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1. 发明申请

WO1994017125A1 STRUCTURED COPOLYMERS USED AS ABSORBENTS, GELS AND CARRIERS OF METAL IONS 审中-公开
标题翻译：用作金属离子的吸收剂，凝胶和载体的结构化共聚物
公开(公告)号：WO1994017125A1
公开(公告)日：1994-08-04
申请号：PCT/US1994000801
申请日：1994-01-21
申请人： THE DOW CHEMICAL COMPANY , HEDSTRAND, David, M. , TOMALIA, Donald, A. , HELMER, Bradley, J.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08G73/02
CPC分类号： C08G83/003 , A01N25/10 , A61K47/59 , A61K47/595 , A61K47/6949 , B82Y5/00 , C07C211/29 , C07C233/11 , C07C237/20 , C08G65/26 , C08G65/332 , C08G73/02 , C08G73/0206 , C08G73/024 , C08G73/028 , C08L25/06 , C08L71/02 , C08L79/02 , C08L101/005 , C12N15/87 , C08L2666/04 , C08L25/00
摘要： Dense star polymers or dendrimers having a highly branched interior structure capable of associating or chelating with metal ions are modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell. The modified dendrimers are useful for dispersing metal ions in a non-aqueous polymer matrix. Also dense star polymers or dendrimers having a highly branched hydrophilic interior structure are modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, which modified polymers are useful as gels and surfactants.
摘要翻译：具有能够与金属离子缔合或螯合的高度支化的内部结构的密集星形聚合物或树枝状大分子通过用能够提供疏水性外壳的疏水基团进行加帽来改性。改性树枝状聚合物可用于将金属离子分散在非水性聚合物基质中。具有高度支化的亲水性内部结构的致密的星形聚合物或树枝状大分子也可通过用能够提供疏水性外壳的疏水基团进行加帽来改性，该改性聚合物可用作凝胶和表面活性剂。

2. 发明申请

WO1994017130A1 SMALL CELL FOAMS AND BLENDS AND A PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译：小细胞和混合物及其制备方法
公开(公告)号：WO1994017130A1
公开(公告)日：1994-08-04
申请号：PCT/US1994000495
申请日：1994-01-21
申请人： THE DOW CHEMICAL COMPANY , HEDSTRAND, David, M. , TOMALIA, Donald, A.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08J09/00
CPC分类号： C08J9/0061 , C08G73/028 , C08J2479/00
摘要： Dense star polymers or dendrimers, modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, act as molecular nucleating agents. These modified dense star polymers or dendrimers are particularly effective for the production of small cell foams.
摘要翻译：通过用能够提供疏水性外壳的疏水基团加成改性的密集星形聚合物或树枝状大分子作为分子成核剂。这些改性的致密星形聚合物或树枝状大分子对于生产小泡沫体是特别有效的。

3. 发明申请

WO1995024221A1 BIOACTIVE AND/OR TARGETED DENDRIMER CONJUGATES 审中-公开
标题翻译：生物和/或目标滴定剂
公开(公告)号：WO1995024221A1
公开(公告)日：1995-09-14
申请号：PCT/US1995003045
申请日：1995-03-07
申请人： THE DOW CHEMICAL COMPANY , DENDRITECH INCORPORATED , REGENTS OF THE UNIVERSITY OF MICHIGAN , TOMALIA, Donald, A. , BAKER, James, R. , BIELINSKA, Anna, U. , BROTHERS, Herbert, M., II , CHENG, Roberta, C. , FAZIO, Michael, J. , HEDSTRAND, David, M. , JOHNSON, Jennifer, A. , KAPLAN, Donald, A. , KLAKAMP, Scott, L. , KRUPER, William, J., Jr , KUKOWSKA-LATALLO, Jolanta , MAXON, Bartley, D. , PIEHLER, Lars, T. , TOMLINSON, Ian, A. , WILSON, Larry, R. , YIN, Rui
发明人： THE DOW CHEMICAL COMPANY , DENDRITECH INCORPORATED , REGENTS OF THE UNIVERSITY OF MICHIGAN
IPC分类号： A61K47/48
CPC分类号： A01N25/10 , A61K47/59 , A61K47/595 , A61K47/61 , A61K47/6949 , A61K49/085 , A61K49/124 , B82Y5/00 , C07C211/29 , C07C233/11 , C07C237/20 , C08G83/003 , C08L101/005 , C12N15/87 , Y10S424/16
摘要： Dendritic polymer conjugates which are composed of at least one dendrimer in association with at least one unit of a carried material, where the carrier material can be a biological response modifier, have been prepared. The conjugate can also have a target director present, and when it is present, then the carried material may be a bioactive agent. Preferred dendritic polymers are dense starr polymers, which have been complexed with biological response modifiers. These conjugates and complexes have particularly advantageous properties due to their unique characteristics.
摘要翻译：已经制备了由载体材料可以是生物反应调节剂的至少一种携带材料的至少一个单元组成的树枝状聚合物共轭物。缀合物还可以具有存在的靶向导体，并且当存在时，载体材料可以是生物活性剂。优选的树枝状聚合物是与生物反应调节剂复合的致密星形聚合物。这些共轭物和复合物由于其独特的特性而具有特别有利的性质。

