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1. 发明授权

US5824818A Process for preparing lactate 失效
标题翻译：制备乳酸盐的方法
公开(公告)号：US5824818A
公开(公告)日：1998-10-20
申请号：US698478
申请日：1996-08-15
申请人： Takafumi Abe , Toshiyuki Gotoh , Takako Uchiyama , Hirofumi Higuchi , Yoshikazu Shima , Kazuto Ikemoto
发明人： Takafumi Abe , Toshiyuki Gotoh , Takako Uchiyama , Hirofumi Higuchi , Yoshikazu Shima , Kazuto Ikemoto
IPC分类号： C07C67/20 , C07C69/66
CPC分类号： C07C67/20
摘要： A process for preparing a lactate which includes: (a) preparing lactonitrile from prussic acid and acetaldehyde, (b) hydrating the lactonitrile to form lactamide, (c) forming the desired lactate and formamide from lactamide and formate (or methanol and carbon monoxide), (d) separating and collecting components, having a lower boiling point than that of lactate from the reaction liquid in step (c), by distillation under specified conditions, and (e) dehydrating formamide from step (d) to form prussic acid and recycling the prussic acid to step (a). Heretofore, lactates had been manufactured by forming lactonitrile (cyanohydrin) from acetaldehyde and prussic acid, and then esterifying lactonitrile with a mineral acid or the like. However, in this conventional process, ammonium salts were formed as by-products in an amount equal to that of the lactate. According to the present invention, a lactate can be efficiently manufactured on a commercial scale without forming a large amount of the ammonium salts as by-products. In particular, the yield of the lactate can be increased by controlling the formation of 2-formyloxy propionate and also a dimer of a lactate.
摘要翻译：一种制备乳酸的方法，其包括：（a）从丙二酸和乙醛制备乳腈，（b）使乳腈水合形成乳酰胺，（c）从乳酰胺和甲酸盐（或甲醇和一氧化碳）形成所需的乳酸盐和甲酰胺，，（d）在步骤（c）中通过蒸馏从特定条件下蒸馏分离和收集沸点低于乳酸盐的组分，并且（e）从步骤（d）中将甲酰胺脱水形成二甲苯，将重要的酸回收到步骤（a）。迄今为止，已经通过从乙醛和氢溴酸形成乳腈（氰醇），然后用无机酸等使乳腈酯化来制造乳酸盐。然而，在该常规方法中，形成铵盐，其量等于乳酸盐的副产物。根据本发明，可以以商业规模有效地制造乳酸盐，而不会形成大量的作为副产物的铵盐。特别地，通过控制2-甲酰氧基丙酸酯和乳酸二聚体的形成可以提高乳酸产率。

2. 发明授权

US5463123A Process for producing .alpha.-hydroxyisobutyramide 失效
标题翻译： α-羟基异丁酰胺的制备方法
公开(公告)号：US5463123A
公开(公告)日：1995-10-31
申请号：US135062
申请日：1993-10-12
申请人： Takako Uchiyama , Hirofumi Higuchi
发明人： Takako Uchiyama , Hirofumi Higuchi
IPC分类号： B01J23/34 , B01J37/16 , C07B61/00 , C07C231/06 , C07C235/06
CPC分类号： C07C231/065 , C07C231/06
摘要： There is disclosed a process for producing .alpha.-hydroxyisobutyramide by hydration reaction of acetone cyanohydrin in the presence of a catalyst consisting essentially of manganese dioxide which process comprises pretreating the catalyst with a reducing agent. The above process is capable of eliminating the catalyst clogging trouble due to the deposition of the by-produced oxamide and thus proceeding with long-term reaction with the stabilized catalyst performance.
摘要翻译：公开了在主要由二氧化锰组成的催化剂存在下，通过丙酮氰醇的水合反应制备α-羟基异丁酰胺的方法，该方法包括用还原剂预处理催化剂。上述方法能够消除由于副产物酰胺沉积引起的催化剂堵塞问题，从而与稳定的催化剂性能进行长期反应。

3. 发明授权

US4987256A Process for production of .alpha.-hydroxycarboxylic acid amide 失效
标题翻译： α-羟基羧酸酰胺的制备方法
公开(公告)号：US4987256A
公开(公告)日：1991-01-22
申请号：US550150
申请日：1990-07-09
申请人： Shuji Ebata , Hiroyuki Hirayama , Takako Uchiyama
发明人： Shuji Ebata , Hiroyuki Hirayama , Takako Uchiyama
IPC分类号： B01J23/34 , C07B61/00 , C07C231/06 , C07C235/06
CPC分类号： C07C231/065
摘要： Process for production of .alpha.-hydroxycarboxylic acid amide of the general formula (A), comprising hydrating cyanhydrin of the general formula (B) by the use of a modified manganese dioxide catalyst containing one or more of zirconium, vanadium, and tin, and an alkali metal element. ##STR1## wherein all the symbols are as defined in the appended claims.

