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1. 发明授权

US07012162B2 Phosphacyclohexanes and the use thereof in the hydroformylation of olefins 失效
标题翻译：磷杂环己烷及其在烯烃加氢甲酰化中的应用
公开(公告)号：US07012162B2
公开(公告)日：2006-03-14
申请号：US10311584
申请日：2001-06-25
申请人： Thomas Mackewitz , Wolfgang Ahlers , Edgar Zeller , Michael Röper , Rocco Paciello , Rainer Papp , Konrad Knoll , Hartwig Voss
发明人： Thomas Mackewitz , Wolfgang Ahlers , Edgar Zeller , Michael Röper , Rocco Paciello , Rainer Papp , Konrad Knoll , Hartwig Voss
IPC分类号： C07C45/50 , C07F9/02 , B01J31/00
CPC分类号： B01J31/2466 , B01J31/20 , B01J31/2423 , B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , C07F9/65683 , C07F15/0026 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07F15/065 , C07C47/21 , C07C47/02
摘要： The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C1-100-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl: R1 to R10 can independently represent hydrogen, C1-20-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl: W, W′ can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to groups VIII to X of the periodic table.
摘要翻译：本发明涉及通式I和II的磷杂环己烷，其中应用以下名称：R可以表示氢，C 1-100 - 烷基，C 7-20〜 C 1 -C 6烷基，C 7-20芳烷基和C 6-12 - 芳基：R 1至R 10， / SUP>可以独立地表示氢，C 1-20 - 烷基，C 7-20-20芳烷基，C 7-20 - 烷芳基，和C 6-12 - 芳基：W，W'可以独立地表示单键或包含1至20个碳原子的桥，其可以形成环状或芳族基团的一部分并且可以被杂原子中断。所述磷杂环己烷用作属于周期表第VIII至X族过渡金属的过渡金属络合物中的配体。

2. 发明申请

US20060224000A1 Stabilization of hydroformylation catalysts based on phoshoramide ligands 有权
标题翻译：基于磷酰胺配体的加氢甲酰化催化剂的稳定化
公开(公告)号：US20060224000A1
公开(公告)日：2006-10-05
申请号：US10576282
申请日：2004-10-22
申请人： Rainer Papp , Wolfgang Ahlers , Thomas Mackewitz , Rocco Paciello , Martin Volland
发明人： Rainer Papp , Wolfgang Ahlers , Thomas Mackewitz , Rocco Paciello , Martin Volland
IPC分类号： C07F15/00 , C07C45/49
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/0238 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The present invention relates to a process for the hydroformylation of ethylenically unsaturated compounds by reaction with carbon monoxide and hydrogen in the presence of a catalytically active fluid which comprises a dissolved metal complex of a metal of transition group VIII of the Periodic Table of the Elements with at least one phosphoramidite compound as ligand, wherein the fluid is brought into contact with a base.
摘要翻译：本发明涉及通过在催化活性流体存在下与一氧化碳和氢气反应来进行烯键式不饱和化合物的加氢甲酰基化的方法，该催化活性流体包含元素周期表的第八族过渡金属的金属络合物与至少一种亚磷酰胺化合物作为配体，其中流体与碱接触。

3. 发明授权

US08110709B2 Stabilization of hydroformylation catalysts based on phosphoramide ligands 有权
标题翻译：基于磷酰胺配体的加氢甲酰化催化剂的稳定化
公开(公告)号：US08110709B2
公开(公告)日：2012-02-07
申请号：US10576282
申请日：2004-10-22
申请人： Rainer Papp , Wolfgang Ahlers , Thomas Mackewitz , Rocco Paciello , Martin Volland
发明人： Rainer Papp , Wolfgang Ahlers , Thomas Mackewitz , Rocco Paciello , Martin Volland
IPC分类号： C07C45/50 , C07F9/572 , C07F9/06
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/0238 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The present invention relates to a process for the hydroformylation of ethylenically unsaturated compounds by reaction with carbon monoxide and hydrogen in the presence of a catalytically active fluid which comprises a dissolved metal complex of a metal of transition group VIII of the Periodic Table of the Elements with at least one phosphoramidite compound as ligand, wherein the fluid is brought into contact with a base.
摘要翻译：本发明涉及通过在催化活性流体存在下与一氧化碳和氢气反应来进行烯键式不饱和化合物的加氢甲酰基化的方法，该催化活性流体包含元素周期表的第八族过渡金属的金属络合物与至少一种亚磷酰胺化合物作为配体，其中流体与碱接触。

