolaldehyde with an aminating agent in the presence of hydrogen and of a catalyst, the catalyst being activated by reducing a catalyst precursor or by reducing a passivated catalyst, which comprises effecting the reaction in the presence of a solvent and contacting the glycolaldehyde with the activated catalyst.
摘要翻译：本发明涉及一种在氢气和催化剂存在下使乙醇醛与胺化剂反应的方法，该催化剂通过还原催化剂前体而被还原或通过还原钝化的催化剂来活化，其包括在存在下进行反应溶剂并使乙醇醛与活化的催化剂接触。

10. 发明授权

US08163139B2 Process for the distillative separation of mixtures comprising monoethylene glycol and diethylentriamine 有权
标题翻译：用于蒸馏分离包含单乙二醇和二乙基三胺的混合物的方法
公开(公告)号：US08163139B2
公开(公告)日：2012-04-24
申请号：US12279372
申请日：2007-02-08
申请人： Karin Pickenäcker , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Gunther van Cauwenberge , Frank-Friedrich Pape
发明人： Karin Pickenäcker , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Gunther van Cauwenberge , Frank-Friedrich Pape
IPC分类号： B01D3/34 , B01D3/00
CPC分类号： C07C209/86 , C07C211/14
摘要： Processes comprising: providing a mixture comprising monoethylene glycol and diethylenetriamine; and subjecting the mixture to extractive distillation with a diethylenetriamine-selective solvent comprising triethylene glycol to provide a first stream comprising monoethylene glycol and a second stream comprising diethylenetriamine; wherein the first stream is substantially free of diethylenetriamine, and wherein the second stream is substantially free of monoethylene glycol.
摘要翻译：方法包括：提供包含单乙二醇和二亚乙基三胺的混合物; 并用包含三甘醇的二亚乙基三胺选择性溶剂对混合物进行萃取蒸馏以提供包含单乙二醇的第一物流和包含二亚乙基三胺的第二物流; 其中所述第一物流基本上不含二亚乙基三胺，并且其中所述第二物流基本上不含单乙二醇。

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