4. 发明授权

US4605477A Electrodialytic recovery of .alpha.-amino acid from its amide 失效
标题翻译：从其酰胺中电渗析回收α-氨基酸
公开(公告)号：US4605477A
公开(公告)日：1986-08-12
申请号：US704596
申请日：1985-02-25
申请人： Masaharu Doya , Toshio Kondo , Hideo Igarashi , Takako Uchiyama
发明人： Masaharu Doya , Toshio Kondo , Hideo Igarashi , Takako Uchiyama
IPC分类号： C07C319/28 , C07C67/00 , C07C227/00 , C07C227/40 , C07C229/02 , C07C313/00 , C07C323/58 , C12P13/04 , B01D13/02
CPC分类号： B01D61/44 , C12P13/04 , B01D2311/2623
摘要： An .alpha.-amino acid is effectively separated and recovered from an aqueous solution containing at least an .alpha.-amino acid and its corresponding .alpha.-amino acid amide by performing ion-exchange electrodialysis in the presence of ammonia. A reaction product liquid obtained by biochemical asymmetric hydrolysis of a D, L-.alpha.-amino acid is used preferably as the raw material aqueous solution for dialysis.
摘要翻译：通过在氨的存在下进行离子交换电渗析，从含有至少α-氨基酸及其相应的α-氨基酰胺的水溶液中有效地分离和回收α-氨基酸。优选使用通过D，L-α-氨基酸的生物化学不对称水解获得的反应产物作为用于透析的原料水溶液。

5. 发明申请

US20130041179A1 AMIDE COMPOUND PRODUCTION CATALYST, AND PROCESS FOR PRODUCTION OF AMIDE COMPOUND 有权
标题翻译：酰胺化合物生产催化剂，以及制备酰胺化合物的方法
公开(公告)号：US20130041179A1
公开(公告)日：2013-02-14
申请号：US13582182
申请日：2011-03-04
申请人： Takako Uchiyama , Shinyou Shirai , Yoshikazu Shima , Masaki Takemoto , Genki Nogami
发明人： Takako Uchiyama , Shinyou Shirai , Yoshikazu Shima , Masaki Takemoto , Genki Nogami
IPC分类号： B01J23/34 , C07C231/06
CPC分类号： B01J23/002 , B01J23/34 , B01J23/688 , B01J23/8472 , B01J23/8892 , B01J27/043 , B01J35/023 , B01J37/0009 , B01J37/009 , B01J37/031 , B01J37/06 , B01J2523/00 , C07C231/065 , B01J2523/22 , B01J2523/36 , B01J2523/54 , B01J2523/72 , B01J2523/55 , C07C235/06
摘要： The present provides a high-efficiency amide compound production catalyst to be used in producing an amide compound through hydration of a nitrile compound and a production method using it. The amide compound production catalyst is for producing an amide compound through reaction of a nitrile compound and water, and comprises a manganese oxide catalyst containing bismuth and further containing yttrium or vanadium. The method for producing an amide compound comprises reacting a nitrile compound and water in a liquid phase in the presence of the amide compound production catalyst.
摘要翻译：本发明提供了通过腈化合物的水合制备酰胺化合物和使用它的制备方法中使用的高效酰胺化合物制备催化剂。酰胺化合物的制造催化剂是通过腈化合物与水的反应来制造酰胺化合物，含有含有铋的氧化锰催化剂，还含有钇或钒。酰胺化合物的制造方法包括在酰胺化合物制造催化剂的存在下，使腈化合物和水以液相反应。

