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    • 4. 发明授权
    • Slippery biaxially stretched polyester films
    • 滑爽的双轴拉伸聚酯薄膜
    • US4439479A
    • 1984-03-27
    • US338652
    • 1982-01-11
    • Tamaki KanaiHirofumi YoshikawaTakashi YamagishiKenji SuzukiYoshikatsu Ohta
    • Tamaki KanaiHirofumi YoshikawaTakashi YamagishiKenji SuzukiYoshikatsu Ohta
    • B05D5/08B05D7/04C08J5/18C09D4/00G03C1/795G11B5/70B32B3/00
    • C08J5/18B05D5/08B05D7/04C09D4/00G03C1/7954G11B5/7013C08J2367/02Y10S428/91Y10T428/24413Y10T428/24612Y10T428/256Y10T428/31786
    • A process for producing a slippery biaxially stretched polyester film, which comprises coating one or both surfaces, preferably one surface, of a running polyester film, before the completion of its crystalline orientation, with an aqueous solution or dispersion containing(A) a metal salt having the composition of the following formula ##STR1## wherein Me represents a metal ion having a valence of 2 to 6, R is H or CH.sub.3, X is one equivalent of an anion, y is 1-6, z is 0-2, w is 0-8, and p is a number equal to the quotient obtained by dividing the total of y+2z+w by the atomic valence of Me, provided that when y is 2 or more, two or more R groups may be identical or different, when w is 2 or more, two or more X ions may be identical or different, and the group ##STR2## in the case of R=CH.sub.3 is contained in a number of not more than 2 for each Me, and(B) a film-forming polymeric compound, a monomer thereof, or a mixture of these; and thereafter heating the coating, before completion of the crystalline orientation of the film, to convert it on the film surface into numerous minute protrusions substantially having form retention; and a slippery biaxially stretched polyester film having a substantially continuous coating with numerous protrusions substantially having form retention, said coating being formed substantially all over on at least one surface of the film and at least comprising a metal salt having the composition of formula (I) above and a film-forming polymeric compound.
    • 一种光滑的双轴拉伸聚酯薄膜的制造方法,其包括在其结晶取向完成之前,用含有(A)金属盐的水溶液或分散体涂覆流动的聚酯薄膜的一个或两个表面,优选一个表面 具有下式的组成式(I)其中Me表示2价〜6价的金属离子,R为H或CH3,X为1当量阴离子,y为1-6,z为0 -2,w是0-8,p是等于通过将y + 2z + w的总和除以Me的原子价得到的商数,条件是当y为2或更大时,两个或更多个R基团 可以相同或不同,当w为2以上时,两个以上的X离子可以相同也可以不同,在R = CH 3的情况下,基团“IMAGE”在每个Me中不超过2个 ,和(B)成膜聚合物,其单体或它们的混合物; 然后在膜的结晶取向完成之前加热涂层,将其在膜表面上转化成基本上具有形状保留的许多微小突起; 和具有基本上具有形状保持性的许多突起的基本上连续的涂层的光滑双轴拉伸聚酯膜,所述涂层基本上形成在膜的至少一个表面上,并且至少包含具有式(I)组成的金属盐, 以及成膜聚合物。
    • 5. 发明授权
    • Process for the production of slippery biaxially stretched polyester
films
    • 生产光滑双轴拉伸聚酯薄膜的方法
    • US4492719A
    • 1985-01-08
    • US555006
    • 1983-11-21
    • Tamaki KanaiHirofumi YoshikawaTakashi YamagishiKenji SuzukiYoshikatsu Ohta
    • Tamaki KanaiHirofumi YoshikawaTakashi YamagishiKenji SuzukiYoshikatsu Ohta
    • B05D5/08B05D7/04C08J5/18C09D4/00G03C1/795G11B5/70B32B3/00
    • C08J5/18B05D5/08B05D7/04C09D4/00G03C1/7954G11B5/7013C08J2367/02
    • A process for producing a slippery biaxially stretched polyester film, which comprises coating one or both surfaces, preferably one surface, of a running polyester film, before the completion of its crystalline orientation, with an aqueous solution or dispersion containing(A) a metal salt having the composition of the following formula ##STR1## wherein Me represents a metal ion having a valence of 2 to 6, R is H or CH.sub.3, X is one equivalent of an anion, y is 1-6, z is 0-2, w is 0-8, and p is a number equal to the quotient obtained by dividing the total of y+2z+w by the atomic valence of Me, provided that when y is 2 or more, two or more R groups may be identical or different, when w is 2 or more, two or more X ions may be identical or different, and the group ##STR2## in the case of R.dbd.CH.sub.3 is contained in a number of not more than 2 for each Me,and (B) a film-forming polymeric compound, a monomer thereof, or a mixture of these; and thereafter heating the coating, before completion of the crystalline orientation of the film, to convert it on the film surface into numerous minute protrusions substantially having form retention; and a slippery biaxially stretched polyester film having a substantially continuous coating with numerous protrusions substantially having form retention, said coating being formed substantially all over on at least one surface of the film and at least comprising a metal salt having the composition of formula (I) above and a film-forming polymeric compound.
    • 一种光滑的双轴拉伸聚酯薄膜的制造方法,其包括在其结晶取向完成之前,用含有(A)金属盐的水溶液或分散体涂覆流动的聚酯薄膜的一个或两个表面,优选一个表面 具有下式的组成:其中Me表示2〜6价的金属离子,R为H或CH3,X为1当量阴离子,y为1-6,z为0 -2,w是0-8,p是等于通过将y + 2z + w的总和除以Me的原子价得到的商数,条件是当y为2或更大时,两个或更多个R基团 可以相同或不同,当w为2以上时,两个以上的X离子可以相同也可以不同,在R = CH 3的情况下,基团“IMAGE”在每个Me中不超过2个 ,和(B)成膜聚合物,其单体或它们的混合物; 然后在膜的结晶取向完成之前加热涂层,将其在膜表面上转化成基本上具有形状保留的许多微小突起; 和具有基本上具有形状保持性的许多突起的基本上连续的涂层的光滑双轴拉伸聚酯膜,所述涂层基本上形成在膜的至少一个表面上,并且至少包含具有式(I)组成的金属盐, 以及成膜聚合物。