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    • 1. 发明授权
    • Ethylene copolymer rubber, process for producing the same, and use
    • 乙烯共聚物橡胶,其制备方法和用途
    • US06635727B1
    • 2003-10-21
    • US09889777
    • 2001-07-20
    • Taku KodaKotaro IchinoMasaaki KawasakiKeiji Okada
    • Taku KodaKotaro IchinoMasaaki KawasakiKeiji Okada
    • C08F4642
    • C08L23/16C08F210/16C08F210/18C08L23/04C08L51/06C08L2666/24C08L2666/04C08F210/08C08F236/22C08F2500/17C08F210/06C08F2500/25C08F236/20C08F2500/21
    • The ethylenic copolymer rubber according to the present invention is a novel and useful ethylenic copolymer rubber which can be cross-linked at a high velocity and is superior in scorching stability, in workability and in moldability, of which cross-linked product is superior in the mechanical properties, such as the cross-linked rubber strength etc., and in the form-preservability. A cross-linkable rubber composition containing this ethylenic copolymer rubber is utilized for producing, for example, cross-linked molded rubber product for use as sealing element and automobile weather strip sponge. The ethylenic copolymer rubber according to the present invention comprises a random copolymer made of ethylene, an &agr;-olefin having 3-20 carbon atoms and a triene represented by the formula (1) given below as well as an optionally incorporated non-conjuagted polyene having two or more polymerizable double bonds in the molecule, wherein the mole ratio of ethylene/&agr;-olefin is 95/5-40/60 and the triene content is 0.1-10 mole %, the intrinsic viscosity (&eegr;) determined in decalin at 135° C. is 0.1-10 dl/g and wherein the ratio of the above intrinsic viscosity (&eegr;) versus the converted intrinsic viscosity (&eegr;)blank′ converted to a linear ethylene/propylene copolymer having 70 mole % of ethylene units determined by gel permeation chromatography (GPC, at 140° C., in o-dichlorobenzene solvent) of the ethylenic copolymer rubber, i.e. (&eegr;)/(&eegr;)blank′=g′, is 0.5-0.95. in which R1 and R2 denote each, independently of each other, hydrogen atom, methyl or ethyl and R3 and R4 denote each, independently of each other, methyl or ethyl.
    • 本发明的乙烯类共聚物橡胶是一种新型有用的乙烯类共聚物橡胶,其可以高速交联,并且焦烧稳定性,加工性和成型性优异,其中交联产物在 机械性能,如交联橡胶强度等,以及形态保存性。 含有该乙烯类共聚物橡胶的交联橡胶组合物用于制造例如用作密封元件和汽车防风条海绵的交联模制橡胶产品。 根据本发明的乙烯共聚物橡胶包括由乙烯,具有3-20个碳原子的α-烯烃和由下面给出的式(1)表示的三烯以及任选掺入的非结合多烯烃制成的无规共聚物,其具有 分子中的两个或更多个可聚合双键,其中乙烯/α-烯烃的摩尔比为95 / 5-40 / 60,三烯含量为0.1-10摩尔%,在十氢化萘中测定的特性粘度(η)为135 ℃为0.1-10dl / g,并且其中上述特性粘度(η)相对于转化的特性粘度(η)空白'与转化成线性乙烯/丙烯共聚物的比例,其具有由凝胶测定的70摩尔%的乙烯单元 乙烯共聚物橡胶的渗透色谱(GPC,140℃,邻二氯苯溶剂)即(η)/(η)空白'= g',为0.5-0.95.其中R 1和R <2>各自独立地表示氢原子,甲基或乙基,R 3和R 4各自独立地表示 各自独立地为甲基或乙基。
    • 4. 发明授权
    • Unconjugated cyclopolyene copolymer, rubber composition, and use
    • 未结合的环戊烯共聚物,橡胶组合物及用途
    • US06787623B1
    • 2004-09-07
    • US09787890
    • 2001-03-26
    • Hidetatsu MurakamiKeiji OkadaMasaaki KawasakiKotaro Ichino
    • Hidetatsu MurakamiKeiji OkadaMasaaki KawasakiKotaro Ichino
    • C08F23620
    • C08L21/00B60C1/0016C08F210/02C08F210/18C08L23/08C08L23/0823Y10T152/10495C08L2666/06C08L2666/04C08F236/20C08F2500/25C08F2500/17C08F210/06
    • A tire provided with a tire tread made from a rubber composition comprising (A) a random copolymer based on non-conjugated cyclic polyene comprising structural units originated from one or more &agr;-olefins (A1) and originated from one or more non-conjugated cyclic polyene (A2), the said random copolymer having a content of the structural unit(s) originated from one or more &agr;-olefins (A1) in the range of 93 to 70 mole %; a content of the structural unit originated from one or more non-conjugated cyclic polyene (A2) in the range of 7 to 30 mole %; an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range of 0.01 to 20 dl/g; a glass transition temperature (Tg) of not higher than 40° C.; and an iodine value in the range of 50 to 150, and (B) a rubber based on diene, in a weight proportion of {the random copolymer based on non-conjugated cyclic polyene (A)} versus {the rubber based on diene (B)} in the range from 60/40 to 0.1/99.9 exhibits a superior braking performance and, compatible therewith, a superior driving fuel cost aspect.
