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1. 发明授权

US5227550A Method for preparation of methyl chloride 失效
标题翻译：氯甲烷的制备方法
公开(公告)号：US5227550A
公开(公告)日：1993-07-13
申请号：US884272
申请日：1992-05-13
申请人： Takaaki Shimizu , Taishi Kobayashi , Hironori Iwasaki
发明人： Takaaki Shimizu , Taishi Kobayashi , Hironori Iwasaki
IPC分类号： C07C17/16
CPC分类号： C07C17/16
摘要： Carbon tetrachloride, which is a material of low value and may be banned due to the problem of the destructiveness against the stratospheric ozone layer, can be efficiently utilized in the preparation of more useful methyl chloride by a catalytic vapor-phase reaction in a vapor mixture of carbon tetrachloride, methyl alcohol and water. The solid catalyst with which the vapor mixture is contacted at 150.degree. to 250.degree. C. is, for example, a zinc chloride catalyst supported on an active carbon carrier. The conversion of carbon tetrachloride is almost 100% when the contacting time is 10 to 20 seconds.
摘要翻译：作为低价值材料，由于对平流层臭氧层的破坏性问题而可能被禁止的四氯化碳可以有效地用于通过在蒸汽混合物中的催化气相反应制备更有用的甲基氯的四氯化碳，甲醇和水。蒸气混合物在150-250℃下接触的固体催化剂是例如负载在活性炭载体上的氯化锌催化剂。当接触时间为10至20秒时，四氯化碳的转化率几乎为100％。

2. 发明申请

US20120121493A1 METHOD FOR PURIFYING CHLOROSILANES 有权
标题翻译：纯化氯霉素的方法
公开(公告)号：US20120121493A1
公开(公告)日：2012-05-17
申请号：US13386926
申请日：2010-07-07
申请人： Naoki Nagai , Takaaki Shimizu , Katsuhiro Uehara , Tohru Kubota
发明人： Naoki Nagai , Takaaki Shimizu , Katsuhiro Uehara , Tohru Kubota
IPC分类号： C01B33/107
CPC分类号： C01B33/10778
摘要： The present invention provides a method for obtaining high purity chlorosilanes from chlorosilanes containing boron impurities and phosphorus impurities. On the basis of the finding that solid by-product formation in the purification of chlorosilanes by adding an aromatic aldehyde results from a catalytic reaction by iron ions or rust-like iron, a Lewis base having a masking effect is added to chlorosilanes. Examples of the Lewis base include a divalent sulfur-containing compound and an alkoxysilane. The divalent sulfur-containing compound is preferably a compound represented by the formula: R—S—R′ (wherein R is a hydrocarbon group or a carbonyl group; and the sum of the carbon atoms in R and R′ is 7 or more), and the alkoxysilane is preferably a compound represented by the formula: RxSi(OR′)4-x (wherein R and R′ are each an alkyl group having 1 to 20 carbon atoms).
摘要翻译：本发明提供从含有硼杂质和磷杂质的氯硅烷中获得高纯度氯硅烷的方法。基于通过添加芳族醛的氯硅烷纯化产生固体副产物的结果是由铁离子或铁锈铁的催化反应产生的，将具有掩蔽效应的路易斯碱加入到氯硅烷中。路易碱碱的实例包括二价含硫化合物和烷氧基硅烷。二价含硫化合物优选为由下式表示的化合物：R-S-R'（其中R为烃基或羰基; R和R'中的碳原子总数为7以上）烷氧基硅烷优选为下式所示的化合物：RxSi（OR'）4-x（式中，R和R'分别为碳原子数为1〜20的烷基）。

