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1. 发明申请

WO2011128760A2 METHOD OF MANUFACTURING FUEL CELL 审中-公开
标题翻译：制造燃料电池的方法
公开(公告)号：WO2011128760A2
公开(公告)日：2011-10-20
申请号：PCT/IB2011/000813
申请日：2011-04-12
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , HASEGAWA, Shigeki , SHINOZAKI, Yoshihiro , IMANISHI, Masahiro , SANO, Seiji
发明人： HASEGAWA, Shigeki , SHINOZAKI, Yoshihiro , IMANISHI, Masahiro , SANO, Seiji
IPC分类号： H01M4/86 , H01M8/10 , H01M4/88
CPC分类号： H01M8/1002 , H01M4/8605 , H01M4/8657 , H01M4/8673 , H01M4/8814 , H01M4/8817 , H01M4/8846 , H01M4/886 , H01M4/8875 , H01M4/8878 , H01M4/8892 , H01M8/1007 , H01M2008/1095 , Y02E60/521 , Y02P70/56
摘要： A method of manufacturing a fuel cell includes: growing carbon nanotubes substantially perpendicular to a substrate formed by loading a growth catalyst on a base material; arranging the substrate and a polymer electrolyte membrane so as to oppose to each other and combining the carbon nanotubes with the polymer electrolyte membrane; and dissolving and removing part of the substrate by immersing the substrate in a solution which dissolves the substrate, after the carbon nanotubes and the polymer electrolyte membrane are combined.
摘要翻译：制造燃料电池的方法包括：生长碳纳米管，其基本上垂直于通过将生长催化剂负载在基材上形成的基材; 将基板和聚合物电解质膜布置成彼此相对并将碳纳米管与聚合物电解质膜组合; 并且在碳纳米管和聚合物电解质膜组合之后，通过将基板浸入溶解基板的溶液中来溶解和去除部分基板。

2. 发明申请

WO2011128761A1 MEMBRANE ELECTRODE ASSEMBLY, METHOD OF MANUFACTURE THEREOF, AND FUEL CELL 审中-公开
标题翻译：膜电极组件，其制造方法和燃料电池
公开(公告)号：WO2011128761A1
公开(公告)日：2011-10-20
申请号：PCT/IB2011/000816
申请日：2011-04-13
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , HASEGAWA, Shigeki , SHINOZAKI, Yoshihiro , IMANISHI, Masahiro , SANO, Seiji
发明人： HASEGAWA, Shigeki , SHINOZAKI, Yoshihiro , IMANISHI, Masahiro , SANO, Seiji
IPC分类号： H01M8/10 , H01M4/88
CPC分类号： H01M8/1004 , H01M4/881 , H01M4/8814 , H01M4/8892 , Y02P70/56
摘要： A cathode catalyst layer (16) includes electron conducting carbon nanotubes (CNTs) (161) having a hollow space formed at an interior. The CNTs (161) are, in a hollow space forming direction thereof, open at a first end and are closed at a second end. The open end (161a) is disposed so as to be in contact with a gas diffusion layer (22). On the other hand, the closed end (161b) is disposed so as to be in contact with a polymer electrolyte membrane (12). Defects are formed on a surface of the CNTs (161). The defects (161c) are formed so as to communicate between an outer surface of the CNTs (161) and the hollow space. Catalyst particles (162) are provided on the outer surface of the CNTs. (161), and an ionomer (163) is provided so as to cover the catalyst particles (162).
摘要翻译：阴极催化剂层（16）包括在内部形成有中空空间的电子传导性碳纳米管（CNT）（161）。 CNT（161）在其中空空间形成方向上在第一端处开放并在第二端封闭。开口端161a配置成与气体扩散层22接触。另一方面，封闭端（161b）配置成与高分子电解质膜（12）接触。在CNT（161）的表面上形成缺陷。缺陷（161c）形成为在CNT（161）的外表面和中空空间之间连通。催化剂颗粒（162）设置在CNT的外表面上。（161）和离聚物（163），以覆盖催化剂颗粒（162）。

