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1. 发明授权

US08012553B2 Biodegradable stretch mold container having excellent heat resistance 有权
标题翻译：具有优异耐热性的可生物降解的拉伸模具容器
公开(公告)号：US08012553B2
公开(公告)日：2011-09-06
申请号：US12303004
申请日：2007-05-08
申请人： Takurou Ito , Hiroki Mori , Hiroaki Sugioka
发明人： Takurou Ito , Hiroki Mori , Hiroaki Sugioka
IPC分类号： B29D22/00 , B29D23/00 , B32B1/08
CPC分类号： B29C49/649 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14106 , B29B2911/14113 , B29B2911/14133 , B29B2911/1414 , B29B2911/14213 , B29B2911/1422 , B29C49/0005 , B29C49/12 , B29K2995/0041 , B29K2995/006 , C08J5/18 , C08J2367/04 , C08L67/04 , Y10T428/1328 , Y10T428/1331 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , C08L2666/18
摘要： A stretch mold container of the present invention is obtained by draw-forming a resin composition containing a poly-L-lactic acid (A) and a poly-D-lactic acid (B) at a molar ratio A:B in a range of 95:5 to 60:40, and has an amount of heat shrinkage of 5.0% or less under heat treatment conditions of 65° C.×24 hours. Despite of being made from the polylactic acids, the stretch mold container exhibits excellent heat resistance.
摘要翻译：通过以摩尔比A：B将含有聚-L-乳酸（A）和聚-D-乳酸（B）的树脂组合物拉伸成一定范围，得到本发明的拉伸模塑容器， 95:5〜60:40，热处理条件为65℃×24小时时的热收缩率为5.0％以下。尽管由聚乳酸制成，但拉伸模塑容器表现出优异的耐热性。

2. 发明申请

US20090186178A1 BIODEGRADABLE STRETCH MOLD CONTAINER HAVING EXCELLENT HEAT RESISTANCE 有权
标题翻译：具有优异耐热性的可生物降解的模具容器
公开(公告)号：US20090186178A1
公开(公告)日：2009-07-23
申请号：US12303004
申请日：2007-05-08
申请人： Takurou Ito , Hiroki Mori , Hiroaki Sugioka
发明人： Takurou Ito , Hiroki Mori , Hiroaki Sugioka
IPC分类号： B29D22/00 , B29C49/18
CPC分类号： B29C49/649 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14106 , B29B2911/14113 , B29B2911/14133 , B29B2911/1414 , B29B2911/14213 , B29B2911/1422 , B29C49/0005 , B29C49/12 , B29K2995/0041 , B29K2995/006 , C08J5/18 , C08J2367/04 , C08L67/04 , Y10T428/1328 , Y10T428/1331 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , C08L2666/18
摘要： A stretch mold container of the present invention is obtained by draw-forming a resin composition containing a poly-L-lactic acid (A) and a poly-D-lactic acid (B) at a molar ratio A:B in a range of 95:5 to 60:40, and has an amount of heat shrinkage of 5.0% or less under heat treatment conditions of 65° C.×24 hours. Despite of being made from the polylactic acids, the stretch mold container exhibits excellent heat resistance.
摘要翻译：通过以摩尔比A：B将含有聚-L-乳酸（A）和聚-D-乳酸（B）的树脂组合物拉伸成一定范围，得到本发明的拉伸模塑容器， 95:5〜60:40，热处理条件为65℃×24小时时的热收缩率为5.0％以下。尽管由聚乳酸制成，但拉伸模塑容器表现出优异的耐热性。

3. 发明申请

US20100200587A1 BIODEGRADABLE RESIN CONTAINER WITH A VACUUM-EVAPORATED FILM AND METHOD OF FORMING A VACUUM-EVAPORATED FILM 有权
标题翻译：具有真空蒸发膜的生物可降解树脂容器和形成真空蒸发膜的方法
公开(公告)号：US20100200587A1
公开(公告)日：2010-08-12
申请号：US12668575
申请日：2008-07-23
申请人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
IPC分类号： B65D90/02 , C23C16/511
CPC分类号： B65D23/02 , B05D1/62 , B05D7/227 , B05D7/52 , B65D65/466 , C23C16/50 , Y02W90/13
摘要： A biodegradable resin bottle having a container wall (1) including a biodegradable resin and having a vacuum-evaporated film (3) formed on the inner surface of the container wall (1) by a plasma CVD method. The vacuum-evaporated film (3) includes a first hydrocarbon vacuum-evaporated layer (3a) positioned on the inner surface of the container wall and a second hydrocarbon vacuum-evaporated layer (3b) formed on the above hydrocarbon vacuum-evaporated layer (3a). The first hydrocarbon vacuum-evaporated layer (3a) has polar groups introduced therein. The second hydrocarbon vacuum-evaporated layer (3b) exhibits hydrocarbon peaks stemming from CH, CH2 and CH3 in a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, has a CH2 ratio of not larger than 35% and a CH3 ratio of not smaller than 40% per the sum of CH, CH2 and CH3 calculated from the hydrocarbon peaks, and has no polar group introduced therein.
摘要翻译：一种具有容器壁（1）的生物降解性树脂瓶，其具有生物降解性树脂，并且通过等离子体CVD法形成在容器壁（1）的内表面上的真空蒸镀膜（3）。真空蒸发膜（3）包括位于容器壁的内表面上的第一烃真空蒸发层（3a）和形成在上述烃真空蒸发层（3a）上的第二烃真空蒸发层（3b））。第一烃真空蒸发层（3a）具有引入其中的极性基团。第二烃真空蒸发层（3b）表现出通过FT-IR测量的波数为3200至2600cm -1的区域中由CH，CH 2和CH 3产生的烃峰，其CH 2比率不大于35％并且由烃峰计算出的CH，CH 2和CH 3之和的CH 3比率不小于40％，并且没有引入极性基团。

