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    • 3. 发明专利
    • Corrosion prevention method for concrete and concrete structure prepared by the corrosion prevention method
    • 腐蚀预防方法制备的混凝土和混凝土结构的腐蚀预防方法
    • JP2011020891A
    • 2011-02-03
    • JP2009167102
    • 2009-07-15
    • Takenaka Komuten Co LtdToagosei Co Ltd東亞合成株式会社株式会社竹中工務店
    • OSAWA SATORUITAYA TAKUMIIHARA TAKESHIYAMAMORI HIROOACHINAMI MASAFUMIKANBE SHINYA
    • C04B41/71B05D7/00C09D5/00C09D5/08C09D7/12C09D133/00
    • PROBLEM TO BE SOLVED: To provide a corrosion prevention method for concrete which gives excellent shielding property to carbon dioxide, excellent crack resistance of concrete, and prevents neutralization of concrete; and to provide a concrete structure prepared by the corrosion prevention method for concrete.
      SOLUTION: The corrosion prevention method for concrete includes applying an under coating layer 3, an intermediate coating layer 4, an upper coating layer 5 in the order on a base material 2 constituted of concrete. The intermediate layer 4 is formed by using a composition for the intermediate layer containing an acrylic resin of a glass transition temperature of at most 20°C, water swellable synthetic inorganic layered silicate to form a film thickness of at least 50 μm when dried. The amount of the water swellable synthetic inorganic layered silicate is 1-50 pts.mass when the amount of the acrylic resin is set to 100 pts.mass Also, the concrete structure is prepared by this corrosion prevention method for concrete.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供对二氧化碳具有优异的屏蔽性,混凝土抗裂性优异,防止混凝土中和的混凝土的防腐蚀方法; 并提供通过混凝土的防腐蚀方法制备的混凝土结构。 解决方案:混凝土的防腐蚀方法包括将下涂层3,中间涂层4,上涂层5按顺序施加到由混凝土构成的基材2上。 中间层4通过使用含有玻璃化转变温度为至多20℃的丙烯酸树脂的中间层用组合物,水溶胀性合成无机层状硅酸盐形成干燥时的至少50μm的膜厚。 当丙烯酸树脂的量设定为100磅时,水溶胀性合成无机层状硅酸盐的量为1-50质量份。另外,通过该混凝土的防腐蚀方法制备混凝土结构体。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Fluorine-based graft copolymer and its application
    • 基于氟基的共聚物及其应用
    • JP2012184400A
    • 2012-09-27
    • JP2012010627
    • 2012-01-23
    • Toagosei Co Ltd東亞合成株式会社
    • KANBE SHINYAMATSUBARA ISAMUMAKI TAKAYUKIMATSUZAKI HIDEO
    • C08F290/04C09D7/12C09D151/00C09D201/04G03G9/113
    • PROBLEM TO BE SOLVED: To provide a graft copolymer which exhibits performance of fluorine characteristics such as water repellency, oil repellency and contamination resistance highly balanced with substrate adhesion, coating film strength and the like, and to provide a coating agent using the same, and a carrier using the coating agent.SOLUTION: The coating agent includes a specific graft copolymer which has a main chain composed of a fluorine-based polymer and 0.7-3.0 meq/g of a polymer having cross-linking functional groups as a side chain. The carrier is coated with the coating agent. In the graft copolymer, the fluorine-based polymer forming the main chain preferably has an 1-10 equivalent amount of cross-linking functional groups per the polymer.
