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1. 发明授权

US5532324A Copolymeric polycarbonates, a method for their preparation, and compositions thereof 失效
标题翻译：共聚聚碳酸酯，其制备方法及其组合物
公开(公告)号：US5532324A
公开(公告)日：1996-07-02
申请号：US542294
申请日：1995-10-12
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
IPC分类号： C08G64/00 , C08G64/06 , C08G64/20 , C08G64/30 , C08K3/00 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/49 , C08K5/524 , C08L69/00
CPC分类号： C08K5/42 , C08G64/06 , C08G64/307 , C08K5/1515 , C08K5/524
摘要： A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
摘要翻译：含有下述式[I]的重复构成单元的共聚聚碳酸酯以及重量以下结构单元的式[II]以摩尔比为98:2至40:60。聚碳酸酯具有优异的耐化学性，耐热性和阻燃性，而不影响耐冲击性和聚碳酸酯固有的良好色调。

2. 发明授权

US5484875A Copolymeric polycarbonate production method 失效
标题翻译：共聚聚碳酸酯生产方法
公开(公告)号：US5484875A
公开(公告)日：1996-01-16
申请号：US444703
申请日：1995-05-19
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura , Shuichi Uchimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura , Shuichi Uchimura
IPC分类号： C08G64/14 , C08G64/00 , C08G64/04 , C08G64/20 , C08G64/30 , C08G64/40 , C08K3/00 , C08K3/24 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/52 , C08L69/00 , C08G63/02
CPC分类号： C08G64/307
摘要： The present invention relates to a method for preparing copolymeric polycarbonates which comprises melt polycondensing a mixture of an aromatic dihydroxy compound containing an amount of 2-90 mol % of hydroquinone or substituted hydroquinones and a diester carbonate in the presence of a catalyst containing an alkali metal compound or an alkaline earth metal compound in an amount of 1.times.10.sup.-8 to 5.times.10.sup.-6 mole per mole of the total amount of the aromatic dihydroxy compound, then adding an acidic compound to the melt polycondensation product.
摘要翻译：本发明涉及制备共聚聚碳酸酯的方法，该方法包括在含有碱金属的催化剂存在下熔融缩聚含有2-90mol％氢醌或取代的氢醌的二芳基二羟基化合物和二酯的混合物化合物或碱土金属化合物，其量为每摩尔芳族二羟基化合物总量为1×10 -8至5×10 -6摩尔，然后向熔融缩聚产物中加入酸性化合物。

3. 发明授权

US5401826A Method for the preparation, of copolymeric polycarbonates 失效
标题翻译：共聚聚碳酸酯的制备方法
公开(公告)号：US5401826A
公开(公告)日：1995-03-28
申请号：US171088
申请日：1993-12-21
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
IPC分类号： C08G64/00 , C08G64/06 , C08G64/20 , C08G64/30 , C08K3/00 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/49 , C08K5/524 , C08L69/00
CPC分类号： C08K5/42 , C08G64/06 , C08G64/307 , C08K5/1515 , C08K5/524
摘要： A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
摘要翻译：含有下述式[I]的重复构成单元的共聚聚碳酸酯以及重量以下结构单元的式[II]以摩尔比为98:2至40:60。聚碳酸酯具有优异的耐化学性，耐热性和阻燃性，而不影响耐冲击性和聚碳酸酯固有的良好色调。

4. 发明授权

US5470938A Copolymeric polycarbonate compositions containing a sulfonic acid compound 失效
标题翻译：含有磺酸化合物的共聚聚碳酸酯组合物
公开(公告)号：US5470938A
公开(公告)日：1995-11-28
申请号：US382728
申请日：1995-02-02
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
IPC分类号： C08G64/00 , C08G64/06 , C08G64/20 , C08G64/30 , C08K3/00 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/49 , C08K5/524 , C08L69/00
CPC分类号： C08K5/42 , C08G64/06 , C08G64/307 , C08K5/1515 , C08K5/524
摘要： A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
摘要翻译：含有下述式[I]的重复构成单元的共聚聚碳酸酯以及重量以下结构单元的式[II]以摩尔比为98:2至40:60。聚碳酸酯具有优异的耐化学性，耐热性和阻燃性，而不影响耐冲击性和聚碳酸酯固有的良好色调。

