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    • 2. 发明授权
    • Process for preparing ink jet system printing plate
    • 制备喷墨系统印版的方法
    • US06539866B1
    • 2003-04-01
    • US08888759
    • 1997-07-07
    • Sadao OsawaEiichi KatoHiroyuki OhishiKazuo Ishii
    • Sadao OsawaEiichi KatoHiroyuki OhishiKazuo Ishii
    • B41C110
    • B41C1/1066
    • A process for preparing an ink-jet system printing plate, wherein in a planographic printing plate precursor having an image receiving layer containing zinc oxide and a binder resin on a water-resistant support, the surface of the image receiving layer has a water-contact angle of 50° or more, and image formation is carried out according to a hot melt type ink-jet system by heat melting an ink composition that is solid at ordinary temperature and spraying the droplets of the ink composition in a heat melt state from a nozzle onto the image receiving layer, and a nonimage area of the image receiving layer is then subjected to a desensitizing treatment by a chemical reaction to prepare a planographic printing plate.
    • 一种制备喷墨系统印版的方法,其中在具有含有氧化锌和粘合剂树脂的图像接收层的平版印刷版原版中,在耐水载体上,图像接收层的表面具有水接触 角度为50°以上,根据热熔型喷墨系统,通过对常温下为固体的油墨组合物进行加热熔融,并从喷嘴喷射加热熔融状态的油墨组合物的液滴,进行图像形成 然后对图像接收层的非图像区域进行化学反应的脱敏处理以制备平版印刷版。
    • 3. 发明授权
    • Oil-based ink for preparing printing plate by ink jet process and method for preparing printing plate by ink jet process
    • 通过喷墨法制备印版的油性油墨和通过喷墨法制备印版的方法
    • US06184267B2
    • 2001-02-06
    • US09009692
    • 1998-01-20
    • Eiichi KatoSadao OsawaKazuo Ishii
    • Eiichi KatoSadao OsawaKazuo Ishii
    • C09D1102
    • C09D11/36G03G13/28G03G13/283
    • An oil-based ink for a printing plate by an ink jet process comprising spraying an oil-based ink comprising at least resin particles dispersed in a nonaqueous carrier liquid having an electric resistance of 109 &OHgr;cm or more and a dielectric constant of 3.5 or less on a water-resistant support having a lithographically printable hydrophilic surface to dropwise from a nozzle form an image, wherein the resin particles dispersed are polymer particles obtained by polymerization granulation of a solution comprising (i), (ii) and (iii): (i) at least one monofunctional monomer (A) which is soluble in a nonaqueous solvent which is at least miscible with the nonaqueous carrier liquid and becomes insoluble therein by polymerization; (ii) (ii-a) at least one monomer (B) which is copolymerizable with the monomer (A), or (ii-b) at least one monofunctional macromonomer (MA) having a weight average molecular weight of 2×104 or less in which a polymerizable double bond group is combined with only one end of a main chain of a polymer comprising a repeating unit corresponding to a monomer; and (iii) at least one resin for dispersion stabilization (P) which is a polymer comprising a repeating unit and is soluble in the nonaqueous solvent, the polymer being crosslinked at a part of its main chain thereof, and a method for preparing a printing plate by an ink jet process using the ink.
    • 一种喷墨方法的印刷用油性油墨,其特征在于,喷涂含有至少分散在电阻为10 9Ω·cm以上且介电常数为3.5以下的非水性载体液中的树脂颗粒的油性油墨, 具有可喷墨亲水表面的防水支撑体从喷嘴形成图像,其中分散的树脂颗粒是通过聚合造粒包含(i),(ii)和(iii)的溶液获得的聚合物颗粒:(i )至少一种单官能单体(A),其可溶于非水溶剂中,所述非水溶剂至少与非水性载体液体可混溶并通过聚合而不溶于其中; (ii)(ii-a)至少一种可与单体(A)共聚的单体(B)或(ii-b)至少一种重均分子量为2x104或更小的单官能大分子单体(MA) 其中可聚合双键基团仅与包含对应于单体的重复单元的聚合物主链的一端结合; 和(iii)至少一种用于分散稳定化的树脂(P),其是包含重复单元并且可溶于非水溶剂的聚合物,该聚合物在其主链的一部分被交联,以及制备印刷的方法 通过使用该油墨的喷墨处理来进行印版。
    • 4. 发明授权
    • Method for preparation of printing plate by electrophotographic process
    • 通过电子照相法制备印版的方法
    • US5620822A
    • 1997-04-15
    • US262029
    • 1994-06-17
    • Eiichi KatoYusuke NakazawaSadao Osawa
    • Eiichi KatoYusuke NakazawaSadao Osawa
    • G03G13/28G03G13/22
    • G03G13/28
    • A method for preparation of a printing plate by an electrophotographic process comprising forming a peelable transfer layer mainly containing a resin (A) capable of being removed upon a chemical reaction treatment on the surface of an electrophotographic light-sensitive element, forming a toner image on the transfer layer by an electrophotographic process, heat-transferring the toner image together with the transfer layer onto a receiving material a surface of which is capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, and removing the transfer layer on the receiving material upon the chemical reaction treatment, wherein prior to or simultaneously with the formation of transfer layer a compound (S) which contains a fluorine atom and/or silicon atom is applied to the surface of electrophotographic light-sensitive element to improve releasability of the surface of electrophotographic light-sensitive element.The method continuously provides printing plates excellent in image qualities in a stable manner and is suitable for a scanning exposure system using a laser beam.An apparatus suitable for performing the present method is also disclosed.
