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1. 发明授权

US3952125A Electrically insulating material 失效
标题翻译：电绝缘材料
公开(公告)号：US3952125A
公开(公告)日：1976-04-20
申请号：US500502
申请日：1974-08-26
申请人： Takatoshi Kuratsuji , Hiroo Shima , Takeo Shima , Shoji Kawase , Sakae Shimotsuma , Masahiro Hosoi
发明人： Takatoshi Kuratsuji , Hiroo Shima , Takeo Shima , Shoji Kawase , Sakae Shimotsuma , Masahiro Hosoi
IPC分类号： H01B3/42 , C08G63/12
CPC分类号： H01B3/423 , Y10T428/266
摘要： An electrically insulating material composed of an unstretched film of a substantially linear polyester at least 85 mol% of the recurring units of which consist of a hexamethylene naphthalene-2,6-dicarboxylate unit and which has an intrinsic viscosity, as measured on its ortho-chlorophenol solution at 35.degree.C., of at least 0.3.
摘要翻译：由绝缘材料构成的电绝缘材料，其基本线性聚酯的至少85摩尔％的重复单元的未拉伸膜由六亚甲基萘-2,6-二甲酸酯单元组成，并且其特性粘度为其邻位 - 氯酚溶液在35℃，至少0.3。

2. 发明授权

US3963844A Extrusion-molded article having good thermal stability 失效
标题翻译：具有良好热稳定性的挤压成型品
公开(公告)号：US3963844A
公开(公告)日：1976-06-15
申请号：US478101
申请日：1974-06-10
申请人： Sakae Shimotsuma , Masahiro Hosoi , Takatoshi Kuratsuji , Shoji Kawase , Takeo Shima
发明人： Sakae Shimotsuma , Masahiro Hosoi , Takatoshi Kuratsuji , Shoji Kawase , Takeo Shima
IPC分类号： B29C47/00 , B29C47/78 , B29C47/88 , B29D7/01 , C08L67/02 , F16L9/12
CPC分类号： C08J7/08 , B29C47/00 , B29C47/0021 , B29C47/0026 , B29C47/786 , B29C47/862 , B29C47/88 , B29C47/8815 , B29C47/8845 , B29C47/8875 , B29C47/8895 , C08J2367/00 , C08J2367/02 , Y10T428/139 , Y10T428/261 , Y10T428/268 , Y10T428/269 , Y10T428/31786
摘要： A thermally stable extrusion-molded article characterized by (1) consisting of a substantially linear polyester in which at least 90 mol% of the total recurring units consist of tetramethylene 2,6-naphthalate units, (2) having a density not in excess of 1.318, and (3) being in the unstretched state.This article is prepared by extruding a melt of a substantially linear polyester in which at least 90 mol% of the total recurring units consist of tetramethylene 2,6-naphthalate units into the form of a molded structure, and cooling the extruded molded structure to room temperature, wherein during the period in which the extruded molded structure is cooled from at least 75%C. to room temperature, the cooling of the molded structure is performed rapidly so that the density of the molded structure does not exceed 1.318.
摘要翻译：一种热稳定的挤出模塑制品，其特征在于（1）由基本上线性的聚酯组成，其中至少90摩尔％的总重复单元由2,6-萘二甲酸丁二烯酯单元组成，（2）密度不超过 1.318，（3）处于未拉伸状态。

