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1. 发明授权

US06841581B2 Extruded styrene resin foam and process for producing the same 失效
标题翻译：挤出苯乙烯树脂泡沫及其制备方法
公开(公告)号：US06841581B2
公开(公告)日：2005-01-11
申请号：US10441398
申请日：2003-05-20
申请人： Takahiro Hayashi , Kenkichi Tanaka , Hiroshi Kobayashi , Jun Fukuzawa , Syunji Kurihara
发明人： Takahiro Hayashi , Kenkichi Tanaka , Hiroshi Kobayashi , Jun Fukuzawa , Syunji Kurihara
IPC分类号： C08J9/00 , C08J9/14 , C09K21/14 , C08J9/12
CPC分类号： C08J9/141 , C08J9/0028 , C08J9/0038 , C08J9/0066 , C08J2201/03 , C08J2325/06 , C08J2375/04 , C09K21/14
摘要： An extruded styrene resin foam which is produced by using a blowing agent imposing a reduced load on the environment and has outstandingly excellent thermal insulating property and flame retardant property adapted for construction use. The foam is obtained by extrusion-foaming of a styrene resin and characterized by containing at least, one or more of saturated hydrocarbons having 3 to 5 carbon atoms as a blowing agent, and containing (A) a halogenated flame retardant, and (B) at least one compound selected from the group consisting of phosphorus type flame retardants containing nitrogen atom in a molecule; tetrazole compounds; specific nitrogen-containing compounds; metal borates; boron oxides; phosphoric acid ester compounds, and having a cell structure constituting the foam wherein a cell anisotropic ratio k, which is defined by the formula: k=a/(a×b×c)1/3 wherein, in sections of the foam, a (mm) is an average cell size in the thickness direction, b (mm) is an average cell size in the transverse direction and c (mm) is an average cell size in the longitudinal direction, satisfies the relationship: k≦1.1, and a satisfies the relationship: 0.05≦a≦0.30, and the method for producing the same.
摘要翻译：一种挤出的苯乙烯树脂发泡体，其通过使用在环境上施加减小的负载的发泡剂并且具有优异的绝热性和适用于建筑用途的阻燃性而产生。泡沫体通过苯乙烯树脂的挤出发泡得到，其特征在于含有至少一种或多种具有3〜5个碳原子的饱和烃作为发泡剂，并含有（A）卤化阻燃剂，（B）选自分子中含有氮原子的磷型阻燃剂中的至少一种化合物; 四唑化合物; 特定含氮化合物; 金属硼酸盐氧化硼; 磷酸酯化合物，并且具有构成泡沫的电池结构，其中由下式定义的电池各向异性比率k：k = a /（axbxc）<1/3>其中，在泡沫的截面中，（mm ）是厚度方向的平均单元尺寸，b（mm）是横向的平均单元尺寸，c（mm）是长度方向的平均单元尺寸，满足关系式：k <= 1.1，a 满足关系：0.05 <= a <= 0.30，及其制造方法。

