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1. 发明申请

WO1998006760A1 SATURATED TRICYCLIC LIGAND CONTAINING METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译：含饱和三元配位金属复合物和烯烃聚合工艺
公开(公告)号：WO1998006760A1
公开(公告)日：1998-02-19
申请号：PCT/US1997013560
申请日：1997-08-01
申请人： THE DOW CHEMICAL COMPANY , NORTHWESTERN UNIVERSITY
发明人： THE DOW CHEMICAL COMPANY , NORTHWESTERN UNIVERSITY , NICKIAS, Peter, N. , OBORA, Yasushi , MARKS, Tobin, J.
IPC分类号： C08F04/642
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/15
摘要： Bridged, group 4 Metal complexes useful as olefin polymerization catalyst components corresponding to the formula: L1ZL2MXmX'n or a dimer, solvated adduct, chelated derivative or mixture thereof, wherein: L1 is a partially salturated tricyclic group, especially octahydrofluorenyl, L2 is a substituted cyclopentadienyl group that is bound to M by means of delocalized pi -electrons, said cyclopentadienyl group being substituted at one and only one of its two distal positions with a bulky ligand group; Z is divalent bridging substituent; X each occurrence is a monovalent, anionic moiety having up to 40 non-hydrogen atoms, optionally, two X groups may be covalently bound together forming a divalent dianionic moiety having both valences bound to M, or, optionally 2 X groups may be covalently bound together to form a neutral, conjugated or nonconjugated diene that is bonded to M by means of delocalized pi -electrons (whereupon M is in the +2 oxidation state), or further optionally one or more X and one or more X' groups may be bonded together thereby forming a moiety that is both covalently bound to M and coordinated thereto; m is 1 or 2 and is equal to two less than the formal oxidation state of M, except when 2 X groups together form a neutral conjugated or non-conjugated diene that is pi -bonded to M, in which case m is equal to the formal oxidation state of M; X' is a neutral ligand having up to 20 non-hydrogen atoms, and n is a number from 0 to 3.
摘要翻译：第4族金属络合物，可用作对应于下式的烯烃聚合催化剂组分：L1ZL2MXmX'n或二聚体，溶剂化加合物，螯合衍生物或其混合物，其中：L1为部分饱和三环基团，特别是八氢芴基，L2为取代的通过离域π电子与M结合的环戊二烯基，所述环戊二烯基在其两个远端位置中的一个且仅一个被取代，具有庞大的配体基团; Z是二价桥连取代基; X每个出现是具有多达40个非氢原子的单价阴离子部分，任选地，两个X基团可以共价键合在一起形成具有与M结合的两个价键的二价二阴离子部分，或者任选地，2个X基团可共价结合一起形成通过离域π电子（因此M处于+2氧化态），或进一步任选地一个或多个X和一个或多个X'基团与M键合的中性，共轭或非共轭二烯结合在一起，从而形成共价结合M并与之配位的部分; m为1或2，并且等于小于M的形式氧化态的2，除了当两个X基团一起形成与M相连接的中性共轭或非共轭二烯时，其中m等于 M的正式氧化态; X'是具有至多20个非氢原子的中性配体，n是0至3的数。

2. 发明申请

WO1998051728A2 HYDROXY-FUNCTIONALIZED POLYESTER AND POLY(ESTER ETHER) OLIGOMERS 审中-公开
标题翻译：羟基官能化聚酯和聚（醚）醚低聚物
公开(公告)号：WO1998051728A2
公开(公告)日：1998-11-19
申请号：PCT/US1997022276
申请日：1997-12-05
申请人： THE DOW CHEMICAL COMPANY , WANG, David, S. , WHITE, Jerry, E. , MANG, Michael, N. , BECKERDITE, John, M.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08G63/00
CPC分类号： C08G63/60 , C08G59/4207 , C08G59/625 , C08G63/66
摘要： Hydroxy-functional polyester oligomers are prepared by contacting a hydroxy-functional aliphatic dicarboxylic acid or a mixture of dicarboxylic acids containing hydroxy-functional aliphatic diacids, with a diglycidyl ether or diglycidyl ester in the presence of an onium catalyst in an ether solvent under conditions suitable for forming the oligomer. The oligomers can be used as hot-melt adhesives, adhesive tackifiers, plasticizers, heat-curable adhesives and heat-curable coatings. Some of these materials are biodegradable and are therefore suitable for application to compostable end products.
摘要翻译：羟基官能的聚酯低聚物是通过使羟基官能的脂族二羧酸或含有羟基官能的脂族二酸的二羧酸的混合物与二缩水甘油醚或二缩水甘油酯在鎓催化剂存在下在醚溶剂中在适合的条件下接触来制备的用于形成低聚物。低聚物可用作热熔粘合剂，粘合剂增粘剂，增塑剂，热固化粘合剂和热固化涂料。这些材料中的一些是可生物降解的，因此适用于可堆肥的最终产品。

