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1. 发明授权

US08759594B2 Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters 有权
标题翻译：低聚和聚酯氢化生产1,6-己二醇的方法
公开(公告)号：US08759594B2
公开(公告)日：2014-06-24
申请号：US13258207
申请日：2010-03-29
申请人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
发明人： Olivier Abillard , Rolf Pinkos , Gerd-Dieter Tebben , Tilman Sirch , Daniel Urbanczyk , Heiko Urtel , Rolf Tompers
IPC分类号： C07C27/00
CPC分类号： C07C45/33 , C07C29/149 , C07C29/50 , C07C51/313 , C07C67/08 , C07C2601/14 , C07C31/20 , C07C35/08 , C07C49/403 , C07C55/14 , C07C69/44
摘要： The present invention relates to a process for hydrogenating oligo- and/or polyesters obtainable by esterifying a DCS with a diol or diol mixture, said hydrogenation being performed in the presence of a catalyst whose catalyst precursor comprises copper oxide, aluminum oxide and at least one oxide of lanthanum, of iron, of tungsten, of molybdenum, of titanium or of zirconium, and to a process for preparing 1,6-hexanediol by catalytically hydrogenating ester mixtures which comprise, as main components, oligo- and polyesters of adipic acid and 6-hydroxycaproic acid, and are obtained by esterifying DCS with diols, especially 1,6-hexanediol or diol mixtures.
摘要翻译：本发明涉及一种氢化通过用二醇或二醇混合物酯化DCS得到的低聚物和/或聚酯的方法，所述氢化在其催化剂前体包含氧化铜，氧化铝和至少一种镧，铁，钨，钼，钛或锆的氧化物，以及通过催化氢化酯混合物制备1,6-己二醇的方法，所述酯混合物作为主要组分包含己二酸的低聚和聚酯和 6-羟基己酸，并且通过用二醇，特别是1,6-己二醇或二醇混合物酯化DCS获得。

2. 发明授权

US08575401B2 Method for purifying crude polymethylols 失效
标题翻译：粗多羟基甲基纤维素的纯化方法
公开(公告)号：US08575401B2
公开(公告)日：2013-11-05
申请号：US13133499
申请日：2009-12-07
申请人： Tilman Sirch , Michael Steiniger , Steffen Maas , Stefan Rittinger
发明人： Tilman Sirch , Michael Steiniger , Steffen Maas , Stefan Rittinger
IPC分类号： C07C29/80
CPC分类号： C07C29/141 , C07C29/80 , C08G18/56 , C08G63/16 , C08L75/04 , C07C31/22 , C07C31/245 , C07C31/20
摘要： The present invention relates to a process for purifying crude polymethylol which comprises polymethylol of the formula (I) (HOCH2)2—C—R2 (I) in which each R is independently a further methylol group or an alkyl group having 1 to 22 carbon atoms or an aryl or aralkyl group having 6 to 22 carbon atoms, and also hydroxy acid of the formula (IV) in which each R is independently as defined above, which comprises performing the purification in a distillation column, the bottom of the distillation column being connected to an evaporator with a short residence time. The present invention further relates to a composition comprising polymethylol and 1 to 10 000 ppm by weight of an ester of polymethylol and of a hydroxy acid and to the use thereof.
摘要翻译：本发明涉及一种纯化粗多羟甲基的方法，其包括式（I）的多羟甲基（HOCH 2）2 -C-R 2（I），其中每个R独立地为另外的羟甲基或具有1至22个碳的烷基原子或具有6至22个碳原子的芳基或芳烷基，以及式（IV）的羟基酸，其中每个R独立地如上定义，其包括在蒸馏塔中进行纯化，蒸馏塔的底部连接到具有短停留时间的蒸发器。本发明还涉及包含多羟甲基和1-10万重量ppm的多羟甲基和羟基酸的酯的组合物及其用途。