4. 发明授权

US08950614B2 Biodegradable resin container with a vacuum-evaporated film and method of forming a vacuum-evaporated film 有权
标题翻译：具有真空蒸发膜的可生物降解树脂容器和形成真空蒸发膜的方法
公开(公告)号：US08950614B2
公开(公告)日：2015-02-10
申请号：US12668575
申请日：2008-07-23
申请人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
IPC分类号： B65D1/40 , B65D23/02 , B05D1/00 , B05D7/22 , B65D65/46 , C23C16/50 , B05D7/00
CPC分类号： B65D23/02 , B05D1/62 , B05D7/227 , B05D7/52 , B65D65/466 , C23C16/50 , Y02W90/13
摘要： A biodegradable resin bottle having a container wall (1) including a biodegradable resin and having a vacuum-evaporated film (3) formed on the inner surface of the container wall (1) by a plasma CVD method. The vacuum-evaporated film (3) includes a first hydrocarbon vacuum-evaporated layer (3a) positioned on the inner surface of the container wall and a second hydrocarbon vacuum-evaporated layer (3b) formed on the above hydrocarbon vacuum-evaporated layer (3a). The first hydrocarbon vacuum-evaporated layer (3a) has polar groups introduced therein. The second hydrocarbon vacuum-evaporated layer (3b) exhibits hydrocarbon peaks stemming from CH, CH2 and CH3 in a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, has a CH2 ratio of not larger than 35% and a CH3 ratio of not smaller than 40% per the sum of CH, CH2 and CH3 calculated from the hydrocarbon peaks, and has no polar group introduced therein.
摘要翻译：一种具有容器壁（1）的生物降解性树脂瓶，其具有生物降解性树脂，并且通过等离子体CVD法形成在容器壁（1）的内表面上的真空蒸镀膜（3）。真空蒸发膜（3）包括位于容器壁的内表面上的第一烃真空蒸发层（3a）和形成在上述烃真空蒸发层（3a）上的第二烃真空蒸发层（3b））。第一烃真空蒸发层（3a）具有引入其中的极性基团。第二烃真空蒸发层（3b）表现出通过FT-IR测量的波数为3200至2600cm -1的区域中由CH，CH 2和CH 3产生的烃峰，其CH 2比率不大于35％并且由烃峰计算出的CH，CH 2和CH 3之和的CH 3比率不小于40％，并且没有引入极性基团。

5. 发明授权

US08133562B2 Plastic formed articles having a vapor deposited film and method of producing the same 有权
标题翻译：具有蒸镀膜的塑料成形体及其制造方法
公开(公告)号：US08133562B2
公开(公告)日：2012-03-13
申请号：US12594683
申请日：2007-07-26
申请人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
IPC分类号： B29C47/00
CPC分类号： C23C16/401 , B05D1/62 , B05D7/52 , B05D2201/00 , B65D23/0814 , B65D23/0835 , C23C16/511 , Y02W90/12 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/24967 , Y10T428/265
摘要： A plastic formed article comprising a plastic substrate and a vapor deposited film formed on the surface of the plastic substrate by a plasma CVD method, wherein the vapor deposited film includes an organometal vapor deposited layer having an element ratio C/Si of 2.5 to 13 and an element ratio O/M of not larger than 0.5, and a hydrocarbon vapor deposited layer; and the hydrocarbon vapor deposited layer has a thickness in a range of 40 to 180 nm, exhibits peaks stemming from CH, CH2 and CH3 over a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, and has a CH2 ratio of not larger than 35% and a CH3 ratio of not less than 40%. A film is deposited on a plastic formed article without deteriorated by oxidation, without thermally deformed or without thermally deteriorated not only when PET or polyolefin is used but also when polylactic acid is used as the plastic substrate.
摘要翻译：一种塑料成形体，其通过等离子体CVD法在塑料基板的表面上形成塑料基板和气相沉积膜，其中，所述蒸镀膜包括元素比C / Si为2.5〜13的有机金属蒸镀层，元素比O / M不大于0.5，烃气相沉积层; 并且烃气相沉积层的厚度在40至180nm的范围内，在通过FT-IR测量的波数为3200至2600cm -1的区域上表现出来自CH，CH 2和CH 3的峰，并且具有 CH2比不大于35％，CH3比不小于40％。膜不沉积在塑料成形体上，而不会因氧化而劣化，不会发生热变形，也不会在使用聚碳酸酯时使用聚酯或聚烯烃而导致热变差。