3. 发明授权

US3961008A Process for preparing polyester shaped articles 失效
标题翻译：聚酯成型制品的制备方法
公开(公告)号：US3961008A
公开(公告)日：1976-06-01
申请号：US500503
申请日：1974-08-26
申请人： Takatoshi Kuratsuji , Shoji Kawase , Takeo Shima , Sakae Shimotsuma , Masahiro Hosoi
发明人： Takatoshi Kuratsuji , Shoji Kawase , Takeo Shima , Sakae Shimotsuma , Masahiro Hosoi
IPC分类号： B29C61/00 , B29C47/00 , B29C47/78 , B29C47/88 , B29D7/01 , B29C25/00 , B29D23/04
CPC分类号： C08J7/08 , B29C47/00 , B29C47/0021 , B29C47/0023 , B29C47/0026 , B29C47/862 , B29C47/88 , B29C47/8805 , B29C47/8815 , B29C47/8845 , B29C47/8895 , B29C47/0019 , C08J2367/00 , C08J2367/02
摘要： A process for preparing a shaped article by melt-extruding a polyester containing tetramethylene naphthalene-2,6-dicarboxylate or hexamethylene naphthalene-2,6-dicarboxylate as a main recurring unit, wherein the extrudate is exposed to a temperature of 75.degree. to 450.degree.C. for 1 to 180 seconds immediately after extrusion.
摘要翻译：通过熔融挤出含有2,6-萘二甲酸2,6-二甲酯或六亚甲基萘-2,6-二羧酸六亚甲酯的聚酯作为主要重复单元制备成型制品的方法，其中将挤出物暴露于75℃至450℃的温度在挤出后立即进行1至180秒。

4. 发明授权

US4060516A Naphthalate polyester filaments 失效
标题翻译：萘二甲酸酯聚酯长丝
公开(公告)号：US4060516A
公开(公告)日：1977-11-29
申请号：US646645
申请日：1976-01-05
申请人： Takatoshi Kuratsuji , Shoji Kawase , Takeo Shima
发明人： Takatoshi Kuratsuji , Shoji Kawase , Takeo Shima
IPC分类号： C08G63/189 , D01F6/62 , C08G63/18 , C08G63/70
CPC分类号： C08G63/189 , D01F6/62
摘要： Naphthalate polyester filaments, yarns or fibers consisting essentially of a naphthalate polyester which has an intrinsic viscosity of 0.3 to 3.5 and a softening point of at least 200.degree. C, and in which at least 85 mol% of the total recurring units consist of units of the formula ##STR1## wherein n is 4 or 6, and having at least one diffraction peak at a Bragg scattering angle 2.theta. = 16.3.degree. -- 16.7.degree. and/or 2.theta. = 25.3.degree. - 25.8.degree. in their X-ray diffraction. These filaments, yarns or fibers are useful especially as an electrically insulating material, an elastomeric reinforcing material, a fluid filter material, a paper-making canvas and a fastener component material.Of these, filaments, yarns or fibers of poly(tetramethylene 2,6-naphthalate) are prepared by melt-spinning the polymer thereby to form undrawn filaments having a birefringence of at lest 0.01 and a density of not more than 1.300, drawing the undrawn filaments in at least one step at a temperature of at least 60.degree. C. at a total draw ratio of at least 1.8, and then heat-treating the drawn filaments at a temperature higher than the temperature employed in the drawing step and within a range of 100.degree. to 240.degree. C. at constant length, under a restricted shrinkage of not more than 15%, or under a stretch of not more than 15%.
摘要翻译：萘二甲酸酯聚酯长丝，基本上由萘甲酸酯聚酯组成的纱线或纤维，其特性粘度为0.3-3.5，软化点为至少200℃，其中至少85mol％的总重复单元由其中n为4或6，并且在其X射线衍射中在布喇格散射角2θ= 16.3°-16.7°和/或2θ= 25.3°-25.8°处具有至少一个衍射峰的式。这些长丝，纱线或纤维特别用作电绝缘材料，弹性体增强材料，流体过滤材料，造纸帆布和紧固件组件材料。

