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1. 发明申请

US20100011656A1 USE OF RYLENES AS MARKERS FOR LIQUIDS 审中-公开
标题翻译：使用作为液体标记的乙烯
公开(公告)号：US20100011656A1
公开(公告)日：2010-01-21
申请号：US12280577
申请日：2007-02-23
申请人： Thomas Gessner , Sophia Ebert , Ruediger Sens , Martin Koenemann , Wolfgang Ahlers , Christos Vamvakaris
发明人： Thomas Gessner , Sophia Ebert , Ruediger Sens , Martin Koenemann , Wolfgang Ahlers , Christos Vamvakaris
IPC分类号： C10L1/232 , C07D471/06 , G01N21/76
CPC分类号： C10L1/003 , C07D471/06 , C09B5/62 , C10M171/007
摘要： The invention relates to the use of rylene derivatives of the general formula (I) as markers for liquids, where the symbols and indices have the meanings given in the specification.
摘要翻译：本发明涉及通式（I）的二烯衍生物作为液体标记物的用途，其中符号和指标具有说明书中给出的含义。

2. 发明申请

US20100113767A1 PREPARATION OF SILICON PHTHALOCYANINES AND GERMANIUM PHTHALOCYANINES AND RELATED SUBSTANCES 审中-公开
标题翻译：硅烷基膦酸酯和锗酸氢钙及其相关物质的制备
公开(公告)号：US20100113767A1
公开(公告)日：2010-05-06
申请号：US12593097
申请日：2008-03-31
申请人： Thomas Gessner , Ruediger Sens , Wolfgang Ahlers , Christos Vamvakaris
发明人： Thomas Gessner , Ruediger Sens , Wolfgang Ahlers , Christos Vamvakaris
IPC分类号： C09B47/04
CPC分类号： C09B47/08 , C09B47/0673 , C09B47/22 , C10L1/003 , C10L1/1608 , C10L1/2383 , C10L1/28 , C10L1/301 , C10M171/007 , C10M2227/09
摘要： A process for preparing compounds of the general formula (I) by reacting the compound of the general formula (II) where L, L′ are the same or different and are each independently Cl or OH in the presence of a. chlorine compounds Cl-M2R1R2R3, Cl-M3R4R5R6, with the proviso that L and L′ are not both simultaneously OH, or b. hydroxyl compounds HO-M2R1R2R3, HO-M3R4R5R6. The use of compounds of the general formula (I) as markers for liquids and a process for detecting markers in liquids.
摘要翻译：通过使通式（II）的化合物，其中L，L'相同或不同，并且各自独立地为Cl或OH，在a的存在下反应，制备通式（I）的化合物的方法。氯化合物C1-M2R1R2R3，C1-M3R4R5R6，条件是L和L'不同时为OH，或b。羟基化合物HO-M2R1R2R3，HO-M3R4R5R6。使用通式（I）的化合物作为液体的标记物，以及检测液体中的标记物的方法。

3. 发明申请

US20080318331A1 Anthraquinone Derivatives as Markers For Liquids 审中-公开
标题翻译：蒽醌衍生物作为液体标记物
公开(公告)号：US20080318331A1
公开(公告)日：2008-12-25
申请号：US12159330
申请日：2007-12-12
申请人： Rüdiger Sens , Thomas Gessner , Sophia Ebert , Christos Vamvakaris , Wolfgang Ahlers
发明人： Rüdiger Sens , Thomas Gessner , Sophia Ebert , Christos Vamvakaris , Wolfgang Ahlers
IPC分类号： G01N33/00 , C07D209/56
CPC分类号： C07D209/58 , C10L1/003 , C10L1/224 , C10L1/2283 , C10L1/232 , C10M171/007 , C10M2215/086 , C10M2215/14 , Y10T436/145555
摘要： The use of compounds of the general formula (I) as markers for liquids, methods for detecting markers in liquids, methods for identifying liquids and selected compounds of the general formula (I).
摘要翻译：使用通式（I）的化合物作为液体标记物，液体中标记物的检测方法，液体鉴定方法和通式（I）的选定化合物。