3. 发明申请

WO1998031723A1 MELT POLYMERIZATION PROCESS FOR PREPARING AROMATIC POLYESTERS 审中-公开
标题翻译：用于制备芳族聚酯的熔融聚合方法
公开(公告)号：WO1998031723A1
公开(公告)日：1998-07-23
申请号：PCT/US1997023369
申请日：1997-12-19
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , DRUMRIGHT, Ray, E. , BREWBAKER, James, Lee , MARSHALL, William, B.
IPC分类号： C08G63/87
CPC分类号： C08G63/19 , C08G63/605 , C08G63/87
摘要： A process for preparing a polyester which includes the step of heating a reaction mixture comprising (i) diesters of dihydric phenols and C1-10 aliphatic monoacids, (ii) aromatic dicarboxylic acids, and (iii) a catalytic amount of an organic cation-containing salt at a temperature above the melt temperature of the diesters, under reaction conditions sufficient to form the corresponding polyester. Use of this process subjects the polymers prepared thereby to a thermal history which causes relatively little deterioration of the polymer's properties.
摘要翻译：一种制备聚酯的方法，其包括加热反应混合物的步骤，该反应混合物包含（i）二元酚和C 1-10脂族一元酸二酯，（ii）芳族二羧酸，和（iii）催化量的含有机阳离子的盐在高于二酯熔融温度的温度下，在足以形成相应聚酯的反应条件下进行。使用该方法使由此制备的聚合物受到热历史的影响，导致聚合物性质相对较少的劣化。

4. 发明申请

WO1998029491A1 POLYMER-ORGANOCLAY-COMPOSITES AND THEIR PREPARATION 审中-公开
标题翻译：聚合物 - 复合材料及其制备
公开(公告)号：WO1998029491A1
公开(公告)日：1998-07-09
申请号：PCT/US1997023861
申请日：1997-12-22
申请人： THE DOW CHEMICAL COMPANY , ANDERSON, Kenneth, W. , WHITE, Jerry, E. , CHOU, Chai-Jing , POLANSKY, Christine, A.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08K03/34
CPC分类号： C09D167/00 , C08G59/42 , C08G59/50 , C08K3/34 , C08K9/04 , C08L71/00 , C08L2666/58 , C09J167/00 , C08L67/00 , C08L63/00
摘要： A polymer composite comprising a hydroxy-phenoxyether or polyester polymer matrix having dispersed therein layers of an inorganic material derived from a multilayered inorganic material having organophilic properties. The dispersion of the multilayered inorganic material in the polymer matrix is such that an increase in the average interlayer spacing of the layered inorganic material occurs. This increase in interlayer spacing occurs to a significant extent resulting in the formation of a nanocomposite. The polymers are preferably derived from a diglycidyl ether or ester or an epihalohydrin and a dinucleophile such as a dicarboxylic acid, a difunctional amine, a bisphenol or a sulfonamide. As the organophilic inorganic material clay minerals modified with organic ammonium compounds are used.
摘要翻译：一种聚合物复合材料，其包含羟基 - 苯氧基醚或聚酯聚合物基质，其分散有衍生自具有亲有性质的多层无机材料的无机材料层。多层无机材料在聚合物基质中的分散体使得层状无机材料的平均层间距的增加发生。层间间隔的这种增加在很大程度上发生，导致形成纳米复合材料。聚合物优选衍生自二缩水甘油醚或酯或表卤代醇和二亲核体如二羧酸，双官能胺，双酚或磺酰胺。由于使用有机铵化合物改性的亲有机无机材料粘土矿物。

5. 发明申请

WO1998028358A1 OPEN-CELLED RIGID POLYURETHANE FOAM 审中-公开
标题翻译：开口刚性聚氨酯泡沫
公开(公告)号：WO1998028358A1
公开(公告)日：1998-07-02
申请号：PCT/US1997023234
申请日：1997-12-12
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , SMITS, Guido, F. , CINI, Giuliano , GRUENBAUER, Henri, J., M. , BROOS, Jacobus, A., F.
IPC分类号： C08J09/00
CPC分类号： C08J9/0061 , C08J9/143 , C08J2375/04 , C08J2427/00 , C08J2433/00
摘要： Disclosed is a process for preparing an open-celled rigid polyurethane foam by reacting a polyisocyanate with a polyol in the presence of a blowing agent, usually water, and a cell opening agent. The cell opening agent comprises a combination of a polyoxyalkylene polysiloxane having a cloud point of 65 DEG C or less, and a second substance that has a critical surface free energy of less than about 23mJ/m . Highly preferred as second substance is fine particulate poly(tetrafluorethylene) polymer.
摘要翻译：公开了一种通过在发泡剂（通常为水）和开孔剂的存在下使多异氰酸酯与多元醇反应制备开孔硬质聚氨酯泡沫体的方法。开孔剂包括浊点为65℃以下的聚氧化烯聚硅氧烷和临界表面自由能小于约23mJ / m 2的第二物质的组合。高度优选的第二种物质是聚（四氟乙烯）微粒聚合物。

