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1. 发明授权

US5364963A Supported rhodium catalyst, method of preparing same and process of producing acetic acid by methanol carbonylation using same 失效
标题翻译：负载型铑催化剂，其制备方法和使用甲醇羰基化生产乙酸的方法
公开(公告)号：US5364963A
公开(公告)日：1994-11-15
申请号：US169639
申请日：1993-12-20
申请人： Takeshi Minami , Kenji Shimokawa , Kazuhiko Hamato , Yoshimi Shiroto , Noriyuki Yoneda
发明人： Takeshi Minami , Kenji Shimokawa , Kazuhiko Hamato , Yoshimi Shiroto , Noriyuki Yoneda
IPC分类号： B01J31/16 , B01J31/18 , C07C51/12 , C07C45/50 , B01J20/26 , B01J23/40
CPC分类号： B01J31/1658 , B01J31/181 , C07C51/12 , B01J2531/822 , Y10S502/507
摘要： A methanol carbonylation catalyst includes a rhodium complex supported on a porous, cross-linked vinylpyridine resin, wherein the vinylpyridine resin has a cross-linking degree of 30-60%, a pore volume of 0.1-0.4 ml/g and an average pore diameter of 20-100 nm. The catalyst may be prepared by contacting the pyridine ring-containing resin with an aqueous solution containing rhodium ion and then contacting the resulting rhodium ion-carrying resin with carbon monoxide and an alkyl iodide in an organic solvent to convert the rhodium ion to a rhodium complex bound to the resin. Acetic acid is produced by reacting carbon monoxide with methanol at a temperature of 140.degree.-250.degree. C. and a partial pressure of carbon monoxide of 7-30 kg/cm.sup.2 in the presence of an alkyl iodide and the above catalyst.
摘要翻译：甲醇羰基化催化剂包括负载在多孔交联乙烯基吡啶树脂上的铑络合物，其中乙烯基吡啶树脂的交联度为30-60％，孔体积为0.1-0.4ml / g，平均孔径为20-100nm。催化剂可以通过使含吡啶环的树脂与含有铑离子的水溶液接触，然后使所得的含铑离子的树脂与一氧化碳和烷基碘在有机溶剂中接触来将铑离子转化成铑络合物结合树脂。在烷基碘和上述催化剂的存在下，一氧化碳与甲醇在140〜250℃的温度和一氧化碳分压为7〜30kg / cm 2下反应生成乙酸。

2. 发明授权

US5334755A Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst 失效
标题翻译：使用负载铑催化剂从甲醇和一氧化碳生产乙酸的方法
公开(公告)号：US5334755A
公开(公告)日：1994-08-02
申请号：US49303
申请日：1993-04-21
申请人： Noriyuki Yoneda , Yoshimi Shiroto , Kazuhiko Hamato , Sachio Asaoka , Tetsuo Maejima
发明人： Noriyuki Yoneda , Yoshimi Shiroto , Kazuhiko Hamato , Sachio Asaoka , Tetsuo Maejima
IPC分类号： B01J31/16 , B01J31/18 , C07C51/12 , C07C67/36 , C07C51/10
CPC分类号： B01J31/181 , B01J31/1658 , C07C51/12 , B01J2531/822
摘要： A liquid feed containing methanol, carbon monoxide, an alkyl iodide and a solvent is contacted with a supported rhodium catalyst to produce acetic acid at a temperature of 140.degree.-250.degree. C. and a pressure of 15-60 kg/cm.sup.2 G with a partial pressure of carbon monoxide of 7-30 kg/cm.sup.2 while maintaining (a) the water concentration of the product solution in the range of 0.5-10% by weight and (b) the carbonylation degree C.sub.r, defined in the specification, of the solution within the reactor at 0.15 or more. The solvent may be a carboxylic acid or a carboxylic acid ester.
摘要翻译：将含有甲醇，一氧化碳，烷基碘和溶剂的液体原料与负载的铑催化剂接触，在140-250℃的温度和15-60kg / cm2G的压力下制备乙酸，一氧化碳压力为7-30kg / cm2，同时维持（a）产品溶液的水浓度在0.5-10重量％的范围内，（b）溶液中规定的羰基化度Cr 在反应器内为0.15以上。溶剂可以是羧酸或羧酸酯。