2. 发明授权

US06696504B1 Extruded styrene resin foams, and methods for producing the same 失效
标题翻译：挤出苯乙烯树脂发泡体及其制造方法
公开(公告)号：US06696504B1
公开(公告)日：2004-02-24
申请号：US09471402
申请日：1999-12-23
申请人： Takahiro Hayashi , Osamu Kobayashi , Jun Fukuzawa , Hiroshi Fujiwara
发明人： Takahiro Hayashi , Osamu Kobayashi , Jun Fukuzawa , Hiroshi Fujiwara
IPC分类号： C08J912
CPC分类号： C08J9/149 , C08J2201/03 , C08J2203/12 , C08J2203/14 , C08J2205/052 , C08J2325/06 , Y10S521/91
摘要： Production of extruded styrene resin foams which are excellent in environmental compatibility and retain highly efficient thermal insulation property and have appropriate strength properties is disclosed which is characterized by using as a blowing agent a blowing agent comprising mainly 40% by weight or more and 85% by weight or less, based on the whole amount of the blowing agent, of at least one ether selected from the group consisting of dimethyl ether, methyl ethyl ether and diethyl ether, and 15% by weight or more and 60% by weight or less, based on the whole amount of the blowing agent, of at least one saturated hydrocarbon selected from the group consisting of saturated hydrocarbons having 3 to 5 carbon atoms. The production is further characterized by providing a more desirable cell structure such as a specified shape of cells or the presence of larger and smaller cells.
摘要翻译：公开了具有优异的环境相容性并且保持高效绝热性并具有适当强度特性的挤出苯乙烯树脂泡沫的制造，其特征在于使用发泡剂作为发泡剂，该发泡剂主要包含40重量％以上且85重量％以上重量或更少，基于发泡剂的总量，至少一种选自二甲醚，甲基乙基醚和乙醚的醚，和15重量％以上且60重量％以下，基于全部量的发泡剂，至少一种选自碳原子数为3〜5的饱和烃的饱和烃。制备的特征还在于提供更理想的细胞结构，例如细胞的特定形状或更大和更小细胞的存在。

3. 发明授权

US08513317B2 Process for producing expanded polyolefin resin particles and expanded polyolefin resin particles 有权
标题翻译：制造发泡聚烯烃树脂颗粒和发泡聚烯烃树脂颗粒的方法
公开(公告)号：US08513317B2
公开(公告)日：2013-08-20
申请号：US12747050
申请日：2008-12-03
申请人： Jun Fukuzawa , Hiroshi Tsuneishi
发明人： Jun Fukuzawa , Hiroshi Tsuneishi
IPC分类号： C08J9/00 , C08J9/18
CPC分类号： B29C44/3461 , C08J9/00 , C08J9/0023 , C08J9/0061 , C08J9/125 , C08J9/18 , C08J9/228 , C08J9/232 , C08J2203/06 , C08J2323/02 , C08J2323/12 , C08J2471/00 , Y10T428/249921 , Y10T428/2982
摘要： Provided is a process for producing expanded polyolefin resin particles whose cells are not made nonuniform or extremely smaller as seen in conventional expanded particles, whose cell diameter and expansion ratio can be easily controlled independently, and which, when subjected to in-mold expansion molding, give in-mold expanded molded products satisfactory in fusibility and excellent in surface properties. The process is a process for producing expanded polyolefin resin particles by: dispersing polyolefin resin particles together with an aqueous dispersion medium into a closed vessel; heating the polyolefin resin particles up to or above a softening temperature of the polyolefin resin particles; and releasing the polyolefin resin particles into a zone whose pressure is lower than an internal pressure of the closed vessel, with use as a foaming agent of water serving as the dispersion medium, the polyolefin resin particles being composed of a polyolefin resin composition including: polyolefin resin; a substance selected from among polyethylene glycol, polyvalent alcohol having a carbon number of not less than 3 to not more than 6, and a water-absorbing substance having no function of forming foaming nuclei; and a foam nucleating agent.
摘要翻译：本发明提供一种制造发泡聚烯烃树脂颗粒的方法，其发泡细胞不均匀或极小，如以往的发泡粒子，其单元直径和膨胀比可以容易地独立地控制，并且当进行模内膨胀成型时，赋予模内发泡成型体，使其熔融性良好，表面性优异。该方法是通过以下方法生产发泡聚烯烃树脂颗粒的方法：将聚烯烃树脂颗粒与水性分散介质一起分散到密闭容器中; 将聚烯烃树脂颗粒加热到聚烯烃树脂颗粒的软化温度以上或更高的程度; 使用作为分散介质的水的发泡剂，将聚烯烃树脂粒子释放到压力低于密闭容器的内部压力的区域中，所述聚烯烃树脂粒子由聚烯烃树脂组合物构成，所述聚烯烃树脂组合物包含：聚烯烃树脂; 选自聚乙二醇，碳数不小于3至多于6的多元醇的物质和不具有形成发泡核的功能的吸水物质; 和泡沫成核剂。