6. 发明申请

WO1998027156A1 PLASTICIZED ALPHA-OLEFIN/VINYLIDENE AROMATIC MONOMER OR HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYLIDENE MONOMER INTERPOLYMERS 审中-公开
标题翻译：塑化的阿尔法 - 烯烃/乙烯基芳族单体或铰链的二醇或环己基乙烯基单体嵌段共聚物
公开(公告)号：WO1998027156A1
公开(公告)日：1998-06-25
申请号：PCT/US1997022009
申请日：1997-12-03
申请人： THE DOW CHEMICAL COMPANY , CHEUNG, Yunwa, W. , GATHERS, John, J. , GUEST, Martin, J. , BETHEA, James, R. , TURLEY, Robert, R.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08L25/08
CPC分类号： C08K5/0016 , Y10T428/31507 , Y10T428/31855 , C08L25/02
摘要： Properties of interpolymers of alpha -olefin/vinylidene aromatic monomer are enhanced with plasticizers selected from phthalate esters, trimellitate esters, benzoates, aliphatic diesters, epoxy compounds, phosphate esters, glutarates, polymeric plasticizers (polyesters of glycols and aliphatic dicarboxylic acids) and oils. These plasticized interpolymers are useful in a wide range of applications including films, sheet, adhesives, sealants and molded parts.
摘要翻译：使用选自邻苯二甲酸酯，偏苯三酸酯，苯甲酸酯，脂肪族二酯，环氧化合物，磷酸酯，戊二酸酯，聚合增塑剂（二醇和脂族二羧酸的聚酯）和油的增塑剂增强了α-烯烃/亚乙烯基芳族单体互聚物的性能。这些增塑互聚物可用于广泛的应用，包括膜，片，粘合剂，密封剂和模塑件。

7. 发明申请

WO1998027132A1 THE USE OF BUTYLENE OXIDE (BO) BASED POLYOLS TO IMPROVE THE COMPATIBILITY OF PENTANE AND CYCLOPENTANE IN RIGID POLYURETHANE FOAMS 审中-公开
标题翻译：使用丁基氧化物（BO）为基础的多元醇提高戊二酸和环戊二烯在刚性聚氨酯泡沫中的相容性
公开(公告)号：WO1998027132A1
公开(公告)日：1998-06-25
申请号：PCT/US1997023803
申请日：1997-12-19
申请人： THE DOW CHEMICAL COMPANY , BHATTACHARJEE, Debkumar , LATHAM, Dwight, David , NELSON, Gilbert, L. , LEIGON, C., R.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08G18/42
CPC分类号： C08J9/141 , C08G18/4244 , C08G18/4252 , C08G18/4854 , C08G2101/0025 , C08J2205/10 , C08J2375/04
摘要： The present invention is a formulated polyether or polyester polyol blend that is useful for preparing polyurethane and polyisocyanurate foams. The formulated polyol blend of the present invention includes: a polyol that is derived from butylene oxide; and a hydrocarbon blowing agent such as pentane or cyclopentane, for example. Use of butylene oxide polyols of the present invention allow inclusion of a sufficient amount of a hydrocarbon blowing agent to produce foams having low density, without incorporating a higher concentration of water into a polyurethane foam formulation.
摘要翻译：本发明是配制的聚醚或聚酯多元醇共混物，其可用于制备聚氨酯和聚异氰脲酸酯泡沫。本发明的配制的多元醇共混物包括：衍生自环氧丁烷的多元醇; 和烃类发泡剂如戊烷或环戊烷。使用本发明的环氧丁烷多元醇可以包含足够量的烃发泡剂来生产具有低密度的泡沫，而不将更高浓度的水掺入到聚氨酯泡沫体制剂中。