3. 发明授权

US6080373A Method of contacting catalyst particles with gas and liquid 失效
标题翻译：催化剂颗粒与气体和液体接触的方法
公开(公告)号：US6080373A
公开(公告)日：2000-06-27
申请号：US939622
申请日：1997-09-29
申请人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
发明人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
IPC分类号： B01J8/00 , B01J8/18 , B01J8/22 , C07C45/50 , C07C51/12 , C07C67/36
CPC分类号： C07C51/12 , B01J8/007 , B01J8/1854 , B01J8/1863 , B01J8/222 , B01J8/226 , B01J8/228 , C07C45/50 , C07C67/36 , B01J2208/00176 , B01J2208/00203 , B01J2208/00212 , B01J2208/003
摘要： Catalyst particles are contacted with a liquid and a gas in a vertically extending cylindrical vessel. The particles and liquid are placed in the vessel into which the gas and liquid are continuously fed from the bottom thereof so that an upwardly flowing mixture comprising the particles, liquid and gas is formed. The mixture is introduced into a gas separating zone disposed adjacent to an upper portion of the vessel to separate the mixture by gravity into a gas phase, a supernatant liquid phase and a phase rich in the catalyst particles. The gas and supernatant phases are continuously withdrawn from the separating zone while the catalyst particles-rich phase is continuously recycled to the bottom of the vessel by gravity.
摘要翻译：催化剂颗粒与垂直延伸的圆柱形容器中的液体和气体接触。将颗粒和液体放置在容器中，气体和液体从其底部连续进料，从而形成包含颗粒，液体和气体的向上流动的混合物。将混合物引入到与容器的上部相邻设置的气体分离区中，以通过重力将混合物分离成气相，上清液相和富含催化剂颗粒的相。气体和上清液相从分离区连续取出，而富含催化剂颗粒的相通过重力连续循环到容器的底部。

4. 发明授权

US5767303A Process of producing carbonic diester 失效
标题翻译：生产碳酸二酯的工艺
公开(公告)号：US5767303A
公开(公告)日：1998-06-16
申请号：US876239
申请日：1997-06-16
申请人： Takeshi Minami , Noriyuki Yoneda , Yoshimi Shiroto , Haruto Kobayashi
发明人： Takeshi Minami , Noriyuki Yoneda , Yoshimi Shiroto , Haruto Kobayashi
IPC分类号： B01J31/02 , B01J31/18 , B01J31/40 , C07C68/00
CPC分类号： B01J31/30 , B01J31/0202 , B01J31/0204 , B01J31/0244 , B01J31/181 , B01J31/403 , C07C68/005 , B01J2531/16 , Y02P20/584
摘要： A process for the production of a carbonic diester, wherein an alcohol is reacted in a reaction zone with carbon monoxide and oxygen in the presence of (a) metallic copper or a copper compound, (b) a heterocyclic compound containing one or more nitrogen atoms in the cyclic skeleton and (c) a glycol ether represented by the following formula (I): R.sup.1 O--(CHR.sup.2 --CH.sub.2 O).sub.n --R.sup.3 (I) wherein R.sup.1 stands for an alkyl group having from 1 to 6 carbon atoms, R.sup.2 stands for a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, R.sup.3 stands for a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and n is an integer of from 1 to 12.
摘要翻译：一种制备碳酸二酯的方法，其中在（a）金属铜或铜化合物存在下，醇在反应区与一氧化碳和氧反应，（b）含有一个或多个氮原子的杂环化合物在环状骨架中，（c）由下式（I）表示的二醇醚：R 1 O-（CHR 2 -CH 2 O）n -R 3（I）其中R 1表示具有1〜6个碳原子的烷基，R 2表示对于氢原子或具有1或2个碳原子的烷基，R 3表示氢原子或具有1至6个碳原子的烷基，n是1至12的整数。

5. 发明授权

US5880311A Method of contacting catalyst particles with gas and liquid 失效
公开(公告)号：US5880311A
公开(公告)日：1999-03-09
申请号：US413626
申请日：1995-03-30
申请人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
发明人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
IPC分类号： B01J8/00 , B01J8/18 , B01J8/22 , C07C45/50 , C07C51/12 , C07C67/36 , C07C69/02
CPC分类号： C07C51/12 , B01J8/007 , B01J8/1854 , B01J8/1863 , B01J8/222 , B01J8/226 , B01J8/228 , C07C45/50 , C07C67/36 , B01J2208/00176 , B01J2208/00203 , B01J2208/00212 , B01J2208/003
摘要： Catalyst particles are contacted with a liquid and a gas in a vertically extending cylindrical vessel. The particles and liquid are placed in the vessel into which the gas and liquid are continuously fed from the bottom thereof so that an upwardly flowing mixture comprising the particles, liquid and gas is formed. The mixture is introduced into a gas separating zone disposed adjacent to an upper portion of the vessel to separate the mixture by gravity into a gas phase, a supernatant liquid phase and a phase rich in the catalyst particles. The gas and supernatant phases are continuously withdrawn from the separating zone while the catalyst particles-rich phase is continuously recycled to the bottom of the vessel by gravity.