3. 发明授权

US06811087B2 Barcode scanner 失效
标题翻译：扫码机
公开(公告)号：US06811087B2
公开(公告)日：2004-11-02
申请号：US10410395
申请日：2003-04-10
申请人： Norio Nakamura , Nobuyasu Goto , Takaaki Shimizu , Yutaka Ichinohe
发明人： Norio Nakamura , Nobuyasu Goto , Takaaki Shimizu , Yutaka Ichinohe
IPC分类号： G06K710
CPC分类号： G06K7/10851
摘要： A barcode scanner comprising a laser driving circuit to drive a laser by a pulse signal generated by an oscillator, a preamplifier to amplify a voltage of a barcode signal from a photodetector corresponding to a reflected light from a barcode scanned by a light output of the laser driven by the pulse signal, a high-pass filter to remove a direct current component contained in an output signal of the preamplifier, a variable gain amplifier which controls an amplification gain of an output signal of the high-pass filter and performs automatic gain control to set an output level almost constant, a synchronous detector to detect a pulse signal contained in an output signal of the variable gain amplifier in synchronization with the output pulse of the oscillator, and a binarization circuit to binarize an output signal of the synchronous detector.
摘要翻译：一种条形码扫描器，包括：激光驱动电路，用于通过由振荡器产生的脉冲信号来驱动激光;前置放大器，用于放大来自光电检测器的条形码信号的电压，所述光电检测器对应于来自由激光的光输出扫描的条形码的反射光由脉冲信号驱动的高通滤波器，去除包含在前置放大器的输出信号中的直流分量;可变增益放大器，其控制高通滤波器的输出信号的放大增益，并执行自动增益控制为了使输出电平几乎恒定，同步检波器与振荡器的输出脉冲同步地检测包含在可变增益放大器的输出信号中的脉冲信号，以及二值化电路，对同步检波器的输出信号进行二值化。

4. 发明授权

US5851426A Twisted nematic liquid crystal composition containing a silacyclohexane compound 失效
标题翻译：含有硅环己烷化合物的扭曲向列型液晶组合物
公开(公告)号：US5851426A
公开(公告)日：1998-12-22
申请号：US873667
申请日：1997-06-12
申请人： Takaaki Shimizu , Tatsushi Kaneko , Tsutomu Ogihara , Mutsuo Nakashima
发明人： Takaaki Shimizu , Tatsushi Kaneko , Tsutomu Ogihara , Mutsuo Nakashima
IPC分类号： C09K19/40 , C09K19/58 , C09K19/34 , C09K19/30
CPC分类号： C09K19/588 , C09K19/40
摘要： This invention provides twisted nematic liquid crystal compositions obtained by adding a cyclohexane ring-containing optically active compound of the following general formula (1) to a mixture of nematic liquid crystal compounds including at least one silacyclohexane compound, as well as guest-host liquid crystal compositions and liquid crystal display devices utilizing the same. ##STR1##
摘要翻译：本发明提供通过将含有下列通式（1）的含环己烷环的光学活性化合物加入到包括至少一种硅环己烷化合物的向列型液晶化合物以及客体主体液晶的混合物中而获得的扭曲向列型液晶组合物组合物和使用其的液晶显示装置。（1）

5. 发明授权

US5665271A Silacyclohexane compounds, preparation thereof, liquid crystal compositions comprising the same, and liquid crystal devices comprising the compositions 失效
标题翻译：硅环己烷化合物，其制备方法，含有它们的液晶组合物和包含该组合物的液晶装置
公开(公告)号：US5665271A
公开(公告)日：1997-09-09
申请号：US598595
申请日：1996-02-12
申请人： Tsutomu Ogihara , Takaaki Shimizu , Takeshi Kinsho , Tatsushi Kaneko , Kazuyuki Asakura , Mutsuo Nakashima
发明人： Tsutomu Ogihara , Takaaki Shimizu , Takeshi Kinsho , Tatsushi Kaneko , Kazuyuki Asakura , Mutsuo Nakashima
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/34
CPC分类号： C07F7/12 , C07F7/0818 , C07F7/0896 , C09K19/406
摘要： Silacyclohexane compounds of the following formula (I) or (II) along with intermediate compounds therefor are described ##STR1## wherein R is an organic residue, one of ##STR2## represents a trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group having a substituent of H, F, Cl or CH.sub.3, and the other represents a trans-1,4-cyclohexylene group, or such a trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group as defined above, n is 0 or 1, L.sub.1 represents H or F, L.sub.2 represents H, F or Cl, and Z represents CN, F, Cl or an organic residue, and ##STR3## The processes for preparing the compounds (I) and (II) are also described along with liquid crystal compositions comprising the compounds and the liquid crystal devices comprising the compositions.
摘要翻译：描述下式（I）或（II）的硅环己烷化合物及其中间体化合物描述：其中R是有机残基，其中一个表示反式-1-硅烷-1,4-二醇，具有H，F，Cl或CH 3的取代基的亚环己基或反式-4-硅烷-1,4-亚环己基，另一个表示反式-1,4-亚环己基或反式-1-硅烷基， 1,4-亚环己基或反式-4-硅烷-1,4-亚环己基，n为0或1，L 1表示H或F，L 2表示H，F或Cl，Z表示CN，F， Cl或有机残基，以及包含化合物的液晶组合物和包含该组合物的液晶装置也描述了（I）和（II）。

