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1. 发明专利

DE3677201D1 未知
公开(公告)号：DE3677201D1
公开(公告)日：1991-02-28
申请号：DE3677201
申请日：1986-03-27
申请人： TOPY IND , JAPAN TOBACCO INC
发明人： SUGIMORI KENICHIRO , YAMAMOTO MASARU , HORII IKUO , ISHIGURO SHIGEO , MATSUSHITA HAJIME NIHON TABAKO , ICHINOSE HIROSHI NIHON TABAKO , MIZUSAKI SHIGENOBU NIHON TABAK
IPC分类号： B01D53/86 , B01J23/22 , B01J23/89 , B01J27/198 , B01D53/36
摘要： A carbon monoxide oxidizing catalyst for removing carbon monoxide from an air comprising a porous carrier, on said carrier, a palladium salt and a copper salt as main active components and a vanadium compound or of a vanadium compound and a said main active components and said promotor.

2. 发明专利

JPS6168139A Carbon monoxide oxidation catalyst 失效
标题翻译：碳氧化物氧化催化剂
公开(公告)号：JPS6168139A
公开(公告)日：1986-04-08
申请号：JP18877784
申请日：1984-09-11
申请人： Japan Tobacco Inc , Topy Ind Ltd
发明人： SUGIMORI KENICHIRO , YAMAMOTO MASARU , HORII IKUO , MATSUSHITA HAJIME , ISHIGURO SHIGEO , ICHISE HIROSHI , MIZUSAKI SHIGENOBU
IPC分类号： B01D53/94 , B01J27/13 , B01J27/198 , B01J27/24
摘要： PURPOSE: To obtain the titled CO oxidation catalyst exhibiting high oxidation activity to CO and having excellent durability of the activity by depositing a promotor component consisting of a V compd. or both V compd. and P compd. on a redox catalyst consisting of a Pd salt and a copper salt.
CONSTITUTION: An essential catalyst component consisting of a Pd salt (e.g., PdCl
2 ) and a copper salt (e.g., CuCl
2 ) and a promotor component consisting of a V compd. (e.g., NH
4 VO
3 ) or both V compd. and phosphorus compd. (e.g., H
3 PO
4 ) are deposited on a porous carrier of zeolite, etc. The amt. of said catalyst components to be deposited on the carrier is regulated to 0.01W0.2mol/g Pd salt, 0.1W2.0mol/g Cu salt, 0.1W3.0wt% V compd. expressed in terms of V, and 0.1W1.0wt% P compd. expressed in terms of P. The CO oxidation catalyst exhibits high oxidation activity to CO, and also has extremely excellent durability of the CO oxidation activity.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过沉积由V化合物组成的促进剂组分，获得对CO具有高氧化活性的标题CO氧化催化剂并具有优异的活性耐久性。或两个V compd。和P compd。在由Pd盐和铜盐组成的氧化还原催化剂上。构成：由Pd盐（例如PdCl 2）和铜盐（例如CuCl 2）组成的必需催化剂组分和由V化合物组成的促进剂组分。（例如NH4VO3）或两种V化合物。和磷肥（例如，H 3 PO 4）沉积在沸石等的多孔载体上。将沉积在载体上的所述催化剂组分调节为0.01-0.2mol / g Pd盐，0.1-2.0mol / g Cu盐，0.1-3.0wt％V化合物。表示为V，和0.1-1.0wt％P compd。以CO表示.CO氧化催化剂对CO具有高的氧化活性，并且还具有非常优异的CO氧化活性的耐久性。