6. 发明授权

US6066762A Process for the production of carbonyl compound 失效
标题翻译：生产羰基化合物的方法
公开(公告)号：US6066762A
公开(公告)日：2000-05-23
申请号：US997552
申请日：1997-12-23
申请人： Noriyuki Yoneda , Takeshi Minami , Yoshihiro Nakagawa , Ikuo Ohta , Akihisa Yamaguchi , Hideki Sugiyama , Fumihiko Uemura
发明人： Noriyuki Yoneda , Takeshi Minami , Yoshihiro Nakagawa , Ikuo Ohta , Akihisa Yamaguchi , Hideki Sugiyama , Fumihiko Uemura
IPC分类号： C07C51/12
CPC分类号： C07C51/12
摘要： A process for the production of a carbonyl compound such as acetic acid by reacting a carbonylatable compound such as methanol with a carbon monoxide in the presence of a carbonylation catalyst containing a noble metal complex supported on a porous, cross-linked vinylpyridine resin at a temperature of 140-250.degree. C., a carbon monoxide partial pressure of 7-30 kg/cm.sup.2 and a hydrogen partial pressure of 0.1-5 kg/cm.sup.2 to obtain a liquid product containing the carbonyl compound and an unreacted CO-containing gas product. The water content and the carbonylation degree of the liquid product within the reactor are maintained at 0.5-10% by weight and 0.5-0.9, respectively, The carbonyl compound is separated from the liquid product in a flasher and/or a distillation tower formed of titanium or a titanium-palladium alloy. The liquid product is introduced into a pressure reducing valve and then mixed with the CO-containing gas product before being fed to the flasher and/or distillation tower.
摘要翻译：一种通过使羰基化合物如甲醇与一氧化碳在羰基化催化剂存在下反应生产羰基化合物的方法，所述羰基化催化剂含有负载在多孔交联的乙烯基吡啶树脂上的贵金属配合物， 140-250℃，一氧化碳分压为7-30kg / cm2，氢分压为0.1-5kg / cm2，得到含有羰基化合物和未反应的含CO气体产物的液体产物。反应器内的液体产物的水含量和羰基化度分别保持在0.5-10重量％和0.5-0.9。羰基化合物与闪蒸器和/或蒸馏塔中的液体产物分离，由钛或钛 - 钯合金。将液体产物引入减压阀中，然后在加入闪蒸器和/或蒸馏塔之前与含CO气体产物混合。

7. 发明授权

US5382711A Process for the production of bishenol A 失效
标题翻译：生产双酚A的方法
公开(公告)号：US5382711A
公开(公告)日：1995-01-17
申请号：US229349
申请日：1994-04-18
申请人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
发明人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
IPC分类号： C07C37/70 , C07C39/16 , C07C37/68
CPC分类号： C07C37/70 , C07C37/685 , C07C37/84
摘要： High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005 % by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
摘要翻译：通过在最大氧含量为0.005体积％的气氛中将加合物熔合，然后蒸发释放的苯酚，由双酚A和苯酚的中性结晶加合物制备高品质双酚A。结晶加合物可以在融合之前与脂族羧酸混合以减少产物的着色。当使用酸性结晶加合物时，适合使用强酸性脂肪族羧酸碱金属盐。用于进行熔化和蒸发的装置的内表面理想地用有机溶剂洗涤以从其中除去氧。苯酚的蒸发适宜地通过二阶段汽提进行，其中在第二阶段中使用在第一阶段中获得的使用的汽提气体作为第一阶段的汽提气体，同时在第二阶段使用蒸汽作为汽提气体。