3. 发明申请

US20110313207A1 PROCESS FOR DISTILLATIVE WORKUP OF A METHANOL/WATER MIXTURE AND PROCESS FOR PREPARING ALKALI METAL METHOXIDES 审中-公开
标题翻译：甲醇/水混合物的分解工艺及制备碱金属甲醇的方法
公开(公告)号：US20110313207A1
公开(公告)日：2011-12-22
申请号：US13203504
申请日：2010-02-17
申请人： Gerd Kaibel , Tilman Sirch , Raimund Felder , Josef Guth
发明人： Gerd Kaibel , Tilman Sirch , Raimund Felder , Josef Guth
IPC分类号： B01D3/00 , C07C29/00
CPC分类号： B01D3/009 , B01D1/2856 , B01D3/14 , C07C29/70 , Y02P20/127 , C07C31/30
摘要： The invention relates to a process for distillative workup of a methanol/water mixture, in which a methanol/water mixture is added to a distillation column (1), an essentially methanol-comprising vapor stream is withdrawn at the top of the distillation column (1) and an essentially water-comprising bottom stream at the bottom of the distillation column (1), at least a portion of the essentially methanol-comprising vapor stream is compressed and the compressed vapor stream is added as heating vapor to an evaporator (11) in which at least a portion of the methanol/water mixture to be separated is evaporated. The invention further relates to a process for preparing alkali metal methoxides in a reaction column (31) by adding methanol and alkali metal hydroxide solution to the reaction column (31), withdrawing alkali metal methoxide dissolved in methanol at the lower end of the reaction column (31) and withdrawing a methanol/water mixture at the upper end of the reaction column (31), and working up the methanol/water mixture by the process for distillative workup.
摘要翻译：本发明涉及一种用于甲醇/水混合物的蒸馏处理方法，其中将甲醇/水混合物加入到蒸馏塔（1）中，基本上含甲醇的蒸气流在蒸馏塔的顶部排出（ 1）和在蒸馏塔（1）底部的基本上含水的底部流，至少部分基本上含甲醇的蒸气流被压缩，并将压缩的蒸气流作为加热蒸气加入到蒸发器（11 ），其中要分离的至少一部分甲醇/水混合物蒸发。本发明还涉及通过向反应塔（31）中加入甲醇和碱金属氢氧化物溶液，在反应塔（31）的下端除去溶解在甲醇中的碱金属甲醇盐，在反应塔（31）中制备碱金属甲醇盐的方法（31），并在反应塔（31）的上端取出甲醇/水混合物，并通过蒸馏处理方法处理甲醇/水混合物。

4. 发明申请

US20100256398A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 失效
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100256398A1
公开(公告)日：2010-10-07
申请号：US12746680
申请日：2008-12-10
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
IPC分类号： C07D313/04
CPC分类号： C07D313/04
摘要： The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要翻译：本发明涉及一种在活性炭作为催化剂存在下随后蒸馏的在气相中由6-羟基己酸酯制备ε-己内酯的方法。

5. 发明申请

US20080207958A1 Method For Production Of 1,6-Hexanediol With A Purity In Excess of 99.5% 失效
标题翻译： 1,6-己二醇生产方法纯度超过99.5％
公开(公告)号：US20080207958A1
公开(公告)日：2008-08-28
申请号：US10569980
申请日：2005-07-07
申请人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
发明人： Andrea Haunert , Rolf Pinkos , Thomas Krug , Tilman Sirch , Michael Koch , Gerd-Dieter Tebben
IPC分类号： C07C29/143
CPC分类号： C07C29/145 , C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
摘要翻译：本发明提供了一种通过以下方式制备1,6-己二醇的方法：通过以下方法将氢化己二酸二烷基酯，6-羟基己酸烷基酯，1,4-环己二酮和4-羟基环己烷-1-酮作为包含杂质的酯混合物，在第一蒸馏阶段（醇去除）中的过量醇和低锅炉的b），b）在第二蒸馏阶段中将底部产物分离成基本上不含1,4-环己二醇的酯馏分和至少包含大部分1,4-环己烷二醇，c）催化氢化基本上不含1,4-环己二醇的酯馏分（酯氢化）和d）在纯化蒸馏阶段，以一种方式从氢化流出物中获得1,6-己二醇本身已知，其包括在阶段a）和/或阶段b）之前选择性地氢化酯混合物（纯化氢化）。

