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1. 发明申请

US20060287449A1 Ultrahigh-molecular ethylene polymer 审中-公开
标题翻译：超高分子乙烯聚合物
公开(公告)号：US20060287449A1
公开(公告)日：2006-12-21
申请号：US10548666
申请日：2004-03-09
申请人： Koichi Miyamoto , Takashi Nozaki , Akio Fujiwara
发明人： Koichi Miyamoto , Takashi Nozaki , Akio Fujiwara
IPC分类号： C08F4/44
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F210/18 , C08F4/65904 , C08F2500/01 , C08F2500/26
摘要： The present invention relates to an ultrahigh molecular weight ethylene polymer which is either an ethylene homopolymer (A) or an ethylene copolymer (B), the ethylene copolymer (B) being obtained by copolymerizing a) 99.9 to 75.0% by weight of ethylene and b) 0.1 to 25.0% by weight of a comonomer which is at least one olefin selected from the group consisting of α-olefins having 3 to 20 carbon atoms, cyclic olefins having 3 to 20 carbon atoms, compounds represented by the formula CH2═CHR (in which R is an aryl group having 6 to 20 carbon atoms) and linear, branched or cyclic dienes having 4 to 20 carbon atoms, the ethylene polymer having i) a viscosity average molecular weight of 1 million or more ii) a molecular weight distribution (Mw/Mn) of more than 3 and iii) a Ti content of not more than 3 ppm and a Cl content of 5 ppm in the polymer.
摘要翻译：本发明涉及一种超高分子量乙烯聚合物，其是乙烯均聚物（A）或乙烯共聚物（B），乙烯共聚物（B）通过以下方式得到：乙烯和乙烯共聚物为99.9〜75.0重量％）0.1〜25.0重量％的共聚单体，其为选自碳原子数3〜20的α-烯烃的至少一种烯烃，碳原子数3〜20的环状烯烃，式CH 2个-CHR（其中R是具有6至20个碳原子的芳基）和具有4至20个碳原子的直链，支链或环状二烯，所述乙烯聚合物具有i）粘均分子量为100万或更多ii）大于3的分子量分布（Mw / Mn）和iii）在聚合物中Ti含量不大于3ppm，Cl含量为5ppm。

2. 发明授权

US06956002B2 Process for polymerization of olefins 有权
标题翻译：烯烃聚合方法
公开(公告)号：US06956002B2
公开(公告)日：2005-10-18
申请号：US10492907
申请日：2002-10-15
申请人： Takashi Nozaki , Akio Fujiwara
发明人： Takashi Nozaki , Akio Fujiwara
IPC分类号： C08F4/618 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/622 , C08F4/642
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , Y10S526/943 , C08F4/6555 , C08F4/65912 , C08F4/65908 , C08F210/14 , C08F2500/24 , C08F2500/18 , C08F4/7006
摘要： A catalyst for olefin polymerization, comprising: a solid catalyst component comprising [A] a solid component having substantially no hydroxyl group, [B] a compound of a transition metal selected from Groups 3-11 of the Periodic Table, and [C] a mixture of an activator compound (C-1) capable of reacting with the transition metal compound [B] to form a metal complex having catalytic activity and an organoaluminum compound (C-2); and [D] an organomagnesium compound soluble in a hydrocarbon solvent which is obtained by reacting (i) an organomagnesium compound represented by the general formula: (Mt)α(Mg)β(R1)a(R2)b wherein Mt is a metal atom belonging to Groups 1-3 of the Periodic Table, R1 and R2 are hydrocarbon groups of 2-20 carbon atoms, and α, β, a and b are numerals satisfying the following relationship: 0≦α, 0 0, and rα+2β=a+b (where r is a valence of Mt) with (ii) a compound selected from an amine, an alcohol and a siloxane.
摘要翻译：一种用于烯烃聚合的催化剂，包括：固体催化剂组分，其包含[A]基本上不含羟基的固体组分，[B]选自周期表第3-11族的过渡金属的化合物和[C] a 能够与过渡金属化合物[B]反应形成具有催化活性的金属络合物的活化剂化合物（C-1）和有机铝化合物（C-2）的混合物; 和[D]可溶于烃溶剂的有机镁化合物，其通过使（i）由以下通式表示的有机镁化合物：<？in-line-formula description =“In-line Formulas”end =“lead” （Mt）α（α）（Mg）β（α1）a（R 2）其中，Mt是属于元素周期表第1-3组的金属原子，其中，Mt是属于元素周期表第1-3组的金属原子， R 1和R 2是2-20个碳原子的烃基，α，β，a和b是满足以下关系的数字：0≤α，0 （ⅱ）选自胺，醇和（Ⅵ）化合物的化合物，其中r为缬氨酸价）硅氧烷。

