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1. 发明申请

WO2009106743A2 DIFUNCTIONAL ADDITIVES FOR LIQUID HYDROCARBONS, OBTAINED BY GRAFTING FROM COPOLYMERS OF ETHYLENE AND/OR PROPYLENE AND VINYL ESTERS 审中-公开
标题翻译：通过从乙烯和/或丙烯和乙烯醇酯的共聚物中获得的液体碳氢化合物的二官能添加剂
公开(公告)号：WO2009106743A2
公开(公告)日：2009-09-03
申请号：PCT/FR2008001816
申请日：2008-12-23
申请人： TOTAL RAFFINAGE MARKETING , DOLMAZON NELLY , PAPIN GERALDINE , TORT FREDERIC , HENOGUEZ VALERIE
发明人： DOLMAZON NELLY , PAPIN GERALDINE , TORT FREDERIC , HENOGUEZ VALERIE
IPC分类号： C08F210/02 , C08F8/12 , C08F8/14 , C08F210/06 , C08F216/06 , C08F218/04 , C08F218/08 , C08F218/10 , C10L1/195 , C10L1/197 , C10L10/08 , C10L10/14 , C10M145/02 , C10N30/06 , C10N30/08
CPC分类号： C08F210/02 , C08F8/12 , C08F8/14 , C08F210/06 , C08F210/16 , C08F2800/20 , C08F2810/50 , C10L1/143 , C10L1/1641 , C10L1/1817 , C10L1/1973 , C10L10/08 , C10L10/14 , C10M145/12 , C10M2209/082 , C10N2230/02 , C10N2230/06 , C10N2230/08 , C10N2260/00 , C08F218/08 , C08F216/06 , C08F210/08 , C10M2209/062 , C10M2205/022
摘要： The invention pertains to the synthesis and use of copolymers based on ethylene and/or propylene and vinyl ester(s) which are modified by grafting and are effective for enhancing both the low-temperature resistance and the lubricity of liquid hydrocarbons, more particularly the middle distillates obtained from the distillation of petroleum and crude oils, especially those with a low sulfur content, and relates to a copolymer comprising: a) units derived from ethylene, of formula A -(CH2-CH2)nl- and/or from propylene, of formula A' -((CH3)CH2-CH2)n2-, with n1 + n2 = n ranging from 98 to 643, preferably ranging from 124 to 515; n1 being advantageously equal to n; b) units of formula B: -(CH2-CHOOCR1)m-x- in which R1 represents a linear or branched C1-C15 alkyl group, preferably methyl or propyl, or a C5 to Cl5 branched alkyl group in which the branching is located at any point of the alkyl radical, preferably in position 2 or 3 of the alkyl chain; and preferably selected from the preferred C5-C15 vinyl comonomers, preferably selected from pivalate, isopentanoate, isohexanoate, isononanoate, isodecanoate and/or isotridecanoate, and advantageously 2-ethylhexanoate, neoalkanoates, especially neononanoate, neodecanoate and/or neoundecanoate; with m being from 2 to 105, preferably from 16 to 71, and x being from 0.2 to 105, preferably from 1.6 to 71; c) units of formula C: -(CH2-CHOH)x1- in which x1 is from 0 to 0.30x, preferably xl = 0; d) units of formula D: -(CH2-CHOOCR2)x2- in which x2 is from 0.70x to x, preferably x2 = x, and R2 represents a saturated or unsaturated C8-C24, preferably C14-C20 or else C14 to C18 linear or branched alkyl group, with x = x1 + x2.
摘要翻译：本发明涉及通过接枝改性的基于乙烯和/或丙烯和乙烯基酯的共聚物的合成和使用，并且对于提高液态烃的耐低温性和润滑性是有效的，特别是中间从蒸馏石油和原油，特别是具有低硫含量的馏分获得的馏出物，涉及一种共聚物，其包含：a）衍生自乙烯，式A-（CH 2 -CH 2）nl-和/或来自丙烯的单元，的式A' - （（CH 3）CH 2 -CH 2）n - ，n1 + n2 = n为98至643，优选为124至515; n1有利地等于n; b）式B单元： - （CH 2 -CHOCR1）mx-，其中R 1表示直链或支链C 1 -C 15烷基，优选甲基或丙基，或其中支化位于任何烷基的位置，优选位于烷基链的2或3位; 优选选自优选的C 5 -C 15乙烯基共聚单体，优选选自新戊酸盐，异戊酸盐，异己酸盐，异壬酸盐，异癸酸盐和/或异十三烷酸盐，有利地是2-乙基己酸盐，新烷酸盐，特别是新戊酸盐，新癸酸盐和/或新戊酸盐; m为2至105，优选为16至71，x为0.2至105，优选为1.6至71; c）式C的单元： - （CH 2 -CHOH）x1，其中x1为0至0.30x，优选x1 = 0; d）式D的单元： - （CH2-CHOOCR2）x2-，其中x2为0.70x至x，优选x2 = x，R2表示饱和或不饱和C8-C24，优选C14-C20或C14至C18 直链或支链烷基，x = x1 + x2。