5. 发明授权

US4066624A Polyesters of naphthalene carboxylic acids and hydroxy alkoxydiphenyl sulfones 失效
标题翻译：萘二羧酸和羟基烷基二苯基磺酸酯的聚酯
公开(公告)号：US4066624A
公开(公告)日：1978-01-03
申请号：US542793
申请日：1975-01-21
申请人： Shoji Kawase , Takatoshi Kuratsuji , Hiroo Inata , Kazuyoshi Suzuki , Takeo Shima
发明人： Shoji Kawase , Takatoshi Kuratsuji , Hiroo Inata , Kazuyoshi Suzuki , Takeo Shima
IPC分类号： C08G63/00 , C08G63/688 , C08G63/18 , C08G63/66 , C08G63/68
CPC分类号： C08G63/6886
摘要： A process for preparing polyesters, which comprises reacting (A) a difunctional carboxylic acid component containing at least 50 mol% of a naphthalene dicarboxylic acid and/or its ester-forming derivative, (B) a diol component containing an aromatic group and at least 50 mol% of a 4,4'-bis-(.omega.-hydroxyalkoxy)diphenylsulfone and (C) an aliphatic or alicyclic diol component, the molar ratio of component (B) to component (A) being 0.05-1, and the molar ratio of the sum of components (B) and (C) to component (A) being 1.1-3.0; and then polymerizing the resulting reaction product in the presence of a catalyst while distilling off the excess of the component (C) out of the reaction system, thereby to form a polymer having a reduced viscosity of at least 0.5.

6. 发明授权

US5175043A Aromatic polymer molded article with modified surface condition and process for producing the same 失效
标题翻译：具有改性表面状态的芳族聚合物成型品及其制造方法
公开(公告)号：US5175043A
公开(公告)日：1992-12-29
申请号：US392929
申请日：1991-01-07
申请人： Akira Yabe , Hiroyuki Niino , Shozaburo Nagano , Masahiro Hosoi , Takatoshi Kuratsuji , Kazuaki Hotta , Masashi Nakano
发明人： Akira Yabe , Hiroyuki Niino , Shozaburo Nagano , Masahiro Hosoi , Takatoshi Kuratsuji , Kazuaki Hotta , Masashi Nakano
IPC分类号： B29C35/08 , B29C59/16 , B41M5/26 , B41M5/36 , G11B7/245 , G11B7/26
CPC分类号： B29C59/16 , B41M5/267 , G11B7/245 , G11B7/263 , B29C2035/0827 , B29C2035/0838 , B29C2791/009 , B29K2063/00 , B29K2067/00 , B29K2069/00 , B29K2071/00 , B29K2077/10 , B29K2079/08 , B29K2081/04 , B29K2081/06 , B29K2995/0021 , B41M5/262 , B41M5/36 , Y10T428/24479 , Y10T428/24942
摘要： The present invention lies in a process for modifying the surface of a molded article, which process comprises irradiating the surface of a molded article composed of an aromatic polymer or a polymer composition containing said aromatic polymer, with an ultraviolet laser beam having a wavelength of about 150 nm-380 nm at a fluence at least lower than the threshold to modify the surface as compared with the condition before the irradiation. The process makes it possible to modify the condition of the laser beam-irradiated surface portions of the molded article to, for example, a white color or black color, whereby the molded article can be endowed with functions and properties required in its use in various applications.
摘要翻译： PCT No.PCT / JP88 / 01252 Sec。 371日期1991年1月7日 102（e）日期1991年1月7日PCT提交1988年12月10日PCT公布。第WO89 / 05330号公报日本1982年6月15日。本发明在于改性成型体的表面的方法，该方法包括将由芳族聚合物或含有所述芳族聚合物的聚合物组合物组成的模塑制品的表面与紫外线与照射前的条件相比，以能量密度至少低于阈值的波长为约150nm-380nm的激光束来修饰表面。该方法使得可以将模制品的激光束照射的表面部分的状态改变为例如白色或黑色，由此模制品可以赋予其在各种使用中所需的功能和性能应用程序。

