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    • 3. 发明申请
    • POLYALKYLENE GLYCOL CHAIN-CONTAINING THIOL POLYMER, THIOL-MODIFIED MONOMER, MIXTURE THEREOF, AND ADMIXTURE FOR CEMENT
    • 聚乙烯甘油链含硫醇聚合物,硫醇改性单体,其混合物和水泥混合物
    • US20120208949A1
    • 2012-08-16
    • US13451997
    • 2012-04-20
    • Noboru SakamotoTsutomu Yuasa
    • Noboru SakamotoTsutomu Yuasa
    • C08L33/02C07C57/03C08F222/02
    • C08F2/38C04B24/165C04B2103/408C08F290/06C08F290/062C08F290/14C08G65/329C08G65/332C08G65/334
    • To provide a polyalkylene glycol chain-containing thiol polymer which is excellent in various performances, particularly significantly excellent in cement dispersibility, and useful in various applications such as an admixture for cement; a thiol-modified monomer or mixture thereof, which can produce such polymer; production methods of the polymer and the monomer; and a dispersant and an admixture for cement, each including the polymer. The polyalkylene glycol chain-containing thiol polymer is a polyalkylene glycol chain-containing thiol polymer, wherein the polymer comprises a polyalkylene glycol chain and a polymer segment bonded to at least one end of the polyalkylene glycol chain with a sulfur atom-containing group therebetween, the polymer segment includes a constitutional unit derived from an unsaturated monomer component, and the unsaturated monomer component includes an unsaturated carboxylic acid monomer and an unsaturated polyalkylene glycol monomer.
    • 提供具有优异的各种性能的聚亚烷基二醇链硫醇聚合物,特别是在水泥分散性方面特别显着优异,并且可用于各种应用如水泥混合物; 可以生产这种聚合物的硫醇改性单体或其混合物; 聚合物和单体的生产方法; 和用于水泥的分散剂和混合物,各自包括聚合物。 含聚亚烷基二醇链的硫醇聚合物是含聚亚烷基二醇链的硫醇聚合物,其中聚合物包含聚亚烷基二醇链和聚合亚烷基二醇链的至少一端与其中含硫原子的基团结合的聚合物链段, 聚合物链段包括衍生自不饱和单体组分的结构单元,不饱和单体组分包括不饱和羧酸单体和不饱和聚亚烷基二醇单体。
    • 5. 发明授权
    • Polymer and cement admixture using the same
    • 聚合物和水泥外加剂使用它们
    • US07851576B2
    • 2010-12-14
    • US11527457
    • 2006-09-27
    • Tsutomu YuasaNoboru SakamotoYuko Matsuda
    • Tsutomu YuasaNoboru SakamotoYuko Matsuda
    • C08F20/06C08F20/02C08J3/00
    • C08F220/06C04B24/2647C04B40/0039C04B2103/408C08F220/28C08F290/062C08F293/00C08F293/005C08L53/00C08L2205/02C04B24/32C04B24/2658C08L2666/24
    • The present invention provides a novel polymer, and a mixture and a cement admixture thereof. The cement admixture has higher dispersibility compared to the previous ones. The novel polymer of the present invention has a different structure from the conventional copolymers used for cement admixtures, using an unsaturated carboxylic acid monomer and an unsaturated polyalkylene glycol monomer as the monomer components.The novel polymer of the present invention basically contains a polyalkylene glycol chain and a polymer segment bonded to the chain. Another type of the novel polymer of the present invention contains two polyalkylene glycol chains and a polymer segment connecting the chains. In these polymers, at least one of unsaturated monomers constituting the polymer segment is an unsaturated carboxylic acid monomer or an unsaturated polyalkylene glycol monomer. The cement admixture of the present invention comprises a polymer, made from these monomers, or a mixture thereof.
    • 本发明提供了一种新型聚合物及其混合物和水泥混合物。 水泥外加剂与以往相比具有较高的分散性。 本发明的新型聚合物与使用不饱和羧酸单体和不饱和聚亚烷基二醇单体作为单体组分的用于水泥混合物的常规共聚物具有不同的结构。 本发明的新型聚合物基本上含有聚亚烷基二醇链和与该链连接的聚合物链段。 本发明的新型聚合物的另一种类型包含两个聚亚烷基二醇链和连接链的聚合物链段。 在这些聚合物中,构成聚合物链段的至少一种不饱和单体是不饱和羧酸单体或不饱和聚亚烷基二醇单体。 本发明的水泥混合物包含由这些单体制成的聚合物或其混合物。
    • 7. 发明申请
    • MULTI-BRANCHED POLYALKYLENE GLYCOL POLYMER, METHOD FOR PRODUCING THE SAME, AND ADMIXTURE FOR CEMENT
    • 多分支聚乙烯甘油聚合物,其生产方法和水泥混合物
    • US20110160393A1
    • 2011-06-30
    • US13063300
    • 2009-09-08
    • Noboru SakamotoTsutomu Yuasa
    • Noboru SakamotoTsutomu Yuasa
    • C04B16/04C08F283/06C07C321/04
    • C04B24/166C04B24/32C04B2103/408C08F283/06C08F290/00C08F290/062C08G65/332C08G65/3322C08G65/334C08L71/02C08L2205/00
    • The present invention provides a multi-branched polyalkylene glycol polymer useful for various applications, especially for an admixture for cement, a dispersant, admixture for cement, and cement composition each comprising the same, a thiol compound having a polyalkylene glycol chain useful for materials and the like of the polymer, and a method for easily and effectively producing the multi-branched polyalkylene glycol polymer and the thiol compound having a polyalkylene glycol chain at low cost. The multi-branched polymer comprises: a polyalkylene glycol chain; a residue of a compound having three or more active hydrogen atoms; and a polymer portion having a constitutional unit derived from a vinyl monomer component, one end of the polyalkylene glycol chain bonding to the residue, and a terminal oxygen atom of at least one of the other ends of the polyalkylene glycol chain bonding to a main chain end of the polymer portion directly or via an organic residue.