4. 发明申请

WO1994024202A1 LATEX COPOLYMERS FOR PAPER COATING COMPOSITIONS 审中-公开
标题翻译：用于纸张涂料组合物的LATEX共聚物
公开(公告)号：WO1994024202A1
公开(公告)日：1994-10-27
申请号：PCT/US1993003618
申请日：1993-04-16
申请人： THE DOW CHEMICAL COMPANY , HELMER, Bradley, J. , LOUGHNEY, Shirley, J. , MACDONAGH-DUMLER, Jon
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08L09/04
CPC分类号： D21H19/58 , C08F220/28 , C08F236/04 , C08F290/062
摘要： The present invention relates to a latex copolymer comprising in polymerized form one or more ethylenically unsaturated poly(ethylene glycol) monomers represented by formula (I) where R is an ethylenically unsaturated functional group, R is H, OH or OCH3, and n is from 3 to 20, and one or more comonomers. Paper coating compositions comprising this latex copolymer impart improved sheet gloss and dry pick characteristics to the coated paper. Additional embodiments include a process for the preparation of the ethylenically unsaturated poly(ethylene glycol) monomer-containing latex copolymer and the paper coating composition.
摘要翻译：本发明涉及一种胶乳共聚物，其包含聚合形式的一种或多种由式（I）表示的烯属不饱和聚（乙二醇）单体，其中R 1是烯属不饱和官能团，R是H，OH或OCH 3，和 n为3至20，和一种或多种共聚单体。包含该胶乳共聚物的纸涂料组合物赋予涂布纸更好的片材光泽度和干燥选择特性。另外的实施方案包括制备含烯属不饱和聚（乙二醇）单体的胶乳共聚物和纸涂料组合物的方法。

5. 发明申请

WO1998001237A1 METHOD OF APPLYING A ROAD MARKING COMPOSITION 审中-公开
标题翻译：道路标记组合物的应用方法
公开(公告)号：WO1998001237A1
公开(公告)日：1998-01-15
申请号：PCT/US1997009474
申请日：1997-06-02
申请人： THE DOW CHEMICAL COMPANY , HELMER, Bradley, J. , BERGMAN, Roger, W.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： B05D03/10
CPC分类号： B05D3/108 , E01F9/506
摘要： A road marking composition is applied by applying (1) an aqueous dispersion of a film-forming binder and (2) a polyamine. The process of the invention provides rapid drying, and the dried composition is not prone to smearing.
摘要翻译：通过应用（1）成膜粘合剂的水分散体和（2）多胺来施加路标组合物。本发明的方法提供快速干燥，并且干燥的组合物不容易涂抹。