2. 发明申请

WO2009044021A9 GRAFT-MODIFIED VINYL ESTER AND ETHYLENE POLYMERS, PREPARATION METHOD THEREOF AND USE OF SAME AS ADDITIVES THAT IMPROVE THE COLD PROPERTIES OF LIQUID HYDROCARBONS 审中-公开
标题翻译：改性乙烯酯和乙烯聚合物，其制备方法和作为添加剂的添加剂的使用，其提高液体烃的冷特性
公开(公告)号：WO2009044021A9
公开(公告)日：2009-07-09
申请号：PCT/FR2008001119
申请日：2008-07-25
申请人： TOTAL RAFFINAGE MARKETING , TORT FREDERIC , PAPIN GERALDINE
发明人： TORT FREDERIC , PAPIN GERALDINE
IPC分类号： C08F255/02 , C08L51/06
CPC分类号： C08F255/026 , C08F293/005 , C08L51/06 , C08L2666/02 , C08L2666/04
摘要： The invention relates to the synthesis and use of novel graft-modified vinyl ester and ethylene polymers in order to improve the solubility thereof in liquid hydrocarbons, as effective bifunctional additives for reducing the low-temperature flowability and filterability of liquid hydrocarbons, particularly middle distillates originating from oil and crude oil distillation.
摘要翻译：本发明涉及新型接枝改性乙烯基酯和乙烯聚合物的合成和用途，以提高其在液态烃中的溶解度，作为有效的双官能添加剂，用于降低液态烃，特别是中间馏分的低温流动性和过滤性从油和原油蒸馏。

3. 发明申请

WO2009106744A3 ETHYLENE/VINYL ACETATE/UNSATURATED ESTERS TERPOLYMER AS ADDITIVE ENCHANCING THE LOW-TEMPERATURE RESISTANCE OF LIQUID HYDROCARBONS 审中-公开
标题翻译：乙烯/醋酸乙烯酯/不饱和酯类三聚物作为添加剂来提高液体碳氢化合物的低温电阻
公开(公告)号：WO2009106744A3
公开(公告)日：2009-10-22
申请号：PCT/FR2008001817
申请日：2008-12-23
申请人： TOTAL RAFFINAGE MARKETING , CHEVROT ERWAN , DALIX LAURENT , TORT FREDERIC
发明人： CHEVROT ERWAN , DALIX LAURENT , TORT FREDERIC
IPC分类号： C10L1/197 , C10L1/14 , C10L10/14
CPC分类号： C10L1/1973 , C10L1/143 , C10L10/14
摘要： The invention pertains to the use, as an additive enhancing the low-temperature resistance and filterability of fuels, of at least one copolymer comprising from 78 to 87 mol% of at least one alpha-olefin, preferably at least ethylene, from 12 to 18 mol% of at least one vinyl ester, preferably at least vinyl acetate, from 1 to 4 mol% of at least one ester of alpha,beta unsaturated monocarboxylic acid, preferably at least 2-ethylhexyl acrylate.
摘要翻译：本发明涉及至少一种包含78至87摩尔％的至少一种α-烯烃，优选至少乙烯，12至18的共聚物作为增强燃料耐低温性和过滤性的添加剂的用途至少一种乙烯基酯，优选至少乙酸乙烯酯，1至4摩尔％的至少一种α，β-不饱和一元羧酸酯，优选至少2-乙基己基丙烯酸酯的摩尔％。

