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1. 发明授权

US08133562B2 Plastic formed articles having a vapor deposited film and method of producing the same 有权
标题翻译：具有蒸镀膜的塑料成形体及其制造方法
公开(公告)号：US08133562B2
公开(公告)日：2012-03-13
申请号：US12594683
申请日：2007-07-26
申请人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
IPC分类号： B29C47/00
CPC分类号： C23C16/401 , B05D1/62 , B05D7/52 , B05D2201/00 , B65D23/0814 , B65D23/0835 , C23C16/511 , Y02W90/12 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/24967 , Y10T428/265
摘要： A plastic formed article comprising a plastic substrate and a vapor deposited film formed on the surface of the plastic substrate by a plasma CVD method, wherein the vapor deposited film includes an organometal vapor deposited layer having an element ratio C/Si of 2.5 to 13 and an element ratio O/M of not larger than 0.5, and a hydrocarbon vapor deposited layer; and the hydrocarbon vapor deposited layer has a thickness in a range of 40 to 180 nm, exhibits peaks stemming from CH, CH2 and CH3 over a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, and has a CH2 ratio of not larger than 35% and a CH3 ratio of not less than 40%. A film is deposited on a plastic formed article without deteriorated by oxidation, without thermally deformed or without thermally deteriorated not only when PET or polyolefin is used but also when polylactic acid is used as the plastic substrate.
摘要翻译：一种塑料成形体，其通过等离子体CVD法在塑料基板的表面上形成塑料基板和气相沉积膜，其中，所述蒸镀膜包括元素比C / Si为2.5〜13的有机金属蒸镀层，元素比O / M不大于0.5，烃气相沉积层; 并且烃气相沉积层的厚度在40至180nm的范围内，在通过FT-IR测量的波数为3200至2600cm -1的区域上表现出来自CH，CH 2和CH 3的峰，并且具有 CH2比不大于35％，CH3比不小于40％。膜不沉积在塑料成形体上，而不会因氧化而劣化，不会发生热变形，也不会在使用聚碳酸酯时使用聚酯或聚烯烃而导致热变差。

2. 发明申请

US20100112252A1 PLASTIC FORMED ARTICLES HAVING A VAPOR DEPOSITED FILM AND METHOD OF PRODUCING THE SAME 有权
标题翻译：具有蒸发沉积膜的塑料成型制品及其制造方法
公开(公告)号：US20100112252A1
公开(公告)日：2010-05-06
申请号：US12594683
申请日：2007-07-26
申请人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
IPC分类号： B32B9/00 , B65D23/08 , C23C16/30 , C23C16/44
CPC分类号： C23C16/401 , B05D1/62 , B05D7/52 , B05D2201/00 , B65D23/0814 , B65D23/0835 , C23C16/511 , Y02W90/12 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/24967 , Y10T428/265
摘要： A plastic formed article comprising a plastic substrate and a vapor deposited film formed on the surface of the plastic substrate by a plasma CVD method, wherein the vapor deposited film includes an organometal vapor deposited layer having an element ratio C/Si of 2.5 to 13 and an element ratio O/M of not larger than 0.5, and a hydrocarbon vapor deposited layer; and the hydrocarbon vapor deposited layer has a thickness in a range of 40 to 180 nm, exhibits peaks stemming from CH, CH2 and CH3 over a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, and has a CH2 ratio of not larger than 35% and a CH3 ratio of not less than 40%. A film is deposited on a plastic formed article without deteriorated by oxidation, without thermally deformed or without thermally deteriorated not only when PET or polyolefin is used but also when polylactic acid is used as the plastic substrate.
摘要翻译：一种塑料成形体，其通过等离子体CVD法在塑料基板的表面上形成塑料基板和气相沉积膜，其中，所述蒸镀膜包括元素比C / Si为2.5〜13的有机金属蒸镀层，元素比O / M不大于0.5，烃气相沉积层; 并且烃气相沉积层的厚度在40至180nm的范围内，在通过FT-IR测量的波数为3200至2600cm -1的区域上表现出来自CH，CH 2和CH 3的峰，并且具有 CH2比不大于35％，CH3比不小于40％。膜不沉积在塑料成形体上，而不会因氧化而劣化，不会发生热变形，也不会在使用聚碳酸酯时使用聚酯或聚烯烃而导致热变差。