4. 发明授权

US06310261B1 Method for the production of aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US06310261B1
公开(公告)日：2001-10-30
申请号：US09582780
申请日：2000-07-03
申请人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
发明人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
IPC分类号： C07C4550
CPC分类号： C08G73/0206 , B01J31/1658 , B01J31/1805 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.
摘要翻译：本发明涉及通过在均匀溶解在含有元素周期表第Ⅷa族金属的反应混合物的络合催化剂存在下烯烃的加氢甲酰化生产醛或醛和醇的方法，在50至100℃的温度和20至1,000巴的压力下适合于络合物形成配位体的多余的多齿氮化合物，并且在加氢甲酰基化反应中再循环催化剂配合物，其中a）使用基本上不相容的衍生的多胺，水溶性且适合于络合物形成，并且具有大于1,000道尔顿和至少10个氮原子的平均分子量; b）一旦加氢甲酰化反应和通过蒸馏醛和醇的分离或部分分离已经被残留在蒸馏塔底部的催化剂络合物和从反应混合物中得到的过量配体在加氢甲酰化反应中被全部或部分再循环完成 c）然后执行从反应混合物的蒸馏底部继续或至少间歇抽出高锅炉的至少一部分。

5. 发明授权

US07145042B2 Method for producing dialdehydes and or ethylenically unsaturated monoaldehydes by hydroformylating ethylenically unsaturated compounds 失效
公开(公告)号：US07145042B2
公开(公告)日：2006-12-05
申请号：US10527635
申请日：2003-09-12
申请人： Martin Volland , Wolfgang Ahlers , Klaus Ebel , Rocco Paciello , Michael Röper , Thomas Mackewitz , Volker Böhm , Xavier Sava , Oliver Löber , Oliver Bey , Jürgen Stephan , Frank Haese
发明人： Martin Volland , Wolfgang Ahlers , Klaus Ebel , Rocco Paciello , Michael Röper , Thomas Mackewitz , Volker Böhm , Xavier Sava , Oliver Löber , Oliver Bey , Jürgen Stephan , Frank Haese
IPC分类号： C07C45/50
CPC分类号： C07F9/6596 , C07C45/50 , C07F9/572 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07C47/12 , C07C47/21
摘要： The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.

6. 发明申请

US20070004939A1 Method for the continuous production of aldehydes 失效
标题翻译：连续生产醛的方法
公开(公告)号：US20070004939A1
公开(公告)日：2007-01-04
申请号：US10575843
申请日：2004-10-14
申请人： Martin Volland , Thomas Mackewitz , Wolfgang Ahlers , Ansgar Schafer , Wolfgang Richter , Rocco Paciello
发明人： Martin Volland , Thomas Mackewitz , Wolfgang Ahlers , Ansgar Schafer , Wolfgang Richter , Rocco Paciello
IPC分类号： C07C45/50
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing α-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95% conversion of the α-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1−Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.
摘要翻译：本发明涉及通过在包含4至20个碳原子并含有具有内部双键的α-烯烃和烯烃的烯烃组合物的均质相中的异构化加氢甲酰化来连续生产含有5至21个碳原子的醛的方法，在与含有氧原子和/或氮原子的有机磷配体和游离配体络合的均匀的铑催化剂的存在下，通过合成气。所述生产在由至少两个反应区组成的多级反应体系中在高温高压下进行。根据所述方法，首先使用具有CO / H 2 O 2的合成气在第一反应区或一组几个第一反应区中以10至40巴的总压力反应烯烃组合物，的摩尔比在4:1和1:2之间，直到获得40-95％的α-烯烃转化率。然后使用具有CO / H 2的合成气使来自第一反应区或几个第一反应区的组的加氢甲酰化产物在随后的反应区或几个反应区的组中以5至30巴的总压力反应， 1摩尔比为1:4-1:1000。后续反应区域或区域中的总压力分别比前述反应区域低1〜（G1-Gf）巴，由此G1表示前述反应区域中的总压力，Gf表示相应的所述第一反应区或区域成功的反应区，条件是G 1和G f之间的差大于1巴，并且后续反应区或区中的部分CO压力分别低于前述反应区。

7. 发明申请

US20100048959A1 METHOD FOR THE HYDROFORMYLATION OF OLEFINS 有权
标题翻译：烯烃氢化方法
公开(公告)号：US20100048959A1
公开(公告)日：2010-02-25
申请号：US12516855
申请日：2007-11-29
申请人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
发明人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
IPC分类号： C07C45/41 , C07C29/151
CPC分类号： C07C45/50 , C07C5/2506 , C07C29/141 , C07C45/74 , C07C47/02 , C07C11/08 , C07C31/125 , C07C47/21
摘要： The present invention relates to a process for preparing hydroformylation products of olefins having at least four carbon atoms, in which a high proportion of both the linear Ci-olefins having a terminal double bond comprised in the olefin-comprising feed used and of the linear Ci-olefins having an internal double bond is converted into hydroformylation products. Furthermore, the invention relates to a process for preparing 2-propylheptanol which comprises such a hydroformylation process.
摘要翻译：本发明涉及一种制备具有至少四个碳原子的烯烃的加氢甲酰化产物的方法，其中在所用含烯烃的原料中包含的具有末端双键的直链C 1 -C 20烯烃和线性C 1 具有内部双键的烯烃转化为加氢甲酰化产物。此外，本发明涉及一种制备2-丙基庚醇的方法，其包括这种加氢甲酰化方法。