4. 发明申请

WO2008006965A3 USE OF EFFICIENCY REVEAL COMPOUNDS OF FILTERABILITY ADDITIVES IN HYDROCARBON DISTILLATES, AND SYNERGIC COMPOSITION COMPRISING THEM 审中-公开
标题翻译：碳氢馏份中过滤性添加剂的效率报告化合物的用途以及包含它们的协同组合物
公开(公告)号：WO2008006965A3
公开(公告)日：2008-02-28
申请号：PCT/FR2007001153
申请日：2007-07-06
申请人： TOTAL FRANCE , DOLMAZON NELLY , DALIX LAURENT , CHEVROT ERWAN , TORT FREDERIC
发明人： DOLMAZON NELLY , DALIX LAURENT , CHEVROT ERWAN , TORT FREDERIC
IPC分类号： C10L1/195 , C10L1/196 , C10L1/197 , C10L10/14 , C10L10/16
CPC分类号： C10L1/146 , C10L1/18 , C10L1/195 , C10L1/1963 , C10L1/1973 , C10L10/14 , C10L10/16 , C10L2200/0438 , C10L2200/0446 , C10L2230/14 , C10L2250/04 , C10L2270/026
摘要： The invention relates to the use, in a hydrocarbon distillate with a boiling temperature of between 150 and 450°C and a crystallization onset temperature as measured by Differential Calorimetric Analysis of greater than or equal to -50°C, preferably of -5°C to +10°C, of a homopolymer obtained from an olefinic ester of carboxylic acid of 3 to 12 carbon atoms and from a fatty alcohol containing a chain of more than 16 carbon atoms and optionally an olefinic double bond, as a compound for revealing the efficiency of filterability additives based on copolymer and/or terpolymers of ethylene and of vinyl ester of a carboxylic acid of 3 to 12 carbon atoms, and of a monoalcohol containing 1 to 10 carbon atoms. The invention is also directed to an additive composition comprising a conventional hydrocarbon filterability additive in combination with an efficiency reveal additive, and also to the combustion fuels, motor fuel and oil fuel that comprise these additive combinations.
摘要翻译：本发明涉及在沸点温度为150-450℃且通过差示量热分析测量的结晶起始温度大于或等于-50℃，优选-5℃的烃馏分中的用途从含有3至12个碳原子的羧酸的烯烃酯和含有超过16个碳原子的链的脂肪醇和任选的烯属双键获得的均聚物作为用于显示基于乙烯和3至12个碳原子的羧酸的乙烯基酯和含有1至10个碳原子的一元醇的共聚物和/或三元共聚物的可过滤添加剂的效率。本发明还涉及添加剂组合物，其包含常规碳氢化合物可滤性添加剂与效率揭示添加剂以及包含这些添加剂组合的燃烧燃料，发动机燃料和油燃料。