    • 本发明提供一种轮胎胎面,其由橡胶组合物制成,该轮胎胎面由(A)基于非共轭环状多烯的无规共聚物构成,所述非共轭环多烯包含源自一种或多种α-烯烃(A1)的结构单元,并且源于一种或多种非共轭环 多烯(A2),所述无规共聚物具有来源于一种或多种α-烯烃(A1)的结构单元的含量在93-70摩尔%范围内; 来自一种或多种7-30摩尔%的非共轭环状多烯(A2)的结构单元的含量; 在135℃的萘烷中测定的特性粘度η在0.01至20dl / g的范围内; 玻璃化转变温度(Tg)不高于40℃; 碘值在50〜150范围内,(B)基于二烯的橡胶,以{非共轭环状多烯(A)}为基准的无规共聚物)与{基于二烯的橡胶 B)}在60/40至0.1 / 99.9的范围内表现出优异的制动性能,并且与其兼容,具有优异的驱动燃料成本方面。
    • 6. 发明授权
    • Process oil composition, oil-extended elastomer containing the same and olefin-based thermoplastic elastomer composition
    • 加工油组合物,含有它的含油弹性体和烯烃类热塑性弹性体组合物
    • US08318846B2
    • 2012-11-27
    • US12085231
    • 2006-11-10
    • Yuichi ItoHidenari NakahamaKotaro Ichino
    • Yuichi ItoHidenari NakahamaKotaro Ichino
    • C08K5/01
    • C08L23/12C08L23/16C08L91/06C08L2666/02C08L2666/06
    • An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition.The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending. The process oil composition for elastomers is a mixture of a purified mineral oil and a synthetic oil obtained by polymerizing (an) olefinic monomer(s), wherein the ratio of the purified mineral oil to the synthetic oil is preferably 40/60 to 80/20.
    • 本发明的目的是提供一种在低温下具有耐候性和柔软性的烯烃类热塑性弹性体组合物,流动性优异,即使在高温下使用也不会发粘。 用作弹性体的工艺油组合物,其用作热塑性弹性体组合物的原料并有助于上述特性; 和含有该工艺油组合物的含油弹性体。 本发明的弹性体的加工油组合物具有如下特性:当相对于100重量份丙烯均聚物共混20重量份用于弹性体的工艺油组合物时,丙烯均聚物的熔点降低 与未共混的丙烯均聚物相比,为2〜4.5℃。 用于弹性体的工艺油组合物是纯化矿物​​油和通过聚合(a)烯烃单体获得的合成油的混合物,其中纯化矿物油与合成油的比例优选为40/60〜80 / 20。
    • 7. 发明申请
    • Process Oil Composition, Oil-Extended Elastomer Containing the Same and Olefin-Based Thermoplastic Elastomer Composition
    • 工艺油组合物,含有其的油扩展弹性体和基于烯烃的热塑性弹性体组合物
    • US20090171006A1
    • 2009-07-02
    • US12085231
    • 2006-11-10
    • Yuichi ItoHidenari NakahamaKotaro Ichino
    • Yuichi ItoHidenari NakahamaKotaro Ichino
    • C08L23/16C08L23/12
    • C08L23/12C08L23/16C08L91/06C08L2666/02C08L2666/06
    • An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition.The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending. The process oil composition for elastomers is a mixture of a purified mineral oil and a synthetic oil obtained by polymerizing (an) olefinic monomer(s), wherein the ratio of the purified mineral oil to the synthetic oil is preferably 40/60 to 80/20.
