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1. 发明授权

US07091157B2 Image recording element comprising extrudable polyester-containing image-receiving layer 有权
标题翻译：图像记录元件，包括可挤出的含聚酯的图像接收层
公开(公告)号：US07091157B2
公开(公告)日：2006-08-15
申请号：US10375500
申请日：2003-02-26
申请人： Teh-Ming Kung , Paul D. Yacobucci , Eric E. Arrington
发明人： Teh-Ming Kung , Paul D. Yacobucci , Eric E. Arrington
IPC分类号： B41M5/035 , B41M5/38
CPC分类号： B41M5/5272 , Y10T428/24802 , Y10T428/31511 , Y10T428/31786
摘要： The present invention is directed to an image-receiving layer comprising a polyester, or a polyester blend, which exhibits excellent lightfade and high dye transfer efficiency, as well as low materials cost. In particular, the invention relates to an image recording element comprising a support having on one side thereof an image-receiving layer comprising a polyester comprising at least 0.1 mole percent of a multifunctional polyol having more than two hydroxy groups and/or a polyacid having more than two carboxylic acid groups, including derivatives thereof, based on the total acid derived units. The invention is useful, for example, as a dye-receiver element for thermal dye transfer having on one side of the support a dye-image receiving layer. The polyester is especially advantageous for use in dye-receiving layers that are extruded instead of solvent-coated.
摘要翻译：本发明涉及一种包含聚酯或聚酯共混物的图像接收层，其表现出优异的光衰和高的染料转移效率以及低的材料成本。特别地，本发明涉及一种图像记录元件，其包括支撑体，其一侧具有图像接收层，该图像接收层包括含至少0.1摩尔％的具有多于两个羟基的多官能多元醇和/或具有多于两个羟基的多酸的聚酯比两个羧酸基团，包括其衍生物，基于总酸衍生的单元。本发明例如作为用于热染料转移的染料 - 接受元件是有用的，其在载体的一侧具有染料 - 图像接收层。聚酯特别有利于用于被代替溶剂涂覆的挤出的染料接受层。

2. 发明授权

US07125611B2 Polyester compositions useful for image-receiving layers 有权
标题翻译：用于图像接收层的聚酯组合物
公开(公告)号：US07125611B2
公开(公告)日：2006-10-24
申请号：US10376188
申请日：2003-02-26
申请人： Teh-Ming Kung , Paul D. Yacobucci , Eric E. Arrington
发明人： Teh-Ming Kung , Paul D. Yacobucci , Eric E. Arrington
IPC分类号： B32B27/36 , C08G63/16 , C08G63/181 , C08G63/19 , C08G63/199
CPC分类号： C08G63/20 , B41M5/5272 , C08L67/00 , C08L69/00 , Y10T428/26 , Y10T428/266 , Y10T428/269 , Y10T428/31663 , Y10T428/31786 , C08L2666/18
摘要： The invention relates to a composition comprising a polyester copolymer that comprises (a) recurring dibasic acid derived units and polyol derived units, at least 50 mole % of the dibasic acid derived units comprising dicarboxylic acid derived units each containing an alicyclic ring, (b) 25 to 75 mole % of the polyol derived units containing an aromatic ring not immediately adjacent to each hydroxyl group of the corresponding polyol, (c) 25 to 75 mole % of the polyol derived units of the polyester are non-aromatic, and (d) at least 0.1 mole percent, in sum total, of units derived from a multifunctional polyol having more than two hydroxy groups and/or units derived from a polyacid having more than two carboxylic acid groups and derivatives thereof. The invention is also directed to shaped articles, especially extruded films, made from such compositions. Examples of such extruded films are image-receiving layers for use in an image-recording element.
摘要翻译：本发明涉及一种包含聚酯共聚物的组合物，其包含（a）重复的二元酸衍生单元和多元醇衍生的单元，至少50摩尔％的二元酸衍生单元包含各自含有脂环族的二羧酸衍生单元，（b） 25〜75摩尔％的多元醇衍生单元，其含有不与相应多元醇的各羟基紧邻的芳环，（c）25〜75摩尔％的多元醇衍生的聚酯单元为非芳香族，（d ）至少0.1摩尔％，总计来自具有多于两个羟基的多官能多元醇和/或衍生自具有多于两个羧酸基团的多酸的单元及其衍生物的单元。本发明还涉及由这种组合物制成的成型制品，特别是挤压薄膜。这种挤出膜的实例是用于图像记录元件的图像接收层。

