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    • 4. 发明申请
    • Catalyst and Method for Catalytic Reduction of Nitrogen Oxides
    • 用于催化还原氮氧化物的催化剂和方法
    • US20070274889A1
    • 2007-11-29
    • US10578664
    • 2004-11-08
    • Tadao NakatsujiNorio SuzukiHiroshi OhnoNaohiro SatoTomoko MoritaKatsuji Wada
    • Tadao NakatsujiNorio SuzukiHiroshi OhnoNaohiro SatoTomoko MoritaKatsuji Wada
    • B01D53/56B01J23/652B01J29/22B01J29/24B01J29/76
    • B01D53/9422B01D2255/102B01D2255/20B01D2255/206B01J23/652B01J29/7415B01J29/7615B01J29/7815B01J35/0006
    • The invention provides a catalyst for catalytic reduction of nitrogen oxides contained in exhaust gases wherein fuel is supplied and subjected to combustion under periodic rich/lean conditions and the resulting exhaust gases are brought into contact therewith, which catalyst comprises: (A) a catalyst component A comprising (c) ceria or (d) praseodymium oxide or (e) an oxide and/or a composite oxide of at least two elements selected from the group consisting of cerium, zirconium, praseodymium, neodymium, terbium, samarium, gadolinium and lanthanum; (B) a catalyst component B comprising (d) a noble metal catalyst component selected from the group consisting of platinum, rhodium, palladium and oxides thereof and (e) a carrier; and (C) a catalyst component C comprising (f) a solid acid, and (g) a solid acid supporting an oxide of at least one element selected from the group consisting of vanadium, tungsten, molybdenum, copper, iron, cobalt, nickel and manganese. The catalyst reduces NOx contained in exhaust gases wherein fuel is supplied and subjected to combustion with a periodic rich/lean excursions, whereby NOx is generated in the exhaust gases, with high durability in a wide temperature range even in the presence of oxygen, sulfur oxides or water.
    • 本发明提供一种用于催化还原废气中所含的氮氧化物的催化剂,其中燃料在周期性富/贫条件下被供应并经历燃烧,并使得到的废气与其接触,该催化剂包括:(A)催化剂组分 A包括(c)二氧化铈或(d)氧化镨或(e)选自铈,锆,镨,钕,铽,钐,钆和镧中的至少两种元素的氧化物和/或复合氧化物 ; (B)催化剂组分B,其包含(d)选自铂,铑,钯及其氧化物的贵金属催化剂组分和(e)载体; 和(C)包含(f)固体酸的催化剂组分C,和(g)支持选自钒,钨,钼,铜,铁,钴,镍, 和锰。 催化剂还原废气中所含的NOx,其中燃料被供给并经历周期性的富/贫漂移的燃烧,从而在废气中产生NOx,即使在存在氧,硫氧化物的情况下,在宽温度范围内具有高耐久性 或水。
    • 10. 发明授权
    • Exhaust gas purifying device for an internal combustion engine
    • 内燃机用废气净化装置
    • US07992378B2
    • 2011-08-09
    • US11980924
    • 2007-10-31
    • Tomoko MoritaNorio SuzukiNaohiro Sato
    • Tomoko MoritaNorio SuzukiNaohiro Sato
    • F01N3/00F01N3/10
    • F01N3/0814F01N3/0842F01N3/0871F01N11/002F01N2550/03F01N2610/03F02D41/0275F02D41/1441F02D2200/0806F02D2200/0808Y02T10/24Y02T10/47
    • An exhaust gas purifying device for an internal combustion engine, comprises: an exhaust purifying catalyst; a NOx purifying catalyst disposed downstream of the exhaust purifying catalyst; upstream and downstream A/F detecting sensors disposed on upstream and downstream sides of the exhaust purifying catalyst, respectively; means for supplying a reducing agent to the NOx purifying catalyst when conducting a reduction control of the NOx; means for calculating an amount of reduced NOx in the NOx purifying catalyst; means for terminating the reduction control when the amount of reduced NOx exceeds a prescribed reduction termination threshold value; means for detecting a degree of deterioration of the exhaust purifying catalyst based on an output from the upstream and downstream A/F detecting sensors; a threshold value correcting means for correcting the reduction termination threshold value according to the degree of deterioration of the exhaust purifying catalyst; and a correction prohibiting means for prohibiting the correction of the reduction termination threshold value when an amount of H2 and/or CH4 in the exhaust gas exceeds a prescribed correction prohibiting judgment value.
    • 一种用于内燃机的废气净化装置,包括:排气净化催化剂; 设置在所述排气净化催化剂的下游的NOx净化催化剂; 分别设置在排气净化催化剂的上游侧和下游侧的上下游A / F检测传感器; 用于在进行NOx的还原控制时向NOx净化催化剂供给还原剂的装置; 用于计算NOx净化催化剂中的还原NOx量的装置; 用于当减少的NOx的量超过规定的减少终止阈值时终止减少控制的装置; 用于根据来自上游和下游的A / F检测传感器的输出来检测排气净化催化剂的劣化程度的装置; 阈值校正装置,用于根据排气净化催化剂的劣化程度来校正所述还原终止阈值; 以及校正禁止装置,用于当排气中的H2和/或CH4的量超过规定的校正禁止判定值时,禁止修正减少终止阈值。