4. 发明申请

US20090189086A1 USE OF ARYL-OR ALKYLOXY-SUBSTITUTED PHTHALOCYANINES AS MARKING SUBSTANCES FOR LIQUIDS 审中-公开
标题翻译：作为液体标记物质使用芳基或烷基取代的苯基甲烷
公开(公告)号：US20090189086A1
公开(公告)日：2009-07-30
申请号：US12282985
申请日：2007-03-07
申请人： Thomas Gessner , Sophia Ebert , Rüdiger Sens , Martin Könemann , Wolfgang Ahlers , Christos Vamvakaris
发明人： Thomas Gessner , Sophia Ebert , Rüdiger Sens , Martin Könemann , Wolfgang Ahlers , Christos Vamvakaris
IPC分类号： G01N21/64 , C07D487/22 , C07C255/51 , C07D209/44 , C10L1/232 , G01N21/85
CPC分类号： C07C255/54 , C07C2603/74 , C07D209/44 , C09B47/0675 , C10L1/003 , C10M133/58 , C10M159/18 , C10M171/007 , C10M2215/227 , C10M2227/09 , C10N2240/56
摘要： Phthalocyanines of the formula (I) where the symbols and indices each have the definitions specified in the description are suitable as markers for liquids, especially mineral oils.
摘要翻译：其中符号和指数各自具有在说明书中指定的定义的式（I）的酞菁适合作为液体，特别是矿物油的标记物。

5. 发明申请

US20100208261A1 SPECTROMETER WITH LED ARRAY 审中-公开
标题翻译：带LED阵列的光谱仪
公开(公告)号：US20100208261A1
公开(公告)日：2010-08-19
申请号：US12680847
申请日：2008-10-08
申请人： Ruediger Sens , Christos Vamvakaris , Wolfgang Ahlers , Erwin Thiel
发明人： Ruediger Sens , Christos Vamvakaris , Wolfgang Ahlers , Erwin Thiel
IPC分类号： G01J3/28 , H01L31/12 , H01J40/14 , G01N21/59 , G01N21/55 , G01J1/58
CPC分类号： G01N21/255 , G01J3/0272 , G01J3/10 , G01J3/42 , G01J2003/104 , G01N21/0303 , G01N21/55 , G01N21/643 , G01N21/645 , G01N33/28 , G01N2021/0143 , G01N2021/0389 , G01N2021/6419 , G01N2021/6421 , G01N2021/6491 , G01N2201/0221 , G01N2201/0222 , G01N2201/0624 , G01N2201/0625 , G01N2201/0627
摘要： A device (110) for determining at least one optical property of a sample (112) is proposed. The device (110) comprises a tuneable excitation light source (114; 410) for applying excitation light (122) to the sample (112). The device (110) furthermore comprises a detector (128, 130; 312) for detecting detection light (132, 136; 314) emerging from the sample (112). The excitation light source (114; 410) comprises a light-emitting diode array (114), which is configured at least partly as a monolithic light-emitting diode array (114). The monolithic light-emitting diode array (114) comprises at least three light-emitting diodes (426) each having a different emission spectrum.
摘要翻译：提出了一种用于确定样品（112）的至少一种光学特性的装置（110）。装置（110）包括用于向样品（112）施加激发光（122）的可调激励光源（114; 410）。装置（110）还包括用于检测从样品（112）出现的检测光（132,136; 314）的检测器（128,130; 312）。激发光源（114; 410）包括至少部分地被配置为单片发光二极管阵列（114）的发光二极管阵列（114）。单片发光二极管阵列（114）包括至少三个各自具有不同发射光谱的发光二极管（426）。