3. 发明申请

US20080071031A1 Ultra High Molecular Weight Ethylene Copolymer Powder 有权
标题翻译：超高分子量乙烯共聚物粉末
公开(公告)号：US20080071031A1
公开(公告)日：2008-03-20
申请号：US11793378
申请日：2005-12-28
申请人： Akio Fujiwara , Koichi Hasebe
发明人： Akio Fujiwara , Koichi Hasebe
IPC分类号： C08F8/00
CPC分类号： C08F210/18 , C08F10/00 , C08F210/16 , C08F4/6555 , C08F210/08 , C08F2500/01 , C08F2500/17 , C08F2500/08 , C08F2500/18 , C08F2500/25
摘要： The present invention relates to an ultrahigh-molecular-weight ethylene copolymer powder having an intrinsic viscosity (η) of 10 dl/g to 34 dl/g, obtainable by copolymerizing ethylene and at least one olefin selected from the group consisting of α-olefins having 3 to 20 carbon atoms, cyclic olefins having 3 to 20 carbon atoms, compounds represented by the formula CH2═CHR1 wherein R1 is an aryl group having 6 to 20 carbon atoms, and linear, branched or cyclic dienes having 4 to 20 carbon atoms, wherein (1) a molded article of the copolymer powder has a haze of from 30% to 80% and (2) the copolymer powder has a bulk density of from 0.35 g/cm3 to 0.60 g/cm3. According to the invention, there can be provided an ultrahigh-molecular-weight ethylene copolymer powder which is excellent in balance of abrasion properties, physical properties, and moldability and also excellent in transparency and flexibility as compared with conventional ultrahigh-molecular-weight polyethylene and which has a high bulk density.
摘要翻译：本发明涉及一种超高分子量乙烯共聚物粉末，其特性粘度（η）为10dl / g至34dl / g，可通过使乙烯和至少一种选自下组的烯烃共聚获得：α-烯烃具有3至20个碳原子，具有3至20个碳原子的环烯烃，由式CH 2 -CHR 1表示的化合物，其中R 1，是碳原子数6〜20的芳基和碳原子数4〜20的直链状，支链状或环状的二烯，其中，（1）共聚物粉末的成型体的雾度为30〜80％，（2）共聚物粉末的堆积密度为0.35g / cm 3至0.60g / cm 3。根据本发明，可以提供与常规超高分子量聚乙烯相比，其耐磨性，物理性能和成型性的平衡优异，透明性和柔软性优异的超高分子量乙烯共聚物粉末，其堆积密度高。

4. 发明授权

US5084368A Electrophotographic toner 失效
标题翻译：电子照相机
公开(公告)号：US5084368A
公开(公告)日：1992-01-28
申请号：US320239
申请日：1989-02-24
申请人： Nobuhiro Hirayama , Masaaki Shin , Shoji Kawasaki , Akira Misawa , Akio Fujiwara , Kenji Uchiyama
发明人： Nobuhiro Hirayama , Masaaki Shin , Shoji Kawasaki , Akira Misawa , Akio Fujiwara , Kenji Uchiyama
IPC分类号： G03G9/087
CPC分类号： G03G9/08795 , Y10S430/105
摘要： This invention discloses electrophotogrpahic toners and the methods for their preparation. The electrophotographic toners contain resin and coloring agents as primary components. The resin is a non-crosslinked polymer of vinyl monomers or its mixtures, and has a number average molecular weight (Mn) of 2,000-15,000, a Z average molecular weight (Mz) of not less than 400,000 and Mz/Mn of 50-600. The electrophotographic toners exert an excellent fixing ability at high duplication speed or at lower temperatures.
摘要翻译： PCT No.PCT / JP87 / 00719 Sec。 371日期1989年2月24日 102（e）日期1989年2月24日PCT提交1987年9月30日PCT公布。出版物WO89 / 00718 日本1989年1月26日。本发明公开了电子白板调色剂及其制备方法。电子照相色调剂含有树脂和着色剂作为主要成分。树脂是乙烯基单体或其混合物的非交联聚合物，其数均分子量（Mn）为2,000-15,000，Z平均分子量（Mz）不小于400,000，Mz / Mn为50- 600。电子照相色调剂在高复制速度或较低温度下具有优异的定影能力。