3. 发明申请

WO2009118649A1 FUEL CELL SYSTEM AND OPERATING METHOD OF A FUEL CELL 审中-公开
标题翻译：燃料电池系统和燃料电池的操作方法
公开(公告)号：WO2009118649A1
公开(公告)日：2009-10-01
申请号：PCT/IB2009/005332
申请日：2009-03-26
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , HASEGAWA, Shigeki , ANDO, Masaki , HAMADA, Kenichi
发明人： HASEGAWA, Shigeki , ANDO, Masaki , HAMADA, Kenichi
IPC分类号： H01M8/04
CPC分类号： H01M8/04104 , H01M8/04119 , H01M8/04149 , H01M8/04291 , H01M8/045 , H01M8/04507 , H01M8/04529 , H01M8/04753 , H01M8/04783 , H01M8/0485
摘要： A fuel cell system operates under at least one of the conditions of no humidity or high temperature, and an operating method thereof, are characterized in that a fuel cell has a fuel gas flow path and an oxidant gas flow path arranged such that fuel gas and oxidant gas flow in opposite directions, a determining apparatus that determines the amount of water near the oxidant gas flow path inlet, and a fuel gas control apparatus which increases the amount of water near the oxidant gas flow path inlet by increasing the fuel gas flowrate and/or reducing the fuel gas pressure if it is determined in the determining apparatus that the amount of water near the oxidant gas flow path inlet is insufficient.
摘要翻译：燃料电池系统在无湿度或高温条件下的至少一个条件下工作，其操作方法的特征在于，燃料电池具有燃料气体流路和氧化剂气体流路，其布置成使得燃料气体和确定氧化剂气体流路入口附近的水量的确定装置和通过增加燃料气体流量而增加氧化剂气体流路入口附近的水量的燃料气体控制装置，以及 /或如果在确定装置中确定氧化剂气体流路入口附近的水量不足，则降低燃料气体压力。

4. 发明申请

WO2013030652A8 CATALYST PRODUCTION METHOD, ELECTRODE CATALYST FOR FUEL CELL PRODUCED BY THIS METHOD, AND CATALYST PRODUCTION APPARATUS 审中-公开
公开(公告)号：WO2013030652A8
公开(公告)日：2013-03-07
申请号：PCT/IB2012/001659
申请日：2012-08-29
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , HASEGAWA, Shigeki , AIZAWA, Satoru
发明人： HASEGAWA, Shigeki , AIZAWA, Satoru
IPC分类号： H01M4/92 , H01M4/88 , H01M4/90 , B01J37/00
摘要： A method for producing a catalyst supporting a metal or an alloy on a support, including: independently controlling a temperature of a first supercritical fluid to be first temperature, the first supercritical fluid containing a precursor of the metal or precursor of the alloy that is dissolved in a supercritical fluid; independently controlling a temperature of the support to be a second temperature higher than the temperature of the first supercritical fluid; and supplying the first supercritical fluid controlled to the first temperature to the support, to cause the metal or the alloy to be supported on the support.

5. 发明申请

WO2009112922A2 FUEL CELL AND FUEL CELL SYSTEM 审中-公开
标题翻译：燃料电池和燃料电池系统
公开(公告)号：WO2009112922A2
公开(公告)日：2009-09-17
申请号：PCT/IB2009/000460
申请日：2009-03-09
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , HASEGAWA, Shigeki , OGAWA, Tomohiro , KAZIWARA, Takashi , FUTAMI, Satoshi , TAKEHIRA, Yuichi , ANDO, Masaki
发明人： HASEGAWA, Shigeki , OGAWA, Tomohiro , KAZIWARA, Takashi , FUTAMI, Satoshi , TAKEHIRA, Yuichi , ANDO, Masaki
IPC分类号： H01M8/02 , H01M8/04
CPC分类号： H01M8/04126 , H01M8/0206 , H01M8/0223 , H01M8/0228 , H01M8/0232 , H01M8/0241 , H01M8/0258 , H01M8/0267 , H01M8/04141 , H01M8/04156 , H01M8/04171 , H01M8/241 , H01M8/2457
摘要： A fuel cell is configured by sandwiching a membrane electrode assembly bonded respectively with an anode (411a) and a cathode (411c) on both sides of an electrolyte membrane (solid polymer membrane) between separators (42CA1, 42AN1). This fuel cell includes an anode side gas flow path (424d1, 424d2) for allowing the flow of a fuel gas in a first direction along the surface of the anode (411a), and a cathode side gas flow path (422d1, 422d2) for allowing the flow of oxidant gas along the surface of the cathode (411c) in a second direction opposite the first direction. A formed water capturing section (424d2, 422d2) for capturing at least one of formed water formed during generation of electricity contained in anode off gas and formed water contained in cathode off gas is provided in at least one of farthermost downstream in the direction of fuel gas flow in the anode side gas flow path (424d1, 424d2) and farthermost downstream in the direction of oxidant gas flow in the cathode side gas flow path (422d1, 422d2).
摘要翻译：燃料电池通过将分别与分离器（42CA1,42AN1）之间的电解质膜（固体聚合物膜）的两侧分别与阳极（411a）和阴极（411c））结合的膜电极组件夹持而构成。该燃料电池包括用于允许燃料气体沿阳极（411a）的表面沿第一方向流动的阳极侧气体流路（424d1,424d2）和阴极侧气体流路（422d1,422d2），用于允许在与第一方向相反的第二方向上沿着阴极（411c）的表面流动氧化剂气体。一种形成水捕获部分（424d2,422d2），用于捕获在阳极废气中包含的电产生期间形成的成形水中的至少一种以及阴极废气中所含的形成的水中的至少一个，在燃料方向的最下游的至少一个阴极侧气体流路（422d1,422d2）中的阳极侧气体流路（424d1,424d2）中的气体流动和氧化剂气体流动方向最下游的气体流动。