6. 发明授权

US5659059A Silacyclohexane compound, a method of preparing it and a liquid crystal composition containing it 失效
标题翻译：硅环己烷化合物，其制备方法和含有它的液晶组合物
公开(公告)号：US5659059A
公开(公告)日：1997-08-19
申请号：US331957
申请日：1994-10-31
申请人： Tsutomu Ogihara , Takaaki Shimizu , Takeshi Kinsho , Tatsushi Kaneko , Ryuichi Saito , Hideshi Kurihara
发明人： Tsutomu Ogihara , Takaaki Shimizu , Takeshi Kinsho , Tatsushi Kaneko , Ryuichi Saito , Hideshi Kurihara
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40
CPC分类号： C07F7/0818 , C07F7/0896 , C07F7/12 , C09K19/406
摘要： A silacyclohexane compound represented by the following general formula (I). ##STR1## In this formula, R denotes a linear-chain alkyl group with a carbon number of 1-10, a mono- or di- fluoro-alkyl group with a carbon number of 1-10, a branched-chain alkyl group with a carbon number of 3-8, an alkoxyalkyl group with a carbon number of 2-7, or an alkenyl group with a carbon number of 2-8. ##STR2## denotes trans-1-sila-1,4-cyclohexylene or trans-4-sila-1,4-cyclohexylene group whose silicon at position 1 or position 4 has a substitutional group(s) of H, F, Cl or CH.sub.3. X denotes a CN, F, Cl, CF.sub.3, CF.sub.2 Cl, CHFCl, OCF.sub.3, OCHF.sub.2, OCF.sub.2 Cl, OCHFCl, R or OR group (R is the same as defined in the general formula (I)). Y.sub.2 and Z denote H or F, independently to each other. Y.sub.1 denotes H, F or Cl.
摘要翻译：由以下通式（I）表示的硅环己烷化合物。（I）在该式中，R表示碳数为1-10的直链烷基，碳数为1〜10的单 - 或二 - 氟 - 烷基，支链碳数为3-8的烷基，碳数为2-7的烷氧基烷基或碳数为2-8的烯基。或其中位置1或位置4的硅具有H，F，Cl或CH 3的取代基的反式-4-硅烷-1,4-亚环己基。 X表示CN，F，Cl，CF 3，CF 2 Cl，CHFCl，OCF 3，OCHF 2，OCF 2 Cl，OCHFCl，R或OR基团（R与通式（I）中定义的相同）。 Y2和Z彼此独立地表示H或F。 Y1表示H，F或Cl。

7. 发明授权

US5573705A Silacyclohexane compound, a method of preparing it and a liquid crystal composition containing it 失效
标题翻译：硅环己烷化合物，其制备方法和含有它的液晶组合物
公开(公告)号：US5573705A
公开(公告)日：1996-11-12
申请号：US362964
申请日：1994-12-23
申请人： Tatsushi Kaneko , Takeshi Kinsho , Takaaki Shimizu , Tsutomu Ogihara , Ryuichi Saito , Hideshi Kurihara
发明人： Tatsushi Kaneko , Takeshi Kinsho , Takaaki Shimizu , Tsutomu Ogihara , Ryuichi Saito , Hideshi Kurihara
IPC分类号： C07F7/08 , C09K19/40 , C09K19/34
CPC分类号： C07F7/0818 , C07F7/0896 , C09K19/406
摘要： A liquid crystal composition comprising a silacyclohexane compound represented by the following formula (I): ##STR1## wherein R and R' denote an alkyl group, a mono- or di-fluoroalkyl group, an alkoxyalkyl group or an alkenyl group; at least one of ##STR2## denotes a silacyclohexylene group whose silicon at positions 1 or 4 has a substitutional group of H, F, Cl of CH.sub.3, and the other denotes a silacyclohexylene group whose silicon at positions 1 or 4 has a substitutional group of H, F, Cl or CH.sub.3 or a cyclohexylene group; and 0-2 of the substitutional groups X on the aromatic rings denote F and the remaining X's denote H.
摘要翻译：一种液晶组合物，其包含由下式（I）表示的硅环己烷化合物：其中R和R'表示烷基，单或二氟烷基，烷氧基烷基或烯基; 和中的至少一个表示其中位置1或4的硅具有H，F，CH 3的取代基的硅环亚己基，另一个表示其1或4位的硅具有的硅环亚己基 H，F，Cl或CH 3或亚环己基的取代基; 芳环上的取代基X的0-2表示F，其余的X表示H.