4. 发明申请

US20130230713A1 PROCESS FOR PRODUCING EXPANDED POLYOLEFIN RESIN PARTICLES AND EXPANDED POLYOLEFIN RESIN PARTICLES 有权
标题翻译：生产膨胀型聚烯烃树脂颗粒和膨胀聚烯烃树脂颗粒的方法
公开(公告)号：US20130230713A1
公开(公告)日：2013-09-05
申请号：US13860847
申请日：2013-04-11
申请人： Toru YOSHIDA , Jun Fukuzawa
发明人： Toru YOSHIDA , Jun Fukuzawa
IPC分类号： B29C44/34
CPC分类号： B29C44/3461 , C08J9/00 , C08J9/0023 , C08J9/0061 , C08J9/125 , C08J9/18 , C08J9/228 , C08J9/232 , C08J2203/06 , C08J2323/02 , C08J2323/12 , C08J2471/00 , Y10T428/249921 , Y10T428/2982
摘要： A process for producing expanded polyolefin resin particles with use as a foaming agent of water contained in an aqueous dispersion medium. The process includes dispersing polyolefin resin particles together with the aqueous dispersion medium into a closed vessel; heating the polyolefin resin particles up to or above a softening temperature of the polyolefin resin particles and pressurizing the polyolefin resin particles; and releasing the polyolefin resin particles into a zone whose pressure is lower than an internal pressure of the closed vessel. The polyolefin resin particles are composed of a polyolefin resin composition including polyolefin resin, a water-absorbing substance, and a foam nucleating agent.
摘要翻译：用作水分散介质中所含水的发泡剂的发泡聚烯烃树脂颗粒的制造方法。该方法包括将聚烯烃树脂颗粒与水分散介质一起分散到密闭容器中; 将聚烯烃树脂颗粒加热至聚烯烃树脂颗粒的软化温度以上或加压聚烯烃树脂颗粒; 并将聚烯烃树脂颗粒释放到压力低于密闭容器的内部压力的区域中。聚烯烃树脂颗粒由包含聚烯烃树脂，吸水物质和泡沫成核剂的聚烯烃树脂组合物组成。

5. 发明授权

US09249281B2 Polyolefin resin foam particles and in-mold foaming molded body of same 有权
标题翻译：聚烯烃树脂泡沫颗粒和模内发泡成型体相同
公开(公告)号：US09249281B2
公开(公告)日：2016-02-02
申请号：US14237491
申请日：2012-08-08
申请人： Jun Fukuzawa
发明人： Jun Fukuzawa
IPC分类号： C08J9/16 , C08J9/18 , C08J9/228 , C08K5/49 , C08K5/5397 , C08J9/00 , B29C44/34 , C08K3/04 , C08J9/12 , C08J9/232 , C08L23/10 , C08L23/16
CPC分类号： C08K5/5397 , B29C44/3415 , B29C44/3461 , C08J9/0028 , C08J9/0038 , C08J9/0061 , C08J9/008 , C08J9/0095 , C08J9/122 , C08J9/125 , C08J9/18 , C08J9/232 , C08J2201/034 , C08J2203/06 , C08J2203/10 , C08J2203/182 , C08J2205/052 , C08J2323/10 , C08J2323/16 , C08J2471/02 , C08K3/04 , C08L23/10 , C08L23/16 , C08L2203/14 , Y10T428/2982
摘要： In order to obtain a flame-retardant polyolefin resin expanding molded product which has excellent in-mold moldability and excellent surface appearance and satisfies the FMVSS flammability even if carbon black is added, polyolefin resin particles containing, with respect to 100 parts by weight of polyolefin resin, (i) 0.03 part by weight to 5 parts by weight of phosphorous flame retardant having a phosphorous content of 7% by weight or more, a melting point of 120° C. or more, and a 5% by weight decomposition temperature within a range of 240° C. to 320° C. and (ii) 0.5 part by weight to 20 parts by weight of carbon black are expanded.
摘要翻译：为了获得即使加入炭黑也能获得模内成型性优异，表面外观优异且满足FMVSS可燃性的阻燃性聚烯烃树脂发泡成型体，相对于100重量份聚烯烃，树脂，（i）0.03重量份至5重量份的磷含量为7重量％以上，熔点为120℃以上的磷阻燃剂和5重量％以下的分解温度 240℃〜320℃的范围，（ii）0.5重量份〜20重量份的炭黑。

