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1. 发明专利

JPH10182114A CONCENTRATION OF SULFURIC ACID 失效
公开(公告)号：JPH10182114A
公开(公告)日：1998-07-07
申请号：JP32317097
申请日：1997-11-25
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： C01B17/88
摘要： PROBLEM TO BE SOLVED: To provide a method for concentrating sulfuric acid, by which a corrosion problem, an energy consumption and a cost are reduced by regulating a temperature of the charging flow of the sulfuric acid and a temperature of a hot air so as to be each a specific temperature and condensing the off-gas from a concentrating tower in vertical glass tubes of a condenser when bringing a charging flow of the sulfuric acid into countercurrent contact with the hot air to concentrate the sulfuric acid into the one having a prescribed concentration in the packed concentrating tower. SOLUTION: This method for concentrating a sulfuric acid 22 by introducing the sulfuric acid 22 condensed in an air-cooling and flowing down film-type condenser 15 and having 90-98% H2 SO4 concentration to a packed concentrating tower 20, and bringing the introduced sulfuric acid 22 into countercurrent contact with a hot air 23 having a regulated temperature by flowing through a heat-exchanger 4, or a thermal process gas from a sulfuric acid plant to provide the sulfuric acid having 95-98.8% H2 GO4 concentration, is performed by regulating both the temperature of the charging liquid of the sulfuric acid 22, and the temperature of the hot air 23 or the thermal process gas so as to be 150-270 deg.C and 350-600 deg.C respectively when introducing the sulfuric acid 22, and the hot air or the thermal process gas into the packed condensation tower 20. Further, the H2 SO4 in a off gas 24 from the tower 20 is condensed in a vertical glass tube of a condenser 15, or in a packed concentration tower in which a circulating sulfonic acid having 160-260 deg.C when removing the tower is brought into countercurrent contact with the gas.

2. 发明专利

JPH05139708A METHOD FOR REGENERATING USED SULFURIC ACID 失效
公开(公告)号：JPH05139708A
公开(公告)日：1993-06-08
申请号：JP13110492
申请日：1992-05-22
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： B01J23/40 , B01J23/22 , B01J27/055 , B01J27/30 , C01B17/50 , C01B17/58 , C01B17/69 , C01B17/76 , C01B17/79 , C01B17/80 , C01B17/90 , C01B17/92
摘要： Process for the regeneration of spent sulphuric acid from chemical processes, which process comprises the steps of evaporating and decomposing the spent sulphuric acid at a temperature of 400-800 DEG C with excess of air, to a gas mainly consisting of carbon dioxide, steam, nitrogen, oxygen, sulphur dioxide and sulphur trioxide together with minor amounts of ammonia, carbon monoxide, residual organic compounds and dust from solids in the spent acid; cooling the gas to 360-450 DEG C and oxidizing oxidizable components in the cooled gas by contact with an oxidation catalyst; cooling the oxidized gas to a temperature of 10-50 DEG C above the sulphuric acid dew point in the gas and condensing sulphuric acid formed in the cooled and oxidized gas.

3. 发明专利

JPH03504714A 失效
公开(公告)号：JPH03504714A
公开(公告)日：1991-10-17
申请号：JP50665389
申请日：1989-05-18
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： C01B17/74 , B01D53/86 , C01B17/76 , C01B17/80 , C01B17/90

4. 发明专利

JPH10314549A METHOD FOR SELECTIVELY REDUCING NOX CONTAINED IN EXHAUST GAS 失效
公开(公告)号：JPH10314549A
公开(公告)日：1998-12-02
申请号：JP6155098
申请日：1998-03-12
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： B01D53/94 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/10 , B01J23/06 , B01J23/745 , B01J35/02 , F01N3/20 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide a method for selectively reducing NOx contained in an exhaust gas catalytically at temperatures of 200-600 deg.C. SOLUTION: A spray of liquid droplets containing a reducing agent which can reduce NOx and/or its precursor is injected into a duct through a spraying nozzle, and an exhaust gas loaded with the liquid droplets is run through a space formed between the plates of stacks of parallel plates in a gas duct. In this case, the plates of the first stack are arranged at an angle of about 45 deg.C with the wall face of the gas duct and the plates of the second stack are arranged at about 90 deg.C with the plates of the first stack and at about 45 deg. with the wall face of the duct. The plates of the third stack are in parallel with the plates of the first stack. Thus the gas passes through the stacks flowing in a zigzag fashion. Further, the gas is run through an integrally formed catalyst having a parallel passageway on the wall face of the duct, so that NOx is selectively reduced with the reducing agent after the last stack.

