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1. 发明授权

US07825166B2 Flexible polyurethane foam, process for its production, and seat for automobile using the flexible polyurethane foam 有权
标题翻译：柔性聚氨酯泡沫，其生产工艺，以及使用柔性聚氨酯泡沫的汽车座椅
公开(公告)号：US07825166B2
公开(公告)日：2010-11-02
申请号：US11944730
申请日：2007-11-26
申请人： Takayuki Sasaki , Takashi Ito , Yoshinori Toyota , Naohiro Kumagai
发明人： Takayuki Sasaki , Takashi Ito , Yoshinori Toyota , Naohiro Kumagai
IPC分类号： C08G18/28
CPC分类号： C08G18/61 , C08G18/3203 , C08G18/3275 , C08G18/4072 , C08G18/4866 , C08G18/632 , C08G18/7607 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2350/00
摘要： To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile.A flexible polyurethane foam obtained by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound, in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that an amino-modified silicone (F) having a silicon atom and a nitrogen atom in its molecule is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds.
摘要翻译：提供具有良好振动特性的柔性聚氨酯泡沫，特别适用于汽车座椅。通过使高分子量聚氧化烯多元醇或含有高分子量聚氧化烯多元醇中的聚合物微粒的聚合物分散多元醇与多异氰酸酯化合物在催化剂，发泡剂和泡沫稳定剂的存在下反应而获得的软质聚氨酯泡沫体其特征在于，相对于100质量份的所有活性氢化合物，其分子中具有硅原子和氮原子的氨基改性硅酮（F）的使用量为0.00001〜1质量份。

2. 发明申请

US20080081847A1 FLEXIBLE POLYURETHANE FOAM, PROCESS FOR ITS PRODUCTION, AND SEAT FOR AUTOMOBILE USING THE FLEXIBLE POLYURETHANE FOAM 有权
标题翻译：柔性聚氨酯泡沫，其生产工艺及使用柔性聚氨酯泡沫的汽车座椅
公开(公告)号：US20080081847A1
公开(公告)日：2008-04-03
申请号：US11944730
申请日：2007-11-26
申请人： Takayuki SASAKI , Takashi Ito , Yoshinori Toyota , Naohiro Kumagai
发明人： Takayuki SASAKI , Takashi Ito , Yoshinori Toyota , Naohiro Kumagai
IPC分类号： C08G18/06
CPC分类号： C08G18/61 , C08G18/3203 , C08G18/3275 , C08G18/4072 , C08G18/4866 , C08G18/632 , C08G18/7607 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2350/00
摘要： To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile. A flexible polyurethane foam obtained by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound, in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that an amino-modified silicone (F) having a silicon atom and a nitrogen atom in its molecule is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds.
摘要翻译：提供具有良好振动特性的柔性聚氨酯泡沫，特别适用于汽车座椅。通过使高分子量聚氧化烯多元醇或含有高分子量聚氧化烯多元醇中的聚合物微粒的聚合物分散多元醇与多异氰酸酯化合物在催化剂，发泡剂和泡沫稳定剂的存在下反应而获得的软质聚氨酯泡沫体其特征在于，相对于100质量份的所有活性氢化合物，其分子中具有硅原子和氮原子的氨基改性硅酮（F）的使用量为0.00001〜1质量份。