7. 发明授权

US4107143A Aromatic polyester carbonate and method for producing the same 失效
标题翻译：芳香族聚碳酸酯及其制造方法
公开(公告)号：US4107143A
公开(公告)日：1978-08-15
申请号：US765333
申请日：1977-02-03
申请人： Hiroo Inata , Tsuto Morinaga , Takatoshi Kuratsuji , Takanori Urasaki , Shoji Kawase
发明人： Hiroo Inata , Tsuto Morinaga , Takatoshi Kuratsuji , Takanori Urasaki , Shoji Kawase
IPC分类号： C08G63/64 , C08G63/62
CPC分类号： C08G63/64
摘要： The present invention provides a substantially linear aromatic polyester carbonate consisting essentially of hydroxybenzoic acid unit, hydroquinone unit, and carbonate unit as well as, depending on the circumstances, aromatic carboxylic acid unit, and having an inherent viscosity of at least 0.5. The present invention also provides an industrially advantageous method for producing such linear aromatic polyester carbonate through the process steps of melt-polycondensation, and, if necessary, followed by a further polycondensation in solid phase.Such aromatic polyester carbonate which the present invention provides exhibits excellent melt-forming property and melt anisotropy, hence any shaped article obtained by melt-forming of this aromatic polyester carbonate exhibits superior mechanical properties, in particular, excellent Young's modulus of longitudinal elasticity, and so on, which is highly useful as the material for industrial applications. The present invention also provides shaped articles in fiber and film forms having such excellent Young's modulus of longitudinal elasticity as produced from the abovementioned aromatic polyester carbonate.
摘要翻译：本发明提供基本上由羟基苯甲酸单元，氢醌单元和碳酸酯单元组成的基本上线性的芳族聚酯碳酸酯，以及根据具体情况，芳族羧酸单元，并且具有至少0.5的特性粘度。本发明还提供了通过熔融缩聚的方法制备这种线性芳族聚酯碳酸酯的工业上有利的方法，并且如果需要，随后进一步在固相中缩聚。

8. 发明授权

US4051112A Polyester granule for melt-shaping and process for the preparation thereof 失效
标题翻译：用于熔融成型的聚酯颗粒及其制备方法
公开(公告)号：US4051112A
公开(公告)日：1977-09-27
申请号：US592312
申请日：1975-07-01
申请人： Takatoshi Kuratsuji , Hiroo Inata , Shoji Kawase
发明人： Takatoshi Kuratsuji , Hiroo Inata , Shoji Kawase
IPC分类号： B01J2/00 , B29B9/00 , B29B9/12 , C08J3/12 , C08G63/70
CPC分类号： C08J3/12 , C08J3/124 , C08J2367/02
摘要： Polyester granule for melt-shaping which is composed of a difficultly crystallizable copolyester having the minimum time for half-crystallization of at least one minute, and has the surfaces resulting from cutting by a cutter, improvement in thatI. the polyester granule has an intrinsic viscosity of at least 0.55 (as measured in o-chlorophenol at 35.degree. C.),ii. the polyester granule has in its surface portion an oriented portion having an N-value of at least 0.04, the N-value being calculated by the equation,N =n..multidot..lambda.dandIii. the inside of the polyester granule other than the said surface portion has an N-value of not higher than 0.02.Said polyester granule can be prepared by cutting a copolyester melt-extrudate having an intrinsic viscosity of at least 0.55 under the conditions as will control the surface temperature t (.degree. C) of the extrudate to satisfy the expressionTg + 30.degree. C. .gtoreq. t > Tg - 15.degree. C.
摘要翻译：用于熔融成型的聚酯颗粒，其由具有至少一分钟的半结晶的最短时间的难结晶的共聚酯组成，并且具有由切割机切割的表面，改进为I.该聚酯颗粒具有本体至少0.55的粘度（在35℃下测量在O-氯苯醇中）