3. 发明授权

US07005406B2 Image-recording element comprising polyester-containing image-receiving layer 有权
标题翻译：图像记录元件包括含聚酯的图像接收层
公开(公告)号：US07005406B2
公开(公告)日：2006-02-28
申请号：US10375512
申请日：2003-02-26
申请人： Teh-Ming Kung , Paul D. Yacobucci , Eric E. Arrington
发明人： Teh-Ming Kung , Paul D. Yacobucci , Eric E. Arrington
IPC分类号： B41M5/035 , B41M5/38
CPC分类号： B41M5/5272 , Y10T428/24802 , Y10T428/31786
摘要： The present invention relates to an image recording element comprising a support having on one side thereof an image-receiving layer, wherein the image-receiving layer comprises a polyester comprising (a) recurring dibasic acid derived units and polyol derived units, at least 50 mole % of the dibasic acid derived units comprising dicarboxylic acid derived units each containing an alicyclic ring comprising 4 to 10 ring carbon atoms, which ring is within two carbon atoms of each carboxyl group of the corresponding dicarboxylic acid, (b) 25 to 75 mole % of the polyol derived units containing an aromatic ring not immediately adjacent to each hydroxyl group of the corresponding polyol; and (c) 25 to 75 mole % of the polyol derived units of the polyester contain an alicyclic ring comprising 4 to 10 ring carbon atoms. Image recording elements of the invention are especially useful for thermal dye transfer printing or electrophotographic printing of images with dyes, pigments, or toner materials.
摘要翻译：图像记录元件本发明涉及一种图像记录元件，其包括一个支撑体，其一侧具有图像接收层，其中该图像接受层包括一个聚酯，该聚酯包含（a）重复的二元酸衍生单元和多元醇衍生的单元，至少50摩尔％的二元酸衍生单元，其包含二羧酸衍生的单元，其各自含有环碳原子数为4〜10个的脂环，该环为相应二羧酸的各羧基的2个碳原子，（b）25〜75摩尔％的多元醇衍生单元，其含有不与相应多元醇的每个羟基紧邻的芳族环; 和（c）聚酯的多元醇衍生单元的25〜75摩尔％含有包含4〜10个环碳原子的脂环。本发明的图像记录元件对于具有染料，颜料或调色剂材料的图像的热染料转印或电子照相特别有用。

4. 发明授权

US06893592B2 Process of making an image recording element with an extruded polyester-containing image-receiving layer 有权
标题翻译：用挤出的含聚酯的图像接收层制造图像记录元件的方法
公开(公告)号：US06893592B2
公开(公告)日：2005-05-17
申请号：US10376187
申请日：2003-02-26
申请人： Eric E. Arrington , Teh-Ming Kung , Paul D. Yacobucci
发明人： Eric E. Arrington , Teh-Ming Kung , Paul D. Yacobucci
IPC分类号： B41M5/382 , B41M5/50 , B41M5/52 , G03G7/00 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5272
摘要： The invention relates to a process of making an image-recording element comprising a support having thereon an image-receiving layer, wherein the process comprises forming a melt of a polyester material, extruding the melt, and applying the extruded melt to the support for the image-receiving element. The polyester material used for the extruded melt comprises a polyester comprising recurring dibasic acid derived units and polyol derived units, at least 50 mole % of the dibasic acid derived units comprising dicarboxylic acid derived units containing an alicyclic ring, and at least 30 mole % of the polyol derived units containing an aromatic ring not immediately adjacent to each hydroxyl group of the corresponding polyol, 25 to 75 mole % of the polyol derived units of the polyester are non-aromatic, and at least 0.5 mole percent of a multifunctional polyol having more than two hydroxy groups and/or a polyacid having more than two carboxylic acid groups, including derivatives thereof, based on the total acid derived units.
摘要翻译：本发明涉及一种制造图像记录元件的方法，该图像记录元件包括其上具有图像接收层的支撑件，其中该方法包括形成聚酯材料的熔体，挤出熔体，并将挤出的熔体施加到支撑体上图像接收元件。用于挤出熔融物的聚酯材料包括含有重复二元酸衍生单元和多元醇衍生单元的聚酯，至少50摩尔％的含二羧酸衍生单元的二元酸衍生单元含有脂环族环烯烃，和至少30摩尔％含有不与相应多元醇的每个羟基紧邻的芳环的多元醇衍生单元，25至75摩尔％的多元醇衍生的聚酯单元是非芳族的，并且至少0.5摩尔％的多官能多元醇具有更多相对于两个羟基和/或具有多于两个羧酸基团的多酸，包括其衍生物，基于总酸衍生单元。