3. 发明申请

US20090215918A1 PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM 失效
标题翻译：生产柔性聚氨酯泡沫的方法
公开(公告)号：US20090215918A1
公开(公告)日：2009-08-27
申请号：US12429762
申请日：2009-04-24
申请人： Takayuki SASAKI , Daisuke Kaku , Takashi Ito , Naohiro Kumagai
发明人： Takayuki SASAKI , Daisuke Kaku , Takashi Ito , Naohiro Kumagai
IPC分类号： C08G18/08
CPC分类号： C08G18/283 , C08G18/4812 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： To provide a flexible polyurethane foam which is excellent in low resiliency and durability without using a plasticizer and which shows little change in hardness against a change in temperature and at the same time, has high air flow.A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture comprising the following polyol (A), the following polyol (B) and the following monool (D) with a polyisocyanate compound in the presence of a blowing agent and a foam stabilizer, at an isocyanate index of at least 90, wherein: Polyol (A) is a polyether polyol having an average of from 2 to 3 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of from 0 to 30 mass %, obtained by ring-opening polymerization of an alkylene oxide to an initiator using a phosphazene compound, a Lewis acid compound or an alkali metal compound catalyst; Polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 70 to 250 mgKOH/g; and Monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g.
摘要翻译：为了提供在不使用增塑剂的情况下具有优异的低弹性和耐久性的柔性聚氨酯泡沫，并且硬度相对于温度变化几乎没有变化，并且同时具有高气流。一种软质聚氨酯泡沫塑料的制造方法，其特征在于，在发泡剂和泡沫体的存在下，使含有下述多元醇（A）的多元醇混合物，下述多元醇（B）和下述一元醇（D）与多异氰酸酯化合物反应稳定剂，异氰酸酯指数至少为90，其中：多元醇（A）是平均具有2至3个羟基的聚醚多元醇，羟值为10至60mgKOH / g，氧化乙烯基含量为 0〜30质量％，使用磷腈化合物，路易斯酸化合物或碱金属化合物催化剂通过烯化氧与引发剂的开环聚合得到的; 多元醇（B）是平均2〜3个羟基，羟值为70〜250mgKOH / g的聚醚多元醇; 单醇（D）是羟值为10〜200mgKOH / g的聚醚一元醇。

4. 发明授权

US08357730B2 Process for producing flexible polyurethane foam 失效
标题翻译：生产柔性聚氨酯泡沫的方法
公开(公告)号：US08357730B2
公开(公告)日：2013-01-22
申请号：US12429762
申请日：2009-04-24
申请人： Takayuki Sasaki , Daisuke Kaku , Takashi Ito , Naohiro Kumagai
发明人： Takayuki Sasaki , Daisuke Kaku , Takashi Ito , Naohiro Kumagai
IPC分类号： C08L75/08 , C08G18/08 , C08G18/48 , C08G18/32
CPC分类号： C08G18/283 , C08G18/4812 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： To provide a flexible polyurethane foam which is excellent in low resiliency and durability without using a plasticizer and which shows little change in hardness against a change in temperature and at the same time, has high air flow.A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture comprising the following polyol (A), the following polyol (B) and the following monool (D) with a polyisocyanate compound in the presence of a blowing agent and a foam stabilizer, at an isocyanate index of at least 90, wherein: Polyol (A) is a polyether polyol having an average of from 2 to 3 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of from 0 to 30 mass %, obtained by ring-opening polymerization of an alkylene oxide to an initiator using a phosphazene compound, a Lewis acid compound or an alkali metal compound catalyst; Polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 70 to 250 mgKOH/g; and Monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g.
摘要翻译：为了提供在不使用增塑剂的情况下具有优异的低弹性和耐久性的柔性聚氨酯泡沫，并且硬度相对于温度变化几乎没有变化，并且同时具有高气流。一种软质聚氨酯泡沫塑料的制造方法，其特征在于，在发泡剂和泡沫体的存在下，使含有下述多元醇（A）的多元醇混合物，下述多元醇（B）和下述一元醇（D）与多异氰酸酯化合物反应稳定剂，异氰酸酯指数至少为90，其中：多元醇（A）是平均具有2至3个羟基的聚醚多元醇，羟值为10至60mgKOH / g，氧化乙烯基含量为 0〜30质量％，使用磷腈化合物，路易斯酸化合物或碱金属化合物催化剂通过烯化氧与引发剂的开环聚合得到的; 多元醇（B）是平均2〜3个羟基，羟值为70〜250mgKOH / g的聚醚多元醇; 单醇（D）是羟值为10〜200mgKOH / g的聚醚一元醇。