3. 发明申请

US20100200587A1 BIODEGRADABLE RESIN CONTAINER WITH A VACUUM-EVAPORATED FILM AND METHOD OF FORMING A VACUUM-EVAPORATED FILM 有权
标题翻译：具有真空蒸发膜的生物可降解树脂容器和形成真空蒸发膜的方法
公开(公告)号：US20100200587A1
公开(公告)日：2010-08-12
申请号：US12668575
申请日：2008-07-23
申请人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
IPC分类号： B65D90/02 , C23C16/511
CPC分类号： B65D23/02 , B05D1/62 , B05D7/227 , B05D7/52 , B65D65/466 , C23C16/50 , Y02W90/13
摘要： A biodegradable resin bottle having a container wall (1) including a biodegradable resin and having a vacuum-evaporated film (3) formed on the inner surface of the container wall (1) by a plasma CVD method. The vacuum-evaporated film (3) includes a first hydrocarbon vacuum-evaporated layer (3a) positioned on the inner surface of the container wall and a second hydrocarbon vacuum-evaporated layer (3b) formed on the above hydrocarbon vacuum-evaporated layer (3a). The first hydrocarbon vacuum-evaporated layer (3a) has polar groups introduced therein. The second hydrocarbon vacuum-evaporated layer (3b) exhibits hydrocarbon peaks stemming from CH, CH2 and CH3 in a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, has a CH2 ratio of not larger than 35% and a CH3 ratio of not smaller than 40% per the sum of CH, CH2 and CH3 calculated from the hydrocarbon peaks, and has no polar group introduced therein.
摘要翻译：一种具有容器壁（1）的生物降解性树脂瓶，其具有生物降解性树脂，并且通过等离子体CVD法形成在容器壁（1）的内表面上的真空蒸镀膜（3）。真空蒸发膜（3）包括位于容器壁的内表面上的第一烃真空蒸发层（3a）和形成在上述烃真空蒸发层（3a）上的第二烃真空蒸发层（3b））。第一烃真空蒸发层（3a）具有引入其中的极性基团。第二烃真空蒸发层（3b）表现出通过FT-IR测量的波数为3200至2600cm -1的区域中由CH，CH 2和CH 3产生的烃峰，其CH 2比率不大于35％并且由烃峰计算出的CH，CH 2和CH 3之和的CH 3比率不小于40％，并且没有引入极性基团。

4. 发明授权

US08950614B2 Biodegradable resin container with a vacuum-evaporated film and method of forming a vacuum-evaporated film 有权
标题翻译：具有真空蒸发膜的可生物降解树脂容器和形成真空蒸发膜的方法
公开(公告)号：US08950614B2
公开(公告)日：2015-02-10
申请号：US12668575
申请日：2008-07-23
申请人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
发明人： Takurou Ito , Hiroki Mori , Kazuhiko Yamazaki
IPC分类号： B65D1/40 , B65D23/02 , B05D1/00 , B05D7/22 , B65D65/46 , C23C16/50 , B05D7/00
CPC分类号： B65D23/02 , B05D1/62 , B05D7/227 , B05D7/52 , B65D65/466 , C23C16/50 , Y02W90/13
摘要： A biodegradable resin bottle having a container wall (1) including a biodegradable resin and having a vacuum-evaporated film (3) formed on the inner surface of the container wall (1) by a plasma CVD method. The vacuum-evaporated film (3) includes a first hydrocarbon vacuum-evaporated layer (3a) positioned on the inner surface of the container wall and a second hydrocarbon vacuum-evaporated layer (3b) formed on the above hydrocarbon vacuum-evaporated layer (3a). The first hydrocarbon vacuum-evaporated layer (3a) has polar groups introduced therein. The second hydrocarbon vacuum-evaporated layer (3b) exhibits hydrocarbon peaks stemming from CH, CH2 and CH3 in a region of wave numbers of 3200 to 2600 cm−1 as measured by FT-IR, has a CH2 ratio of not larger than 35% and a CH3 ratio of not smaller than 40% per the sum of CH, CH2 and CH3 calculated from the hydrocarbon peaks, and has no polar group introduced therein.
摘要翻译：一种具有容器壁（1）的生物降解性树脂瓶，其具有生物降解性树脂，并且通过等离子体CVD法形成在容器壁（1）的内表面上的真空蒸镀膜（3）。真空蒸发膜（3）包括位于容器壁的内表面上的第一烃真空蒸发层（3a）和形成在上述烃真空蒸发层（3a）上的第二烃真空蒸发层（3b））。第一烃真空蒸发层（3a）具有引入其中的极性基团。第二烃真空蒸发层（3b）表现出通过FT-IR测量的波数为3200至2600cm -1的区域中由CH，CH 2和CH 3产生的烃峰，其CH 2比率不大于35％并且由烃峰计算出的CH，CH 2和CH 3之和的CH 3比率不小于40％，并且没有引入极性基团。