8. 发明授权

US4956326A Method for dehalogenation of a halide and catalyst used therefor 失效
标题翻译：用于其的卤化物和催化剂脱卤的方法
公开(公告)号：US4956326A
公开(公告)日：1990-09-11
申请号：US71964
申请日：1987-07-10
申请人： Noriyuki Yoneda , Toshiji Makabe , Jun Kaita , Munekazu Nakamura , Yoshiko Endoh , Hidehiko Kudoh , Shunji Higashi
发明人： Noriyuki Yoneda , Toshiji Makabe , Jun Kaita , Munekazu Nakamura , Yoshiko Endoh , Hidehiko Kudoh , Shunji Higashi
IPC分类号： B01J23/40 , B01J27/22 , B01J27/24 , C01B9/00 , C01B33/107 , C01G31/04 , C01G33/00
CPC分类号： C01G31/04 , B01J23/40 , B01J27/22 , B01J27/24 , C01B33/1071 , C01B9/00 , C01G33/00 , C01P2004/32 , C01P2006/10 , C01P2006/11 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , C01P2006/19 , C01P2006/80
摘要： A catalyst for dehalogenation of a halide comprising a corrosion-resistant ceramic or graphite having a surface area of 5.0 m.sup.2 /g or less and, supported thereon, at least one of a platinum group metal and a silicide thereof, and a method of dehalogenation of a halide using this catalyst.
摘要翻译：一种卤化物的脱卤催化剂，其包含表面积为5.0m 2 / g以下的耐腐蚀陶瓷或石墨，并且在其上负载有铂族金属及其硅化物中的至少一种，以及脱卤的方法使用该催化剂的卤化物。

9. 发明申请

US20100022771A1 REACTION APPARATUS, AND REACTION METHOD 审中-公开
标题翻译：反应装置和反应方法
公开(公告)号：US20100022771A1
公开(公告)日：2010-01-28
申请号：US12441674
申请日：2007-09-14
申请人： Noriyuki Yoneda , Yuichi Oda , Yasuo Nakanishi
发明人： Noriyuki Yoneda , Yuichi Oda , Yasuo Nakanishi
IPC分类号： C07D487/02 , B01J19/00 , C07C55/06
CPC分类号： C07D487/04 , B01J19/243 , B01J2219/00063 , C07C67/343 , C07C69/716
摘要： The present invention is directed at obtaining a high yield of a target substance and simultaneously securing high productivity.A reaction apparatus 10 has: a main flow channel 12 having an inner diameter of 3 mm, in which a raw material M1 flows; an introduction flow channel 14 in which a raw material M2 that causes a chemical reaction with the raw material M1 flows; and five branch introduction flow channels 16a to 16e which are branched from the introduction flow channel 14 and introduce the raw material M2 to the main flow channel 12, at predetermined introduction points 12o to 12s in the main flow channel 12. Here, in the main flow channel 12, the flow channel lengths of the flow channels 12b to 12d between adjacent introduction points 12p to 12s are not longer than those of the flow channels 12a to 12c between the next previous adjacent introduction points 12o to 12r in a flow direction of the raw material M1. At least one length of the flow channels 12b to 12d between the adjacent introduction points 12p to 12s is shorter than lengths of the flow channels 12a to 12c between previous adjacent introduction points 12o to 12r in the flow direction of the raw material M1.
摘要翻译：本发明涉及获得高产率的目标物质并同时确保高生产率。反应装置10具有：原料M1流过的内径为3mm的主流路12; 导入与原料M1发生化学反应的原料M2的导入流路14; 以及从导入流路14分支并将原料M2引入主流路12的五个分支导入流路16a〜16e，在主流路12中的预定的导入点12o〜12s。这里，主在流路12中，相邻导入点12p〜12s之间的流路12b〜12d的流路长度不比前一相邻导入点12o〜12r之间的流路12a〜12c的流路长度在原料M1。在相邻的导入点12p〜12s之间的流路12b〜12d的至少一个长度比原料M1的流动方向的前一相邻导入点12o〜12r之间的流路12a〜12c的长度短。

10. 发明授权

US5371304A Process for the production of bisphenol A 失效
标题翻译：生产双酚A的方法
公开(公告)号：US5371304A
公开(公告)日：1994-12-06
申请号：US228871
申请日：1994-04-18
申请人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukudome , Ryuichi Inaba , Takashi Imazeki , Karou Shimogawara
发明人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukudome , Ryuichi Inaba , Takashi Imazeki , Karou Shimogawara
IPC分类号： C07C37/70 , C07C37/68 , C07C39/16
CPC分类号： C07C37/70 , C07C37/685 , C07C37/84
摘要： High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005% by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
摘要翻译：通过在最大氧含量为0.005体积％的气氛中将加合物熔合，然后蒸发释放的苯酚，由双酚A和苯酚的中性结晶加合物制备高品质双酚A。结晶加合物可以在融合之前与脂族羧酸混合以减少产物的着色。当使用酸性结晶加合物时，适合使用强酸性脂肪族羧酸碱金属盐。用于进行熔化和蒸发的装置的内表面理想地用有机溶剂洗涤以从其中除去氧。苯酚的蒸发适宜地通过两步蒸汽汽提进行，其中在第一阶段中使用在第一阶段中获得的使用的汽提气体作为第一阶段的汽提气体，同时在第二阶段使用蒸汽作为汽提气体。

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