    • 一种通过电子照相方法制备印版的方法,包括形成主要包含在电子照相感光元件的表面上进行化学反应处理能够除去的树脂(A)的可剥离转印层,形成调色剂图像 通过电子照相方法将转印层与转印层一起热转印到其表面上的能够提供适合于印刷时的平版印刷的亲水表面的接收材料上,并且将转印层除去 在化学反应处理时的接收材料,其中在形成转移层之前或同时形成含有氟原子和/或硅原子的化合物(S)施加到电子照相感光元件的表面上,以提高 电子照相感光元件的表面。 该方法以稳定的方式连续提供图像质量优异的印刷版,并且适用于使用激光束的扫描曝光系统。 还公开了适用于执行本方法的装置。
    • 6. 发明授权
    • Oil-based ink for preparing printing plate by ink jet process and method for preparing printing plate by ink jet process
    • 通过喷墨法制备印版的油性油墨和通过喷墨法制备印版的方法
    • US06197847B1
    • 2001-03-06
    • US09009131
    • 1998-01-20
    • Eiichi KatoSadao OsawaKazuo Ishii
    • Eiichi KatoSadao OsawaKazuo Ishii
    • G09D1102
    • G03G13/286G03G13/28G03G13/283
    • An oil-based ink for a printing plate by an ink jet process comprising spraying an oil-based ink comprising at least resin particles dispersed in a non aqueous carrier liquid having an electric resistance of 109 &OHgr;cm or more and a dielectric constant of 3.5 or less on a water-resistant support having a lithographically printable hydrophilic surface dropwise from a nozzle to form an image, wherein said resin particles dispersed are copolymer resin particles obtained by polymerization granulation of a solution comprising (i) and (ii): (i) at least one monofunctional monomer (A) which is soluble in a nonaqueous solvent which is at least miscible with the nonaqueous carrier liquid and becomes insoluble in the nonaqueous solvent by polymerization; (ii) at least one resin for dispersion stabilization (P) which is soluble in the nonaqueous solvent and is a polymer comprising a repeating unit, wherein a part of the polymer is crosslinked and a polymerizable double bond group which is copolymerizable with the monomer (A) is combined with only one end of at least one main chain of the polymer, and a method for preparing a printing plate by an ink jet process using the ink.