6. 发明授权

US07301058B2 Method for increasing yield in the production of polyvalent alcohols by splitting by-products containing acetal 失效
标题翻译：通过分解含缩醛的副产物来提高多元醇生产中产率的方法
公开(公告)号：US07301058B2
公开(公告)日：2007-11-27
申请号：US10521810
申请日：2003-07-18
申请人： Alexander Wartini , Tilman Sirch , Johann-Peter Melder , Matthias Dernbach
发明人： Alexander Wartini , Tilman Sirch , Johann-Peter Melder , Matthias Dernbach
IPC分类号： C07C31/18
CPC分类号： C07C29/141 , C07C29/10 , C07C29/88 , C07C45/75 , C07C31/22 , C07C47/19
摘要： The invention relates to a method for increasing yield in the production of polyvalent alcohols, especially trimethylolpropane, obtained by condensing formaldehyde with a higher aldehyde. According to the inventive method, acid treatment is carried out on a mixture (high-boiling fraction) that is obtained by reprocessing, contains derivatives of said alcohols and has a higher boiling point than the respective alcohol, and the polyvalent alcohol is recovered from the acid-treated high-boiling fraction. The inventive method is characterised in that the water content of the high-boiling fraction amounts to between 20 and 90 wt. % in relation to the entire mixture of the high-boiling fraction and water.
摘要翻译：本发明涉及通过将甲醛与较高级醛缩合而获得的多价醇，特别是三羟甲基丙烷的生产中提高产量的方法。根据本发明的方法，通过后处理获得的含有所述醇的衍生物并且具有比各醇更高的沸点的混合物（高沸点馏分）进行酸处理，并且从所述醇中回收多元醇酸处理的高沸点馏分。本发明的方法的特征在于高沸点馏分的含水量在20-90wt。之间。相对于高沸点馏分和水的整个混合物的％。

7. 发明申请

US20050148802A1 Method for producing polyetherols 审中-公开
标题翻译：聚乙烯醇生产方法
公开(公告)号：US20050148802A1
公开(公告)日：2005-07-07
申请号：US10513323
申请日：2003-05-21
申请人： Alexander Wartini , Matthias Dernbach , Claus Hackmann , Tilman Sirch
发明人： Alexander Wartini , Matthias Dernbach , Claus Hackmann , Tilman Sirch
IPC分类号： C07C29/38 , C07C31/22 , C08G65/26 , C08G65/28 , C07C43/32 , C07C43/30
CPC分类号： C08G65/2609
摘要： The invention provides a process for preparing polyetherols of polyhydric alcohols by reacting an alkylene oxide with the appropriate polyhydric alcohol in the presence of a base and in the presence or absence of a solvent, wherein the polyhydric alcohol used has a formaldehyde acetal content of less than 500 ppm.
摘要翻译：本发明提供了一种通过在碱的存在下和在存在或不存在溶剂的情况下使烯化氧与适当的多元醇反应制备多元醇的多元醇的方法，其中所用的多元醇具有的甲醛缩醛含量小于 500 ppm。

8. 发明授权

US08217186B2 Process for preparing epsilon-caprolactone 失效
标题翻译：制备ε-己内酯的方法
公开(公告)号：US08217186B2
公开(公告)日：2012-07-10
申请号：US12746680
申请日：2008-12-10
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Daniel Breuninger , Tilman Sirch , Christophe Bauduin , Maria Guixa Guardia , Thomas Krug
IPC分类号： C07D313/00
CPC分类号： C07D313/04
摘要： The invention relates to a process for preparing ε-caprolactone from 6-hydroxycaproic ester in the gas phase in the presence of activated carbon as a catalyst and subsequent distillation.
摘要翻译：本发明涉及一种在活性炭作为催化剂存在下随后蒸馏的在气相中由6-羟基己酸酯制备ε-己内酯的方法。