8. 发明授权

US07615645B2 Method for the continuous production of aldehydes 失效
标题翻译：连续生产醛的方法
公开(公告)号：US07615645B2
公开(公告)日：2009-11-10
申请号：US10575843
申请日：2004-10-14
申请人： Martin Volland , Thomas Mackewitz , Wolfgang Ahlers , Ansgar Schäfer , Wolfgang Richter , Rocco Paciello
发明人： Martin Volland , Thomas Mackewitz , Wolfgang Ahlers , Ansgar Schäfer , Wolfgang Richter , Rocco Paciello
IPC分类号： C07C45/50 , C07D207/00
CPC分类号： B01J31/186 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02
摘要： The invention relates to a method for the continuous production of aldehydes by the isomerising hydroformylation in a homogenous phase of olefin compositions by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. The production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to the method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95% conversion of the α-olefins is obtained.
摘要翻译：本发明涉及通过在与含氧原子的有机磷配体络合的均匀铑催化剂的存在下，通过合成气在烯烃组合物的均相中通过异构化加氢甲酰化连续生产醛的方法和/ 或氮原子和游离配体。在由至少两个反应区组成的多级反应体系中，在高温高压下进行生产。根据该方法，首先使用CO / H 2摩尔比为4：4的合成气，在10-400巴的总压力下，在第一反应区或几个第一反应区的一组中反应烯烃组合物。 1和1：2，直到获得40-95％的α-烯烃转化率。

9. 发明授权

US09266808B2 Method for the hydroformylation of olefins 有权
标题翻译：烯烃加氢甲酰化的方法
公开(公告)号：US09266808B2
公开(公告)日：2016-02-23
申请号：US12516855
申请日：2007-11-29
申请人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
发明人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
IPC分类号： C07C29/141 , C07C45/50 , C07C5/25 , C07C45/74
CPC分类号： C07C45/50 , C07C5/2506 , C07C29/141 , C07C45/74 , C07C47/02 , C07C11/08 , C07C31/125 , C07C47/21
摘要： The present invention relates to a process for preparing hydroformylation products of olefins having at least four carbon atoms, in which a high proportion of both the linear Ci-olefins having a terminal double bond comprised in the olefin-comprising feed used and of the linear Ci-olefins having an internal double bond is converted into hydroformylation products. Furthermore, the invention relates to a process for preparing 2-propylheptanol which comprises such a hydroformylation process.
摘要翻译：本发明涉及一种制备具有至少四个碳原子的烯烃的加氢甲酰化产物的方法，其中在所用含烯烃的原料中包含的具有末端双键的直链C 1 -C 20烯烃和线性C 1 具有内部双键的烯烃转化为加氢甲酰化产物。此外，本发明涉及一种制备2-丙基庚醇的方法，其包括这种加氢甲酰化方法。

10. 发明授权

US06977312B2 Phosphor, arsenic and antimony compounds based upon diaryl-anellated bicyclo[2.2.n] parent substances and catalysts containing same 失效
标题翻译：基于二芳基 - 苯氧基双环[2.2.n]母体物质和含有它们的催化剂的磷光体，砷和锑化合物
公开(公告)号：US06977312B2
公开(公告)日：2005-12-20
申请号：US10203296
申请日：2001-02-09
申请人： Wolfgang Ahlers , Michael Röper , Peter Hofmann , Daniel C. M. Warth , Rocco Paciello
发明人： Wolfgang Ahlers , Michael Röper , Peter Hofmann , Daniel C. M. Warth , Rocco Paciello
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42 , C07F9/02
CPC分类号： C07F9/65746 , B01J31/1658 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/2457 , B01J2231/12 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/543 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/46 , C07F9/5027 , C07F9/6561 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： Novel compounds of phosphorus, of arsenic and of antimony can be used as ligands to form complexes of metals of transition group VIII which can be used in catalysts for hydroformylation, hydrocyanation, carbonylation, hydrogenations, oligomerization and polymerization of olefins and for metathesis.
摘要翻译：可以使用磷，砷和锑的新型化合物作为配体，形成可用于加氢甲酰化，氢化氰化，羰基化，氢化，烯烃低聚和聚合的复合催化剂的过渡基团VIII的金属络合物和复分解。

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