5. 发明申请

US20090062416A1 FLEXIBLE POLYURETHANE FOAM AND PROCESS FOR ITS PRODUCTION 失效
标题翻译：柔性聚氨酯泡沫及其生产工艺
公开(公告)号：US20090062416A1
公开(公告)日：2009-03-05
申请号：US12200145
申请日：2008-08-28
申请人： Takayuki Sasaki , Daisuke Kaku , Naohiro Kumagai , Hideo Sakurai , Takashi Ito
发明人： Takayuki Sasaki , Daisuke Kaku , Naohiro Kumagai , Hideo Sakurai , Takashi Ito
IPC分类号： C08G18/32
CPC分类号： C08G18/4804 , C08G18/283 , C08G18/409 , C08G18/4812 , C08G18/4816 , C08G18/4866 , C08G18/721 , C08G18/7621 , C08G18/7664 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083 , C08L83/00
摘要： A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture with a polyisocyanate compound in the presence of a urethane-forming catalyst and a blowing agent, characterized in that the polyol mixture comprises the following polyol (A) and the polyol (B), and the proportion of the polyisocyanate compound to the polyol mixture is at least 90 by isocyanate index, and the total amount of Zn and Co contained in the polyol mixture is from 0.1 to 200 ppm.
摘要翻译：一种制备柔性聚氨酯泡沫的方法，其包括在氨基甲酸酯形成催化剂和发泡剂的存在下使多元醇混合物与多异氰酸酯化合物反应，其特征在于多元醇混合物包含下列多元醇（A）和多元醇 B），并且多异氰酸酯化合物与多元醇混合物的比例通过异氰酸酯指数为至少90，多元醇混合物中所含的Zn和Co的总量为0.1〜200ppm。

6. 发明授权

US08487015B2 Flexible polyurethane foam and process for its production 失效
标题翻译：柔性聚氨酯泡沫及其生产工艺
公开(公告)号：US08487015B2
公开(公告)日：2013-07-16
申请号：US12200145
申请日：2008-08-28
申请人： Takayuki Sasaki , Daisuke Kaku , Naohiro Kumagai , Hideo Sakurai , Takashi Ito
发明人： Takayuki Sasaki , Daisuke Kaku , Naohiro Kumagai , Hideo Sakurai , Takashi Ito
IPC分类号： C08G18/28
CPC分类号： C08G18/4804 , C08G18/283 , C08G18/409 , C08G18/4812 , C08G18/4816 , C08G18/4866 , C08G18/721 , C08G18/7621 , C08G18/7664 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083 , C08L83/00
摘要： A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture with a polyisocyanate compound in the presence of a urethane-forming catalyst and a blowing agent, characterized in that the polyol mixture comprises the following polyol (A) and the polyol (B), and the proportion of the polyisocyanate compound to the polyol mixture is at least 90 by isocyanate index, and the total amount of Zn and Co contained in the polyol mixture is from 0.1 to 200 ppm.
摘要翻译：一种制备柔性聚氨酯泡沫的方法，其包括在氨基甲酸酯形成催化剂和发泡剂的存在下使多元醇混合物与多异氰酸酯化合物反应，其特征在于多元醇混合物包含下列多元醇（A）和多元醇 B），并且多异氰酸酯化合物与多元醇混合物的比例通过异氰酸酯指数为至少90，多元醇混合物中所含的Zn和Co的总量为0.1〜200ppm。

7. 发明授权

US08642668B2 Polymer-dispersed polyol and process for producing flexible polyurethane foam 失效
标题翻译：聚合物分散的多元醇和生产柔性聚氨酯泡沫的方法
公开(公告)号：US08642668B2
公开(公告)日：2014-02-04
申请号：US12644043
申请日：2009-12-22
申请人： Takayuki Sasaki , Yasuyuki Sasao , Naohiro Kumagai , Chitoshi Suzuki , Shigeru Ikai
发明人： Takayuki Sasaki , Yasuyuki Sasao , Naohiro Kumagai , Chitoshi Suzuki , Shigeru Ikai
IPC分类号： C08J9/00
CPC分类号： C08G18/3206 , C08F2/20 , C08F2/44 , C08F283/06 , C08G18/4072 , C08G18/4841 , C08G18/4891 , C08G18/632 , C08G18/638 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083 , C08J2205/06
摘要： To provide a process for producing a flexible polyurethane foam having a higher biomass degree than a conventional flexible polyurethane foam and excellent in foam physical properties and its appearance.A polymer-dispersed polyol obtained by polymerizing a vinyl monomer in the presence of the following polyol (a1) derived from a natural fat/oil and/or the following polyoxyalkylene polyol (a2) is used: Polyol (a1) derived from a natural fat/oil: a polyol derived from a natural fat/oil, which is obtained by providing a natural fat/oil with hydroxy groups by chemical reaction, and which has a hydroxy value of from 20 to 250 mgKOH/g and a molecular weight distribution of at least 1.2; Polyoxyalkylene polyol (a2): a polyoxyalkylene polyol which is produced by ring-opening polymerization of an alkylene oxide (c) with the polyol (a1) derived from a natural fat/oil in the presence of at least one polymerization catalyst (b) selected from the group consisting of a coordination anionic polymerization catalyst and a cationic polymerization catalyst.
摘要翻译：提供一种具有比常规柔性聚氨酯泡沫塑料具有更高生物质量并且具有优异的泡沫物理性能及其外观的柔性聚氨酯泡沫塑料的方法。使用通过在天然油脂和/或下列聚氧化烯多元醇（a2）得到的下列多元醇（a1）存在下使乙烯基单体聚合得到的聚合物分散多元醇：来自天然脂肪的多元醇（a1） /油：衍生自天然油脂的多元醇，其通过化学反应提供具有羟基的天然脂肪/油而得到，羟基值为20〜250mgKOH / g，分子量分布为至少1.2; 聚氧化烯多元醇（a2）：在至少一种聚合催化剂（b）的存在下，通过环氧烷（c）与由天然油脂衍生的多元醇（a1）的开环聚合制备的聚氧化烯多元醇由配位阴离子聚合催化剂和阳离子聚合催化剂组成。