    • 本发明提供了可用于各种用途的多支链聚亚烷基二醇聚合物,特别是用于水泥的混合物,分散剂,水泥混合物和各自包含它们的水泥组合物,具有聚亚烷基二醇链的硫醇化合物,其用于材料和 聚合物的类似物,以及低成本地容易且有效地制备多支链聚亚烷基二醇聚合物和具有聚亚烷基二醇链的硫醇化合物的方法。 多支链聚合物包括:聚亚烷基二醇链; 具有三个或更多个活性氢原子的化合物的残基; 和具有源自乙烯基单体成分的结构单元的聚合物部分,与残基键合的聚亚烷基二醇链的一端和与主链结合的聚亚烷基二醇链的至少一个末端的末端氧原子 直接或通过有机残余物的聚合物部分的末端。
    • 8. 发明申请
    • METHOD FOR PRODUCING POLYCARBOXYLIC ACID COPOLYMER AND COPOLYMER COMPOSITION FOR CEMENT ADMIXTURE
    • 生产聚碳酸酯共聚物的方法和水泥混合物的共聚物组合物
    • US20110065847A1
    • 2011-03-17
    • US12992502
    • 2009-05-08
    • Hiroshi KawabataNoboru Sakamoto
    • Hiroshi KawabataNoboru Sakamoto
    • C08K5/42C08F20/06
    • C04B24/165C04B24/2647C04B2103/408C04B2111/62C08F4/40C08F216/1416C08F220/06C08F283/06C09D4/00
    • Provided is a production method for a polycarboxylic acid-based copolymer including a structural unit derived from an unsaturated polyalkylene glycol ether-based monomer and a structural unit derived from an unsaturated carboxylic acid-based monomer, by which the production cost of the copolymer is reduced and an unprecedentedly high-performance cement admixture can be provided. Also provided is a copolymer composition for a cement admixture, including a structural unit derived from an unsaturated polyalkylene glycol ether-based monomer and a structural unit derived from an unsaturated carboxylic acid-based monomer, with which an unprecedentedly high-performance cement admixture can be provided. The production method for a polycarboxylic acid-based copolymer of the present invention is a production method for a polycarboxylic acid-based copolymer including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), in which monomer components including the monomer (a) and the monomer (b) are polymerized using a peroxide and a reductant as polymerization initiators in combination while the pH during polymerization is controlled to 3 or less in the presence of a pH adjustor. The copolymer composition for a cement admixture of the present invention includes a polycarboxylic acid-based copolymer including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), and a nonpolymerizable organic sulfonic acid having a molecular weight of 300 or less and/or a salt thereof.
    • 提供一种包含来自不饱和聚亚烷基二醇醚类单体的结构单元和来自不饱和羧酸系单体的结构单元的多元羧酸系共聚物的制造方法,共聚物的制造成本降低 并且可以提供前所未有的高性能水泥外加剂。 还提供了一种用于水泥混合物的共聚物组合物,其包括衍生自不饱和聚亚烷基二醇醚基单体的结构单元和衍生自不饱和羧酸基单体的结构单元,其前所未有的高性能水泥掺合物可以 提供。 本发明的聚羧酸类共聚物的制造方法是包含来自不饱和聚亚烷基二醇醚系单体(a)的结构单元(I)和结构单元(a)的多元羧酸系共聚物的制造方法, II),其中包含单体(a)和单体(b)的单体组分在使用过氧化物和还原剂作为聚合引发剂的情况下进行聚合,而聚合反应时的pH为 在pH调节剂存在下控制在3以下。 本发明的水泥混合物用共聚物组合物包括由不饱和聚亚烷基二醇醚类单体(a)衍生的结构单元(I)和不饱和羧酸衍生物的结构单元(II)的多元羧酸系共聚物 酸性单体(b)和分子量为300以下的不可聚合的有机磺酸和/或其盐。