5. 发明申请

US20100140205A1 BIODEGRADABLE RESIN BOTTLE AND METHOD OF PRODUCING THE SAME 有权
标题翻译：生物可降解树脂瓶及其生产方法
公开(公告)号：US20100140205A1
公开(公告)日：2010-06-10
申请号：US12598895
申请日：2008-06-05
申请人： Takuro Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
发明人： Takuro Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
IPC分类号： B65D23/02 , B05D7/22
CPC分类号： C23C16/045 , B65D23/0814 , C23C16/26 , Y02W90/12 , Y02W90/13 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/139
摘要： [Problem] To provide a polylactic acid bottle having a vacuum-evaporated film on the inner surface of the bottle wall, effectively preventing the thermal deformation of the bottle at the time of forming the film and exhibiting excellent barrier property against oxygen and water.[Means for Solution] A biodegradable resin bottle has a wall formed by a biodegradable resin and a vacuum-evaporated film on an inner surface of the wall by a plasma CVD method, and wherein said vapor-evaporated film exhibits hydrocarbon peaks stemming from CH, CH2 and CH3 in a region of a wave number of 3200 to 2600 cm−1 as measured by FT-IR, and per the sum of CH, CH2 and CH3 calculated from the hydrocarbon peaks, a CH2 ratio is not larger than 35% and a CH3 ratio is not smaller than 40%.
摘要翻译：为了在瓶壁的内表面提供具有真空蒸发膜的聚乳酸瓶，有效地防止了在形成膜时瓶的热变形，并且对氧和水具有优异的阻隔性。 [解决方案]生物降解性树脂瓶具有通过等离子体CVD法在壁的内表面上由生物可降解树脂和真空蒸发膜形成的壁，并且其中所述蒸发蒸发膜表现出源自CH， CH 2和CH 3在通过FT-IR测量的波数为3200至2600cm -1的区域中，并且根据由烃峰计算的CH，CH 2和CH 3的总和，CH 2比率不大于35％，并且 CH3比不小于40％。

6. 发明授权

US08470421B2 Biodegradable resin bottle and method of producing the same 有权
标题翻译：生物降解树脂瓶及其生产方法
公开(公告)号：US08470421B2
公开(公告)日：2013-06-25
申请号：US12598895
申请日：2008-06-05
申请人： Takuro Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
发明人： Takuro Ito , Hiroki Mori , Hiroshi Nakao , Kazuhiko Yamazaki
IPC分类号： B32B1/02 , B32B23/00
CPC分类号： C23C16/045 , B65D23/0814 , C23C16/26 , Y02W90/12 , Y02W90/13 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/139
摘要： [Problem] To provide a polylactic acid bottle having a vacuum-evaporated film on the inner surface of the bottle wall, effectively preventing the thermal deformation of the bottle at the time of forming the film and exhibiting excellent barrier property against oxygen and water.[Means for Solution] A biodegradable resin bottle has a wall formed by a biodegradable resin and a vacuum-evaporated film on an inner surface of the wall by a plasma CVD method, and wherein said vapor-evaporated film exhibits hydrocarbon peaks stemming from CH, CH2 and CH3 in a region of a wave number of 3200 to 2600 cm−1 as measured by FT-IR, and per the sum of CH, CH2 and CH3 calculated from the hydrocarbon peaks, a CH2 ratio is not larger than 35% and a CH3 ratio is not smaller than 40%.
摘要翻译：为了在瓶壁的内表面提供具有真空蒸发膜的聚乳酸瓶，有效地防止了在形成膜时瓶的热变形，并且对氧和水具有优异的阻隔性。 [解决方案]生物降解性树脂瓶具有通过等离子体CVD法在壁的内表面上由生物可降解树脂和真空蒸发膜形成的壁，并且其中所述蒸发蒸发膜表现出源自CH， CH 2和CH 3在通过FT-IR测量的波数为3200至2600cm -1的区域中，并且根据由烃峰计算的CH，CH 2和CH 3的总和，CH 2比率不大于35％，并且 CH3比不小于40％。

