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1. 发明授权

US5708523A Counterelectrode for smart window and smart window 失效
标题翻译： Countererelectrode智能窗口和智能窗口
公开(公告)号：US5708523A
公开(公告)日：1998-01-13
申请号：US633932
申请日：1996-04-17
申请人： Takaya Kubo , Hiroshi Kobayashi , Yoshinori Nishikitani , Nobuyuki Kuroda , Tetsuya Seike , Junichi Nagai
发明人： Takaya Kubo , Hiroshi Kobayashi , Yoshinori Nishikitani , Nobuyuki Kuroda , Tetsuya Seike , Junichi Nagai
IPC分类号： G02F1/155 , G02F1/153
CPC分类号： G02F1/155
摘要： A counterelectrode for a smart window contains a transparent electrically conductive substrate and a plurality of electrically conductive dots arrayed on the transparent electrically conductive substrate. Each of the electrically conductive dots contains fine particles having capacitance of not less than 1 farad/g or fine particles capable of storing electrical charge of not less than 1 coulomb/g. A smart window contains the aforementioned counterelectrode.
摘要翻译：用于智能窗的反电极包含透明导电衬底和排列在透明导电衬底上的多个导电点。每个导电点包含具有不小于1法拉德/克的电容的细颗粒或能够存储不少于1库伦/克的电荷的微粒。智能窗口包含上述的反电极。

2. 发明授权

US5940202A Counterelectrode for smart window and smart window 失效
标题翻译： Countererelectrode智能窗口和智能窗口
公开(公告)号：US5940202A
公开(公告)日：1999-08-17
申请号：US911229
申请日：1997-08-15
申请人： Yoshinori Nishikitani , Takaya Kubo , Nobuyuki Kuroda
发明人： Yoshinori Nishikitani , Takaya Kubo , Nobuyuki Kuroda
IPC分类号： G02F1/155 , G02F1/153
CPC分类号： G02F1/155 , G02F2001/1555
摘要： A counterelectrode for a smart window contains a transparent substrate and a linear electrically conductive material formed on a surface of the transparent substrate. The electrically conductive material has a surface area of not less than 10 m.sup.2 /g and electrical conductivity of not less than 10.sup.-6 .OMEGA..sup.-1 .multidot.cm.sup.-1 at 25.degree. C. A smart window contains an electrochromic electrode having a layer of an electrochromic material formed on its surface, and a layer of an electrolyte arranged between the counterelectrode and the electrochromic electrode and in contact with the layer of the electrochromic material.
摘要翻译：用于智能窗的反电极包含形成在透明基板的表面上的透明基板和线性导电材料。导电材料在25℃下的表面积不小于10m 2 / g，电导率不小于10-6MEGA-1×cm-1。智能窗包括具有电致变色材料层的电致变色电极形成在其表面上，以及布置在反电极和电致变色电极之间并与电致变色材料层接触的电解质层。

3. 发明授权

US5724176A Counterelectrode for smart window and smart window 失效
公开(公告)号：US5724176A
公开(公告)日：1998-03-03
申请号：US536957
申请日：1995-09-29
申请人： Yoshinori Nishikitani , Takaya Kubo , Nobuyuki Kuroda
发明人： Yoshinori Nishikitani , Takaya Kubo , Nobuyuki Kuroda
IPC分类号： G02F1/155 , G02F1/153
CPC分类号： G02F1/155 , G02F2001/1555
摘要： A counterelectrode for a smart window contains a transparent substrate and a linear electrically conductive material formed on a surface of the transparent substrate. The electrically conductive material has a surface area of not less than 10 m.sup.2 /g and electrical conductivity of not less than 10.sup.-6 .OMEGA..sup.-1 .multidot.cm.sup.-1 at 25.degree. C. A smart window contains an electrochromic electrode having a layer of an electrochromic material formed on its surface, and a layer of an electrolyte arranged between the counterelectrode and the electrochromic electrode and in contact with the layer of the electrochromic material.