5. 发明授权

US5418315A Copolymeric polycarbonate production method 失效
标题翻译：共聚聚碳酸酯生产方法
公开(公告)号：US5418315A
公开(公告)日：1995-05-23
申请号：US212077
申请日：1994-03-14
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura , Shuichi Uchimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura , Shuichi Uchimura
IPC分类号： C08G64/14 , C08G64/00 , C08G64/04 , C08G64/20 , C08G64/30 , C08G64/40 , C08K3/00 , C08K3/24 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/52 , C08L69/00 , C08G63/02
CPC分类号： C08G64/307
摘要： The method of this invention prepares copolymeric polycarbonates which have excellent mechanical properties, heat resistance and transparency, and which also have improved chemical resistance, hue, and residence stability by inducing the melt polycondensation of an aromatic dihydroxy compound containing an amount of 2-90 mol % of hydroquinone and/or substituted hydroquinones with a diester carbonate in the presence of a catalyst containing alkali metal compounds and/or alkaline earth metal compounds in an amount of 1.times.10.sup.-8 to 5.times.10.sup.-6 mole per mole of the total amount of the aromatic dihydroxy compound.
摘要翻译：本发明的方法制备具有优异的机械性能，耐热性和透明性的共聚聚碳酸酯，并且还通过引入含量为2-90mol的芳族二羟基化合物的熔融缩聚而具有改善的耐化学性，色调和停留稳定性在含有碱金属化合物和/或碱土金属化合物的催化剂的存在下，每摩尔芳族化合物的总量为1×10 -8至5×10 -6摩尔的量的氢醌和/或取代的氢醌与二酯碳酸酯二羟基化合物。

6. 发明授权

US5286834A Melt preparation of copolycarbonate with alkaline compound catalyst and boric acid compound catalyst 失效
标题翻译：用碱性化合物催化剂和硼酸化合物催化剂熔融共聚碳酸酯制备
公开(公告)号：US5286834A
公开(公告)日：1994-02-15
申请号：US944377
申请日：1992-09-14
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura
IPC分类号： C08G64/00 , C08G64/06 , C08G64/20 , C08G64/30 , C08K3/00 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/49 , C08K5/524 , C08L69/00
CPC分类号： C08K5/42 , C08G64/06 , C08G64/307 , C08K5/1515 , C08K5/524
摘要： A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
摘要翻译：含有下述式（I）的重复结构单元的聚合物聚碳酸酯，并以98:2至40:60的摩尔比重复以下式（II）的结构单元。（*化学结构*）（I）（*化学结构*）（II）上述共聚聚碳酸酯具有优异的耐化学性，耐热性和阻燃性，而不损害耐冲击性和聚碳酸酯固有的良好色调。

7. 发明授权

US5324809A Melt catalytic preparation of copolymeric polycarbonate from hydroquinone 失效
标题翻译：从氢醌催化制备共聚聚碳酸酯
公开(公告)号：US5324809A
公开(公告)日：1994-06-28
申请号：US903318
申请日：1992-06-24
申请人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura , Shuichi Uchimura
发明人： Takeshi Sakashita , Tomoaki Shimoda , Kotaro Kishimura , Shuichi Uchimura
IPC分类号： C08G64/14 , C08G64/00 , C08G64/04 , C08G64/20 , C08G64/30 , C08G64/40 , C08K3/00 , C08K3/24 , C08K5/00 , C08K5/1515 , C08K5/36 , C08K5/42 , C08K5/52 , C08L69/00
CPC分类号： C08G64/307
摘要： The present invention relates to a method of preparing a copolymeric polycarbonate which comprises melt-polycondensing a mixture of an aromatic dihydroxy compound comprising hydroquinone or substituted hydroquinones and a diester carbonate in the presence of a catalyst containing alkali metal compounds and/or alkaline earth metal compounds.
摘要翻译：本发明涉及制备共聚聚碳酸酯的方法，该方法包括在含有碱金属化合物和/或碱土金属化合物的催化剂存在下，将包含氢醌或取代的氢醌的芳族二羟基化合物和二酯碳酸酯的混合物熔融缩聚。