6. 发明申请

WO1996022338A2 FAST HARDENING AQUEOUS COATING COMPOSITION AND PAINT 审中-公开
标题翻译：快速硬化水性涂料组合物和油漆
公开(公告)号：WO1996022338A2
公开(公告)日：1996-07-25
申请号：PCT/US1996000802
申请日：1996-01-18
申请人： THE DOW CHEMICAL COMPANY , HELMER, Bradley, J. , YOUNG, James, W., Jr.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C09D05/00
CPC分类号： C09D133/06 , C08L79/00 , C08L2666/14
摘要： The invention relates to a fast hardening aqueous coating composition comprising from 95 to 99 weight percent of an anionically stabilized aqueous emulsion of a copolymer having a Tg of from -10 DEG C to 50 DEG C, the copolymer containing two or more ethylenically unsaturated monomers, wherein from 0 to 5 weight percent of the monomers are alpha , beta -ethylenically unsaturated aliphatic carboxylic acid monomers; from 0.2 to 5 weight percent of a polyimine having a molecular weight of from 250 to 20,000; and from 0.2 to 5 weight percent of a volatile base, wherein the composition has a pH from 8 to 11, and wherein a cast film of the composition has a hardening rate measurement rating of at least 5 within 20 minutes after casting under ambient conditions of temperature up to 30 DEG C and relative humidity no less than 50 percent. Within the scope of the invention are a process for the preparation of a fast hardening aqueous coating composition, a fast hardening aqueous traffic paint, and a fast hardening migration-resistant binder for composites.
摘要翻译：本发明涉及一种快速硬化水性涂料组合物，其包含95至99重量％的Tg为-10℃至50℃的共聚物的阴离子稳定的水性乳液，所述共聚物含有两种或更多种烯属不饱和单体，其中0至5重量％的单体是α，β-烯属不饱和脂族羧酸单体; 0.2至5重量％的分子量为250至20,000的聚亚胺; 和0.2至5重量％的挥发性碱，其中所述组合物的pH为8至11，并且其中所述组合物的流延膜在铸造后的20分钟内的硬化速率测量等级为至少5，在环境条件下温度可达30℃，相对湿度不低于50％。本发明的范围是用于制备快速硬化水性涂料组合物，快速硬化水性交联漆和用于复合材料的快速硬化耐迁移粘合剂的方法。

7. 发明申请

WO1998051728A2 HYDROXY-FUNCTIONALIZED POLYESTER AND POLY(ESTER ETHER) OLIGOMERS 审中-公开
标题翻译：羟基官能化聚酯和聚（醚）醚低聚物
公开(公告)号：WO1998051728A2
公开(公告)日：1998-11-19
申请号：PCT/US1997022276
申请日：1997-12-05
申请人： THE DOW CHEMICAL COMPANY , WANG, David, S. , WHITE, Jerry, E. , MANG, Michael, N. , BECKERDITE, John, M.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08G63/00
CPC分类号： C08G63/60 , C08G59/4207 , C08G59/625 , C08G63/66
摘要： Hydroxy-functional polyester oligomers are prepared by contacting a hydroxy-functional aliphatic dicarboxylic acid or a mixture of dicarboxylic acids containing hydroxy-functional aliphatic diacids, with a diglycidyl ether or diglycidyl ester in the presence of an onium catalyst in an ether solvent under conditions suitable for forming the oligomer. The oligomers can be used as hot-melt adhesives, adhesive tackifiers, plasticizers, heat-curable adhesives and heat-curable coatings. Some of these materials are biodegradable and are therefore suitable for application to compostable end products.
摘要翻译：羟基官能的聚酯低聚物是通过使羟基官能的脂族二羧酸或含有羟基官能的脂族二酸的二羧酸的混合物与二缩水甘油醚或二缩水甘油酯在鎓催化剂存在下在醚溶剂中在适合的条件下接触来制备的用于形成低聚物。低聚物可用作热熔粘合剂，粘合剂增粘剂，增塑剂，热固化粘合剂和热固化涂料。这些材料中的一些是可生物降解的，因此适用于可堆肥的最终产品。

8. 发明申请

WO1998031723A1 MELT POLYMERIZATION PROCESS FOR PREPARING AROMATIC POLYESTERS 审中-公开
标题翻译：用于制备芳族聚酯的熔融聚合方法
公开(公告)号：WO1998031723A1
公开(公告)日：1998-07-23
申请号：PCT/US1997023369
申请日：1997-12-19
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , DRUMRIGHT, Ray, E. , BREWBAKER, James, Lee , MARSHALL, William, B.
IPC分类号： C08G63/87
CPC分类号： C08G63/19 , C08G63/605 , C08G63/87
摘要： A process for preparing a polyester which includes the step of heating a reaction mixture comprising (i) diesters of dihydric phenols and C1-10 aliphatic monoacids, (ii) aromatic dicarboxylic acids, and (iii) a catalytic amount of an organic cation-containing salt at a temperature above the melt temperature of the diesters, under reaction conditions sufficient to form the corresponding polyester. Use of this process subjects the polymers prepared thereby to a thermal history which causes relatively little deterioration of the polymer's properties.
摘要翻译：一种制备聚酯的方法，其包括加热反应混合物的步骤，该反应混合物包含（i）二元酚和C 1-10脂族一元酸二酯，（ii）芳族二羧酸，和（iii）催化量的含有机阳离子的盐在高于二酯熔融温度的温度下，在足以形成相应聚酯的反应条件下进行。使用该方法使由此制备的聚合物受到热历史的影响，导致聚合物性质相对较少的劣化。