5. 发明授权

US06939828B2 Thermal dye-transfer receiver element comprising a silicone release agent in the dye-image receiving layer 有权
标题翻译：在染料影像接收层中包含有机硅脱模剂的热染料转移接收元件
公开(公告)号：US06939828B2
公开(公告)日：2005-09-06
申请号：US10376186
申请日：2003-02-26
申请人： Eric E. Arrington , Brett Z. Blaisdell
发明人： Eric E. Arrington , Brett Z. Blaisdell
IPC分类号： B41M5/382 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/529
摘要： A dye-receiver element for thermal dye transfer includes a support having on one side thereof a dye image-receiving layer characterized in that a release agent is present in the dye-image receiving layer which release agent comprises a siloxane-containing polymer having a weight average molecular weight of at least 150,000 and a viscosity in the range of 10 million mm2/sec to 50 million mm2/second. The invention also relates to a process of making a dye-receiver element for thermal dye transfer from a dye-donor element, said dye-receiver element comprising a support having thereon a dye image-receiving layer made by a process comprising forming a melt of a thermoplastic material comprising the release agent, extruding or coextruding the melt as a single-layer film or a layer of a composite (multilayer) film; and applying the extruded film or composite film to a support for the dye-receiver element. The use of such a release agent provides improved non-sticking and improved image quality compared to other release agents.
摘要翻译：用于热染料转移的染料接受元件包括在其一侧上具有染料影像接收层的支持体，其特征在于，在染料 - 影像接收层中存在脱模剂，该脱模剂包含具有重量的含硅氧烷聚合物平均分子量至少为150,000，粘度为1000万mm 2 /秒至5000万mm 2 /秒。本发明还涉及一种制备用于从染料供体元件转移热染料的染料接收元件的方法，所述染料 - 受体元件包括其上具有染料影像接收层的载体，该染料影像接收层通过以下工艺制备：包含脱模剂的热塑性材料，将熔体挤出或共挤出为单层膜或复合（多层）膜的层; 以及将挤出的膜或复合膜施加到染料接受元件的载体上。与其它脱模剂相比，这种脱模剂的使用提供了改进的不粘附和改善的图像质量。

6. 发明授权

US5824463A Method to increase the production rate of photographic paper through application of ozone 失效
标题翻译：通过施加臭氧来提高相纸生产率的方法
公开(公告)号：US5824463A
公开(公告)日：1998-10-20
申请号：US823527
申请日：1997-03-24
申请人： Eric E. Arrington
发明人： Eric E. Arrington
IPC分类号： G03C1/79 , G03C1/91 , G03C1/795 , G03C1/775
CPC分类号： G03C1/79 , G03C1/915 , Y10S430/136
摘要： This invention describes a method for manufacturing a photographic support which includes providing a support and laminating a surface of the support with a polymer resin formulation containing from 0.001 to 1 weight percent antioxidant at a temperature of from 305.degree. to 360.degree. C. while exposing the polymer resin formulation to an ozone containing gas at a rate of greater than 0.1 mg/m.sup.2 of said support.
摘要翻译：本发明描述了一种用于制造照相支持体的方法，该方法包括提供载体并将载体的表面与含有0.001至1重量％抗氧化剂的聚合物树脂制剂在305至360℃的温度下进行层压，聚合物树脂制剂以大于0.1mg / m 2的速率加入到含臭氧气体中。