8. 发明申请

US20120208912A1 FLEXIBLE POLYURETHANE FOAM AND ITS PRODUCTION PROCESS, AND SEAT CUSHION FOR AUTOMOBILE 审中-公开
标题翻译：柔性聚氨酯泡沫及其生产工艺及汽车座椅
公开(公告)号：US20120208912A1
公开(公告)日：2012-08-16
申请号：US13438994
申请日：2012-04-04
申请人： Takayuki Sasaki , Naohiro Kumagai
发明人： Takayuki Sasaki , Naohiro Kumagai
IPC分类号： C08J9/04 , C08G59/02
CPC分类号： C08G18/6547 , C08G18/36 , C08G18/4063 , C08G18/4858 , C08G18/6262 , C08G18/7607 , C08G18/7621 , C08G18/7664 , C08G2101/0008 , C08G2101/0083
摘要： A process for producing a flexible polyurethane foam by reacting and expansion-molding a reactive mixture containing: (A) a polyol component containing a polyoxyalkylene polyol (A1) and a polyol (A2) derived from a natural fat/oil; (X) an epoxidized natural fat/oil obtained by reacting an oxidizing agent with a natural fat/oil containing unsaturated bonds; (C) a catalyst; and (D) a blowing agent, wherein the polyoxyalkylene polyol (a1) has a hydroxy value from 5 to 30 mgKOH/g and is obtained by polymerizing propylene oxide (b1), by ring-opening addition polymerization, in the presence of an initiator and a double metal cyanide complex catalyst (a1) containing an organic ligand, and then, polymerizing ethylene oxide (b2), by ring-opening addition polymerization, in the presence of an alkali metal catalyst (a2).
摘要翻译：一种通过使包含以下物质的反应性混合物反应并膨胀成型来制造软质聚氨酯泡沫体的方法：（A）含有聚氧化烯多元醇（A1）的多元醇组分和衍生自天然油脂的多元醇（A2）（X）通过使氧化剂与含有不饱和键的天然油脂反应得到的环氧化天然油/油; （C）催化剂; 和（D）发泡剂，其中聚氧化烯多元醇（a1）的羟值为5〜30mgKOH / g，通过开环加成聚合在引发剂存在下聚合环氧丙烷（b1）而得到和含有有机配体的双金属氰化物配合物催化剂（a1），然后通过开环加成聚合在碱金属催化剂（a2）的存在下聚合环氧乙烷（b2）。