6. 发明申请

US20080194446A1 Use of Dibenzanthrone and Isodibenzanthrone Derivatives as Marking Substances for Liquids 审中-公开
标题翻译：二苯胺酮和异二苯并二酮衍生物作为液体标记物质的应用
公开(公告)号：US20080194446A1
公开(公告)日：2008-08-14
申请号：US11817325
申请日：2006-03-09
申请人： Sophia Ebert , Rudiger Sens , Christos Vamvakaris , Wolfgang Ahlers
发明人： Sophia Ebert , Rudiger Sens , Christos Vamvakaris , Wolfgang Ahlers
IPC分类号： C10M129/24 , C10L1/18 , C07C49/115
CPC分类号： C09B3/06 , C10L1/003 , C10M171/007 , C10N2270/02
摘要： The present invention relates to the use of selected dibenzanthrone or isodibenzanthrone derivatives as markers for liquids, in particular for mineral oils. The present invention further relates both to fuel and lubricant additive concentrates and to mineral oils which comprise at least one such dibenzanthrone or isodibenzanthrone derivative.
摘要翻译：本发明涉及选择的二苯并胍或异二苯并二酮衍生物作为液体，特别是矿物油的标记物的用途。本发明还涉及燃料和润滑剂添加剂浓缩物以及包含至少一种这样的二苯烷酮或异二苯并二酮衍生物的矿物油。

7. 发明申请

US20090006004A1 Method for Determining the Identity, Absence and Concentration of a Chemical Compound in a Medium 审中-公开
公开(公告)号：US20090006004A1
公开(公告)日：2009-01-01
申请号：US12159005
申请日：2006-12-27
申请人： Rudiger Sens , Christos Vamvakaris , Wolfgang Ahlers , Erwin Thiel
发明人： Rudiger Sens , Christos Vamvakaris , Wolfgang Ahlers , Erwin Thiel
IPC分类号： G01N21/00
CPC分类号： G01J3/4406 , G01J3/02 , G01J3/0232 , G01J3/457 , G01J2001/4242 , G01N21/31 , G01N21/643 , G01N21/645 , G01N2021/6491 , G01N2201/129
摘要： A method is proposed for detecting at least one chemical compound V contained in a medium (312). The method comprises a verification step (420) which is used to determine whether V is contained in the medium (312). The method furthermore comprises an analysis step (424) in which a concentration c of the at least one chemical compound V is determined.The verification step comprises the following substeps: (a1) the medium (312) is exposed to a first analysis radiation (316) of a variable wavelength λ, the wavelength λ assuming at least two different values; (a2) at least one spectral response function A(λ) is generated with the aid of the radiation (324) absorbed and/or emitted and/or reflected and/or scattered by the medium (312) in response to the first analysis radiation (316); (a3) at least one spectral correlation function K(δλ) is formed by spectral comparison of the at least one spectral response function A(λ) with at least one pattern function R(λ+δλ), the at least one pattern function R(λ) representing a spectral measurement function of a medium (312) containing the chemical compound V and δλ being a coordinate shift; (a4) the at least one spectral correlation function K(δλ) is examined in a pattern recognition step (418), and a conclusion is made as to whether the at least one chemical compound V is contained in the medium (312); The analysis step (424) comprises the following substeps: (b1) the medium (312) is exposed to at least one second analysis radiation (318) having at least one excitation wavelength λEX; (b2) at least one spectral analysis function B(λEX,λRES) is generated with the aid of the radiation (326) of the response wavelength λRES absorbed and/or emitted and/or reflected and/or scattered by the medium (312) in response to the second analysis radiation (318) of the wavelength λEX and the concentration c is deduced therefrom.

8. 发明申请

US20070004939A1 Method for the continuous production of aldehydes 失效
标题翻译：连续生产醛的方法
公开(公告)号：US20070004939A1
公开(公告)日：2007-01-04
申请号：US10575843
申请日：2004-10-14
申请人： Martin Volland , Thomas Mackewitz , Wolfgang Ahlers , Ansgar Schafer , Wolfgang Richter , Rocco Paciello
发明人： Martin Volland , Thomas Mackewitz , Wolfgang Ahlers , Ansgar Schafer , Wolfgang Richter , Rocco Paciello
IPC分类号： C07C45/50
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing α-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95% conversion of the α-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1−Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.
摘要翻译：本发明涉及通过在包含4至20个碳原子并含有具有内部双键的α-烯烃和烯烃的烯烃组合物的均质相中的异构化加氢甲酰化来连续生产含有5至21个碳原子的醛的方法，在与含有氧原子和/或氮原子的有机磷配体和游离配体络合的均匀的铑催化剂的存在下，通过合成气。所述生产在由至少两个反应区组成的多级反应体系中在高温高压下进行。根据所述方法，首先使用具有CO / H 2 O 2的合成气在第一反应区或一组几个第一反应区中以10至40巴的总压力反应烯烃组合物，的摩尔比在4:1和1:2之间，直到获得40-95％的α-烯烃转化率。然后使用具有CO / H 2的合成气使来自第一反应区或几个第一反应区的组的加氢甲酰化产物在随后的反应区或几个反应区的组中以5至30巴的总压力反应， 1摩尔比为1:4-1:1000。后续反应区域或区域中的总压力分别比前述反应区域低1〜（G1-Gf）巴，由此G1表示前述反应区域中的总压力，Gf表示相应的所述第一反应区或区域成功的反应区，条件是G 1和G f之间的差大于1巴，并且后续反应区或区中的部分CO压力分别低于前述反应区。

