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1. 发明授权

US07220809B1 Optical material containing fluorine-containing polymer having functional group 有权
标题翻译：含有具有官能团的含氟聚合物的光学材料
公开(公告)号：US07220809B1
公开(公告)日：2007-05-22
申请号：US10654888
申请日：2003-09-05
申请人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu , Yoshito Ando
发明人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu , Yoshito Ando
IPC分类号： C08F16/24
CPC分类号： G02B1/04 , C08K3/10 , C08K5/0091 , C08L29/10 , C08L33/16 , H01S3/178
摘要： There is provided an optical material obtained from an organic composition which is suitable for an optical material in optical communication and comprises a fluorine-containing polymer having functional group and a rare earth metal ion, in which the fluorine-containing polymer having functional group has at least one ketone structure in its side chain and a maximum absorption coefficient of not more than 1 cm−1 in each wavelength range of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion, europium (Eu) ion, dysprosium (Dy) ion, samarium (Sm) ion and cerium (Ce) ion.
摘要翻译：提供了一种由有机组合物获得的光学材料，其适用于光学连接的光学材料，并且包括具有官能团的含氟聚合物和稀土金属离子，其中具有官能团的含氟聚合物具有其侧链中的至少一个酮结构和在1,290至1,320nm，1,530至1,570nm和600至900nm的每个波长范围内的最大吸收系数不超过1cm -1 -1 稀土金属离子选自铒（Er）离子，ium（Tm）离子，镨（Pr）离子，钬（Ho）离子，钕（Nd）离子，铕（Eu）离子，镝（Dy）离子，钐（Sm）离子和铈（Ce）离子。

2. 发明申请

US20050084231A1 Fluorine-containing optical material containing fluorine-containing polymer having functional group capable of forming complex with rare earth metal ion 审中-公开
标题翻译：含有能够与稀土金属离子形成络合物的具有官能团的含氟聚合物的含氟光学材料
公开(公告)号：US20050084231A1
公开(公告)日：2005-04-21
申请号：US10970650
申请日：2004-10-22
申请人： Takayuki Araki , Yoshito Tanaka , Yoshito Ando , Yuzo Komatsu
发明人： Takayuki Araki , Yoshito Tanaka , Yoshito Ando , Yuzo Komatsu
IPC分类号： G02B6/00 , H01S3/17
CPC分类号： H01S3/17 , H01S3/178
摘要： There is provided an optical material which is an organic composition comprising a rare earth metal ion and a fluorine-containing polymer having functional group being capable of forming a complex with the rare earth metal ion and is suitable as an optical material for optical communication, in which the fluorine-containing polymer having functional group being capable of forming a complex with the rare earth metal ion has a side chain having at least two hetero-atoms in its structural unit and has a maximum absorption coefficient of not more than 1 cm−1 in each bandwidth of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm, and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion, europium (Eu) ion, dysprosium (Dy) ion, samarium (Sm) ion, cerium (Ce) ion and terbium (Tb) ion.
摘要翻译：提供了一种光学材料，其是包含稀土金属离子的有机组合物和具有能够与稀土金属离子形成络合物的官能团的含氟聚合物，并且适合作为用于光学通信的光学材料，具有能够与稀土金属离子形成络合物的官能团的含氟聚合物在其结构单元中具有至少两个杂原子的侧链，并且其最大吸收系数不大于1cm

3. 发明申请

US20060189788A1 Cyclic ether copolymer, coating resin composition, optical devices, and process for production of the devices 审中-公开
标题翻译：环状醚共聚物，涂料树脂组合物，光学元件以及器件生产工艺
公开(公告)号：US20060189788A1
公开(公告)日：2006-08-24
申请号：US10552684
申请日：2004-03-31
申请人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu
发明人： Takayuki Araki , Yoshito Tanaka , Yuzo Komatsu
IPC分类号： C08G65/34
CPC分类号： G02B6/1221 , C08F234/02 , C08G65/14 , C08G65/16 , C08L71/02 , C08L2205/05 , C09D145/00 , C08L2666/04
摘要： This invention provides a cyclic ether copolymer such as a cyclic ether copolymer excellent in solubility in solvents and easy to form uniform thin films therefrom. The present invention relates to a cyclic ether copolymer obtained from a 1,3-dioxole ring structure-containing compound represented by the following general formula (I) and an ethylenically unsaturated monomer: (wherein R1 and R2 are the same or different and each represents F, H, Cl or a perfluoroalkyl group containing 1 to 5 carbon atoms and X1 and X2 are the same or different and each represents F, H, Cl or —OR3, and R3 represents a perfluoroalkyl group containing 1 to 5 carbon atoms, provided that at least one of R1 and R2 is F or a perfluoroalkyl group containing 1 to 5 carbon atoms), which compolymer has a glass transition point of 100 to 135° C. and an intrinsic viscosity of 0.01 to 0.4 dl/g as determined at 35° C. in perfluoro-2-butyltetrahydrofuran.
摘要翻译：本发明提供了一种环状醚共聚物，例如在溶剂中溶解性优异的环状醚共聚物，并且易于形成均匀的薄膜。本发明涉及由以下通式（I）表示的含1,3-二氧杂环环结构的化合物和烯属不饱和单体（其中R 1和R 2）和R 2个相同或不同，各自表示F，H，Cl或含有1至5个碳原子的全氟烷基，X 1和X 2 2 >相同或不同，各自表示F，H，Cl或-OR 3，并且R 3表示含有1至5个碳原子的全氟烷基，条件是在 R 1和R 2中的至少一个为F或含有1至5个碳原子的全氟烷基），该共聚物的玻璃化转变点为100至135℃。并且在35℃下在全氟-2-丁基四氢呋喃中测定的特性粘度为0.01至0.4dl / g。