8. 发明授权

US4918133A Cycloolefin type random copolymer compositions 失效
标题翻译：环烯烃型无规共聚物组合物
公开(公告)号：US4918133A
公开(公告)日：1990-04-17
申请号：US363884
申请日：1989-06-07
申请人： Satoru Moriya , Akio Ishimoto , Yoshinori Akana , Yozo Yamamoto , Kotaro Kishimura , Fumitoshi Ikejiri
发明人： Satoru Moriya , Akio Ishimoto , Yoshinori Akana , Yozo Yamamoto , Kotaro Kishimura , Fumitoshi Ikejiri
IPC分类号： C08L23/16 , C08L65/00
CPC分类号： C08L23/16 , C08L23/0823 , C08L65/00
摘要： In accordance with the present invention, there are provided cycloolefin type random copolymer compositions excellent in heat resistance, chemical resistance, rigidity, impact resistance, etc., which comprise(A) a cycloolefin type random copolymer containing an ethylene component and a cycloolefin component and having an intrinsic viscosity [.eta.] of 0.05-10 dl/g as measured at 135.degree. C. in decalin and a softening temperature (TMA) of not lower than 70.degree. C., and(B) one or more non-rigid copolymers selected from the group consisting of:(i) a cycloolefin type random copolymer containing an ethylene component, at least one other .alpha.-olefin component and a cycloolefin component and having an intrinsic viscosity [.eta.] of 0.01-10 dl/g as measured at 135.degree. C. in decalin and a softening temperature (TMA) of below 70.degree. C.,(ii) a non-crystalline to low crystalline .alpha.-olefin type elastomeric copolymer formed from at least two .alpha.-olefins,(iii) an .alpha.-olefin-diene type elastomeric copolymer formed from at least two .alpha.-olefins and at least one non-conjugated diene, and(iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, and optionally(c) an inorganic filler or organic filler.
摘要翻译： PCT No.PCT / JP88 / 01027 Sec。 371日期1989年6月7日第 102（e）日期1989年6月7日PCT提交1988年10月7日PCT公布。第WO89 / 03413号公报根据本发明，提供了耐热性，耐化学性，刚性，耐冲击性等优异的环烯烃型无规共聚物组合物，其包含（A）含有乙烯组分和环烯烃组分，并且在135℃下在十氢化萘中测得的特性粘度η为0.05-10dl / g，软化温度（TMA）不低于70℃，（B）一种或多种选自以下的非刚性共聚物：（i）含有乙烯组分，至少一种其它α-烯烃组分和环烯烃组分的环烯烃型无规共聚物，其特性粘度η为0.01- 在135℃下在十氢化萘中测得的10dl / g，软化温度（TMA）低于70℃，（ii）由至少两个α - 烯烃形成的非结晶至低结晶的α-烯烃型弹性体共聚物，烯烃，（iii）α 由至少两种α-烯烃和至少一种非共轭二烯形成的α-烯烃 - 二烯型弹性体共聚物，和（iv）芳族乙烯基型烃 - 共轭二烯共聚物或其氢化产物，和任选地（c）无机填料或有机填料。