    • 一种喷墨法用于印版的油性油墨,其特征在于,喷涂至少含有分散在电阻为10 9Ω·cm以上,介电常数为3.5以下的非水性载体液中的树脂颗粒的油性油墨 在具有可喷墨亲水性表面的防水支撑体上从喷嘴滴落形成图像,其中所述分散的树脂颗粒是通过将包含(i)和(ii)的溶液聚合制粒得到的共聚物树脂颗粒:(i) 至少一种可溶于非水溶剂的单官能单体(A),该非水溶剂与非水载体液体至少可混溶,并通过聚合变得不溶于非水溶剂; (ii)至少一种用于分散稳定化的树脂(P),其可溶于非水溶剂,并且是包含重复单元的聚合物,其中一部分交联,和可与单体共聚的可聚合双键基团 A)仅与聚合物的至少一个主链的一端结合,以及通过使用该油墨的喷墨方法制备印刷版的方法。
    • 7. 发明授权
    • Oil-based ink for preparing printing plate by ink jet process and method
for preparing printing plate by ink jet process
    • 通过喷墨法制备印版的油性油墨和通过喷墨法制备印版的方法
    • US6143806A
    • 2000-11-07
    • US8544
    • 1998-01-16
    • Eiichi KatoSadao OsawaKazuo Ishii
    • Eiichi KatoSadao OsawaKazuo Ishii
    • C09D11/00C09D11/10C09D11/02C03G13/28
    • C09D11/106C09D11/36
    • An oil-based ink for a printing plate by an ink jet process comprising spraying an oil-based ink comprising at least resin particles dispersed in a nonaqueous carrier liquid having an electric resistance of 10.sup.9 .OMEGA.cm or more and a dielectric constant of 3.5 or less on a water-resistant support having a lithographically printable hydrophilic surface to dropwise from a nozzle form an image, wherein the resin particles dispersed are polymer particles obtained by polymerization granulation of a solution comprising (i), (ii) and (iii): (i) at least one monofunctional monomer (A) which is soluble in a nonaqueous solvent at least miscible with the nonaqueous carrier liquid and becomes insoluble therein by polymerization; (ii) (ii-a) at least one monomer (B) represented having a specific substituent copolymerizable with the monomer (A), or (ii-b) at least one specific monofunctional macromonomer (MA) having a weight average molecular weight of 2.times.10.sup.4 or less; and (iii) at least one dispersion-stabilizing resin soluble in the nonaqueous solvent and having no graft group polymerizing with a monomer, and a method for preparing a printing plate by an ink jet process using the ink.
    • 一种喷墨方法的印刷用油性油墨,其特征在于,喷涂含有至少分散在电阻为10 9Ω·cm以上,介电常数为3.5以下的非水载体液中的树脂颗粒的油性油墨 在具有由喷嘴形成的可平版印刷的亲水性表面的耐水支撑体上形成图像,其中分散的树脂颗粒是通过聚合造粒包含(i),(ii)和(iii)的溶液获得的聚合物颗粒:( i)至少一种单官能单体(A),其可溶于至少与非水性载体液体混溶并且通过聚合而不溶于其中的非水溶剂; (ii)(ii-a)表示具有可与单体(A)共聚的特定取代基的至少一种单体(B),或(ii-b)至少一种具有重均分子量的特定单官能大分子单体 2x104以下; 和(iii)至少一种可溶于非水溶剂且不与单体聚合的接枝基团的分散体稳定树脂,以及使用该油墨通过喷墨方法制备印版的方法。
    • 8. 发明授权
    • Method of preparation of electrophotographic printing plate
    • 电子照相印版的制备方法
    • US5714289A
    • 1998-02-03
    • US457604
    • 1995-06-01
    • Eiichi KatoSadao OsawaSeishi Kasai
    • Eiichi KatoSadao OsawaSeishi Kasai
    • G03G5/147G03G13/28
    • G03G13/283G03G5/14786
    • A method for preparation of an electrophotographic printing plate which can provide a printing plate excellent in image qualities of plate-making and printing, and continuously produce such printing plates in a stable manner for a long period of time and which is suitable for a scanning exposure system using a laser beam. The method comprises forming a toner image by an electrophotographic process on a peelable transfer layer of an electrophotographic light-sensitive material which comprises an electrophotographic light-sensitive element a surface of which has releasability and the peelable transfer layer provided on the surface thereof which contains a thermoplastic resin capable of being removed upon a chemical reaction treatment, thermally transferring the toner image together with the transfer layer onto a support for a lithographic printing plate and removing the thermoplastic resin upon a treatment, for example, with an aqueous alkaline solution, whereby a printing plate is obtained.