6. 发明授权

US4613684A Process for the preparation of carboxylic acid esters 失效
标题翻译：羧酸酯的制备方法
公开(公告)号：US4613684A
公开(公告)日：1986-09-23
申请号：US655331
申请日：1984-09-27
申请人： Tetsuo Aoyama , Koichi Kida , Takako Uchiyama
发明人： Tetsuo Aoyama , Koichi Kida , Takako Uchiyama
IPC分类号： C07C67/20 , C07C69/54 , C07C69/675 , C07C69/68 , C07C103/127
CPC分类号： C07C69/675 , C07C67/20 , C07C69/54 , C07C69/68 , Y02P20/582
摘要： A commercially economical process for preparing a carboxylic acid ester from a carboxylic acid amide is disclosed. The process is very meritorious, since it produces neither ammonia nor ammonium sulfates. Rather, the process by-produces formamides which are very useful compounds as solvents. Further, formamide can easily be converted to hydrogen cyanide by dehydration. The process comprises reacting a carboxylic acid amide with a formic acid ester and/or methanol and carbon monoxide in the presence of a bicyclic amidine or tertiary amine catalyst and optionally in the co-existence of a metal carbonyl. An industrial process for preparing methyl methacrylate which is a materialization of the process shown above is described in detail referring to a figure.
摘要翻译：公开了一种从羧酸酰胺制备羧酸酯的商业经济方法。该方法非常有价值，因为它不产生氨和硫酸铵。相反，该方法副产生甲酰胺，其是非常有用的化合物作为溶剂。此外，甲酰胺可以通过脱水容易地转化为氰化氢。该方法包括在双环脒或叔胺催化剂的存在下，任选地在羰基金属的共存下使羧酸酰胺与甲酸酯和/或甲醇和一氧化碳反应。下面参照附图详细描述制备甲基丙烯酸甲酯的工业过程，这是上述过程的实现。

7. 发明授权

US07704917B2 Process for producing catalyst for cyanhydrin hydration and product of the process 有权
标题翻译：用于生产氰醇水合催化剂的方法和该方法的产物
公开(公告)号：US07704917B2
公开(公告)日：2010-04-27
申请号：US11994629
申请日：2006-07-06
申请人： Hideho Matsuda , Takako Uchiyama , Yoshikazu Shima , Masaki Takemoto
发明人： Hideho Matsuda , Takako Uchiyama , Yoshikazu Shima , Masaki Takemoto
IPC分类号： B01J23/32 , C01G45/12 , C07C231/00
CPC分类号： B01J23/34 , B01J35/1014 , B01J35/1042 , B01J35/1066 , B01J37/0236 , B01J37/03 , C07C231/06 , C07C235/06
摘要： A process for producing a catalyst for cyanhydrin hydration, which comprises a manganese oxide as a main component and is excellent in both physical strength and reaction activity, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process. Specifically, a process for producing a catalyst which is useful for cyanhydrin hydration and contains a manganese oxide as a main component, potassium, and one or more elements selected from the group consisting of bismuth, vanadium and tin, in which the above compounds are mixed together in an aqueous system; the resulting slurry precipitate is subjected to solid-liquid separation; and the resulting hydrous cake is dried in at least two separate stages comprising a predrying and a main drying, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process.
摘要翻译：本发明提供一种生产氰醇水合催化剂的方法，该方法包括以氧化锰为主要成分，并具有优异的物理强度和反应活性，以及通过制备方法获得的氰醇水合催化剂。具体而言，可以使用用于氰醇水合并含有氧化锰作为主要成分的催化剂的方法，钾和选自铋，钒和锡中的一种或多种元素，其中混合上述化合物一起在水系统中; 将所得浆料沉淀物进行固液分离; 并且将所得含水饼在包括预干燥和主干燥的至少两个分开的阶段中进行干燥，以及通过生产方法获得的用于氰醇水合的催化剂。

8. 发明授权

US4918196A Process for recimization of an optically active alpha-amino acid amides and process for producing optically active alpha-amino acids 失效
标题翻译：用于重新获得光学活性α-氨基酸酰胺的方法和用于制备光学活性α-氨基酸的方法
公开(公告)号：US4918196A
公开(公告)日：1990-04-17
申请号：US831915
申请日：1986-02-21
申请人： Masaharu Doya , Toshio Kondo , Hideo Igarashi , Takako Uchiyama
发明人： Masaharu Doya , Toshio Kondo , Hideo Igarashi , Takako Uchiyama
IPC分类号： C07D233/72 , C12P13/04 , C12P41/00
CPC分类号： C12P41/006 , C12P13/04
摘要： A process for optically isomerizing an optically active alpha-amino acid amide comprising heating a D-alpha-amino acid amide or an L-alpha-amino acid amide in the presence of a strongly basic compound; and a process for producing an L-alpha-amino acid, which comprises(1) subjecting a D,L-alpha-amino acid amide or a mixture of a major amount of a D-alpha-amino acid amide and a minor amount of an L-alpha-amino acid amide to the action of a microorganism having the ability to hydrolyze the L-alpha-amino acid to obtain a hydrolyzate containing the L-alpha-amino acid and D-alpha-amino acid,(2) separating the L-alpha-amino acid from the hydrolyzate and recovering the remaining D-alpha-amino acid amide.(3) heating all or part of the recovered D-alpha-amino acid amide in the presence of a strongly basic substance to obtain a D,L-alpha-amino acid amide or a mixture of a major amount of the D-alpha-amino acid amide and a minor amount of the L-alpha-amino acid amide, and(4) recycling the D,L-alpha-amino acid amide or the mixture to step (1) as part or all of the starting material.
摘要翻译：包括光学异构化光学活性α-氨基酸酰胺的方法，包括在强碱性化合物存在下加热D-α-氨基酸酰胺或L-α-氨基酸酰胺; 以及制备L-α-氨基酸的方法，其包括（1）使D，L-α-氨基酸酰胺或主要量的D-α-氨基酸酰胺和少量的 L-α-氨基酸酰胺，具有水解L-α-氨基酸的能力的微生物的作用，得到含有L-α-氨基酸和D-α-氨基酸的水解产物，（2）分离来自水解产物的L-α-氨基酸并回收剩余的D-α-氨基酸酰胺。（3）在强碱性物质存在下加热全部或部分回收的D-α-氨基酸酰胺，得到D，L-α-氨基酸酰胺或大量D-α-氨基酸酰胺的混合物，氨基酸酰胺和少量的L-α-氨基酸酰胺，和（4）将D，L-α-氨基酸酰胺或混合物循环到步骤（1）中作为起始原料的一部分或全部。