9. 发明申请

US20100096768A1 POLYMER-DISPERSED POLYOL AND PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM 失效
标题翻译：聚合物分散聚合物和生产柔性聚氨酯泡沫的方法
公开(公告)号：US20100096768A1
公开(公告)日：2010-04-22
申请号：US12644043
申请日：2009-12-22
申请人： Takayuki SASAKI , Yasuyuki Sasao , Naohiro Kumagai , Chitoshi Suzuki , Shigeru Ikai
发明人： Takayuki SASAKI , Yasuyuki Sasao , Naohiro Kumagai , Chitoshi Suzuki , Shigeru Ikai
IPC分类号： C08J9/06 , C08K5/06 , C08K5/05 , C08J9/00
CPC分类号： C08G18/3206 , C08F2/20 , C08F2/44 , C08F283/06 , C08G18/4072 , C08G18/4841 , C08G18/4891 , C08G18/632 , C08G18/638 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083 , C08J2205/06
摘要： To provide a process for producing a flexible polyurethane foam having a higher biomass degree than a conventional flexible polyurethane foam and excellent in foam physical properties and its appearance.A polymer-dispersed polyol obtained by polymerizing a vinyl monomer in the presence of the following polyol (a1) derived from a natural fat/oil and/or the following polyoxyalkylene polyol (a2) is used: Polyol (a1) derived from a natural fat/oil: a polyol derived from a natural fat/oil, which is obtained by providing a natural fat/oil with hydroxy groups by chemical reaction, and which has a hydroxy value of from 20 to 250 mgKOH/g and a molecular weight distribution of at least 1.2; Polyoxyalkylene polyol (a2): a polyoxyalkylene polyol which is produced by ring-opening polymerization of an alkylene oxide (c) with the polyol (a1) derived from a natural fat/oil in the presence of at least one polymerization catalyst (b) selected from the group consisting of a coordination anionic polymerization catalyst and a cationic polymerization catalyst.
摘要翻译：提供一种具有比常规柔性聚氨酯泡沫塑料具有更高生物质量并且具有优异的泡沫物理性能及其外观的柔性聚氨酯泡沫体的方法。使用通过在天然油脂和/或下列聚氧化烯多元醇（a2）得到的下列多元醇（a1）存在下使乙烯基单体聚合得到的聚合物分散多元醇：来自天然脂肪的多元醇（a1） /油：衍生自天然油脂的多元醇，其通过化学反应提供具有羟基的天然脂肪/油而得到，羟基值为20〜250mgKOH / g，分子量分布为至少1.2; 聚氧化烯多元醇（a2）：在至少一种聚合催化剂（b）的存在下，通过环氧烷（c）与由天然油脂衍生的多元醇（a1）的开环聚合制备的聚氧化烯多元醇由配位阴离子聚合催化剂和阳离子聚合催化剂组成。

10. 发明申请

US20120252916A1 PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM AND SEAT 审中-公开
标题翻译：生产柔性聚氨酯泡沫和座椅的方法
公开(公告)号：US20120252916A1
公开(公告)日：2012-10-04
申请号：US13438460
申请日：2012-04-03
申请人： Takayuki SASAKI , Naohiro Kumagai , Chitoshi Suzuki , Masahito Furumi
发明人： Takayuki SASAKI , Naohiro Kumagai , Chitoshi Suzuki , Masahito Furumi
IPC分类号： C08G71/04 , C08J9/00
CPC分类号： C08G18/4866 , C08G18/4825 , C08G18/4833 , C08G65/2663 , C08G2101/0008
摘要： A process for producing a flexible polyurethane foam excellent in mechanical strength, and exhibiting reduced shrinkage. The foam is produced using a polyol (A) containing from 40 to 100 mass % of a polyoxyalkylene polyol (A1). The polyoxyalkylene polyol (A1) is produced through an initial step of adding, to a reaction liquid containing an initiator and a double metal cyanide complex catalyst, 5 to 20 mass % of an alkylene oxide, based on the content of the initiator. After the initial step, an alkylene oxide is newly supplied to carry out polymerization. In the initial step, the temperature of the reaction system when addition of the alkylene oxide is started is from 120 to 165° C., and the maximum temperature of the reaction system after the alkylene oxide has been added in the initial step is higher by 15 to 50° C. than the temperature when addition of the alkylene oxide was started.
摘要翻译：一种制造机械强度优异且缩小收缩率低的柔性聚氨酯泡沫的方法。使用含有40〜100质量％聚氧化烯多元醇（A1）的多元醇（A）制造泡沫体。基于引发剂的含量，通过向包含引发剂和双金属氰化物配合物催化剂的反应液中添加5〜20质量％的烯化氧的初始工序来制造聚氧化烯多元醇（A1）。在初始步骤之后，新提供烯化氧以进行聚合。在初始步骤中，开始加入烯化氧时反应体系的温度为120〜165℃，初始阶段加入环氧烷后的反应体系的最高温度高于比加入环氧烷的温度高15〜50℃。

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