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    • 4. 发明授权
    • Method of producing dimethyl ether
    • 生产二甲醚的方法
    • US5389689A
    • 1995-02-14
    • US87757
    • 1993-09-09
    • Kaoru FujimotoTsutomu ShikadaYojiro YamaokaTakashi Sumigama
    • Kaoru FujimotoTsutomu ShikadaYojiro YamaokaTakashi Sumigama
    • C07C41/01
    • C07C41/01
    • In a method of producing dimethyl ether from a mixed gas containing carbon monoxide and either or both of hydrogen and water vapor or a mixed gas of them further containing carbon dioxide, the improvement which comprises using a mixed catalyst prepared by pulverizing a mixed catalyst containing at least zinc oxide, copper oxide or chrominum oxide, and aluminum oxide, compressing to bind them by a high pressure press and then pulverizing again or a mixed catalyst comprising at least zinc oxide, copper oxide and alumina, in a slurry state formed by suspending in a solvent. In the method of the invention, the yield of dimethyl ether is high, and the conversion water produced through reaction to hydrogen is high. There is no problem of clogging with catalyst, and mechanical strength is not required. Besides, the applicable range of the ratio of carbon monoxide and hydrogen is wide and the reaction is possible in the presence of carbon dioxide in a high concentration. Moreover, affects by impurities and catalyst poisons are small.
    • PCT No.PCT / JP92 / 01467 Sec。 371日期:1993年9月9日 102(e)1993年9月9日PCT 1993年7月9日PCT公布。 WO93 / 10069 PCT出版物 日期:1993年5月27日。在从含有一氧化碳和氢气和水蒸气中的任一种或两者的混合气体中制备二甲醚的方法或其还含有二氧化碳的混合气体的方法中,包括使用由 粉碎至少包含氧化锌,氧化铜或氧化铬的氧化铝和氧化铝的混合催化剂,通过高压压缩压缩以使其结合,然后再次粉碎或至少包含氧化锌,氧化铜和氧化铝的混合催化剂, 通过悬浮在溶剂中形成淤浆状态。 在本发明的方法中,二甲醚的收率高,通过与氢反应生成的转化水高。 催化剂没有堵塞的问题,不需要机械强度。 此外,一氧化碳和氢气的比例的适用范围宽,并且在高浓度的二氧化碳存在下可以进行反应。 此外,杂质和催化剂毒物的影响也很小。
    • 6. 发明授权
    • Method of producing dimethyl ether
    • 生产二甲醚的方法
    • US5466720A
    • 1995-11-14
    • US321521
    • 1994-10-12
    • Kaoru FujimotoTsutomu ShikadaYojiro YamaokaTakashi Sumigama
    • Kaoru FujimotoTsutomu ShikadaYojiro YamaokaTakashi Sumigama
    • C07C41/01
    • C07C41/01
    • In a method of producing dimethyl ether from a mixed gas containing carbon monoxide and either or both of hydrogen and water vapor or a mixed gas of them further containing carbon dioxide, the improvement which comprises using a mixed catalyst prepared by pulverizing a mixed catalyst containing at least zinc oxide, copper oxide or chromium oxide, and aluminum oxide, compressing to bind them by a high pressure press and then pulverizing again or a mixed catalyst comprising at least zinc oxide, copper oxide and alumina, in a slurry state formed by suspending in a solvent. In the method of the invention, the yield of dimethyl ether is high, and the conversion water produced through reaction to hydrogen is high. There is no problem of clogging with catalyst, and mechanical strength is not required. Besides, the applicable range of the ratio of carbon monoxide and hydrogen is wide and the reaction is possible in the presence of carbon dioxide in a high concentration. Moreover, affects by impurities and catalyst poisons are small.
    • 在从含有一氧化碳和氢气和水蒸气中的一种或两种的混合气体中制备二甲醚的方法或其还含有二氧化碳的混合气体的方法中,包括使用通过粉碎含有 最小氧化锌,氧化铜或氧化铬和氧化铝,通过高压压缩机压缩以使其结合,然后再次粉碎,或者将至少包含氧化锌,氧化铜和氧化铝的混合催化剂以悬浮状态形成, 溶剂。 在本发明的方法中,二甲醚的收率高,通过与氢反应生成的转化水高。 催化剂没有堵塞的问题,不需要机械强度。 此外,一氧化碳和氢气的比例的适用范围宽,并且在高浓度的二氧化碳存在下可以进行反应。 此外,杂质和催化剂毒物的影响也很小。