6. 发明授权

US09216525B2 Process for producing expanded polyolefin resin particles and expanded polyolefin resin particles 有权
标题翻译：制造发泡聚烯烃树脂颗粒和发泡聚烯烃树脂颗粒的方法
公开(公告)号：US09216525B2
公开(公告)日：2015-12-22
申请号：US13860847
申请日：2013-04-11
申请人： Toru Yoshida , Jun Fukuzawa
发明人： Toru Yoshida , Jun Fukuzawa
IPC分类号： B29C44/34 , C08J9/00 , C08J9/18 , C08J9/228
CPC分类号： B29C44/3461 , C08J9/00 , C08J9/0023 , C08J9/0061 , C08J9/125 , C08J9/18 , C08J9/228 , C08J9/232 , C08J2203/06 , C08J2323/02 , C08J2323/12 , C08J2471/00 , Y10T428/249921 , Y10T428/2982
摘要： A process for producing expanded polyolefin resin particles with use as a foaming agent of water contained in an aqueous dispersion medium. The process includes dispersing polyolefin resin particles together with the aqueous dispersion medium into a closed vessel; heating the polyolefin resin particles up to or above a softening temperature of the polyolefin resin particles and pressurizing the polyolefin resin particles; and releasing the polyolefin resin particles into a zone whose pressure is lower than an internal pressure of the closed vessel. The polyolefin resin particles are composed of a polyolefin resin composition including polyolefin resin, a water-absorbing substance, and a foam nucleating agent.
摘要翻译：用作水分散介质中所含水的发泡剂的发泡聚烯烃树脂颗粒的制造方法。该方法包括将聚烯烃树脂颗粒与水分散介质一起分散到密闭容器中; 将聚烯烃树脂颗粒加热至聚烯烃树脂颗粒的软化温度以上或加压聚烯烃树脂颗粒; 并将聚烯烃树脂颗粒释放到压力低于密闭容器的内部压力的区域中。聚烯烃树脂颗粒由包含聚烯烃树脂，吸水物质和泡沫成核剂的聚烯烃树脂组合物组成。

7. 发明申请

US20140171534A1 POLYOLEFIN RESIN FOAM PARTICLES AND IN-MOLD FOAMING MOLDED BODY OF SAME 有权
标题翻译： POLYOLEFIN树脂泡沫颗粒和模内泡沫成型体
公开(公告)号：US20140171534A1
公开(公告)日：2014-06-19
申请号：US14237491
申请日：2012-08-08
申请人： Jun Fukuzawa
发明人： Jun Fukuzawa
IPC分类号： C08K5/5397 , C08K3/04 , B29C44/34
CPC分类号： C08K5/5397 , B29C44/3415 , B29C44/3461 , C08J9/0028 , C08J9/0038 , C08J9/0061 , C08J9/008 , C08J9/0095 , C08J9/122 , C08J9/125 , C08J9/18 , C08J9/232 , C08J2201/034 , C08J2203/06 , C08J2203/10 , C08J2203/182 , C08J2205/052 , C08J2323/10 , C08J2323/16 , C08J2471/02 , C08K3/04 , C08L23/10 , C08L23/16 , C08L2203/14 , Y10T428/2982
摘要： In order to obtain a flame-retardant polyolefin resin expanding molded product which has excellent in-mold moldability and excellent surface appearance and satisfies the FMVSS flammability even if carbon black is added, polyolefin resin particles containing, with respect to 100 parts by weight of polyolefin resin, (i) 0.03 part by weight to 5 parts by weight of phosphorous flame retardant having a phosphorous content of 7% by weight or more, a melting point of 120° C. or more, and a 5% by weight decomposition temperature within a range of 240° C. to 320° C. and (ii) 0.5 part by weight to 20 parts by weight of carbon black are expanded.
摘要翻译：为了获得即使加入炭黑也能获得模内成型性优异，表面外观优异且满足FMVSS可燃性的阻燃性聚烯烃树脂发泡成型体，相对于100重量份聚烯烃，树脂，（i）0.03重量份至5重量份的磷含量为7重量％以上，熔点为120℃以上的磷阻燃剂和5重量％以下的分解温度 240℃〜320℃的范围，（ii）0.5重量份〜20重量份的炭黑。