6. 发明申请

US20100112252A1 PLASTIC FORMED ARTICLES HAVING A VAPOR DEPOSITED FILM AND METHOD OF PRODUCING THE SAME 有权
标题翻译：具有蒸发沉积膜的塑料成型制品及其制造方法
公开(公告)号：US20100112252A1
公开(公告)日：2010-05-06
申请号：US12594683
申请日：2007-07-26
申请人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
IPC分类号： B32B9/00 , B65D23/08 , C23C16/30 , C23C16/44
CPC分类号： C23C16/401 , B05D1/62 , B05D7/52 , B05D2201/00 , B65D23/0814 , B65D23/0835 , C23C16/511 , Y02W90/12 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/24967 , Y10T428/265
摘要： A plastic formed article comprising a plastic substrate and a vapor deposited film formed on the surface of the plastic substrate by a plasma CVD method, wherein the vapor deposited film includes an organometal vapor deposited layer having an element ratio C/Si of 2.5 to 13 and an element ratio O/M of not larger than 0.5, and a hydrocarbon vapor deposited layer; and the hydrocarbon vapor deposited layer has a thickness in a range of 40 to 180 nm, exhibits peaks stemming from CH, CH2 and CH3 over a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, and has a CH2 ratio of not larger than 35% and a CH3 ratio of not less than 40%. A film is deposited on a plastic formed article without deteriorated by oxidation, without thermally deformed or without thermally deteriorated not only when PET or polyolefin is used but also when polylactic acid is used as the plastic substrate.
摘要翻译：一种塑料成形体，其通过等离子体CVD法在塑料基板的表面上形成塑料基板和气相沉积膜，其中，所述蒸镀膜包括元素比C / Si为2.5〜13的有机金属蒸镀层，元素比O / M不大于0.5，烃气相沉积层; 并且烃气相沉积层的厚度在40至180nm的范围内，在通过FT-IR测量的波数为3200至2600cm -1的区域上表现出来自CH，CH 2和CH 3的峰，并且具有 CH2比不大于35％，CH3比不小于40％。膜不沉积在塑料成形体上，而不会因氧化而劣化，不会发生热变形，也不会在使用聚碳酸酯时使用聚酯或聚烯烃而导致热变差。

7. 发明授权

US5747633A Resin composition having improved mechanical properties and bio-disintegrating property and containers comprising thereof 失效
标题翻译：具有改善的机械性能和生物分解性能的树脂组合物和包含它们的容器
公开(公告)号：US5747633A
公开(公告)日：1998-05-05
申请号：US668717
申请日：1996-06-24
申请人： Takurou Ito , Yoshitsugu Maruhashi
发明人： Takurou Ito , Yoshitsugu Maruhashi
IPC分类号： B65D1/00 , B29C49/00 , B29L22/00 , B32B27/28 , B32B27/30 , B65D1/02 , B65D65/46 , C08K3/26 , C08L23/26 , C08L29/04 , C08L67/00 , C08L67/04 , C08L101/16 , C08G63/02
CPC分类号： C08L29/04 , B65D1/0207 , B65D1/0215 , B65D65/466 , C08K3/26 , C08L67/04 , B29K2995/0056 , B29K2995/006 , C08L2201/06 , Y02W90/13 , Y10T428/1352
摘要： A resin composition comprising a saturated polyester resin consisting chiefly of a hydroxyalkanoate unit, a heat-moldable hydroxyl group-containing resin having a vinyl alcohol unit, and an alkaline earth metal carbonate, a molded article composed of this resin composition and, particularly, a container and a multi-layer plastic container having an outer layer formed of this resin composition and an inner layer of a resin consisting chiefly of an ethylene-vinyl alcohol copolymer. The resin composition and the molded articles thereof exhibit not only excellent mechanical properties but also excellent bio-disintegrating property.
摘要翻译：一种树脂组合物，其包含主要由羟基链烷酸酯单元组成的饱和聚酯树脂，具有乙烯醇单元的含热可模塑羟基的树脂和碱土金属碳酸盐，由该树脂组合物组成的模制品，特别是容器和由该树脂组合物形成的外层和主要由乙烯 - 乙烯醇共聚物组成的树脂的内层的多层塑料容器。树脂组合物及其模制品不仅具有优异的机械性能，而且具有优异的生物分解性能。

