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    • 3. 发明授权
    • Production process of silver halide photographic emulsion and silver halide photographic light-sensitive material
    • 卤化银照相乳剂和卤化银照相感光材料的制备工艺
    • US06838231B2
    • 2005-01-04
    • US10270296
    • 2002-10-15
    • Katsumi KobayashiTakeshi SuzumotoTakanori Hioki
    • Katsumi KobayashiTakeshi SuzumotoTakanori Hioki
    • G03C1/12G03C1/29G03C5/18G03C5/26
    • G03C1/12G03C1/29
    • A process for producing a spectrally sensitized silver halide photographic emulsion having high sensitivity. A process for producing a silver halide photographic emulsion comprising as a sensitizing dye at least one connection dye having two or more chromophores connected through a covalent bond, the process comprising adding said connection dye to a silver halide photographic emulsion and allowing at least one chromophore out of a plurality of chromophores in the molecule of the connection dye to change in the adsorption strength to a silver halide grain; and a process for producing a silver halide photographic emulsion comprising a silver halide grain having adsorbed on the surface thereof a sensitizing dye in multiple layers, the process comprising adding one or a plural of sensitizing dye(s) to said silver halide emulsion and allowing at least one sensitizing dye out of added sensitizing dyes to change in the adsorption strength to a silver halide grain.
    • 一种生产具有高灵敏度的光谱增感卤化银照相乳剂的方法。 一种制备卤化银照相乳剂的方法,其包含至少一种具有通过共价键连接的两个或更多个发色团的连接染料作为致敏染料,该方法包括将所述连接染料加入到卤化银照相乳剂中并允许至少一种发色团出来 的连接染料分子中的多个发色团,以将吸附强度改变为卤化银颗粒; 以及一种制备卤化银照相乳剂的方法,其包含在其表面吸附多层感光染料的卤化银颗粒,该方法包括在所述卤化银乳剂中加入一种或多种致敏染料,并允许 加入敏化染料中的至少一种敏化染料,以改变对卤化银颗粒的吸附强度。
    • 6. 发明授权
    • Methine compound and silver halide photographic material
    • 甲基化合物和卤化银照相材料
    • US06465166B1
    • 2002-10-15
    • US09717224
    • 2000-11-22
    • Katsumi KobayashiTakanori Hioki
    • Katsumi KobayashiTakanori Hioki
    • G03C1005
    • G03C1/12G03C1/127G03C1/14G03C1/16G03C1/18G03C1/22
    • Compounds represented by formula (I) and silver halide photographic materials comprising these compounds: wherein Q1 represents a methine or polymethine group necessary for completing the compound as a methine dye; Z1 represents atoms necessary to complete a 5- or 6-membered nitrogen-containing heterocyclic ring, provided that Z1 may be condensed with a ring; L1 and L2 each represent a methine group; p1 represents 0 or 1; L represents a divalent linking group and Ar represents an aromatic group, provided that L or Ar contains at least one proton dissociative group as a substituent group or a part of the linkage or aromatic group and the proton dissociative group has a pKa value of from 3 to 12; M1 represents a counter ion for charge balance; and m1 represents a number of counter ions required for neutralizing charges on the molecule, and ranges from 0 to 10.
    • 由式(I)表示的化合物和包含这些化合物的卤化银照相材料:其中Q1表示完成作为次甲基染料的化合物所必需的次甲基或聚甲炔基; Z1表示完成5或6元含氮杂环所需的原子,条件是可以与环稠合Z1; L1和L2各自表示次甲基; p1表示0或1; L表示二价连接基团,Ar表示芳基,条件是L或Ar含有至少一个质子离解基团作为取代基或部分连接基团或芳族基团和质子离解基团的pKa值为3 至12; M1代表电荷平衡的抗衡离子; m1表示分子上的中和电荷所需的抗衡离子数,为0〜10。