8. 发明授权

US5547606A Silacyclohexane compound, a method of preparing it and a liquid crystal composition containing it 失效
标题翻译：硅环己烷化合物，其制备方法和含有它的液晶组合物
公开(公告)号：US5547606A
公开(公告)日：1996-08-20
申请号：US322549
申请日：1994-10-13
申请人： Takeshi Kinsho , Tatsushi Kaneko , Takaaki Shimizu , Tsutomu Ogihara , Ryuichi Saito , Hideshi Kurihara
发明人： Takeshi Kinsho , Tatsushi Kaneko , Takaaki Shimizu , Tsutomu Ogihara , Ryuichi Saito , Hideshi Kurihara
IPC分类号： C07F7/08 , C07F7/12 , C09K19/40 , C09K19/34 , C09K19/30 , G02F1/13
CPC分类号： C07F7/0818 , C07F7/0896 , C07F7/12 , C09K19/406
摘要： A silacyclohexane compound represented by the following general formula (I). ##STR1## In this formula, R denotes hydrogen, a linear-chain alkyl group with a carbon number of 1-10, a branched-chain alkyl group with a carbon number of 3-8, an alkoxyalkyl group with a carbon number of 2-7, a fluoroalkyl group with a carbon number of 1-10 in which one or two hydrogen atoms are substituted by florine atom(s), or an alkenyl group with a carbon number of 2-8. For the groups ##STR2## at least one of these is a trans-1-sila-1,4-cyclohexylene or trans-4-sila-1,4-cyclohexylene group whose silicon at position 1 or position 4 has a substitutional group(s) of H, F, Cl or CH.sub.3, and the other denotes a trans-1,4-cyclohexylene group. X denotes a CN, F, Cl, CF.sub.3, CF.sub.2 Cl, CHFCl, OCF.sub.3, OCHF.sub.2, OCF.sub.2 Cl, OCHFCl, R or OR group (R is the same as defined earlier). Y denotes H or F. Z denotes H or F.
摘要翻译：由以下通式（I）表示的硅环己烷化合物。（I）在该式中，R表示氢，碳数为1〜10的直链烷基，碳数为3〜8的支链烷基，碳数为烷氧基烷基数为2-7，碳数为1-10的氟代烷基，其中一个或两个氢原子被氟原子取代，或碳数为2-8的烯基。对于组，其中至少一个是位于1或4位的硅具有取代基的反式-1-硅烷-1,4-亚环己基或反式-4-硅烷-1,4-亚环己基， s）H，F，Cl或CH 3，另一个表示反式-1,4-亚环己基。 X表示CN，F，Cl，CF 3，CF 2 Cl，CHFCl，OCF 3，OCHF 2，OCF 2 Cl，OCHFCl，R或OR基团（R与前述相同）。 Y表示H或F.Z表示H或F.

9. 发明授权

US5045574A Film-forming agent 失效
标题翻译：成膜剂
公开(公告)号：US5045574A
公开(公告)日：1991-09-03
申请号：US467387
申请日：1990-01-19
申请人： Satoshi Kuwata , Takashi Ohkawara , Takaaki Shimizu
发明人： Satoshi Kuwata , Takashi Ohkawara , Takaaki Shimizu
IPC分类号： A61K9/70 , A61K8/00 , A61K8/25 , A61K8/72 , A61K8/89 , A61K8/891 , A61K8/892 , A61K47/34 , A61Q17/00 , C08K3/36 , C08K9/06 , C08L83/04 , C08L83/06 , C09D183/04 , C09D183/06 , C09G1/00 , C09G1/12
CPC分类号： A61K8/892 , A61Q17/00 , C08K3/36 , C08L83/04 , C08G77/16
摘要： The film-forming agent of the invention is a blend of a silica organosol, of which the silica particles have a specified specific surface area and specified densities of surface groups including silanol groups, alkoxy groups and trimethyl silyl groups, and a diorganopolysiloxane of a specified viscosity terminated at each molecular chain end with a silanolic hydroxy group. The film-forming agent is useful as a skin-care preparation for preventing chapping of hands of people having frequent occasions of contacting with water to exhibit durable water repellency.