8. 发明申请

US20100267850A1 PROCESS FOR PRODUCING EXPANDED POLYOLEFIN RESIN PARTICLES AND EXPANDED POLYOLEFIN RESIN PARTICLES 有权
标题翻译：生产膨胀型聚烯烃树脂颗粒和膨胀聚烯烃树脂颗粒的方法
公开(公告)号：US20100267850A1
公开(公告)日：2010-10-21
申请号：US12747050
申请日：2008-12-03
申请人： Toru Yoshida , Jun Fukuzawa , Takamasa Imai , Kiyoshi Mori , Hiroshi Tsuneishi
发明人： Toru Yoshida , Jun Fukuzawa , Takamasa Imai , Kiyoshi Mori , Hiroshi Tsuneishi
IPC分类号： C08J9/16
CPC分类号： B29C44/3461 , C08J9/00 , C08J9/0023 , C08J9/0061 , C08J9/125 , C08J9/18 , C08J9/228 , C08J9/232 , C08J2203/06 , C08J2323/02 , C08J2323/12 , C08J2471/00 , Y10T428/249921 , Y10T428/2982
摘要： Provided is a process for producing expanded polyolefin resin particles whose cells are not made nonuniform or extremely smaller as seen in conventional expanded particles, whose cell diameter and expansion ratio can be easily controlled independently, and which, when subjected to in-mold expansion molding, give in-mold expanded molded products satisfactory in fusibility and excellent in surface properties. The process is a process for producing expanded polyolefin resin particles by: dispersing polyolefin resin particles together with an aqueous dispersion medium into a closed vessel; heating the polyolefin resin particles up to or above a softening temperature of the polyolefin resin particles; and releasing the polyolefin resin particles into a zone whose pressure is lower than an internal pressure of the closed vessel, with use as a foaming agent of water serving as the dispersion medium, the polyolefin resin particles being composed of a polyolefin resin composition including: polyolefin resin; a substance selected from among polyethylene glycol, polyvalent alcohol having a carbon number of not less than 3 to not more than 6, and a water-absorbing substance having no function of forming foaming nuclei; and a foam nucleating agent.
摘要翻译：本发明提供一种制造发泡聚烯烃树脂颗粒的方法，其发泡细胞不均匀或极小，如以往的发泡粒子，其单元直径和膨胀比可以容易地独立地控制，并且当进行模内膨胀成型时，赋予模内发泡成型体，使其熔融性良好，表面性优异。该方法是通过以下方法生产发泡聚烯烃树脂颗粒的方法：将聚烯烃树脂颗粒与水性分散介质一起分散到密闭容器中; 将聚烯烃树脂颗粒加热到聚烯烃树脂颗粒的软化温度以上或更高的程度; 使用作为分散介质的水的发泡剂，将聚烯烃树脂粒子释放到压力低于密闭容器的内部压力的区域中，所述聚烯烃树脂粒子由聚烯烃树脂组合物构成，所述聚烯烃树脂组合物包含：聚烯烃树脂; 选自聚乙二醇，碳数不小于3至多于6的多元醇的物质和不具有形成发泡核的功能的吸水物质; 和泡沫成核剂。

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