8. 发明授权

US5191779A Method of producing a metallic can using a saturated branched chain containing hydrocarbon lubricant 失效
标题翻译：使用含有碳氢化合物润滑剂的饱和分支链制造金属罐的方法
公开(公告)号：US5191779A
公开(公告)日：1993-03-09
申请号：US743350
申请日：1991-08-05
申请人： Katsuhiro Imazu , Kazuhiro Sato , Takurou Ito , Shunji Kaneko , Toshio Sue
发明人： Katsuhiro Imazu , Kazuhiro Sato , Takurou Ito , Shunji Kaneko , Toshio Sue
IPC分类号： B21D22/20 , C10M177/00
CPC分类号： C10M177/00 , B21D22/201 , C10M2201/062 , C10M2201/08 , C10M2201/081 , C10M2201/082 , C10M2201/084 , C10M2201/102 , C10M2201/103 , C10M2201/105 , C10M2205/00 , C10M2205/022 , C10M2205/024 , C10M2205/14 , C10M2205/16 , C10M2205/17 , C10M2209/00 , C10M2209/02 , C10M2209/04 , C10M2209/06 , C10M2209/062 , C10M2209/084 , C10M2209/10 , C10M2209/102 , C10M2211/06 , C10M2213/02 , C10M2213/062 , C10M2217/044 , C10M2217/045 , C10N2210/02 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2250/121 , C10N2280/00
摘要： In a method of producing a metallic container by subjecting a metallic material having an organic resin coating to single-staged or multiple-staged drawing, uniformly coating a lubricant on the surface of the organic resin coating of the metallic material and draw-forming the coated material, according to the present invention, a high lubricating property is obtained at the time of drawing by using a small amount of a saturated hydrocarbon as the lubricant, and by simply heating the formed can, a major portion of the lubricant can be removed and the degreasing and washing steps or the subsequent drying step essential in the conventional method, can be omitted, with the result that the printability or the flavor-retaining property can be markedly improved, and consumption of water resource and energy resource can be reduced and a high effect of preventing environmental pollution can be attained.
摘要翻译： PCT No.PCT / JP90 / 01595 Sec。 371日期：1991年8月5日 102（e）日期1991年8月5日PCT 1990年12月6日PCT PCT。公开号WO91 / 08066 日期：1991年6月13日。在通过使具有有机树脂涂层的金属材料进行单级或多级拉伸来制造金属容器的方法中，在金属的有机树脂涂层的表面均匀地涂覆润滑剂根据本发明的材料和拉伸成型涂层材料，通过使用少量的饱和烃作为润滑剂在拉伸时获得高的润滑性，并且通过简单地加热形成的罐，将主要部分的润滑剂可以被除去，并且可以省略常规方法中必要的脱脂和洗涤步骤或随后的干燥步骤，结果是可显着提高印刷性或香味保持性，并且消耗水资源和可以减少能源，可以实现防止环境污染的高效果。

9. 发明授权

US07052752B2 Container for oxidation dye 有权
标题翻译：氧化染料容器
公开(公告)号：US07052752B2
公开(公告)日：2006-05-30
申请号：US10662507
申请日：2003-09-16
申请人： Mitsugu Iwatsubo , Yuuji Yamaguchi , Takurou Ito
发明人： Mitsugu Iwatsubo , Yuuji Yamaguchi , Takurou Ito
IPC分类号： B32B7/00 , C09K15/04
CPC分类号： B32B27/32 , B32B1/08 , B65D35/46 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/31909 , Y10T428/31938
摘要： A blow molding multilayered resin container used for holding contents containing an oxidation dye which comprises a moisture barrier layer having a water vapor transmission rate of 0.4 g·mm/(m2·d) or lower and an oxygen barrier layer having an oxygen transmission rate of 10 cm3·mm/(m2·d·MPa) or lower, the oxygen barrier layer being closer to the outside of the container than the moisture barrier layer.
摘要翻译：一种吹塑多层树脂容器，其用于容纳含有氧化染料的含量，该氧化染料含有水蒸气透过率为0.4g·mm /（m·SUP·2··SUP·d）以下的防潮层，阻氧层的氧气透过率为10cm 3·mm /（m 2·s·dm）以下，氧阻隔层越靠近容器比防潮层。

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