    • 要解决的问题:提供一种表现出具有防水性,拒油性和耐基材性,与基板粘合性,涂膜强度等高度均衡的氟特性的接枝共聚物,并提供使用 和使用该涂层剂的载体。 解决方案:涂层剂包括具有由氟基聚合物构成的主链和0.7-3.0meq / g具有交联官能团作为侧链的聚合物的特定接枝共聚物。 载体涂覆有涂层剂。 在接枝共聚物中,形成主链的氟系聚合物优选每个聚合物具有1-10当量的交联官能团。 版权所有(C)2012,JPO&INPIT
    • 5. 发明专利
    • Aqueous dispersing agent and watercolor ink
    • 水性分散剂和水溶性油墨
    • JP2007231180A
    • 2007-09-13
    • JP2006055642
    • 2006-03-02
    • Toagosei Co Ltd東亞合成株式会社
    • HAYASHI KATSUHIROHIGUCHI YUKAKOKANBE SHINYAMATSUNAGA MORIATSUMORI YOSHIO
    • C08F220/18C08F212/06C08F220/28C09D11/00C09D11/322C09D11/328
    • PROBLEM TO BE SOLVED: To provide an aqueous dispersing agent comprising graft copolymer that has excellent dispersion property of dispersoids such as pigment and can stably maintain dispersion state for a long period, and provide a watercolor ink using the dispersing agent.
      SOLUTION: The aqueous dispersing agent comprises a graft copolymer in which the side chain has a structure represented by general formula [1] (wherein R
      1 , R
      2 are each H atom or an alkyl group, X is an oxygen atom, an alkylenedioxy group or urethane group, m is 1 to 20, and n is 1 to 5), the main chain includes a vinyl aromatic monomer and an alicyclic (meth)acrylic group as essential components and which has an acid value in the range of 40 to 150 mg-KOH/g. A watercolor ink comprises the aqueous dispersing agent and contains coloring agent such as pigment or the like and an aqueous medium.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决问题的方法:提供一种包含接枝共聚物的水性分散剂,该接枝共聚物具有优异的分散性,例如颜料的分散性,并可长期稳定地保持分散状态,并提供使用该分散剂的水彩油墨。 解决方案:水分散剂包括其侧链具有由通式[1]表示的结构的接枝共聚物(其中R 1 ,R SB 2 为 每个H原子或烷基,X为氧原子,亚烷基二氧基或氨基甲酸酯基,m为1-20,n为1至5),主链包括乙烯基芳族单体和脂环族(甲基)丙烯酸酯 作为必需组分,其酸值在40至150mg-KOH / g的范围内。 水彩墨水包含水性分散剂,并含有颜料等着色剂和水性介质。 版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • Silicone-based graft copolymer and method for producing the same
    • 基于硅酮的共聚物及其制备方法
    • JP2009197042A
    • 2009-09-03
    • JP2008036877
    • 2008-02-19
    • Toagosei Co Ltd東亞合成株式会社
    • KANBE SHINYASUGIURA TETSUYAMAKI TAKAYUKIMORI YOSHIO
    • C08F290/06C08F6/06C08F8/44
    • C08L51/085C08F283/12C08F290/06C08F290/068C08G77/442C09D151/085C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a silicone-based graft copolymer that has a silicone-based polymer part as a hydrophobic branch part and has a polymer as a trunk part having a structural unit originated from a polymerizable hydrophilic monomer, and to provide a method for producing the same. SOLUTION: The silicone-based graft copolymer is obtained by copolymerization of a (meth)acrylate represented by formula: CH 2 =C(R 1 )-COO-(R 2 -O) n -R 3 , an ethylenic unsaturated carboxylic acid or its salt, and a silicone-based macromonomer having an Mw of 5,000-35,000, and occasionally other monomers. In the formula, R 1 is H or methyl, R 2 is an ethylene or propylene group, R 3 is H or a 1-6C hydrocarbon group, and n is 1-25, however, R 3 is a univalent 1-6C hydrocarbon group when n=1. In the method for producing a water-based polymer composition for coating containing the graft copolymer and the graft copolymer, the monomers are copolymerized in a mixed solvent comprising a group (A) solvent (ketone, ether, ester, aromatic hydrocarbon, chlorinated aromatic hydrocarbon, aliphatic hydrocarbon, chlorinated aliphatic hydrocarbon, and alicyclic hydrocarbon) and a group (B) solvent (mono- or polyvalent alcohol and glycol ether). COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种硅氧烷基接枝共聚物,其具有硅氧烷类聚合物部分作为疏水性分支部分,并且具有聚合物作为具有源自可聚合亲水性单体的结构单元的主体部分,以及 提供其制造方法。 