4. 发明授权

US07262252B2 Nonlinear optical materials comprising fluorine-containing polymer 有权
标题翻译：包含含氟聚合物的非线性光学材料
公开(公告)号：US07262252B2
公开(公告)日：2007-08-28
申请号：US10704829
申请日：2003-11-12
申请人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi , Yuzo Komatsu
发明人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi , Yuzo Komatsu
IPC分类号： F21V9/04 , C07D211/78 , C07D211/90 , C08F20/02 , C08F4/34 , C08F226/06 , C09K19/52
CPC分类号： G02F1/3615 , G02F1/3616 , G02F1/3617
摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.
摘要翻译：提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键并且还提供了由含氟树脂组合物制造的非线性光波导器件。产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

5. 发明申请

US20050004253A1 Nonlinear optical materials comprising fluorine-containing polymer 有权
标题翻译：包含含氟聚合物的非线性光学材料
公开(公告)号：US20050004253A1
公开(公告)日：2005-01-06
申请号：US10704829
申请日：2003-11-12
申请人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi , Yuzo Komatsu
发明人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi , Yuzo Komatsu
IPC分类号： G02F1/361 , C08F2/46
CPC分类号： G02F1/3615 , G02F1/3616 , G02F1/3617
摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.
摘要翻译：提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键并且还提供了由含氟树脂组合物制造的非线性光波导器件。产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

6. 发明申请

US20070197718A1 Photofunctional optical material comprising fluorine-containing acrylate polymer 审中-公开
标题翻译：包含含氟丙烯酸酯聚合物的光功能光学材料
公开(公告)号：US20070197718A1
公开(公告)日：2007-08-23
申请号：US10594922
申请日：2005-03-11
申请人： Yoshito Ando , Takayuki Araki , Yoshito Tanaka
发明人： Yoshito Ando , Takayuki Araki , Yoshito Tanaka
IPC分类号： C08L33/00
CPC分类号： C08F214/18 , C08K3/10 , C08L33/16 , G02B6/138 , G03F7/0046 , G03F7/027 , H01S3/168 , C08L2666/02
摘要： There is provided the photofunctional optical material which is excellent in an intensity of light emission, light emitting efficiency and/or light amplifying property and also is excellent in processability, for example, easy processing into an optical waveguide device. The photofunctional optical material contains a fluorine-containing acrylate, a polyfunctional acrylate and a rare earth metal compound. There is also provided the composition containing a fluorine-containing acrylate, a polyfunctional acrylate and a rare earth metal compound and is suitable for an optical material.
摘要翻译：提供了发光强度，发光效率和/或光放大性优异的光功能性光学材料，并且加工性能优异，例如易于加工成光波导器件。光功能性光学材料含有含氟丙烯酸酯，多官能丙烯酸酯和稀土金属化合物。还提供了含有含氟丙烯酸酯，多官能丙烯酸酯和稀土金属化合物的组合物，并且适用于光学材料。