3. 发明专利

JPS6168135A Agent for removing carbon monoxide in tobacco smoke 失效
标题翻译：在烟草烟雾中去除一氧化碳的代理
公开(公告)号：JPS6168135A
公开(公告)日：1986-04-08
申请号：JP18877684
申请日：1984-09-11
申请人： Japan Tobacco Inc , Topy Ind Ltd
发明人： SUGIMORI KENICHIRO , YAMAMOTO MASARU , HORII IKUO , MATSUSHITA HAJIME , ISHIGURO SHIGEO , ICHISE HIROSHI , MIZUSAKI SHIGENOBU
IPC分类号： B01D53/62 , A24D3/16 , B01D53/34 , B01J20/02 , B01J20/20 , B01J27/055 , B01J27/13 , B01J27/25
CPC分类号： Y02A50/2341
摘要： PURPOSE: To obtain a CO-removing agent capable of reducing remarkably CO in smoke without deteriorating the flavor of tobacco smoke by using a mixed composition of metallic oxides and activated carbon as a carrier, and depositing a Pd salt and a copper salt on the carrier.
CONSTITUTION: A mixture of a Pd salt and a copper salt is deposited on a carrier consisting of a mixed composition of metallic oxides and activated carbon. A material contg. ≥1 kind selected from a group consisting of MgO, Al
2 O
3 , SiO
2 , P
2 O
5 , or transition metal oxides (e.g., CuO) is used as said metallic oxides. Besides, said metallic oxide is a silicate ore contg. ≥1 kind between MgO or Al
2 O
3 in the composition, and kaolinite and zeolite can be exemplified. In this case, the amt. of the metallic oxide to be contained in the mixed composition of activated carbon and metallic oxides is preferably regulated to 10W90wt%. By this CO-removing agent thus obtained, CO in smoke can be remarkably reduced without deteriorating the flavor of the tobacco smoke.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了获得能够通过使用金属氧化物和活性炭作为载体的混合组合物而使烟雾中的烟味恶化而能够显着降低烟气中的CO的CO除去剂，并将Pd盐和铜盐沉积在载体上。构成：将Pd盐和铜盐的混合物沉积在由金属氧化物和活性炭的混合组合物组成的载体上。材料限制使用从MgO，Al 2 O 3，SiO 2，P 2 O 5或过渡金属氧化物（例如CuO）组成的组中选择的1种作为所述金属氧化物。此外，所述金属氧化物是硅酸盐矿石。 > = 1种组合物中的MgO或Al2O3，可以列举高岭石和沸石。在这种情况下，的活性炭和金属氧化物的混合组合物中所含的金属氧化物的含量优选为10〜90重量％。通过这样获得的这种除氧剂，可以显着降低烟气中的CO，而不会降低烟草烟雾的味道。

4. 发明专利

JPS5929036A Preparation of catalyst for removing carbon monooxide 失效
标题翻译：催化剂的制备用于去除一氧化碳
公开(公告)号：JPS5929036A
公开(公告)日：1984-02-16
申请号：JP13681982
申请日：1982-08-07
申请人： Japan Tobacco Inc
发明人： MATSUSHITA HAJIME , ISHIGURO SHIGEO , NITORI YASUHEI , ICHISE HIROSHI , IWASHITA AYUMI
IPC分类号： B01D53/94 , A24D3/16 , B01J23/64 , B01J23/656
摘要： PURPOSE:To reduce a content of Pd greatly and to obtain a catalyst remarkably distinguished in CO oxidation activity, by producing activated MnO2 from Mn salt in the presence of Pd or Pd compd. in the method of preparing the catalyst consisting of a mixture of Pd or Pd compd. and activated MnO2. CONSTITUTION:For example, 10g manganese nitrate is dissolved in 100ml water, 2ml water dissolving 40mg palladium chloride is added to said soln., and further, 5ml concd. nitric acid is added. A 100ml 5% aq. soln. of KMnO4 is gradually dropped while said soln. is being well stirred, and stirring is continued after the end of dropping. The produced ppt. is sufficiently washed with distilled water, and when the purple color of MnO 4 ions almost disappears, the ppt. is filtered by suction, the obtd. solid matter is air dried, and further dried at 100 deg.C for 24hr, resulting in obtaining about 0.6g blackish brown powder catalyst.
摘要翻译：目的：通过在Pd或Pd化合物的存在下，通过在Mn盐中生成活性MnO 2，大大降低Pd的含量并获得显着区别于CO氧化活性的催化剂。在制备由Pd或Pd混合物组成的催化剂的方法中。并激活MnO2。构成：将10g硝酸锰溶解于100ml水中，向该溶液中加入溶解有40mg氯化钯的2ml水，加入硝酸。 100ml 5％水溶液 SOLN。的KMnO4逐渐下降，而soln。搅拌均匀，滴加结束后继续搅拌。生产的ppt。用蒸馏水充分洗涤，当MnO - 4离子的紫色几乎消失时，ppt。通过抽吸过滤。将固体物质风干，并在100℃下进一步干燥24小时，得到约0.6g黑褐色粉末催化剂。