解决方案:硅氧烷基接枝共聚物通过以下方式获得:由下式表示的(甲基)丙烯酸酯共聚:CH 2 SBB = C(R SP 1)/ CO 2 - (R 2 SP 3),和/或具有Mw的聚硅氧烷类大分子单体, 5000-35,000,偶尔还有其他单体。 在该式中,R 1是H或甲基,R 2 SP 2是亚乙基或亚丙基,R 3是H或1-6C 烃基,n为1-25,但当n = 1时,R 3为一价1-6C烃基。 在含有接枝共聚物和接枝共聚物的涂料用水性聚合物组合物的制造方法中,单体在包含(A)溶剂(酮,醚,酯,芳香族烃,氯化芳香族烃)的混合溶剂中共聚 ,脂族烃,氯化脂族烃和脂环烃)和(B)溶剂(单价或多价醇和二醇醚)。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Emulsion composition for producing oil-resistant moistureproof film and its utilization
    • 用于生产耐油性防水膜的乳液组合物及其应用
    • JP2006328235A
    • 2006-12-07
    • JP2005154309
    • 2005-05-26
    • Toagosei Co Ltd東亞合成株式会社
    • KURITA HIDEKIKANBE SHINYA
    • C09D133/06C08K3/34C08L33/04C09D5/02C09D7/12C09D157/10
    • PROBLEM TO BE SOLVED: To provide an emulsion composition which forms a film excellent in oil resistance, moistureproofness, and water resistance and a method for producing an article having a film excellent in oil resistance, moistureproofness, and water resistance.
      SOLUTION: The emulsion composition for producing an oil-resistant moistureproof film comprises a hydrophobic resin having, as structural units, 30-65 pts.mass units of methyl methacrylate, 35-70 pts.mass units of an alkyl (meth)acrylate having ≥8C alkyl group, 0.1-15 pts.mass units of a monomer having one carboxy group other than acrylic acid, and 0-30 pts.mass units of other monomers and an average particle diameter of ≤200 nm and a water swelling synthetic inorganic phyllosilicate having an average particle diameter of 3-60 μm which are dispersed in an aqueous medium.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成耐油性,耐湿性和耐水性优异的膜的乳液组合物和具有优异的耐油性,耐湿性和耐水性的膜的制品的制造方法。 解决方案:用于生产耐油性防湿膜的乳液组合物包括具有作为结构单元的疏水性树脂,其具有30-65个单位甲基丙烯酸甲酯,35-70个单位的(甲基) 具有≥8C烷基的丙烯酸酯,具有一个除丙烯酸以外的一个羧基的单体为0.1-15个单位的单体,以及0-30个单位的其它单体,平均粒径为≤200nm,水溶胀 平均粒径为3-60μm的合成无机页硅酸盐分散在水性介质中。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Electroless plating method
    • 电镀法
    • JP2012072440A
    • 2012-04-12
    • JP2010218073
    • 2010-09-29
    • Kanto Gakuin Univ Surface Engineering Research InstituteToagosei Co Ltd東亞合成株式会社株式会社関東学院大学表面工学研究所
    • HIRAOKA HIDEKIKANBE SHINYAHORIE YOJIHONMA HIDEOWATANABE MITSUHIROSAITO YUICHI
    • C23C18/30H01L21/288H05K3/18
    • PROBLEM TO BE SOLVED: To provide an electroless plating method, which can ensure good adhesion between a plating film and a workpiece without using any noble metal such as palladium and without using any harmful chemical such as chromic acid and can permit repeated use of a plating solution.SOLUTION: The electroless plating method includes: a step (1) of applying a polymer containing, as side chains, organic residues having the ability to reduce metallic ions of a plating metal onto the surface of a workpiece; a step (2) of depositing a partially reduced metal oxide of the metal ion on the surface of the workpiece with the applied polymer in a solution containing the metallic ions but not containing a reducing agent capable of reducing the metallic ions; a step (3) of reducing the partially reduced metal oxide into a self-catalytic plating metal in a solution containing a reducing agent capable of reducing the metal ions; and a step (4) of forming a coat of the plating metal on the surface of the workpiece in an electroless plating solution.