    • 一种电子照相印版的制备方法,其可以提供制版和印刷图像质量优异的印刷版,并且以长时间稳定的方式连续生产这种印版,并且适合于扫描曝光 系统使用激光束。 该方法包括通过电子照相方法在电子照相感光材料的可剥离转印层上形成调色剂图像,该电子照相感光材料的表面具有可释放性的电子照相感光元件和其表面上设置的可剥离转印层,其含有 能够在化学反应处理时被去除的热塑性树脂,将调色剂图像与转印层一起热转印到平版印刷版的载体上,并且例如用碱性水溶液处理除去热塑性树脂,由此 得到印版。
    • 9. 发明授权
    • Electrophotographic material for color proofing
    • 用于彩色打样的电子照相材料
    • US5626996A
    • 1997-05-06
    • US376630
    • 1995-01-23
    • Eiichi KatoSadao Osawa
    • Eiichi KatoSadao Osawa
    • G03F3/10G03G5/05G03G5/147G03G13/01G03G5/04
    • G03G13/01G03F3/105G03G5/0589G03G5/0592G03G5/147
    • An electrophotographic material for color proofing which comprises a substrate, a photoconductive layer and a transfer layer in this order, wherein said photoconductive layer comprises a polymer (P) which contains at least one polymer segment (X) containing not less than 50% by weight of units having fluorine atom(s) and/or silicon atom(s) and at least one polymer segment (Y) containing units having photosetting and/or thermosetting group(s); a polymer (Q) which contains units represented by the formula I--CH(a.sub.1)--C(a.sub.2)(COOR.sub.3)--wherein a.sub.1 and a.sub.2 each independently represent a hydrogen atom, and R.sub.3 represents a hydrocarbon group; and contains at least one polar group such as --PO.sub.3 H.sub.2, --SO.sub.3 H, --COOH; and a polymer (R) containing at least one unit having photo and/or thermosetting group(s),the polymer (P) is present at least in the region near the surface facing said transfer layer, andthe surface of said photoconductive layer which contacts with the transfer layer has tack strength of not more than 150 gram.multidot.force.
    • 一种用于彩色打印的电子照相材料,其依次包括基底,光电导层和转印层,其中所述光电导层包含含有至少一个含有不少于50重量%的聚合物链段(X)的聚合物(P) 的具有氟原子和/或硅原子的单元和至少一个含有具有光固化和/或热固性基团的单元的聚合物链段(Y); 含有由式I-CH(a1)-C(a2)(COOR3)表示的单元的聚合物(Q) - 其中a1和a2各自独立地表示氢原子,R3表示烃基; 并含有至少一个极性基团,例如-PO 3 H 2,-SO 3 H,-COOH; 和含有至少一个具有光和/或热固性基团的单元的聚合物(R),聚合物(P)至少存在于靠近面向所述转移层的表面的区域中,并且所述光电导层的表面 与转印层的接触粘合强度不超过150克力。
    • 10. 发明授权
    • Method of forming an electrophotographic color transfer image and
electrophotographic light-sensitive material for use therein
    • 形成用于其中的电子照相转印图像和电子照相感光材料的方法
    • US5582943A
    • 1996-12-10
    • US217060
    • 1994-03-24
    • Eiichi KatoYusuke NakazawaSadao Osawa
    • Eiichi KatoYusuke NakazawaSadao Osawa
    • G03G5/02G03G5/147G03G7/00
    • G03G5/14795G03G5/02G03G5/147G03G7/00G03G7/0093
    • A method of forming an electrophotographic color transfer image comprising forming at least one color toner image on a transfer layer provided on the surface of an electrophotographic light-sensitive element by an electrophotographic process and heat-transferring the toner image together with the transfer layer onto a receiving material wherein the surface of the electrophotographic light-sensitive element has an adhesive strength of not more than 200 gram.force, which is measured according to JIS Z 0237-1980 "Testing methods of pressure sensitive adhesive tapes and sheets" and the transfer layer mainly contains a thermoplastic resin (AH) having a glass transition point of not more than 140.degree. C. or a softening point of not more than 180.degree. C. and a thermoplastic resin (AL) having a glass transition point of not more than 45.degree. C. or a softening point of not more than 60.degree. C. in which a difference in the glass transition point or softening point between the resin (AH) and the resin (AL) is at least 2.degree. C.The method is excellent in obtaining color duplicates having good image quality without color shear and good storage stability at a low cost. An electrophotographic light-sensitive material suitable for use in the method is also described.
    • 一种形成电子照相彩色转印图像的方法,包括通过电子照相方法在设置在电子照相感光元件的表面上的转印层上形成至少一种彩色调色剂图像,并将调色剂图像与转印层一起热转印到 接收材料,其中电子照相感光元件的表面具有不超过200克力的粘合强度,其根据JIS Z 0237-1980“压敏粘合带和片材的测试方法”和转印层 主要含有玻璃化转变点不超过140℃或软化点不超过180℃的热塑性树脂(AH)和玻璃化转变点不大于45的热塑性树脂(AL) ℃或软化点不超过60℃,其中树脂(AH)和树脂之间的玻璃化转变点或软化点的差异 n(AL)至少为2℃。该方法在低颜色下获得具有良好的图像质量而无色剪切和良好储存稳定性的颜色复制品。 还描述了适用于该方法的电子照相感光材料。