5. 发明专利

JPS6363654A FLUORANTHENE-3-ISOTHIOCYANATE AND FLUORESCENT LABELING REAGENT COMPOSED OF SAID COMPOUND 失效
公开(公告)号：JPS6363654A
公开(公告)日：1988-03-22
申请号：JP20603186
申请日：1986-09-03
申请人： JAPAN TOBACCO INC
发明人： WATABE YOSHIHIRO , ISHIGURO SHIGEO , KANEKO HAJIME
IPC分类号： G01N33/52 , C07C67/00 , C07C325/00 , C07C331/16 , C07C331/28 , C09K11/06 , G01N21/76 , G01N21/78 , G01N31/00 , G01N31/22 , G01N33/58
摘要： NEW MATERIAL:Fluoranthene-3-isothiocyanate of formula. USE:A fluorescent labeling reagent for a compound having amino group. PREPARATION:3-Nitrofluoranthene is dissolved in a benzene-methanol solution and added with a methanol solution containing copper chloride. Sodium borohydride is added to the mixture and excess sodium borohydride is decomposed by the addition of 1N hydrochloric acid. The solvent is distilled out under reduced pressure to dryness and the residue is added with 1N aqueous solution of sodium hydroxide. The solution is extracted with benzene, the extract is dried with potassium carbonate anhydride and benzene is removed under reduced pressure to obtain a crude oily substance. The substance is crystallized in ethanol to obtain 3-aminofluoranthene. The product is made to react with an anhydrous benzene solution of thiophosgene, half of the benzene is distilled out and the residue is subjected e.g. to filtration, etc., to obtain the objective compound of formula.

6. 发明专利

JPS61227842A REMOVING AGENT FOR CARBON MONOXIDE 失效
公开(公告)号：JPS61227842A
公开(公告)日：1986-10-09
申请号：JP6505385
申请日：1985-03-30
申请人： JAPAN TOBACCO INC
发明人： MATSUSHITA HAJIME , ISHIGURO SHIGEO , ICHISE HIROSHI , IZUMI AKIRA , MIZUSAKI SHIGENOBU
IPC分类号： B01D53/94 , B01J23/68 , B01J23/89
摘要： PURPOSE:To decrease the amount to be used of Pd and to obtain a high-activity removing agent of CO by adding one or more kinds selected from among the oxides of Cu, Co, Ag and Ni to the removing agent of CO consisting of MnO2 and a palladium compd. CONSTITUTION:After MnO2 is immersed into a mixed soln. of both an aqueous palladium salt such as palladium nitrate and an aqueous salt of one or more kinds of metals selected from among Cu, Co, Ag and Ni, the salt is stuck on the surface of MnO2 by distilling the solvent. Then a removing agent of CO consisting of MnO2, a palladium compd. and metallic oxide is obtained by oxidizing the salt with ozone. Since the metallic oxide is present, the removing agent of CO has the high activity even when the palladium compd. contains a small amount of 0.0001-0.01 Pd for 1 MnO2 and the activity is maintained at the room temp. and it has the excellent characteristics so that the deactivation is hardly caused with water content.