7. 发明授权

US09423184B2 Drainage structure for corrugated-fin heat exchanger 有权
标题翻译：瓦楞纸板换热器排水结构
公开(公告)号：US09423184B2
公开(公告)日：2016-08-23
申请号：US14125736
申请日：2012-04-02
申请人： Takeshi Yoshida , Kazuhiko Yamazaki
发明人： Takeshi Yoshida , Kazuhiko Yamazaki
IPC分类号： F25D21/14 , F28D1/053 , F28F17/00 , F28F1/12 , F25B39/02 , F28F1/26
CPC分类号： F28D1/05383 , F25B39/022 , F25B2500/01 , F25D21/14 , F28F1/128 , F28F1/26 , F28F17/005
摘要： A corrugated-fin heat exchanger is constructed by arranging a plurality of flat heat exchange tubes parallel to each other in a horizontal direction between a pair of opposing header pipes, joining, at a position between the plurality of flat heat exchange tubes, corrugated fins formed by alternately repeating peak folding and valley folding portions, and forming water flow passages from lug pieces that are obtained by obliquely cutting and raising flange portions extending along end portions of each of the plurality of flat heat exchange tubes (3) in a width direction thereof. A pitch (P) of each of the corrugated fins between a peak and a valley thereof, a width (L) of each of the lug pieces in a vertical direction thereof, and a thickness (T) of the each of the plurality of flat heat exchange tubes have a relationship of P×2≧L≧T.
摘要翻译：波纹翅片式热交换器通过在一对相对的总管之间沿水平方向彼此平行地布置多个扁平的热交换管而构成，在多个扁平换热管之间的位置处接合形成的波纹状翅片通过交替地重复峰值折叠和谷折叠部分，并且从通过沿多个扁平换热管（3）的宽度方向的端部延伸的凸缘部分倾斜切割并提高的凸耳片形成水流动通道。每个波峰状翅片在其峰谷之间的间距（P），每个凸耳片在其垂直方向上的宽度（L）和多个平面中的每一个的厚度（T）热交换管的关系为P×2≥L≥T。

8. 发明申请

US20140069620A1 HEAT EXCHANGER OBTAINED FROM ALUMINUM OR ALUMINUM ALLOY 审中-公开
标题翻译：从铝或铝合金获得的热交换器
公开(公告)号：US20140069620A1
公开(公告)日：2014-03-13
申请号：US14116436
申请日：2012-03-21
申请人： Reiko Takaswa , Kazuhiko Yamazaki
发明人： Reiko Takaswa , Kazuhiko Yamazaki
IPC分类号： F28F13/18
CPC分类号： F28F13/18 , C09D133/16 , F28D1/05333 , F28F1/126 , F28F19/04 , F28F2245/02 , F28F2245/04 , C08F220/06 , C08F220/18 , C08F212/08 , C08L39/02 , C08L63/00 , C08L2205/03
摘要： Provided is a heat exchanger including a heat exchange fin in which frost formation at the time of heater operation can be prevented to the extent possible, and under such a condition that condensation is liable to occur on a fin surface, a water droplet of condensed water can be quickly removed by bringing the water droplet into contact with a hydrophilic film, and as a result, a favorable heat exchange function can be continuously obtained without any increase in ventilation resistance. The heat exchanger includes a heat exchange fin made of an aluminum plate material that has a crosslinked hydrophobic film having a frost formation-suppressing effect and a hydrophilic film, in which: an area occupied by the crosslinked hydrophobic film in a square area measuring 10 mm by 10 mm at an arbitrary position on a surface of the heat exchange fin is 20 to 80%; and the crosslinked hydrophobic film is formed of an aqueous hydrophobic coating composition containing a resin (A) having a fluorine atom-containing group, a quaternary ammonium salt group-containing modified epoxy resin (B), and an amino resin (C) in which the solid content of the resin (A) is 1 to 30 parts by mass with respect to 100 parts by mass of the total of the solid contents of the resin (B) and the resin (C).
摘要翻译：提供了一种热交换器，其包括热交换翅片，其中可以在可能的程度上防止加热器操作时的结霜，并且在这样的情况下，在翅片表面上容易发生冷凝的情况，冷凝水的水滴可以通过使水滴与亲水膜接触而快速除去，结果，可以连续获得良好的热交换功能而不会增加通气阻力。热交换器包括由铝板材制成的热交换翅片，该热交换翅片具有具有霜冻抑制效果的交联疏水膜和亲水膜，其中：交联疏水膜在方形区域中占据的面积为10mm 热交换翅片表面的任意位置为10mm，为20〜80％。并且交联的疏水性膜由含有含氟原子的基团的树脂（A），含季铵盐基的改性环氧树脂（B）和氨基树脂（C）的含水疏水性涂料组合物形成，其中，相对于树脂（B）和树脂（C）的固体成分的总量100质量份，树脂（A）的固体成分为1〜30质量份。