7. 发明授权

US5633041A Method of making photographic paper 失效
标题翻译：制作相纸的方法
公开(公告)号：US5633041A
公开(公告)日：1997-05-27
申请号：US644558
申请日：1996-05-10
申请人： Eric E. Arrington
发明人： Eric E. Arrington
IPC分类号： D21H19/20 , D21H19/22 , D21H19/24 , D21H23/48 , D21H25/06 , G03C1/79 , B05D3/00
CPC分类号： D21H25/06 , G03C1/79 , D21H19/20 , D21H19/22 , D21H19/24 , D21H23/48 , Y10S118/04
摘要： The invention provides a method of making thermoplastic resin-coated paper which comprises coating a paper sheet with a liquid thermoplastic resin, passing the thermoplastic resin-coated paper sheet through a nip of a pressure roll and a thermally conductive medium to form a resin-medium interface, heating the interface to a temperature of from 35.degree. C. to 350.degree. C. for a nip time period of from 0.002 to 10 seconds and a pressure of from 17,500 to 1,750,000 Pa-m, cooling the interface to a temperature of -73.degree. to 32.degree. C. for a cooling time period of from 0.001 to 100 seconds, and separating the thermoplastic resin-coated paper from the medium.
摘要翻译：本发明提供一种制造热塑性树脂涂布纸的方法，其包括用液态热塑性树脂涂布纸张，使热塑性树脂涂布的纸张通过压辊和导热介质的辊隙，形成树脂介质界面，将界面加热至35℃至350℃的温度，压区时间为0.002至10秒，压力为17,500至1,750,000Pa-m，将界面冷却至 - 73℃至32℃，冷却时间为0.001至100秒，并将热塑性树脂涂布纸与介质分离。

8. 发明授权

US07189299B2 Thermal-dye-transfer label capable of reproducing flesh tones 有权
标题翻译：能够再现肉色调的热染料转印标签
公开(公告)号：US07189299B2
公开(公告)日：2007-03-13
申请号：US10602839
申请日：2003-06-24
申请人： Thomas M. Laney , Eric E. Arrington , Robert P. Bourdelais
发明人： Thomas M. Laney , Eric E. Arrington , Robert P. Bourdelais
IPC分类号： B32B31/18
CPC分类号： B31D1/021 , B32B37/153 , B32B38/145 , B32B2038/0028 , B32B2305/30 , B32B2519/00 , Y10T156/1067
摘要： Processes for making a pragmatic label, a receiver sheet for making such a pragmatic label, and intermediates thereof are described. The receiver sheet comprises a pragmatic pre-label sheet, a lower strippable carrier, a pressure-sensitive adhesive layer between said lower strippable carrier and the pragmatic pre-label sheet. The pragmatic pre-label sheet is made by coextruding a first melt for a polymeric image-receiving layer with one or more other melts for forming a single-layer or multiple-layer pragmatic polymer sheet, wherein said other melts includes a second melt comprising an orientable thermoplastic polymeric material for forming a microvoided layer, said coextruded melts forming a multilayer composite film that is subsequently subjected to stretching. The pragmatic labels and receiver sheets of the present invention can advantageously be made without the use of solvent coating.
摘要翻译：描述了制作实用标签的过程，制作这样一个实用标签的接收片及其中间体。接收片包括实用的预标签片，下可剥离载体，在所述下可剥离载体和实际预标签片之间的压敏粘合剂层。通过用用于形成单层或多层实用聚合物片的一种或多种其它熔体共挤出用于聚合物图像接收层的第一熔体来制备实用的预标签片，其中所述其它熔体包括第二熔体，其包含用于形成微空隙层的可取向的热塑性聚合物材料，所述共挤出的熔体形成随后进行拉伸的多层复合膜。本发明的实用标签和接收片可以有利地在不使用溶剂涂层的情况下制成。