7. 发明授权

US07214470B2 Fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and fluorine-containing polymer prepared by polymerization of same 有权
标题翻译：具有羟基或氟代烷基羰基的含氟乙烯性单体和通过聚合制备的含氟聚合物
公开(公告)号：US07214470B2
公开(公告)日：2007-05-08
申请号：US10644953
申请日：2003-08-21
申请人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
发明人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
IPC分类号： G03F7/038
CPC分类号： G03F7/091 , C07C33/423 , C07C43/178 , C07C45/45 , C07C49/227 , C07C49/255 , C08F16/04 , C08F16/34 , C08F216/04 , G03F7/0046 , G03F7/0382 , G03F7/0392
摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.
摘要翻译：提供具有羟基或氟代烷基羰基并由式（1）表示的含氟乙烯性单体：和式（14）：其中X 1和X 2 相同或不同，分别为H或F; X 3是H，F，Cl或CF 3; Rf 1和Rf 2相同或不同，各自为具有1至20个碳原子的全氟烷基; Rf 3是具有1〜40个碳原子的含氟亚烷基或具有1〜100个碳原子的醚键的含氟亚烷基，碳原子和氧原子之和为2 或者更多; a为0或1，具有上述单体的结构单元的含氟聚合物和光致抗蚀剂的组合物。单体具有良好的聚合性，特别是自由基聚合性，通过聚合单体获得的聚合物具有优异的光学特性，可用作抗反射膜和抗蚀剂组合物的基础聚合物。

8. 发明申请

US20070172763A1 Fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and fluorine-containing polymer prepared by polymerization of same 审中-公开
公开(公告)号：US20070172763A1
公开(公告)日：2007-07-26
申请号：US11727908
申请日：2007-03-29
申请人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
发明人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
IPC分类号： G03C1/00 , C08F12/20 , C07C43/17
CPC分类号： G03F7/091 , C07C33/423 , C07C43/178 , C07C45/45 , C07C49/227 , C07C49/255 , C08F16/04 , C08F16/34 , C08F216/04 , G03F7/0046 , G03F7/0382 , G03F7/0392
摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.

9. 发明授权

US07378154B2 Photofunctional laminated article 有权
标题翻译：光功能层压制品
公开(公告)号：US07378154B2
公开(公告)日：2008-05-27
申请号：US11578054
申请日：2005-03-11
申请人： Yoshito Ando , Takayuki Araki
发明人： Yoshito Ando , Takayuki Araki
IPC分类号： B32B7/02 , B32B17/06 , B32B9/00 , B32B27/30
CPC分类号： H05B33/20 , C09K11/06 , C09K2211/182 , H01L51/0089 , Y10T428/31504 , Y10T428/3154
摘要： There is provided a photofunctional laminated article being excellent in various photofunctionalities, particularly an intensity of light emission, light emitting efficiency and further fluorescence life and light amplifying property. The photofunctional laminated article comprises the transparent substrate (L0), the photofunctional layer (L1) comprising the fluorine-containing polymer (A) and the rare earth metal compound (B) and being formed on the substrate (L0) and the low refractive index layer (L2) formed on the photofunctional layer (L1), and when refractive indices of each layer are assumed to be n(L0), n(L1) and n(L2), the following equation: n(L0)≧n(L1)>n(L2) is satisfied.
摘要翻译：提供了各种光功能特别优异的发光强度，发光效率和荧光寿命以及光放大性能的光功能性层压制品。光功能性层压制品包括透明基材（L0），包含含氟聚合物（A）和稀土金属化合物（B）的光官能层（L1）并形成在基材（L0）上，低折射率形成在光功能层（L1）上的层（L2），并且当各层的折射率被假设为n（L0），n（L1）和n（L2）时，下列等式：n（L0）> = n （L1）> n（L2）。

10. 发明申请

US20070218289A1 Photofunctional Laminated Article 有权
标题翻译：光功能层压制品
公开(公告)号：US20070218289A1
公开(公告)日：2007-09-20
申请号：US11578054
申请日：2005-03-11
申请人： Yoshito Ando , Takayuki Araki
发明人： Yoshito Ando , Takayuki Araki
IPC分类号： B32B27/30 , B32B7/02
CPC分类号： H05B33/20 , C09K11/06 , C09K2211/182 , H01L51/0089 , Y10T428/31504 , Y10T428/3154
摘要： There is provided a photofunctional laminated article being excellent in various photofunctionalities, particularly an intensity of light emission, light emitting efficiency and further fluorescence life and light amplifying property. The photofunctional laminated article comprises the transparent substrate (L0), the photofunctional layer (L1) comprising the fluorine-containing polymer (A) and the rare earth metal compound (B) and being formed on the substrate (L0) and the low refractive index layer (L2) formed on the photofunctional layer (L1), and when refractive indices of each layer are assumed to be n(L0), n(L1) and n(L2), the following equation: n(L0)≧n(L1)>n(L2) is satisfied.
摘要翻译：提供了各种光功能特别优异的发光强度，发光效率和荧光寿命以及光放大性能的光功能性层压制品。光功能性层压制品包括透明基材（L0），包含含氟聚合物（A）和稀土金属化合物（B）的光官能层（L1）并形成在基材（L0）上，低折射率形成在光功能层（L1）上的层（L2），并且当各层的折射率被假设为n（L0），n（L1）和n（L2）时，下列等式：n（L0）> = n （L1）> n（L2）。

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