9. 发明授权

US5916635A Water-based hydrophilic coatings and a process for manufacturing precoated fin materials for heat exchangers with use of said coatings 失效
标题翻译：水性亲水涂料以及使用所述涂料制造用于热交换器的预涂翅片材料的方法
公开(公告)号：US5916635A
公开(公告)日：1999-06-29
申请号：US894812
申请日：1998-03-26
申请人： Toru Ishii , Kazuhiko Yamazaki , Reiko Takasawa
发明人： Toru Ishii , Kazuhiko Yamazaki , Reiko Takasawa
IPC分类号： C09D5/00 , F28F13/18 , B05D3/02
CPC分类号： F28F13/18 , C09D5/00 , F28F2245/02
摘要： This invention relates to water-based hydrophilic coatings suitable for giving hydrophilicity primarily to the surface of aluminum and to a process for manufacturing precoated fin materials for heat exchangers with use of said coatings. The coatings are composed of colloidal silica with a dispersed particle diameter of 5 to 100 nm, water-soluble polymers containing at least carboxylic acid polymers, anionic surfactants and water; the colloidal silica and the water-soluble polymers are present at a weight ratio of 30:70 to 70:30 on a solid basis in a combined content of 4 to 20% by weight, the content of carboxyl group in the carboxylic acid polymers contained in the water-soluble polymers is 20 to 63% by weight, the anionic surfactants are alkali salts of sulfosuccinic acid monoalkyl esters with alkyl groups containing 1 to 18 carbon atoms and present in an amount of 5 to 20% by weight of the combined solid content of the colloidal silica and the water-soluble polymers, and the pH is 1 to 5 as a whole. The process for manufacturing precoated fin materials for heat exchangers comprises applying the water-based hydrophilic coatings to the surface of aluminum fin materials to a solid weight of 0.3 to 1.5 g/m.sup.2 and drying under heat.
摘要翻译： PCT No.PCT / JP97 / 01024 Sec。 371日期：1998年3月26日 102（e）1998年3月26日PCT 1997年3月26日PCT公布。公开号WO97 / 35938 日期1997年10月2日本发明涉及适用于主要给予铝的亲水性的水性亲水性涂料以及使用所述涂层制造用于热交换器的预涂翅片材料的方法。涂层由分散粒径为5-100nm的胶态二氧化硅组成，至少含有羧酸聚合物，阴离子表面活性剂和水的水溶性聚合物; 胶体二氧化硅和水溶性聚合物的重量比为30:70至70:30，固体含量为4至20重量％，羧酸聚合物中的羧基含量为在水溶性聚合物中为20〜63重量％，阴离子表面活性剂为含有1〜18个碳原子的烷基的磺基琥珀酸单烷基酯的碱金属盐，其含量为组合固体重量的5〜20重量％胶体二氧化硅和水溶性聚合物的含量，pH为1〜5。用于制造用于热交换器的预涂翅片材料的方法包括将水性亲水涂层施加到铝翅片材料的表面至0.3-1.5g / m 2的固体重量，并在加热下进行干燥。

10. 外观设计

USD373578S Portable personal computer 失效
公开(公告)号：USD373578S
公开(公告)日：1996-09-10
申请号：US46665
申请日：1995-10-20
申请人： Hisashi Shima , Kazuhiko Yamazaki
设计人： Hisashi Shima , Kazuhiko Yamazaki

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