9. 发明授权

US06897183B2 Process for making image recording element comprising an antistat tie layer under the image-receiving layer 失效
标题翻译：用于制造图像记录元件的方法，该图像记录元件包括在图像接收层下方的抗静电连接层
公开(公告)号：US06897183B2
公开(公告)日：2005-05-24
申请号：US10375744
申请日：2003-02-26
申请人： Eric E. Arrington , Thomas M. Laney
发明人： Eric E. Arrington , Thomas M. Laney
IPC分类号： G03G7/00 , B29C47/06 , B29C47/82 , B29C47/84 , B32B27/08 , B32B27/28 , B41M5/00 , B41M5/382 , B41M5/42 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/42 , B29C47/0021 , B29C47/065 , B29C47/145 , B29C47/82 , B29C47/84 , B32B27/08 , B32B27/28 , B32B37/153 , B32B38/0012 , B32B2038/0028 , B32B2307/21 , B32B2307/75 , B41M5/52 , B41M5/5272 , B41M2205/02 , B41M2205/32 , G03G7/0046 , G03G7/008
摘要： This invention relates to a process for making an image-recording element, for example a dye-receiving element for thermal dye transfer, that includes a support having on one side thereof a image-receiving layer and, between the image-receiving layer and the support, a tie layer comprising a thermoplastic antistat polymer. In one embodiment, the process comprises (a) forming a first melt of a polymer for the surface layer and a second melt comprising a thermoplastic antistat polymer in a polymeric binder; (b) coextruding the two melts onto a polyolefin support; (c) stretching the coextruded layers to reduce the thickness; and (d) applying the coextruded melts to a support while simultaneously reducing the temperature below the Tg of the composition of the surface layer.
摘要翻译：本发明涉及一种用于制造图像记录元件（例如用于热染料转移的染料接收元件）的方法，其包括在其一侧具有图像接收层的支撑体，以及在图像接收层和支撑体，包含热塑性抗静电聚合物的粘结层。在一个实施方案中，该方法包括（a）形成用于表面层的聚合物的第一熔体和在聚合物粘合剂中包含热塑性抗静电聚合物的第二熔体; （b）将两种熔体共挤出到聚烯烃载体上; （c）拉伸共挤出层以减小厚度; 和（d）将共挤出的熔体施加到载体上同时将温度降低到表面层组合物的Tg以下。

10. 发明授权

US06475696B2 Imaging elements with nanocomposite containing supports 有权
标题翻译：具有纳米复合材料的成像元件
公开(公告)号：US06475696B2
公开(公告)日：2002-11-05
申请号：US09751192
申请日：2000-12-28
申请人： Debasis Majumdar , Narasimharao Dontula , Dennis J. Massa , Thomas N. Blanton , Jose L. Garcia , Eric E. Arrington , Thaddeus S. Gula
发明人： Debasis Majumdar , Narasimharao Dontula , Dennis J. Massa , Thomas N. Blanton , Jose L. Garcia , Eric E. Arrington , Thaddeus S. Gula
IPC分类号： G03C1765
CPC分类号： G03C1/795 , G03C1/79
摘要： The invention relates to an imaging member comprising an image layer and a support comprising at least one layer comprising an inorganic particle having an aspect ratio of at least 10 to 1, a lateral dimension of between 0.01 &mgr;m and 5 &mgr;m, and a vertical dimension between 0. 5 nm and 10 nm, and polymeric resin.
摘要翻译：本发明涉及一种成像构件，其包括图像层和支撑体，该支撑体包括至少一层，该层包含长宽比为至少10:1，横向尺寸为0.01μm和5μm之间的无机颗粒，以及垂直尺寸为 0.5nm和10nm，以及聚合树脂。

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