4. 发明授权

US5231329A Organic thin film electroluminescent device 失效
标题翻译：有机薄膜电致发光器件
公开(公告)号：US5231329A
公开(公告)日：1993-07-27
申请号：US728646
申请日：1991-07-11
申请人： Yoshinori Nishikitani , Naoki Kataoka , Nobuyuki Kuroda , Kazuo Matsuura
发明人： Yoshinori Nishikitani , Naoki Kataoka , Nobuyuki Kuroda , Kazuo Matsuura
IPC分类号： C08F20/34 , C09K11/06 , H01L51/30 , H01L51/50 , H05B33/14 , H05B33/20 , H05B33/28
CPC分类号： H05B33/28 , H01L51/004 , H01L51/5012 , H05B33/14 , H05B33/20 , Y10S428/917
摘要： An organic thin film electroluminescent device is composed of an electron transport layer, a hole transport layer and a transparent electrode. The electron transport layer is constituted of an electron conducting polymer represented by the formula (I) ##STR1## wherein R.sup.1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R.sup.2 is a hydrogen atom, an alkyl or alkoxy group having 1 to 4 carbon atoms, an aryl group, an aryloxy group, a thioether group, an amino group, a halogen atom, an aldehyde group, a cyano group, a nitro group or a hydroxyl group, x is an integer of 1 to 6, on the condition that, if x is an integer of 2 to 6, R.sup.2 may be the same or different, and n is an integer not less than 2.
摘要翻译：有机薄膜电致发光器件由电子传输层，空穴传输层和透明电极组成。电子传输层由式（I）表示的电子传导性聚合物构成：其中R1是氢原子或具有1-4个碳原子的烷基，R2是氢原子，烷基或具有1至4个碳原子的烷氧基，芳基，芳氧基，硫醚基，氨基，卤素原子，醛基，氰基，硝基或羟基，x是在1〜6的情况下，如果x为2〜6的整数，则R2可以相同也可以不同，n为2以上的整数。

5. 发明授权

US5013802A Process for preparing ethylene polymers 失效
标题翻译：制备乙烯聚合物的方法
公开(公告)号：US5013802A
公开(公告)日：1991-05-07
申请号：US427941
申请日：1989-10-25
申请人： Yoshio Tajima , Kazutosi Nomiyama , Yoshinori Nishikitani , Nobuyuki Kuroda , Kazuo Matsuura
发明人： Yoshio Tajima , Kazutosi Nomiyama , Yoshinori Nishikitani , Nobuyuki Kuroda , Kazuo Matsuura
IPC分类号： C08F2/14 , C08F4/60 , C08F4/62 , C08F4/64 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F210/16 , Y10S526/905
摘要： A process for preparing an ethylene polymer by a two-stage polymerization of ethylene or ethylene and an .alpha.-olefin in an inert hydrocarbon at 50.degree.-100.degree. C. using a coordination polymerization catalyst containing a solid component and an organoaluminum compound, said solid component containing a transition metal compound, which process comprises:(a) in a first stage, producing 10-90% by weight based on the total polymer quantity of a polymer having a melt index in the range of 0.0001 to 0.5 g/10 min as measured according to ASTM D 1238-73, Condition E, using as said solid component a solid product obtained by supporting chromium trioxide or a compound which on calcining forms chromium oxide at least partially, on an inorganic oxide carrier followed by calcining, and using as said organoaluminum compound a compound of the general formula ##STR1## wherein R is a hydrocarbon radical having 1 to 18 carbon atoms and n is 2.ltoreq.n.ltoreq.100; and(b) in a second stage, producing 90-10% by weight based on the total polymer quantity of a polymer having a melt index in the range of 0.01 to 50 g/10 min as measured according to ASTM D 1238-73, Condition E, using as said solid component a solid material containing at least magnesium and titanium, and using as said organoaluminum compound a compound of the general formula AlR'.sub.p X.sub.3-p wherein R' is a hydrocarbon radical having 1 to 20 carbon atoms, X is halogen and/or alkoxy and p is 0
摘要翻译：一种通过使用含有固体组分和有机铝化合物的配位聚合催化剂在50-100℃下在惰性烃中进行乙烯或乙烯和α-烯烃两步聚合制备乙烯聚合物的方法，所述固体含有过渡金属化合物的组分，该方法包括：（a）在熔融指数在0.0001至0.5g / 10min范围内的聚合物的总聚合物量的第一阶段中，产生10-90重量％根据ASTM D 1238-73，条件E测量，使用通过将无机氧化物载体上的三氧化铬或煅烧至少部分形成的氧化铬上的化合物或三价氧化物得到的固体产物作为所述固体成分进行煅烧，并使用所述有机铝化合物是通式为“IMAGE”的化合物，其中R为具有1至18个碳原子的烃基，n为2