10. 发明授权

US5013585A Method for the preparation of surface-modified silica particles 失效
标题翻译：表面改性二氧化硅颗粒的制备方法
公开(公告)号：US5013585A
公开(公告)日：1991-05-07
申请号：US534450
申请日：1990-06-06
申请人： Takaaki Shimizu , Tsutomu Ogihara , Masatoshi Takita
发明人： Takaaki Shimizu , Tsutomu Ogihara , Masatoshi Takita
IPC分类号： B01J20/32 , C01B33/145 , C01B33/149 , C09C1/30 , C10M113/16
CPC分类号： B82Y30/00 , C01B33/145 , C01B33/149 , C09C1/3081 , C10M113/16 , C01P2002/86 , C01P2004/64 , C01P2006/10 , C01P2006/12 , C10M2201/14 , C10M2227/04 , Y10T428/2995
摘要： A method for the preparation of a stable silica organosol in a hydrophobic organic solvent is proposed. The method comprises (a) hydrolyzing a tetraalkoxy silane, e.g. tetraethoxy silane, in an alcoholic medium in the presence of a limited amount of water and ammonia as a catalyst under controlled conditions so as to produce a silica alcosol in which the silica particles satisfy the requirements that the alkoxy groups and silanolic hydroxy groups are bonded to the silicon atoms on the surface in densities of at least 3.5 .mu. moles/m.sup.2 and not exceeding 2 .mu. mmoles/m.sup.2, respectively, and the specific surface area S given in m.sup.2 /g and the average particle diameter D given in nm of the silica particles satisfy the relationship of S.times.D.gtoreq.5000, D being 1 nm or larger, and (b) admixing the alcosol of silica particles with an organosilicon compound selected from the group consisting of the compounds represented by the general formula R.sub.4-n SiX.sub.n, (R.sub.3 Si).sub.2 NH, or YO--(--SiR.sub.2 --O--).sub.m --Y, in which each R is, independently from the others, a hydrogen atom or a monovalent hydrocarbon group, X is a hydroxy group or an alkoxy group, Y is a hydrogen atom or an alkyl group, n is 1, 2 or 3 and m is a positive integer not exceeding 20, in an amount, for example, in the range from 0.01 to 10 moles per mole of the silica particles under agitation of the mixture to effect a reaction for the modification of the surface of the silica particles followed by replacement of the alcoholic medium with a desired organic solvent.
摘要翻译：提出了一种在疏水性有机溶剂中制备稳定的二氧化硅有机溶胶的方法。该方法包括（a）水解四烷氧基硅烷，例如四乙氧基硅烷，在有限量的水和氨作为催化剂的存在下，在控制条件下在醇介质中，以产生二氧化硅颗粒，其中二氧化硅颗粒满足烷氧基和硅烷醇羟基键合的要求表面上的硅原子的密度分别为至少3.5μmol/ m 2并且不超过2um mmoles / m 2，并且以m2 / g给出的比表面积S和以二氧化硅计的平均粒径D 颗粒满足SxD> / = 5000，D为1nm以上的关系，（b）将二氧化硅粒子的醇溶胶与选自由通式R4-nSiXn表示的化合物的有机硅化合物混合，（ R3Si）2NH或YO - （ - SiR2-O-）mY，其中每个R独立地为氢原子或一价烃基，X为羟基或烷氧基，Y为氢原子或烷基，n为1， 2或3，并且m是不超过20的正整数，其量例如在混合物搅拌下每摩尔二氧化硅颗粒为0.01至10摩尔，以实现改性表面的反应二氧化硅颗粒，然后用所需的有机溶剂置换醇介质。

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