5. 发明专利

JPH10202059A METHOD FOR DESULFURIZING GASEOUS SUBSTANCE 失效
公开(公告)号：JPH10202059A
公开(公告)日：1998-08-04
申请号：JP35925497
申请日：1997-12-26
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： B01D53/86 , B01J23/22 , C01B17/74 , C01B17/76 , C01B17/765 , C01B17/79
摘要： PROBLEM TO BE SOLVED: To enhance treating ability by changing over a desulfurizing process in each of plural reactors connected in series and contg. oxidation catalyst layers laminated on inert material layers so that the direction of a flow of gas is reversed at intervals of a specified time and keeping the oxidation catalyst layers in a specified temp. range. SOLUTION: When a gaseous substance contg. O2 , SO2 , SO3 , etc., and/or org. sulfur-contg. components is desulfurized in reactors 3a, 3b connected in series and contg. oxidation catalyst layers 5a, 5b laminated on inert material layers 4a, 4b, combustible components are oxidized to H2 O, CO2 and SO2 , all SO2 is further oxidized to SO3 and all SO3 is hydrated with at least one equiv. H2 O based on the amt. of SO3 in the gas. The hydrated SO3 is condensed as sulfuric acid. At this time, the direction of a flow of gas in each of the reactors is reversed after about 1-40min and the layers 5a, 5b are kept in the temp. range of 300-500 deg.C. A flow of gas after the reactions is kept at a temp. below the dew point of the gas giving H2 SO4 by at least 50 deg.C.

6. 发明专利

JP2001200764A OPERATING METHOD OF COMPRESSION IGNITION ENGINE 失效
公开(公告)号：JP2001200764A
公开(公告)日：2001-07-27
申请号：JP2000374294
申请日：2000-12-08
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER , NIELSEN PAUL ERIK HOJLUND , BLOM NIELS JORGEN
IPC分类号： F01N5/02 , F02B1/14 , F02B3/06 , F02B3/08 , F02B43/10 , F02B43/12 , F02B69/04 , F02D19/06 , F02D19/12 , F02M21/02 , F02M27/02 , F02M31/08 , F02M31/16 , F02M37/00 , F02M53/02
摘要： PROBLEM TO BE SOLVED: To provide a method changing methanol primary fuel into dimethyl ether-contained fuel on a vehicle body for operating a compression ignition engine, by eliminating the difficulty in handling and storing of the fuel, particularly on a vehicle. SOLUTION: In this operating method of a compression ignition engine, using dimethly ether-contained fuel obtained by converting methanol primary fuel, the operating method includes each step as follows, (a) methanol primary fuel is compressed in a liquid-state to the end engine injection pressure, (b) this compressed primary fuel is preheated by heat provided in exhaust gas of the engine, (c) primary fuel is introduced at injection temperature and injection pressure of the engine and converted into dimethyl ether-contained fuel by contact with methanol dewatered catalyst and (d) this dimethyl ether- contained fuel is injected at injection pressure and injection temperature into the engine.

7. 发明专利

JPH11263605A PRODUCTION OF AMMONIUM THIOSULFATE 失效
公开(公告)号：JPH11263605A
公开(公告)日：1999-09-28
申请号：JP304599
申请日：1999-01-08
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： C01B17/62 , C01B17/64 , C01B21/093 , C01C20060101 , C01C1/00 , C01C1/24
摘要： PROBLEM TO BE SOLVED: To provide a method for continuously producing ammonium thiosulfate from H2 S, SO2 and NB3 . SOLUTION: In the 1st absorption stage, a 1st gas flow containing SO2 is brought into contact with an aq. solution containing NH3 and ammonium hydrogen sulfite in one or more absorbers connected in series to prepare a solution of ammonium hydrogen sulfite, a vent gas is discharged from one of the absorbers and the solution prepared in the 1st absorption stage is fed to the 2nd absorption stage, where a 2nd gas flow containing H2 S is brought into contact with the aq. solution containing NH3 and ammonium thiosulfate to produce a solution enriched in ammonium thiosulfate.