6. 发明授权

US5051486A Preparation of polymers useful as polymeric solid electrolytes and compatibilizers 失效
标题翻译：可用作聚合固体电解质和增容剂的聚合物的制备
公开(公告)号：US5051486A
公开(公告)日：1991-09-24
申请号：US576152
申请日：1990-08-29
申请人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
发明人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
IPC分类号： C08G65/08 , C07F7/18 , C08F20/10 , C08F120/10 , C08F290/00 , C08F290/06 , C08F299/00 , C08G65/02 , C08G65/336
CPC分类号： C08G65/336 , C07F7/184 , C08F290/062
摘要： A macromer of the general formula (3) is prepared by a reaction between a silane compound of the general formula (1) and a polyethylene glycol monoalkyl ether of the general formula (2). ##STR1##H--OCH.sub.2 CH.sub.2 .sub.m OR.sub.3 (2) ##STR2## R.sub.1 : H, or C.sub.1 -C.sub.5 alkyl group; R.sub.2 : H, C.sub.1 -C.sub.5 alkyl group, or --OCH.sub.2 CH.sub.2).sub.p OR.sub.4 ;R.sub.3 : C.sub.1 -C.sub.10 alkyl;R.sub.4 : C.sub.1 -C.sub.10 alkyl;l: integer of from 1 to 10 (1.ltoreq.l.ltoreq.10);m: integer of from 1 to 30 (1.ltoreq.m.ltoreq.30); andp: integer of from 1 to 30 (1.ltoreq.p.ltoreq.30).

7. 发明授权

US5194490A Preparation process of polymeric solid electrolyte 失效
标题翻译：聚合物固体电解质的制备工艺
公开(公告)号：US5194490A
公开(公告)日：1993-03-16
申请号：US668889
申请日：1991-03-13
申请人： Masanobu Suga , Hiroshi Kobayashi , Nobuyuki Kuroda , Kazuo Matsuura , Seiichi Akita
发明人： Masanobu Suga , Hiroshi Kobayashi , Nobuyuki Kuroda , Kazuo Matsuura , Seiichi Akita
IPC分类号： C08F290/06 , H01B1/12 , H01M6/18
CPC分类号： H01M6/181 , C08F290/062 , H01B1/122
摘要： The invention provides a process for readily preparing polymeric solid electrolyte, i.e., ion conductive polymer having excellent properties.The process of the invention comprises steps of subjecting at least one of the following component A and component B to contain an alkali metal salt and/or an ammonium salt and mixing the components A and the component B.Component A: a solution obtained by dissolving a radical polymerization promotor in a specific polyether base macromonomer.Component B: a solution obtained by dissolving a radical polymerization initiator in a specific polyether base oligomer and/or an organic non-aqueous solvent.To at least one of the component A and component B, a radical polymerization retarder is added, if desired.The process of the invention can be carried out by a simple step comprised of mixing the two components at room temperature and provides the solid polyelectrolyte having a high inonic conductivity.The high-ion-conductive solid polyelectrolyte prepared by the process of the invention is very useful as a raw material for lithium cells, plastic cells, large capacity electrostatic capacitors, electrochromic displays and other overall solidificated systems.