5. 发明专利

JP2013076093A Use of compound improving efficiency of filter-passing additive in hydrocarbon fraction, and composition containing the compound and having synergy 有权
$Use of compound improving efficiency of filter-passing additive in hydrocarbon fraction, and composition containing the compound and having synergy$
标题翻译：化合物的使用提高了滤油添加剂在油气分离中的效率，以及含有该化合物并具有合成性的组合物
公开(公告)号：JP2013076093A
公开(公告)日：2013-04-25
申请号：JP2013012919
申请日：2013-01-28
申请人： Total Raffinage Marketing , トータル・ラフィナージュ・マーケティング
发明人： DOLMAZON NELLY , DALIX LAURENT , CHEVROT ERWAN , TORT FREDERIC
IPC分类号： C10L1/196 , C10L1/00 , C10L1/04 , C10L1/08
CPC分类号： C10L1/146 , C10L1/18 , C10L1/195 , C10L1/1963 , C10L1/1973 , C10L10/14 , C10L10/16 , C10L2200/0438 , C10L2200/0446 , C10L2230/14 , C10L2250/04 , C10L2270/026
摘要： PROBLEM TO BE SOLVED: To provide use of a compound enabling a conventional filter-passing additive to be applied to a new kind of a hydrocarbon fraction showing a crystallization initiation temperature of n-paraffin of nearly zero and/or containing not less than 4 wt.% of 18 or more C n-paraffins.SOLUTION: There is provided the use of a homopolymer as a compound improving the efficiency of the filter-passing additive in the hydrocarbon fraction. The hydrocarbon fraction has a boiling point of 150 to 450°C and a crystallization initiation temperature of not less than -5°C. The homopolymer is an olefinic ester of 3 to 12C carboxylic acid and an aliphatic alcohol having a 16 or more C chain. The filter-passing additive is based on a copolymer and/or terpolymer of ethylene and a vinyl ester of a 3 to 5C carboxylic acid and a 1 to 10C monoalcohol.
摘要翻译：要解决的问题：为了提供使常规过滤器添加剂能够应用于新型烃馏分的化合物的使用，其显示出正链烷烃的结晶起始温度几乎为零和/或不少于超过4重量％的18个或更多的C正链烷烃。解决方案：提供均聚物作为化合物的用途，其提高了烃馏分中过滤剂过滤添加剂的效率。烃馏分的沸点为150-450℃，结晶起始温度不低于-5℃。均聚物是3-12C羧酸的烯属酯和具有16个或更多个C链的脂族醇。过滤添加剂基于乙烯和3至5℃羧酸的乙烯基酯和1至10元一元醇的共聚物和/或三元共聚物。版权所有（C）2013，JPO＆INPIT

6. 发明专利

TWI439541B 包含乙烯及／或丙烯及乙烯酯共聚物之雙效型液態碳氫化合物添加劑失效
简体标题：包含乙烯及／或丙烯及乙烯酯共聚物之双效型液态碳氢化合物添加剂
公开(公告)号：TWI439541B
公开(公告)日：2014-06-01
申请号：TW097150592
申请日：2008-12-25
申请人：道達爾勞夫奈吉行銷股份有限公司 , TOTAL RAFFINAGE MARKETING
发明人：尼莉多瑪桑 , DOLMAZON NELLY , 吉瑞丁帕賓 , PAPIN GERALDINE , 佛德瑞克托特 , TORT FREDERIC
IPC分类号： C10L1/192 , C10L1/197 , C08F210/02 , C08F218/04 , C10L10/08 , C10L10/16
CPC分类号： C08F210/02 , C08F8/12 , C08F8/14 , C08F210/06 , C08F210/16 , C08F2800/20 , C08F2810/50 , C10L1/143 , C10L1/1641 , C10L1/1817 , C10L1/1973 , C10L10/08 , C10L10/14 , C10M145/12 , C10M2209/082 , C10N2230/02 , C10N2230/06 , C10N2230/08 , C10N2260/00 , C08F218/08 , C08F216/06 , C08F210/08 , C10M2209/062 , C10M2205/022