6. 发明公开

EP2882017A1 FUEL CELL ELECTRODE, AS WELL AS METHOD FOR MANUFACTURING FUEL CELL ELECTRODE, MEMBRANE ELECTRODE ASSEMBLY, AND FUEL CELL 有权
标题翻译：燃料电池电极及其制备方法的燃料电池电极，电极装置和燃料电池膜
公开(公告)号：EP2882017A1
公开(公告)日：2015-06-10
申请号：EP12882288.9
申请日：2012-08-02
申请人： Toyota Jidosha Kabushiki Kaisha
发明人： HASEGAWA, Shigeki , MURATA, Shigeaki , IMANISHI, Masahiro , NAMBA, Ryoichi
IPC分类号： H01M4/96 , H01M4/86 , H01M4/88 , H01M8/02 , H01M8/24 , H01M8/10
CPC分类号： H01M4/9083 , H01M4/8663 , H01M4/8828 , H01M4/8882 , H01M4/9041 , H01M8/1004 , H01M2008/1095 , H01M2300/0082
摘要： This electrode for fuel cell comprises: carbon nanotubes; a catalyst for fuel cell supported on the carbon nanotubes; and an ionomer provided to coat the carbon nanotubes and the catalyst for fuel cell, wherein when a length of the carbon nanotubes is represented by La [µm] and an inter-core pitch of the carbon nanotubes is represented by Pa [nm], the length La and the inter-core pitch Pa satisfy two expressions given below: 30 ≤ La ≤ 240; and 0.351×La+75 30 ≤ Pa 30 ≤ 250.
摘要翻译：此用于燃料电池的电极包括：碳纳米管; 对于支撑在碳纳米管燃料电池用催化剂; 并且在设置于外套离聚物碳纳米管和燃料电池，worin当碳纳米管的长度由拉[微米]，并在碳纳米管的核间的间距为代表的催化剂是通过帕代表[nm]的，所述长度La和纤芯间间距Pa满足以下给出两个表达式：30‰¤拉‰¤240; 和0351×的La + 75 30‰¤30帕‰¤第二百五

7. 发明授权

EP3089253B1 FUEL CELL SYSTEM 失效
公开(公告)号：EP3089253B1
公开(公告)日：2018-04-18
申请号：EP14875461.7
申请日：2014-11-04
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： KAWAHARA, Shuya , HASEGAWA, Shigeki , YAMAUE, Keita
IPC分类号： H01M8/04858 , H01M8/04746 , H01M8/1018 , H01M8/04537
CPC分类号： H01M8/04753 , H01M8/04544 , H01M8/04559 , H01M8/04634 , H01M8/04895 , H01M2008/1095
摘要： In order to make a power generation quantity of a cell for fuel cell increase in a short time when a drop in moistness of the cell causes the power generation quantity of the cell to decrease, a cathode of the cell includes a conductive material, catalyst, and ionomer which covers the conductive material and catalyst. If an output voltage value VFC of the cell is lower than a predetermined threshold voltage value VFCTH and an electrical resistance value RFC of the cell is higher than a predetermined threshold resistance value RFCTH, control for increasing an oxidizing gas amount which increases an amount QOFC of oxidizing gas sent to the cell is performed.

8. 发明授权

EP2667437B1 METHOD OF MANUFACTURING MEMBRANE ELECTRODE ASSEMBLY FOR SOLID POLYMER ELECTROLYTE FUEL CELL 有权
标题翻译：制造用于固体聚合物电解质燃料电池的膜电极组件的方法
公开(公告)号：EP2667437B1
公开(公告)日：2018-01-03
申请号：EP11822789.1
申请日：2011-01-18
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： HASEGAWA, Shigeki
IPC分类号： H01M4/88 , H01M8/1004 , H01M8/1018
CPC分类号： H01M8/10 , H01M4/8814 , H01M4/8892 , H01M4/8896 , H01M8/1004 , H01M2008/1095 , Y02E60/521 , Y02P70/56
摘要： The present invention relates a method for manufacturing a fuel cell. An object of the present invention is to provide a method for manufacturing a membrane electrode assembly capable of solving an electrical connection problem caused by uneven tube lengths and improving an output, and a solid polymer electrolyte fuel cell. The method for manufacturing the membrane electrode assembly of the present invention includes a seed catalyst layer forming process (1), a CNT growing process (2), a CNT entanglement promoting process (3), a catalyst carrying process (4), an ionomer arranging process (5), and a transferring (MEA conversion) process (6). According to the present invention, entanglement of adjacent CNTs can be promoted by the CNT entanglement promoting process (3) and therefore the electrical connection of the CNTs can be ensured. Thus, the output of the cell can be improved.

