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    • 2. 发明授权
    • Electrochromic device and multilayer glazing
    • 电致变色装置和多层玻璃
    • US5721633A
    • 1998-02-24
    • US616252
    • 1996-03-15
    • Junichi NagaiTetsuya Seike
    • Junichi NagaiTetsuya Seike
    • G02F1/15G02F1/153
    • G02F1/1525
    • An electrochromic device of wholly solid type comprising a transparent substrate and a transparent electroconductive film formed on the substrate, and having an oxidation color forming oxide, a cation conductive layer as an electrolyte, a reduction color forming oxide and a transparent electroconductive film, formed sequentially on said transparent electroconductive film formed on the substrate, wherein: (1) the oxidation color forming oxide is a p-type semiconductor of nickel oxide or cobalt oxide, (2) the cation conductive layer has OH groups showing a peak at about 3,300 (1/cm) in its infrared reflectance spectrum and is made of proton conductive SbO.sub.c wherein 1.3.ltoreq.c.ltoreq.2.7, or at least one lithium conductive lithium-containing oxide of LiO.sub.d MO.sub.e wherein 0.01.ltoreq.d.ltoreq.1.0, 1.3.ltoreq.e.ltoreq.2.7, and M is an element selected from the group consisting of Nb, Sb, B, P, Si, Ge, Al, Ce, La and Zr and (3) the reduction color forming oxide is tungsten oxide, molybdenum oxide or titanium oxide.
    • 一种完全固体型的电致变色装置,包括透明基板和形成在基板上的透明导电膜,并且具有形成氧化色的氧化物,阳离子导电层作为电解质,还原成色氧化物和透明导电膜,顺序地形成 在所述基板上形成的所述透明导电膜上,其中:(1)所述氧化形成型氧化物为氧化镍或氧化钴的p型半导体,(2)所述阳离子导电层的OH基在3300左右 1 / cm),由质子传导性SbOc(其中1.3%= 2.7)或LiOdMOe的至少一种含锂导电的含锂氧化物制成,其中0.01≤d≤1.0, 1.3是选自Nb,Sb,B,P,Si,Ge,Al,Ce,La和Zr的元素,(3)还原形成氧化物是 氧化钨,氧化钼或氧化钛。