9. 发明授权

US4026973A Process for preparing heat-resistant aromatic polyester filaments 失效
标题翻译：制备耐热芳香聚酯长丝的方法
公开(公告)号：US4026973A
公开(公告)日：1977-05-31
申请号：US601232
申请日：1975-08-01
申请人： Takeo Shima , Seiichi Yamashiro , Masao Yoshimura , Takayuki Kobayashi , Takatoshi Kuratsuji , Hiroo Inata
发明人： Takeo Shima , Seiichi Yamashiro , Masao Yoshimura , Takayuki Kobayashi , Takatoshi Kuratsuji , Hiroo Inata
IPC分类号： D01F6/62 , B29C25/00
CPC分类号： D01F6/62
摘要： Heat-resistant aromatic polyester filaments having heretofore unknown physical properties and a combination of excellent heat resistance and mechanical strength, which (1) is composed of an aromatic polyester in which at least 90 mole % of the structural units are ethylene-2,6-naphthalate units, (2) has a melting point at a constant length (Tm;.degree.C.) of at least 287.degree. C., (3) has a density (d)(g/cm.sup.3) of at least 1.370, (4) is insoluble in a phenol/orthodichlorobenzene mixed solvent (mixing ratio = 6/4 on the weight basis) at 160.degree. C. and (5) meets the requirements expressed by the following formulaeL(Tm - 280) = 400 (I).DELTA. n(d - 1.350) = 70 .times. 10.sup.-.sup.3 (II)L = .lambda.K/(B-b)cos .theta. (III)and the process for the preparation thereof.
摘要翻译：耐热芳香族聚酯长丝具有迄今未知的物理性能和优异的耐热性和机械强度的组合，（1）由芳族聚酯组成，其中至少90摩尔％的结构单元是乙烯 - （2）具有至少287℃的恒定长度（Tm;℃）的熔点，（3）密度（d）（g / cm 3）至少为1.370，（4））在160℃下不溶于苯酚/邻二氯苯混合溶剂（混合比为6/4），（5）满足下式L（Tm-280）= 400（I）表示的要求， DELTA n（d-1.350）= 70×10 -3（II）L =λK /（Bb）cosθ（III）及其制备方法。

10. 发明授权

US3984600A Zip fasteners made of polyester monofilaments 失效
标题翻译：拉链紧固件由聚酯单丝制成
公开(公告)号：US3984600A
公开(公告)日：1976-10-05
申请号：US596188
申请日：1975-07-15
申请人： Shoji Kawase , Takatoshi Kuratsuji
发明人： Shoji Kawase , Takatoshi Kuratsuji
IPC分类号： A44B19/12 , D01F6/62 , A44B19/00 , D02G3/00
CPC分类号： A44B19/12 , D01F6/62 , Y10T24/2532 , Y10T428/2913 , Y10T428/2969
摘要： A zip fastener made of a monofilament of 200 to 20,000 denier composed of a polymethylene terephthalate containing at least 85 mole % of trimethylene terephthalate, tetramethylene terephthalate or hexamethylene terephthalate as a recurring unit, said monofilament having an intrinsic viscosity of 0.35 to 3.5 and a circularity of not more than 1.01. The monofilament is prepared by melt-extruding the polymethylene terephthalate in the form of a filament, passing the extruded filament through an air gap, passing it through a cooling bath of an inert quenching liquid held at a temperature of about 60.degree. to 100.degree.C., then passing it through a cooling zone at a temperature of below 35.degree.C., and then drawing the filament.
摘要翻译：一种由200至20,000旦尼尔单丝组成的拉链，其由含有至少85摩尔％的对苯二甲酸丙二醇酯，对苯二甲酸丁二醇酯或对苯二甲酸己二醇酯作为重复单元的聚对苯二甲酸乙二醇酯组成，所述单丝的特性粘度为0.35至3.5，圆形度不超过1.01。单丝通过熔融挤出长丝形式的聚对苯二甲酸乙二醇酯制备，使挤出的细丝通过气隙，使其通过保持在约60℃至100℃的惰性淬火液体的冷却浴中然后在低于35℃的温度下通过冷却区，然后拉长丝。

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