8. 发明专利

JP2758470B2 失效
公开(公告)号：JP2758470B2
公开(公告)日：1998-05-28
申请号：JP50665389
申请日：1989-05-18
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： C01B17/74 , B01D53/86 , C01B17/76 , C01B17/80 , C01B17/90

9. 发明专利

JP2501716B2 失效
公开(公告)号：JP2501716B2
公开(公告)日：1996-05-29
申请号：JP13110492
申请日：1992-05-22
申请人： TOPSOE HALDOR AS
发明人： SCHOUBYE PETER
IPC分类号： B01J23/40 , B01J23/22 , B01J27/055 , B01J27/30 , C01B17/50 , C01B17/58 , C01B17/69 , C01B17/76 , C01B17/79 , C01B17/80 , C01B17/90 , C01B17/92
摘要： Process for the regeneration of spent sulphuric acid from chemical processes, which process comprises the steps of evaporating and decomposing the spent sulphuric acid at a temperature of 400-800 DEG C with excess of air, to a gas mainly consisting of carbon dioxide, steam, nitrogen, oxygen, sulphur dioxide and sulphur trioxide together with minor amounts of ammonia, carbon monoxide, residual organic compounds and dust from solids in the spent acid; cooling the gas to 360-450 DEG C and oxidizing oxidizable components in the cooled gas by contact with an oxidation catalyst; cooling the oxidized gas to a temperature of 10-50 DEG C above the sulphuric acid dew point in the gas and condensing sulphuric acid formed in the cooled and oxidized gas.

10. 发明申请

WO2011147538A2 PROCESS AND APPARATUS FOR SULPHURIC ACID PRODUCTION 审中-公开
标题翻译：硫酸生产工艺及装置
公开(公告)号：WO2011147538A2
公开(公告)日：2011-12-01
申请号：PCT/EP2011002379
申请日：2011-05-13
申请人： TOPSOE HALDOR AS , MOELLERHOEJ MARTIN , LYKKE MADS , THELLEFSEN MORTEN , SCHOUBYE PETER
发明人： MOELLERHOEJ MARTIN , LYKKE MADS , THELLEFSEN MORTEN , SCHOUBYE PETER
IPC分类号： C01B17/765
CPC分类号： C01B17/765
摘要： A process for the conversion of sulphur dioxide contained in a feed gas to sulphur trioxide, comprising the steps of a) alternatingly providing a first feed gas containing a high concentration of sulphur dioxide and a second feed gas containing a low concentration of sulphur dioxide as a process gas, b) preheating the process gas by heat exchange with a heat exchange medium, c) reacting the process gas in the presence of a catalytically active material in a catalytic reaction zone, d) converting at least in part the sulphur dioxide of the process gas into sulphur trioxide contained in a product gas in the catalytic reaction zone, e) cooling the product gas by contact with a heat exchange medium, wherein a thermal buffer zone is provided in relation to one of said process steps, providing thermal energy produced during super-autothermal operation for heating the process gas during sub-autothermal operation.
摘要翻译：一种将进料气体中所含的二氧化硫转化为三氧化硫的方法，包括以下步骤：a）交替地提供含有高浓度二氧化硫的第一进料气体和含有低浓度二氧化硫的第二进料气体作为工艺气体，b）通过与热交换介质的热交换来预热工艺气体，c）在催化反应区域中使催化活性材料存在下使工艺气体反应，d）至少部分地将二氧化硫将催化反应区中产物气体中所含的三氧化硫气体加工成三氧化硫，e）通过与热交换介质接触来冷却产物气体，其中相对于所述工艺步骤之一提供热缓冲区，提供产生的热能在超自热操作期间，在亚热自动加热过程中加热工艺气体。

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