7. 发明专利

JPS61204143A METHOD OF REDUCING ALDEHYDE AND KETONE 失效
公开(公告)号：JPS61204143A
公开(公告)日：1986-09-10
申请号：JP4193085
申请日：1985-03-05
申请人： JAPAN TOBACCO INC
发明人： MIZUSAKI SHIGENOBU , MATSUSHITA HAJIME , ISHIGURO SHIGEO , ICHISE HIROSHI , IZUMI AKIRA
IPC分类号： C07C29/136 , B01J21/00 , C07B31/00 , C07B41/02 , C07B61/00 , C07C27/00 , C07C29/14 , C07C29/143 , C07C29/145 , C07C31/02 , C07C33/20 , C07C33/22 , C07C35/08 , C07C37/07 , C07C39/08 , C07C67/00
摘要： PURPOSE:To obtain a corresponding alcohol in high yield with easy isolation of reaction product, by reacting an aldehyde or a ketone with an alcohol by the use of hydrous zirconium hydroxide as a catalyst. CONSTITUTION:An alkali aqueous solution is added to an aqueous solution of zirconium oxychloride, the system is adjusted to 6-7pH, very small gel is filtered off, excess aqueous solution of salt is removed, formed bulky gel is washed with deionized water, dried, to give hydrous zirconium hydroxide stable in water, an alchol, and other solvents. It is heated to about 80 deg.C, dried, classified, to prepare a reaction catalyst. 1-3g of the catalyst is added to 1 millimol aldehyde or ketone and 1-3ml isopropyl alcohol, which are heated, or a reaction tank filled with the catalyst is heated to 75-110 deg.C, and gasified isopropyl alcohol, the aldehyde or ketone together with a carrier gas are passed through it, to give a corresponding alcohol.

8. 发明专利

JPS5765331A Removing agent of carbon monoxide 失效
标题翻译：二氧化碳去除剂
公开(公告)号：JPS5765331A
公开(公告)日：1982-04-20
申请号：JP13942280
申请日：1980-10-07
申请人： Japan Tobacco Inc
发明人： OONISHI AKIO , ISHIGURO SHIGEO , ITORI YASUHEI , IWASHITA AYUMI
IPC分类号： B01D53/94 , A24D3/16 , A24F13/06 , B01J23/64 , B01J23/656 , B01J27/02 , B01J27/055 , B01J27/10 , B01J27/13 , B01J27/24 , B01J27/25 , C01B32/40
摘要： PURPOSE:To provide a new removing agent with high activity selectively removing CO from a CO containing gas at a room temp. which comprises Pd or a Pd compound and active MnO2. CONSTITUTION:The titled CO removing agent is obtained by combining Pd or a Pd compound (e.g.; PdCl2) against active manganese dioxide (MnOx, 1
摘要翻译：目的：提供一种具有高活性的新型去除剂，在室温下选择性地从含CO的气体中除去CO。其包括Pd或Pd化合物和活性MnO 2。构成：通过将Pd或Pd化合物（例如PdCl 2）与重量组成比为0.06-0.3的活性二氧化锰（MnO x，1

9. 发明专利

JPS60224483A AGENT FOR REMOVING CARBON MONOOXIDE IN TOBACCO SMOKE 失效
公开(公告)号：JPS60224483A
公开(公告)日：1985-11-08
申请号：JP8020084
申请日：1984-04-23
申请人： TOPY IND , JAPAN TOBACCO & SALT PUBLIC
发明人： ICHISE SHIGEO , SUGIMORI KENICHIROU , MATSUSHITA HAJIME , ICHISE HIROSHI , IZUMI AKIRA , ISHIGURO SHIGEO , NAKANISHI AYUMI
IPC分类号： A24D3/16

10. 发明专利

JPS6120566A Self-lifesaving device for carbon monoxide 失效
标题翻译：一氧化碳自激活装置
公开(公告)号：JPS6120566A
公开(公告)日：1986-01-29
申请号：JP14140684
申请日：1984-07-10
申请人： Japan Tobacco & Salt Public , Topy Ind
发明人： MATSUSHITA HAJIME , ISHIGURO SHIGEO , ICHISE HIROSHI , MIZUSAKI SHIGENOBU , ICHISE SHIGEO , SUGIMORI KENICHIROU , YAMAMOTO MASARU , HORII IKUO
IPC分类号： A62B19/00 , A62B23/04 , B01D53/94

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