9. 发明授权

US07012162B2 Phosphacyclohexanes and the use thereof in the hydroformylation of olefins 失效
标题翻译：磷杂环己烷及其在烯烃加氢甲酰化中的应用
公开(公告)号：US07012162B2
公开(公告)日：2006-03-14
申请号：US10311584
申请日：2001-06-25
申请人： Thomas Mackewitz , Wolfgang Ahlers , Edgar Zeller , Michael Röper , Rocco Paciello , Rainer Papp , Konrad Knoll , Hartwig Voss
发明人： Thomas Mackewitz , Wolfgang Ahlers , Edgar Zeller , Michael Röper , Rocco Paciello , Rainer Papp , Konrad Knoll , Hartwig Voss
IPC分类号： C07C45/50 , C07F9/02 , B01J31/00
CPC分类号： B01J31/2466 , B01J31/20 , B01J31/2423 , B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , C07F9/65683 , C07F15/0026 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07F15/065 , C07C47/21 , C07C47/02
摘要： The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C1-100-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl: R1 to R10 can independently represent hydrogen, C1-20-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl: W, W′ can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to groups VIII to X of the periodic table.
摘要翻译：本发明涉及通式I和II的磷杂环己烷，其中应用以下名称：R可以表示氢，C 1-100 - 烷基，C 7-20〜 C 1 -C 6烷基，C 7-20芳烷基和C 6-12 - 芳基：R 1至R 10， / SUP>可以独立地表示氢，C 1-20 - 烷基，C 7-20-20芳烷基，C 7-20 - 烷芳基，和C 6-12 - 芳基：W，W'可以独立地表示单键或包含1至20个碳原子的桥，其可以形成环状或芳族基团的一部分并且可以被杂原子中断。所述磷杂环己烷用作属于周期表第VIII至X族过渡金属的过渡金属络合物中的配体。

10. 发明授权

US06835855B2 Metal complex carrying a 2-phospa-tricyclo[3.3.1.1(3.7)]decyl radical as a ligand in hydroformylation 失效
标题翻译：在加氢甲酰化中携带2-磷杂三环[3.3.1.1（3.7）]癸基作为配体的金属络合物
公开(公告)号：US06835855B2
公开(公告)日：2004-12-28
申请号：US10275562
申请日：2002-11-07
申请人： Wolfgang Ahlers
发明人： Wolfgang Ahlers
IPC分类号： C07C4550
CPC分类号： C07F15/008 , B01J31/1845 , B01J31/2485 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C45/50 , C07C47/02
摘要： In a process for the hydroformylation of ethylenically unsaturated compounds, at least one ethylenically unsaturated compound is reacted with carbon monoxide and hydrogen in the presence of a ligand-metal complex of ruthenium, rhodium, palladium, iridium and/or platinum, where the ligand-metal complex comprises a monophosphine, monophosphinite or monophosphinamidite ligand of the formula I where A together with the phosphorus atom to which it is bound forms a 2-phosphatricyclo[3.3.1.1{3,7}]decyl radical in which one or more nonadjacent carbon atoms may be replaced by heteroatoms and which may be substituted, and R′ is hydrogen or an organic radical having a molecular weight of up to 20 000 bound via a carbon atom or oxygen atom or nitrogen atom. The process is particularly useful for the hydroformylation of internal branched olefins and lower pressures and/or temperatures are required in the hydroformylation than when using other phosphorus ligands.

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