9. 发明授权

EP2269257B1 FUEL CELL SYSTEM AND OPERATING METHOD OF A FUEL CELL 失效转让
标题翻译：燃料电池系统及其操作方法的燃料电池
公开(公告)号：EP2269257B1
公开(公告)日：2014-02-26
申请号：EP09723982.6
申请日：2009-03-26
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： HASEGAWA, Shigeki , ANDO, Masaki , HAMADA, Kenichi
IPC分类号： H01M8/04
CPC分类号： H01M8/04104 , H01M8/04119 , H01M8/04149 , H01M8/04291 , H01M8/045 , H01M8/04507 , H01M8/04529 , H01M8/04753 , H01M8/04783 , H01M8/0485
摘要： A fuel cell system operates under at least one of the conditions of no humidity or high temperature, and an operating method thereof, are characterized in that a fuel cell has a fuel gas flow path and an oxidant gas flow path arranged such that fuel gas and oxidant gas flow in opposite directions, a determining apparatus that determines the amount of water near the oxidant gas flow path inlet, and a fuel gas control apparatus which increases the amount of water near the oxidant gas flow path inlet by increasing the fuel gas flowrate and/or reducing the fuel gas pressure if it is determined in the determining apparatus that the amount of water near the oxidant gas flow path inlet is insufficient.

10. 发明公开

EP2432059A1 FUEL CELL 有权转让
标题翻译：燃料电池
公开(公告)号：EP2432059A1
公开(公告)日：2012-03-21
申请号：EP10829645.0
申请日：2010-05-21
申请人： Toyota Jidosha Kabushiki Kaisha
发明人： TAKEUCHI, Hiroaki , OGAWA, Tomohiro , NANBA, Ryouichi , TANIGUCHI, Takumi , JOMORI, Shinji , IKEDA, Koichiro , HASEGAWA, Shigeki , ITO, Masayuki , HAMADA, Hitoshi , TAKESHITA, Naohiro
IPC分类号： H01M8/02 , H01M8/10
CPC分类号： H01M8/04089 , H01M4/8605 , H01M4/8668 , H01M8/0267 , H01M8/0273 , H01M8/04119 , H01M8/242 , H01M2008/1095 , Y02E60/50
摘要： A fuel cell is disclosed comprising: a power generation layer including an electrolyte membrane, and an anode and a cathode provided on respective surfaces of the electrolyte membrane; a fuel gas flow path layer located on a side of the anode of the power generation layer to supply a fuel gas to the anode while flowing the fuel gas along a flow direction of the fuel gas approximately orthogonal to a stacking direction in which respective layers of the fuel cell are stacked; and an oxidizing gas flow path layer located on a side of the cathode of the power generation layer to supply an oxidizing gas to the cathode while flowing the oxidizing gas along a flow direction of the oxidizing gas opposed to the flow direction of the fuel gas. A power generation area of the fuel cell, in which electric power is generated, has an upstream region including a most upstream position along the flow direction of the fuel gas and a downstream region including a most downstream position along the flow direction of the fuel gas. A midstream region, which is a remaining region of the power generation area other than the upstream region and the downstream region, has higher water vapor transfer resistance between the anode side and the cathode side than the upstream region and the downstream region.
摘要翻译：公开了一种燃料电池，其包括：发电层，其包括电解质膜，以及设置在所述电解质膜的各个表面上的阳极和阴极; 燃料气体流路层，其位于所述发电层的阳极侧，向所述阳极供给燃料气体，并使所述燃料气体沿着与所述燃料气体的流动方向大致正交的方向燃料电池堆叠; 以及位于发电层的阴极一侧的氧化气体流路层，以在使氧化气体沿着与燃料气体的流动方向相反的氧化气体的流动方向流动的同时向阴极供应氧化气体。其中产生电力的燃料电池的发电区域具有包括沿燃料气体的流动方向的最上游位置的上游区域和包括沿着燃料气体的流动方向的最下游位置的下游区域。作为上游区域和下游区域以外的发电区域的剩余区域的中游区域与上游区域和下游区域相比，阳极侧和阴极侧之间的水蒸气传递阻力较高。

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