    • 要解决的问题:提供一种化学镀方法,其可以在不使用任何贵金属如钯并且不使用任何有害化学物质如铬酸的情况下确保镀膜和工件之间的良好粘附,并且可以重复使用 的电镀液。 解决方案:化学镀方法包括:将包含作为侧链的聚合物的聚合物施加到具有将电镀金属的金属离子还原到工件表面的能力的有机残余物的步骤(1) 将所述金属离子的部分还原的金属氧化物沉积在所述工件的表面上,使所述涂覆的聚合物在含有所述金属离子但不包含能够还原金属离子的还原剂的溶液中; 在含有能够还原金属离子的还原剂的溶液中将部分还原的金属氧化物还原成自催化电镀金属的步骤(3) 以及在化学镀溶液中在工件的表面上形成电镀金属的涂层的工序(4)。 版权所有(C)2012,JPO&INPIT
    • 9. 发明专利
    • 活性エネルギー線硬化型樹脂組成物
    • 活性能量可固化树脂组合物
    • JP2015025087A
    • 2015-02-05
    • JP2013156224
    • 2013-07-29
    • 東亞合成株式会社Toagosei Co Ltd
    • KANBE SHINYA
    • C08F290/04
    • 【課題】硬化物の強度、柔軟性及び耐久性に優れ、且つ、硬化性の良好な活性エネルギー線硬化型組成物を提供する。【解決手段】エチレン性不飽和基含有化合物(A)、片末端に(メタ)アクリロイル基を有するマクロモノマー(B)及び光重合開始剤(C)を含み、前記(B)のガラス転移温度が−85〜20℃である活性エネルギー線硬化性樹脂組成物。さらには、前記(A)及び(B)の合計を100質量部としたときに、前記(A)を30〜90質量部、前記(B)を10〜70質量部含むことが好ましい。【選択図】なし
    • 要解决的问题:提供一种固化物的强度,柔软性,耐久性优异的活性能量射线固化性组合物。固体活性能量射线固化性树脂组合物含有烯属不饱和基团的化合物 (A),在一个末端具有(甲基)丙烯酰基的大分子单体(B)和光聚合引发剂(C)。 (B)的玻璃化转变温度为-85〜20℃。 当(A)和(B)的总量为100质量%时,优选(A)为30〜90质量%,(B)为10〜70质量%。
    • 10. 发明专利
    • Production method of (meth)acrylic polymer composition having (meth)acryloyl group in side chain
    • 具有(甲基)丙烯酰基的(甲基)丙烯酸聚合物组合物在侧链中的生产方法
    • JP2013072050A
    • 2013-04-22
    • JP2011213649
    • 2011-09-29
    • Toagosei Co Ltd東亞合成株式会社
    • KOKETSU AKIYOSHIKANBE SHINYA
    • C08F8/14C08G59/17
    • PROBLEM TO BE SOLVED: To provide a production method for stably obtaining a target product without thickening, gelling, etc. of a curable copolymer, when producing a curable resin composition containing the curable copolymer having a (meth)acryloyl group, which is obtained by adding a compound having a carboxyl group and a (meth)acryloyl group to an epoxy-group containing copolymer.SOLUTION: The epoxy-group containing copolymer is obtained by polymerization of a monomer mixture containing an epoxy-group containing (meth)acrylate of 30-100 pt.mass in which the content of a polyfunctional component is 0.01-0.3 mass%. Then, glycidyl (meth)acrylate is preferable as the epoxy-group containing (meth)acrylate.
    • 解决问题:为了提供稳定获得目标产物而不使固化性共聚物发生增稠,凝胶化等的制造方法,在制造含有具有(甲基)丙烯酰基的固化性共聚物的固化性树脂组合物时, 通过向含环氧基的共聚物中加入具有羧基和(甲基)丙烯酰基的化合物而得到。 解决方案:含环氧基的共聚物通过聚合含有含30-30重量%(甲基)丙烯酸环氧基的单体混合物而获得,其中多官能组分的含量为0.01-0.3质量% 。 然后,作为含环氧基的(甲基)丙烯酸酯,优选(甲基)丙烯酸缩水甘油酯。 版权所有(C)2013,JPO&INPIT