5. 发明授权

US4748228A Process for producing organic silicon-terminated polyimide precursor and polyimide 失效
标题翻译：有机硅封端聚酰亚胺前体和聚酰亚胺的制备方法
公开(公告)号：US4748228A
公开(公告)日：1988-05-31
申请号：US863241
申请日：1986-05-14
申请人： Fusaji Shoji , Haruhiko Matsuyama , Akio Fujiwara , Fumio Kataoka , Teruji Aizawa
发明人： Fusaji Shoji , Haruhiko Matsuyama , Akio Fujiwara , Fumio Kataoka , Teruji Aizawa
IPC分类号： C08G73/00 , C08G73/10 , C08G77/00
CPC分类号： C08G73/1017
摘要： An organic silicon-terminated polyimide precursor having a very stable solution viscosity is produced by polycondensing 100 parts by weight of a mixture composed of 90 to 99.5% by mole of an organic diamine represented by the following general formula (I) and 10 to 0.5% by weight by mole of an organic silyl represented by the following general formula (II): ##STR1## wherein R.sup.1 and R.sup.2 are divalent organic groups; R.sup.3 and R.sup.4 are monovalent organic groups; m is 0, 1, 2, or 3, with an organic tetracarboxylic acid dianhydride represented by the following general formula (III) in a molar amount corresponding to the 100 parts by weight of the mixture of the organic diamine and the organic silyl represented by the said general formulae (I) and (II), respectively, in an organic polar solvent at 0.degree. to 40.degree. C., thereby obtaining a solution of organic silicon-terminated polyimide precursor, and heating the solution at 50.degree. to 80.degree. C.: ##STR2## wherein R.sup.5 is a tetravelent organic group. The polyimide having good adhesion and mechanical characteristics is obtained by further heating the precursor solution at 100.degree. to 450.degree. C.
摘要翻译：通过将100重量份由以下通式（I）表示的有机二胺和90至99.5摩尔％的由下列通式（I）表示的混合物和10至0.5重量％的混合物进行缩聚来制备具有非常稳定的溶液粘度的有机硅封端的聚酰亚胺前体，（II）表示的有机甲硅烷基：其中R 1和R 2是二价有机基团;其中R 1和R 2是二价有机基团; R3和R4是一价有机基团; m为0,1,2或3，与由以下通式（III）表示的有机四羧酸二酐的摩尔量相当于有机二胺和有机甲硅烷基的混合物的100重量份，由所述通式（I）和（II）分别在有机极性溶剂中在0至40℃下进行，从而获得有机硅封端的聚酰亚胺前体溶液，并在50℃至80℃下加热该溶液（III）其中R5是四价有机基团。通过在100〜450℃下进一步加热前体溶液得到具有良好粘附性和机械特性的聚酰亚胺