9. 发明授权

US4521638A Process for preparation of tertiary olefins 失效
标题翻译：叔烯烃的制备方法
公开(公告)号：US4521638A
公开(公告)日：1985-06-04
申请号：US580633
申请日：1984-02-16
申请人： Koichi Kida , Tetsuo Aoyama , Takako Uchiyama
发明人： Koichi Kida , Tetsuo Aoyama , Takako Uchiyama
IPC分类号： B01J27/00 , B01J27/16 , B01J27/28 , C07B61/00 , C07C1/00 , C07C1/20 , C07C11/02 , C07C67/00
CPC分类号： B01J27/28 , B01J27/16 , C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2521/16 , C07C2523/12 , C07C2527/173 , C07C2529/04 , Y02P20/584
摘要： Disclosed is a process for the preparation of tertiary olefins which comprises catalytically decomposing a tertiary ether to a tertiary olefin, wherein the catalytic decomposition of the tertiary olefin is carried out in the presence of a solid phosphoric acid catalyst which has been calcined at a temperature of at least 500.degree. C. in an inert gas.
摘要翻译：公开了一种制备叔烯烃的方法，其包括将叔醚催化分解成叔烯烃，其中，在固体磷酸催化剂的存在下进行叔烯烃的催化分解，所述固体磷酸催化剂在已经在在惰性气体中至少500℃。

10. 发明授权

US08603939B2 Amide compound production catalyst, and process for production of amide compound 有权
标题翻译：酰胺化合物生产催化剂，酰胺化合物生产方法
公开(公告)号：US08603939B2
公开(公告)日：2013-12-10
申请号：US13582182
申请日：2011-03-04
申请人： Takako Uchiyama , Shinyou Shirai , Yoshikazu Shima , Masaki Takemoto , Genki Nogami
发明人： Takako Uchiyama , Shinyou Shirai , Yoshikazu Shima , Masaki Takemoto , Genki Nogami
IPC分类号： B01J23/34 , C07C231/06
CPC分类号： B01J23/002 , B01J23/34 , B01J23/688 , B01J23/8472 , B01J23/8892 , B01J27/043 , B01J35/023 , B01J37/0009 , B01J37/009 , B01J37/031 , B01J37/06 , B01J2523/00 , C07C231/065 , B01J2523/22 , B01J2523/36 , B01J2523/54 , B01J2523/72 , B01J2523/55 , C07C235/06
摘要： The present provides a high-efficiency amide compound production catalyst to be used in producing an amide compound through hydration of a nitrile compound and a production method using it. The amide compound production catalyst is for producing an amide compound through reaction of a nitrile compound and water, and comprises a manganese oxide catalyst containing bismuth and further containing yttrium or vanadium. The method for producing an amide compound comprises reacting a nitrile compound and water in a liquid phase in the presence of the amide compound production catalyst.
摘要翻译：本发明提供了通过腈化合物的水合制备酰胺化合物和使用它的制备方法中使用的高效酰胺化合物制备催化剂。酰胺化合物的制造催化剂是通过腈化合物与水的反应来制造酰胺化合物，含有含有铋的氧化锰催化剂，还含有钇或钒。酰胺化合物的制造方法包括在酰胺化合物制造催化剂的存在下，使腈化合物和水以液相反应。

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