8. 发明授权

US5045619A N-alkenylcarbamate macromer 失效
标题翻译： N-链烯基氨基甲酸酯大分子单体
公开(公告)号：US5045619A
公开(公告)日：1991-09-03
申请号：US336588
申请日：1989-04-10
申请人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
发明人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
IPC分类号： C07C271/42 , C07C67/00 , C07C239/00 , C07C271/10 , C08F26/00 , C08F26/02 , C08F290/06 , H01B1/12
CPC分类号： C08F26/02 , C08F290/062
摘要： A novel N-alkenylcarbamate macromer is disclosed. The macromer can be prepared by reacting an alkenyl isocyanate with a polyalkylene glycol monoalkyl ether. When polymerized or copolymerized with other monomers, the macromer produces comb-shaped polymers useful as compatibilizing agents, matrices for polymeric solid electrolytes, etc.
摘要翻译：公开了一种新的N-链烯基氨基甲酸酯大分子单体。大分子单体可以通过烯基异氰酸酯与聚亚烷基二醇单烷基醚反应来制备。当与其他单体聚合或共聚时，大分子单体产生可用作相容剂的梳状聚合物，聚合物固体电解质的基质等。

9. 发明授权

US4978473A Polymeric solid electrolyte 失效
标题翻译：聚合物固体电解质
公开(公告)号：US4978473A
公开(公告)日：1990-12-18
申请号：US354374
申请日：1989-05-19
申请人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
发明人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
IPC分类号： C08F299/00 , C08F2/44 , C08F290/00 , C08F290/06 , C08F299/02 , G02F1/15 , H01B1/06 , H01B1/12 , H01M6/18
CPC分类号： G02F1/1525 , H01M6/181
摘要： The present invention relates to a polymeric solid electrolyte which comprises a network molecule formed by polymerizing a polyethylene glycol with acrylic or methacrylic groups at both ends, and containing therein (a) a specific acrylate-type copolymer, (b) a low molecular polyethylene glycol with both ends methyl-esterified, and (c) an alkali metal salt or ammonium salt. The polymeric solid electrolyte of the present invention has an ionic conductivity of 10.sup.-5 S/cm or higher at room temperature, is strong in film strength even with a thickness of 100 .mu.m or less, and is superb in adherence to electrodes.
摘要翻译：聚合物固体电解质本发明涉及聚合物固体电解质，其包含通过在两端聚合聚乙二醇与丙烯酸或甲基丙烯酸基团而形成的网络分子，并且其中含有（a）特定的丙烯酸酯类共聚物，（b）低分子量聚乙二醇其两端被甲基酯化，和（c）碱金属盐或铵盐。本发明的聚合物固体电解质在室温下的离子电导率为10-5S / cm以上，即使是100μm以下的厚度，膜强度也很强，并且对电极的粘附性极好。

10. 发明授权

US4970012A Polymeric solid electrolytes and production process thereof 失效
标题翻译：聚合固体电解质及其制备方法
公开(公告)号：US4970012A
公开(公告)日：1990-11-13
申请号：US444947
申请日：1989-12-04
申请人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
发明人： Nobuyuki Kuroda , Hiroshi Kobayashi , Kazuo Matsuura
IPC分类号： C08F299/00 , C08F290/00 , C08F299/02 , C08L57/00 , C08L71/02 , H01B1/12 , H01G9/02 , H01G9/025 , H01M6/18
CPC分类号： H01G9/025 , C08L71/02 , H01B1/122 , H01M6/181
摘要： Polymeric solid electrolytes are formed by the present invention, namely, by incorporating a low molecular weight polyethylene glycol, a high molecular weight polyethylene oxide and an alkali metal or ammonium salt in a specific cinnamate ester compound, followed by a polymerization and crosslinking. The polymeric solid electrolytes have high ionic conductivity, high strength as a film, and good adhesion with electrodes. Therefore, they can be applied widely as ionics materials, e.g., for the total solidification of lithium batteries and plastic batteries and high capacity condensers and as electrolytes for electrochromic displays.
摘要翻译：通过本发明形成聚合物固体电解质，即通过在特定肉桂酸酯化合物中引入低分子量聚乙二醇，高分子量聚环氧乙烷和碱金属盐或铵盐，然后进行聚合和交联。聚合物固体电解质具有高离子导电性，作为膜的高强度，以及与电极的良好粘合性。因此，它们可以广泛地用作离子材料，例如用于锂电池和塑料电池和高容量电容器的总体固化，以及用于电致变色显示器的电解质。

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