6. 发明授权

US06812303B1 Olefin polymerizaion catalyst and method for polymerizing an olefin using the catalyst 有权
标题翻译：烯烃聚合催化剂和使用该催化剂聚合烯烃的方法
公开(公告)号：US06812303B1
公开(公告)日：2004-11-02
申请号：US09569579
申请日：2000-05-10
申请人： Fumio Matsushita , Akio Fujiwara
发明人： Fumio Matsushita , Akio Fujiwara
IPC分类号： C08F464
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65916 , C08F210/08 , C08F2500/18 , C08F210/14
摘要： A novel olefin polymerization catalyst comprising: (A) a transition metal compound comprising a transition metal having &eegr;-bonded thereto a cyclic anionic ligand; (B) a mixture of (B-1) an activator compound capable of forming, together with component (A), a metal complex having a catalytic activity and (B-2) an organometal compound, the activator compound (B-1) comprising a cation and a noncoordinating, compatible anion; (C) a solid component; and optionally (D) an organoaluminum compound, wherein the catalyst is obtained by contacting components (A) to (C) and optionally component (D). The olefin polymerization catalyst of the present invention is advantageous not only in that it has high polymerization activity, but also in that an olefin polymer having excellent powder characteristics can be efficiently produced by suspension polymerization (slurry polymerization) or gaseous phase polymerization in a continuous manner, using a commercial scale plant, while preventing the occurrence of adherence of the polymer to the inside surfaces associated with a polymerizer.
摘要翻译：一种新型烯烃聚合催化剂，其包含：（A）包含与其结合的环状阴离子配体的过渡金属的过渡金属化合物; （B）与（A）成分的活化剂化合物（B-1），具有催化活性的金属络合物和（B-2）有机金属化合物的混合物，活化剂化合物（B-1）包括阳离子和非配位的相容阴离子; （C）固体成分; 和任选的（D）有机铝化合物，其中催化剂通过使组分（A）与（C）和任选的组分（D）接触而获得。本发明的烯烃聚合催化剂不仅具有高聚合活性的优点，而且通过悬浮聚合（淤浆聚合）或气相聚合连续地有效地制备具有优异粉末特性的烯烃聚合物，同时防止聚合物粘附到与聚合反应器相关的内表面。

7. 发明授权

US5362595A Electrophotographic toner production process 失效
标题翻译：电子照相调色剂生产工艺
公开(公告)号：US5362595A
公开(公告)日：1994-11-08
申请号：US966570
申请日：1992-10-26
申请人： Nobuhiro Hirayama , Masaaki Shin , Shoji Kawasaki , Akira Misawa , Akio Fujiwara , Kenji Uchiyama
发明人： Nobuhiro Hirayama , Masaaki Shin , Shoji Kawasaki , Akira Misawa , Akio Fujiwara , Kenji Uchiyama
IPC分类号： G03G9/087
CPC分类号： G03G9/08795 , Y10S430/105
摘要： This invention discloses electrophotographic toners and the methods for their preparation. The electrophotographic toners contain resin and coloring agents as primary components. The resin is a non-crosslinked polymer of vinyl monomers or its mixtures, and has a number average molecular weight (Mn) of 2,000-15,000, a Z average molecular weight (Mz) of not less than 400,000 and Mz/Mn of 50-600. The electrophotographic toners exert an excellent fixing ability at high duplication speed or at lower temperatures.
摘要翻译：本发明公开了电子照相色调剂及其制备方法。电子照相色调剂含有树脂和着色剂作为主要成分。树脂是乙烯基单体或其混合物的非交联聚合物，其数均分子量（Mn）为2,000-15,000，Z平均分子量（Mz）不小于400,000，Mz / Mn为50- 600。电子照相色调剂在高复制速度或较低温度下具有优异的定影能力。

8. 发明授权

US4963512A Method for forming conductor layers and method for fabricating multilayer substrates 失效
标题翻译：形成导体层的方法和用于制造多层基板的方法
公开(公告)号：US4963512A
公开(公告)日：1990-10-16
申请号：US281879
申请日：1988-12-08
申请人： Shoichi Iwanaga , Akio Fujiwara , Takayoshi Sowa , Hitoshi Yokono
发明人： Shoichi Iwanaga , Akio Fujiwara , Takayoshi Sowa , Hitoshi Yokono
IPC分类号： H01L21/48 , H05K3/00 , H05K3/38 , H05K3/46
CPC分类号： H01L21/4846 , H01L21/4857 , H05K3/465 , H05K2201/0154 , H05K2203/072 , H05K2203/0733 , H05K3/0041 , H05K3/388 , H05K3/4661
摘要： A method for forming conductor layers of substrates for mounting LSIs and the like and a fabrication method of multilayer substrates are disclosed. These methods comprise steps of forming a metal underlayer having a shape similar to that of a conductor pattern on the substrate, forming an insulation layer over portions of the substrate which are not covered by the metal underlayer, and disposing a plating layer on the metal underlayer by carrying out electroless plating while using the insulation layer as the resist and thereby forming conductors. As compared with a conventional conductor layer forming method, the number of fabrication steps is reduced. And the elimination of the surface grinding step facilitates the fabrication.
摘要翻译：公开了一种用于形成用于安装LSI等的基板的导体层的方法和多层基板的制造方法。这些方法包括以下步骤：在基板上形成类似于导体图案的形状的金属底层，在基底的不被金属底层覆盖的部分上形成绝缘层，并在金属底层上设置镀层通过在使用绝缘层作为抗蚀剂的同时进行化学镀，从而形成导体。与常规的导体层形成方法相比，制造步骤的数量减少。并且消除表面研磨步骤有助于制造。