9. 发明申请

WO1998029491A1 POLYMER-ORGANOCLAY-COMPOSITES AND THEIR PREPARATION 审中-公开
标题翻译：聚合物 - 复合材料及其制备
公开(公告)号：WO1998029491A1
公开(公告)日：1998-07-09
申请号：PCT/US1997023861
申请日：1997-12-22
申请人： THE DOW CHEMICAL COMPANY , ANDERSON, Kenneth, W. , WHITE, Jerry, E. , CHOU, Chai-Jing , POLANSKY, Christine, A.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08K03/34
CPC分类号： C09D167/00 , C08G59/42 , C08G59/50 , C08K3/34 , C08K9/04 , C08L71/00 , C08L2666/58 , C09J167/00 , C08L67/00 , C08L63/00
摘要： A polymer composite comprising a hydroxy-phenoxyether or polyester polymer matrix having dispersed therein layers of an inorganic material derived from a multilayered inorganic material having organophilic properties. The dispersion of the multilayered inorganic material in the polymer matrix is such that an increase in the average interlayer spacing of the layered inorganic material occurs. This increase in interlayer spacing occurs to a significant extent resulting in the formation of a nanocomposite. The polymers are preferably derived from a diglycidyl ether or ester or an epihalohydrin and a dinucleophile such as a dicarboxylic acid, a difunctional amine, a bisphenol or a sulfonamide. As the organophilic inorganic material clay minerals modified with organic ammonium compounds are used.
摘要翻译：一种聚合物复合材料，其包含羟基 - 苯氧基醚或聚酯聚合物基质，其分散有衍生自具有亲有性质的多层无机材料的无机材料层。多层无机材料在聚合物基质中的分散体使得层状无机材料的平均层间距的增加发生。层间间隔的这种增加在很大程度上发生，导致形成纳米复合材料。聚合物优选衍生自二缩水甘油醚或酯或表卤代醇和二亲核体如二羧酸，双官能胺，双酚或磺酰胺。由于使用有机铵化合物改性的亲有机无机材料粘土矿物。

10. 发明申请

WO1998028358A1 OPEN-CELLED RIGID POLYURETHANE FOAM 审中-公开
标题翻译：开口刚性聚氨酯泡沫
公开(公告)号：WO1998028358A1
公开(公告)日：1998-07-02
申请号：PCT/US1997023234
申请日：1997-12-12
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , SMITS, Guido, F. , CINI, Giuliano , GRUENBAUER, Henri, J., M. , BROOS, Jacobus, A., F.
IPC分类号： C08J09/00
CPC分类号： C08J9/0061 , C08J9/143 , C08J2375/04 , C08J2427/00 , C08J2433/00
摘要： Disclosed is a process for preparing an open-celled rigid polyurethane foam by reacting a polyisocyanate with a polyol in the presence of a blowing agent, usually water, and a cell opening agent. The cell opening agent comprises a combination of a polyoxyalkylene polysiloxane having a cloud point of 65 DEG C or less, and a second substance that has a critical surface free energy of less than about 23mJ/m . Highly preferred as second substance is fine particulate poly(tetrafluorethylene) polymer.
摘要翻译：公开了一种通过在发泡剂（通常为水）和开孔剂的存在下使多异氰酸酯与多元醇反应制备开孔硬质聚氨酯泡沫体的方法。开孔剂包括浊点为65℃以下的聚氧化烯聚硅氧烷和临界表面自由能小于约23mJ / m 2的第二物质的组合。高度优选的第二种物质是聚（四氟乙烯）微粒聚合物。

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