7. 发明专利

CA2709009C BIFUNCTIONAL ADDITIVES FOR LIQUID HYDROCARBONS OBTAINED BY GRAFTING STARTING WITH COPOLYMERS OF ETHYLENE AND/OR PROPYLENE AND VINYL ESTER 未知
公开(公告)号：CA2709009C
公开(公告)日：2016-05-03
申请号：CA2709009
申请日：2008-12-23
申请人： TOTAL RAFFINAGE MARKETING
发明人： DOLMAZON NELLY , PAPIN GERALDINE , TORT FREDERIC , HEROGUEZ VALERIE
IPC分类号： C10L10/14 , C10L1/195 , C10L1/197 , C10L10/08 , C10M145/08
摘要： The present invention relates to the synthesis and the use of novel copolymers based on ethylene and/or propylene and vinyl ester(s) modified by grafting, effective for improving both the resistance to cold and the lubricity of liquid hydrocarbons, in particular middle distillates originating from the distillation of petroleum and crude oils, in particular those with a low sulphur content.

8. 发明专利

FR2977895B1 COMPOSITIONS D'ADDITIFS AMELIORANT LA STABILITE ET LES PERFORMANCES MOTEUR DES GAZOLES NON ROUTIERS 未知
公开(公告)号：FR2977895B1
公开(公告)日：2015-04-10
申请号：FR1156363
申请日：2011-07-12
申请人： TOTAL RAFFINAGE MARKETING
发明人： TORT FREDERIC , VERMOREL CHRISTIAN
IPC分类号： C10L1/183 , C10L1/08 , C10L1/192 , C10L1/222 , C10L1/228 , C10L1/232 , C10L10/00 , C10L10/04

9. 发明专利

AU2008351922B2 Ethylene/vinyl acetate/unsaturated esters terpolymer as additive enchancing the low-temperature resistance of liquid hydrocarbons 未知
公开(公告)号：AU2008351922B2
公开(公告)日：2012-12-13
申请号：AU2008351922
申请日：2008-12-23
申请人： TOTAL RAFFINAGE MARKETING
发明人： DALIX LAURENT , TORT FREDERIC , CHEVROT ERWAN
IPC分类号： C10L1/197 , C10L1/14 , C10L10/14
摘要： The invention pertains to the use, as an additive enhancing the low-temperature resistance and filterability of fuels, of at least one copolymer comprising • from 78 to 87 mol% of at least one alpha-olefin, preferably at least ethylene, • from 12 to 18 mol% of at least one vinyl ester, preferably at least vinyl acetate, • from 1 to 4 mol% of at least one ester of alpha,beta unsaturated monocarboxylic acid, preferably at least 2-ethylhexyl acrylate.

10. 发明专利

SG174911A1 LOW MOLECULAR WEIGHT (METH) ACRYLIC POLYMERS FREE OF SULPHUR-CONTAINING, METALLIC AND HALOGENATED COMPOUNDS AND WITH A LOW DEGREE OF RESIDUAL MONOMERS, PROCESS FOR THE PREPARATION THEREOF AND USES THEREOF 未知
公开(公告)号：SG174911A1
公开(公告)日：2011-11-28
申请号：SG2011069291
申请日：2010-03-25
申请人： TOTAL RAFFINAGE MARKETING
发明人： DOLMAZON NELLY , SANTIAGO JOSE , STORET YVAN , TORT FREDERIC
摘要： LOW MOLECULAR WEIGHT (METH)ACRYLIC POLYMERS. FREEOF SULPHUR-CONTAINING, METALLIC AND HALOGENATED5 COMPOUNDS AND WITH LOW RESIDUAL MONOMER CONTENT,METHOD FOR PREPARING THE SAME AND USES THEREOF The subject of the invention concerns C8 or higher, linear or branched fatty chain (meth)acrylic polymers possibly containing at least one ethylene unsaturation,10 having a weight average molecular weight Mw of less than 20,000 g/mole, free of sulphur-containing, metallic and halogenated compounds and with a residual monomer content measured by GPC of no more than 10 % by weight, preferably no more than 7 % by weight.A further subject of the invention is the synthesis method and the uses of these 15 polymers.

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