9. 发明授权

US4056412A Method for hardening steel pipes 失效
标题翻译：钢管硬化方法
公开(公告)号：US4056412A
公开(公告)日：1977-11-01
申请号：US612927
申请日：1975-09-12
申请人： Yoshihisa Fujii , Akio Fujiwara
发明人： Yoshihisa Fujii , Akio Fujiwara
IPC分类号： C21D1/667 , C21D9/08
CPC分类号： C21D9/085 , C21D1/667
摘要： This invention relates to a method wherein the setting angles of cooling water jetting orifices an outer quenching head and an inner quenching head are made 30.degree..+-.10.degree. in the pipe advancing direction with the pipe axis and the number of jetting orifices of the inner quenching head are greater for purposes of higher density for the front one-third of the length of the head and lower for purposes of lower density for the rear two-thirds of the length of the head.Further, the first contact point of inner quenching water within the inner surface of the pipe is so set as to be delayed by 20 to 150mm. from the first contact point of quenching water with the outer surface of the pipe, the outer quenching being carried out when the steel pipe heating temperature is above the A.sub.3 transformation point and the inner quenching is carried out when the temperature of the inner surface of the pipe is just below the A.sub.1 transformation point.As both heads have a fixed angle, water or steam will not enter the unquenched part and the quenching velocity and the hardness of the cross-section of the steel pipe will be improved.

10. 发明授权

US09000645B2 Rotating electrical machine 有权
标题翻译：旋转电机
公开(公告)号：US09000645B2
公开(公告)日：2015-04-07
申请号：US13805934
申请日：2011-05-19
申请人： Toshiyuki Onishi , Masafumi Okazaki , Katsumi Ohata , Akio Fujiwara , Wataru Hirosue
发明人： Toshiyuki Onishi , Masafumi Okazaki , Katsumi Ohata , Akio Fujiwara , Wataru Hirosue
IPC分类号： H02K21/26 , H02K1/18 , H02K1/17 , H02K23/04
CPC分类号： H02K1/185 , H02K1/17 , H02K23/04 , H02K2213/12
摘要： The rotating electrical machine of the present invention includes: a magnet holder made of a non-magnetic material, which is formed by coupling a columnar portion for retaining the permanent magnet in a circumferential direction, and an annular portion for covering each axial side surface of the permanent magnet. The magnet holder includes, on an outer diameter side of both circumferential side surfaces of the columnar portion, engaging portions which engage with respective locking portions of the magnet cover, and includes, on an inner diameter side of each of both the circumferential side surfaces of the columnar portion, an extending portion extending along an inner peripheral surface of the magnet cover with a clearance (D) with respect to the inner peripheral surface of the magnet cover.
摘要翻译：本发明的旋转电机包括：由非磁性材料构成的磁体保持架，其通过将用于保持永久磁铁的圆周方向的圆柱状部分沿圆周方向连接而形成，以及环形部分，用于覆盖每个轴向侧表面永久磁铁。所述磁体保持器在所述柱状部的两个周向侧面的外径侧具有与所述磁体盖的各个卡定部卡合的卡合部，并且在所述两个所述周向侧面的每一个的内径侧所述柱状部分是沿着所述磁体盖的内周面延伸的延伸部分，所述延伸部分相对于所述磁体盖的内周表面具有间隙（D）。

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