8. 发明申请

WO1998027103A1 FUSED RING SUBSTITUTED INDENYL METAL COMPLEXES AND POLYMERIZATION PROCESS 审中-公开
标题翻译：熔融取代的金属复合物和聚合方法
公开(公告)号：WO1998027103A1
公开(公告)日：1998-06-25
申请号：PCT/US1997021585
申请日：1997-11-21
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , MCADON, Mark, H. , NICKIAS, Peter, N. , PATTON, Jasson, T. , SHANKAR, Ravi, B. , TIMMERS, Francis, J. , VANDERLENDE, Daniel, D. , KOLTHAMMER, Brian, W., S. , UELIGGER, Steven, M.
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F212/08 , C08F2500/08 , C08F2500/12 , C08F210/14 , C08F210/06 , C08F236/20 , C08F2500/25
摘要： Group 4 metal constrained geometry complexes comprising a fused ring indenyl derivative ligand, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.
摘要翻译：公开了包含稠环茚基衍生物配体的第4族金属约束几何配合物，其催化衍生物，其制备方法及其作为烯烃聚合催化剂组分的用途。

9. 发明申请

WO1998021165A1 METHOD OF PREPARING COATED NITRIDE POWDER AND THE COATED POWDER PRODUCED THEREBY 审中-公开
标题翻译：制备涂覆氮化硅粉末的方法和生产的涂层粉末
公开(公告)号：WO1998021165A1
公开(公告)日：1998-05-22
申请号：PCT/US1997019934
申请日：1997-11-06
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , EISMAN, Glenn, A. , KIRCHHOFF, Robert, A. , YALVAC, Selim , HOWARD, Kevin, E. , BANKER, Brian, M. , KESTERSON, Matthew, R.
IPC分类号： C04B41/50
CPC分类号： C04B41/009 , C01B21/06 , C01B21/0728 , C04B41/4584 , C04B41/81 , C04B2111/00844 , C04B2111/27 , H01L23/15 , H01L2924/0002 , Y10T428/12056 , C04B41/4535 , C04B41/455 , C04B41/4556 , C04B41/5022 , C04B41/5027 , C04B35/58 , C04B35/581 , H01L2924/00
摘要： The invention is a process for the preparation of coated nitride powder, comprising contacting one or more metal complex(es), organo-aluminum material, optionally one or more silicon compounds or mixtures thereof, with nitride powder under conditions such that coated nitride powder is formed. A metal complex is a metal-containing system which is soluble in a host liquid. The process of the invention is a process for making coated nitride powder and obtaining the desirable properties of coated nitride powder, while maintaining the desirable properties of the uncoated powder, such as good thermal conductivity, for use in electronics applications. In another aspect, the invention is a coated nitride powder which has the advantageous properties of the uncoated powder and is a desirable alternative to current nitride coatings.
摘要翻译：本发明是一种制备涂覆氮化物粉末的方法，包括使一种或多种金属络合物，有机铝材料，任选的一种或多种硅化合物或其混合物与氮化物粉末接触，使得涂覆的氮化物粉末为形成。金属络合物是可溶于主体液体的含金属体系。本发明的方法是制备涂覆氮化物粉末并获得涂覆的氮化物粉末的期望性能的方法，同时保持未涂覆的粉末的期望性质，例如良好的导热性，用于电子应用中。在另一方面，本发明是涂覆的氮化物粉末，其具有未涂覆粉末的有利性质，并且是目前氮化物涂层的理想替代方案。

10. 发明申请

WO1998018804A1 FUNCTIONALIZED-PHENOXY PHOSPHAZENES AND USE OF SAME AS A LUBRICANT 审中-公开
标题翻译：功能化 - 苯氧基磷灰石，同时作为润滑剂使用
公开(公告)号：WO1998018804A1
公开(公告)日：1998-05-07
申请号：PCT/US1997016651
申请日：1997-09-17
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , MORGAN, Ted, A. , PAWLOSKI, Chester, E. , KAR, Kishore
IPC分类号： C07F09/6581
CPC分类号： C07F9/65814 , C10M105/74 , C10M2223/02 , C10M2223/049 , C10N2240/00 , C10N2240/20 , C10N2240/201 , C10N2240/202 , C10N2240/203 , C10N2240/204 , C10N2240/205 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , G11B5/71 , G11B5/725
摘要： Functionalized-phenoxy phosphazenes and use of same as lubricants for magnetic recording media are disclosed. In particular, cyclic phosphazenes having six or eight atoms in the ring structure and having at least one trifluoromethylphenoxy group; hydroxyphenoxy, aminophenoxy, carboxymethyl phenoxy, cyanophenoxy, 2-hydroxyethoxyphenoxy groups or a combination thereof; and, optionally, fluorophenoxy groups.
摘要翻译：公开了官能化的苯氧基磷腈，并将其用作磁记录介质的润滑剂。特别是环状结构中具有六个或八个原子并且具有至少一个三氟甲基苯氧基的环状磷腈; 羟基苯氧基，氨基苯氧基，羧甲基苯氧基，氰基苯氧基，2-羟基乙氧基苯氧基或其组合; 和任选的氟苯氧基。

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