9. 发明授权

US4755553A Primer composition for substrates 失效
标题翻译：底物底漆组合物
公开(公告)号：US4755553A
公开(公告)日：1988-07-05
申请号：US922785
申请日：1986-10-23
申请人： Kotaro Kishimura , Riichiro Nagano
发明人： Kotaro Kishimura , Riichiro Nagano
IPC分类号： C08J5/12 , C08F8/22 , C08F8/46 , C08F255/00 , C08F255/02 , C08J7/04 , C09D123/02 , C09D151/00 , C09D151/06 , C09J151/06 , C08L51/06 , C08F8/18
CPC分类号： C08J7/047 , C08F8/22 , C09D151/06 , C09J151/06 , C08J2323/02 , Y10T428/31678
摘要： A primer composition composed of 1 to 100 parts by weight of a chlorinated carboxyl group-containing .alpha.-olefin polymer and 100 parts by weight of an organic solvent therefor, the improvement wherein(i) said chlorinated carboxyl group-containing .alpha.-olefin polymer is a post-chlorination product [C] of a graft-modified propylene polymer [B] having a chlorine content of 10 to 35% by weight, said graft-modified propylene polymer [B] having an acid value of 6 to 187 mg-KOH/g-polymer and obtained by grafting an unsaturated dicarboxylic acid anhydride to a propylene polymer [A] having an intrinsic viscosity [.eta.], determined at 135.degree. C. in decalin, of 0.6 to 10 dl/g and comprising 70 to 100 mole % of propylene and 0 to 30 mole % of an .alpha.-olefin other than propylene, and(ii) said solvent is an organic solvent boiling at about 60.degree. to about 200.degree. C.
摘要翻译：由1〜100重量份的含氯化的含羧基的α-烯烃聚合物和100重量份的有机溶剂组成的底漆组合物，其中（i）所述含氯化的含羧基的α-烯烃聚合物为所述接枝改性的丙烯聚合物[B]的酸值为6至187mg-KOH的接枝改性的丙烯聚合物[B]的后氯化产物[C]为氯含量为10至35重量％ / g聚合物，并且通过将不饱和二羧酸酐接枝到在十氢萘中在135℃下测定的特性粘度η为0.6至10dl / g的丙烯聚合物[A]并且包含70至100摩尔丙烯和0〜30摩尔％的除丙烯以外的α-烯烃的％，和（ii）所述溶剂是在约60〜约200℃沸腾的有机溶剂。

10. 发明授权

US4461809A Surface treating agent as an undercoat on surface of polyolefin shaped articles 失效
标题翻译：表面处理剂作为聚烯烃制品表面的底涂层
公开(公告)号：US4461809A
公开(公告)日：1984-07-24
申请号：US416377
申请日：1982-09-09
申请人： Teiichi Shiomi , Kotaro Kishimura
发明人： Teiichi Shiomi , Kotaro Kishimura
IPC分类号： C08L101/00 , C08F255/04 , C08J7/04 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C09D151/00 , B32B27/36 , C08K5/01
CPC分类号： C08J7/047 , C08F255/04 , C08J2323/02 , C08J2431/02 , Y10T428/31511 , Y10T428/31576 , Y10T428/31794 , Y10T428/31797 , Y10T428/31913 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： A surface treating agent for a shaped article of a polyolefin is provided which is composed of a solution in an organic solvent of a propylene-ethylene copolymer having a monoalkyl ester of a monolefinic dicarboxylic acid, such as monomethyl maleate, grafted thereto. The propylene-ethylene copolymer has a propylene content of 50 to 75 mole %, and a crystallinity, determined by an X-ray diffraction method, of 2 to 20%. The esterification degree of the alkyl ester of the monolefinic dicarboxylic acid is 45 to 100% if the esterification degree is taken as 200% when all of the carboxyl groups of the dicarboxylic acid are esterified. The amount of the monoalkyl ester grafted is 0.5 to 15% by weight. The grafted propylene-ethylene copolymer has an intrinsic viscosity [.eta.] of at least 0.3 and is dissolved in an amount of 10 to 100 kg per cubic meter of the organic solvent. The surface treating agent is suitable as an undercoat for a polyolefin shaped article. It greatly improves the adhesion of a paint to the polyolefin article, and has excellent storage stability.
摘要翻译：提供了一种聚烯烃成型制品的表面处理剂，其由具有单烯属二羧酸单烷基酯如马来酸单甲酯接枝的丙烯 - 乙烯共聚物的有机溶剂中的溶液组成。丙烯 - 乙烯共聚物的丙烯含量为50〜75摩尔％，通过X射线衍射法测定的结晶度为2〜20％。如果二羧酸的全部羧基被酯化，酯化度为200％，则单烯属二羧酸的烷基酯的酯化度为45〜100％。接枝的单烷基酯的量为0.5〜15重量％。接枝丙烯 - 乙烯共聚物的特性粘度η至少为0.3，溶解量为每立方米有机溶剂10至100kg。表面处理剂适合用作聚烯烃成形制品的底涂层。它大大提高了油漆对聚烯烃制品的附着力，并且具有优异的储存稳定性。

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