9. 发明授权

US08183411B2 Process for preparing 6-hydroxycaproic esters 有权
标题翻译： 6-羟基己酸酯的制备方法
公开(公告)号：US08183411B2
公开(公告)日：2012-05-22
申请号：US12867509
申请日：2009-01-29
申请人： Rolf Pinkos , Tilman Sirch , Gerd-Dieter Tebben , Rolf-Hartmuth Fischer
发明人： Rolf Pinkos , Tilman Sirch , Gerd-Dieter Tebben , Rolf-Hartmuth Fischer
IPC分类号： C07C51/42
CPC分类号： C07C29/50 , C07C45/33 , C07C51/367 , C07C67/08 , C07C2601/14 , C07C49/403 , C07C59/01 , C07C69/675 , C07C35/08
摘要： The present application relates to an improved process for preparing 6-hydroxycaproic esters from the by-product mixtures which are obtained in the oxidation of cyclohexane to cyclohexanol and cyclohexanone with oxygen or oxygen-comprising gas mixtures.
摘要翻译：本申请涉及一种从副产物混合物中制备6-羟基己酸酯的改进方法，该方法是在用含氧或含氧气体混合物将环己烷氧化成环己醇和环己酮时获得的。

10. 发明申请

US20110272270A1 Process for Preparing Polymethylols 有权
标题翻译：制备多羟基睾酮的方法
公开(公告)号：US20110272270A1
公开(公告)日：2011-11-10
申请号：US13144124
申请日：2010-01-07
申请人： Stephan Schlitter , Michael Steiniger , Stefan Rittinger , Tilman Sirch , Steffen Maas
发明人： Stephan Schlitter , Michael Steiniger , Stefan Rittinger , Tilman Sirch , Steffen Maas
IPC分类号： B01D3/36
CPC分类号： C07C29/80 , C07C29/141 , C07C45/75 , C07C45/82 , C07C31/22 , C07C31/245 , C07C47/19
摘要： The present invention relates to a process for recovering components from a low boiler mixture which is obtained in the distillation of hydrogenation effluents from the preparation of polymethylols, by multistage distillation of the low boiler mixture comprising a tertiary amine, water, methanol, polymethylol of the formula (I) methylolalkanal of the formula (II) alcohol of the formula (III) and an alkanal with a methylene group in the α position to the carbonyl group, and in which each R is independently a further methylol group or an alkyl group having 1 to 22 carbon atoms or an aryl or aralkyl group having 6 to 22 carbon atoms, a first distillation stage involving separating the low boiler mixture into a higher-boiling, predominantly water-rich fraction and into a lower-boiling aqueous organic fraction comprising the tertiary amine, and the second distillation stage involving separating the aqueous organic fraction from the first distillation stage into a predominantly amine-containing fraction and a further amine-depleted fraction, wherein the tertiary amine is trimethylamine or triethylamine, and the bottom temperature in the second distillation stage is 110° C. and more.
摘要翻译：本发明涉及一种从低沸点混合物中回收组分的方法，该方法是从多羟甲基的制备中蒸馏氢化流出物获得的，通过多级蒸馏包含叔胺，水，甲醇，多羟甲基的低沸点混合物式（I）式（II）醇的式（I）的羟甲基烷醛和式（III）的醇的亚烷基与在羰基的α位上具有亚甲基的链烷醛，其中每个R独立地是另外的羟甲基或具有 1至22个碳原子或具有6至22个碳原子的芳基或芳烷基，第一蒸馏阶段包括将低锅炉混合物分离成较高沸点，主要是富水部分和低沸点含水有机部分，叔胺，第二蒸馏阶段将含水有机部分从第一蒸馏阶段分离成主要是胺其中叔胺为三甲胺或三乙胺，第二蒸馏阶段的底部温度为110℃以上。

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