    • 本发明的目的是提供一种在低温下具有耐候性和柔软性的烯烃类热塑性弹性体组合物,流动性优异,即使在高温下使用也不会发粘。 用作弹性体的工艺油组合物,其用作热塑性弹性体组合物的原料并有助于上述特性; 和含有该工艺油组合物的含油弹性体。 本发明的弹性体的加工油组合物具有如下特性:当相对于100重量份丙烯均聚物共混20重量份的弹性体用工艺油组合物时,丙烯均聚物的熔点降低 与未共混的丙烯均聚物相比,为2〜4.5℃。 用于弹性体的工艺油组合物是纯化矿物​​油和通过聚合(a)烯烃单体获得的合成油的混合物,其中纯化矿物油与合成油的比例优选为40/60〜80 / 20。
    • 8. 发明授权
    • Copolymer rubber, rubber composition and rubber molded product
    • 共聚橡胶,橡胶组合物和橡胶成型品
    • US07977443B2
    • 2011-07-12
    • US11990139
    • 2006-08-09
    • Kotaro IchinoMasao KunizaneTakashi Hakuta
    • Kotaro IchinoMasao KunizaneTakashi Hakuta
    • C08F236/20C08L19/00
    • C08L23/16C08F210/18C08K3/04C08K3/22C08K3/26C08K5/09C08L71/00C08L2312/00C08L2666/22C08L2666/02C08F210/06C08F236/20C08F2500/25C08F2500/17
    • The invention provides a copolymer rubber excellent in processability in kneading and processability in extrusion; rubber compositions containing the rubber; and crosslinked moldings of the compositions excellent in sealing properties and shape retention. A random copolymer rubber of ethylene (A), a C3-20 α-olefin (B) and a nonconjugated polyene (C) which satisfies the following requirements (1) to (5): (1) the structural units (A) and (B) are contained at an (A)/(B) molar ratio of 40/60 to 95/5, (2) the structural unit (C) content is 0.01 to 5% by mole, (3) the limiting viscosity [η] is 1.0 to 5.0 dl/g as determined in decahydronaphthalene at 135°., (4) the Mw/Mn is 1 to 8, and (5) the P value is 0.46 to 1.00 as defined by formula (1): P=Ln(limiting viscosity [η])−5.0×105×η*(10) (1) (wherein Ln is a natural logarithm; and η*(10) is viscosity (Pa·sec) as determined at 190° C. and at 10 rad/sec.
    • 本发明提供一种挤出加工性优异的挤出加工性的共聚物橡胶, 含有橡胶的橡胶组合物; 和密封性能和形状保持性优异的组合物的交联模塑品。 (A),C3-20α-烯烃(B)和非共轭多烯(C)的无规共聚物橡胶,其满足以下要求(1)至(5):(1)结构单元(A)和 (A)/(B)摩尔比为40/60〜95/5,(2)结构单元(C)含量为0.01〜5摩尔%,(3)极限粘度[ (10)Mw / Mn为1〜8,(5)如式(1)所定义,P值为0.46〜1.00:(摩尔) P = Ln(特性粘度[eegr]) - 5.0×105×&eegr *(10)(1)(其中Ln为自然对数;&eegr; *(10)为粘度(Pa·sec) 190℃和10弧度/秒。
    • 9. 发明申请
    • Copolymer Rubber, Rubber Composition and Rubber Molded Product
    • 共聚橡胶,橡胶组合物和橡胶成型产品
    • US20100144997A1
    • 2010-06-10
    • US11990139
    • 2006-08-09
    • Kotaro IchinoMasao KunizaneTakashi Hakuta
    • Kotaro IchinoMasao KunizaneTakashi Hakuta
    • C08F236/20
    • C08L23/16C08F210/18C08K3/04C08K3/22C08K3/26C08K5/09C08L71/00C08L2312/00C08L2666/22C08L2666/02C08F210/06C08F236/20C08F2500/25C08F2500/17
    • The invention provides a copolymer rubber excellent in processability in kneading and processability in extrusion; rubber compositions containing the rubber; and crosslinked moldings of the compositions excellent in sealing properties and shape retention. A random copolymer rubber of ethylene (A), a C3-20 α-olefin (B) and a nonconjugated polyene (C) which satisfies the following requirements (1) to (5): (1) the structural units (A) and (B) are contained at an (A)/(B) molar ratio of 40/60 to 95/5, (2) the structural unit (C) content is 0.01 to 5% by mole, (3) the limiting viscosity [η] is 1.0 to 5.0 dl/g as determined in decalin at 135° C., (4) the Mw/Mn is 1 to 8, and (5) the P value is 0.46 to 1.00 as defined by formula (1): P=Ln(limiting viscosity [η]−5.0×105×η*(10) (1) (wherein Ln is a natural logarithm; and η*(10) is a viscosity (Pa·sec) as determined at 190° C. and at 10 rad/sec).
    • 本发明提供一种挤出加工性优异的挤出加工性的共聚物橡胶, 含有橡胶的橡胶组合物; 和密封性能和形状保持性优异的组合物的交联模塑品。 (A),C3-20α-烯烃(B)和非共轭多烯(C)的无规共聚物橡胶,其满足以下要求(1)至(5):(1)结构单元(A)和 (A)/(B)摩尔比为40/60〜95/5,(2)结构单元(C)含量为0.01〜5摩尔%,(3)极限粘度[ 在135℃下在十氢化萘中测定为1.0〜5.0dl / g,(4)Mw / Mn为1〜8,(5)式(1)定义的P值为0.46〜1.00, :P = Ln(特性粘度[ - eegr]] - 5.0×105×&eegr *(10)(1)(其中Ln为自然对数,&eegr * *(10)为粘度(Pa·sec) 在190℃和10弧度/秒)。