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1. 发明授权

US06576302B1 Method for producing a metal oxide and method for forming a minute pattern 失效
标题翻译：金属氧化物的制造方法及形成微小图案的方法
公开(公告)号：US06576302B1
公开(公告)日：2003-06-10
申请号：US09513814
申请日：2000-02-25
申请人： Susumu Mizuta , Tetsuo Tsuchiya , Akio Watanabe , Yoji Imai , Iwao Yamaguchi , Toshiya Kumagai , Takaaki Manabe , Hiroyuki Niino , Akira Yabe
发明人： Susumu Mizuta , Tetsuo Tsuchiya , Akio Watanabe , Yoji Imai , Iwao Yamaguchi , Toshiya Kumagai , Takaaki Manabe , Hiroyuki Niino , Akira Yabe
IPC分类号： C08J718
CPC分类号： C23C18/14 , C23C18/06 , C23C18/1216
摘要： There is disclosed a method for producing a metal oxide, which comprises the steps of: dissolving a metal organic compound (e.g. a metal organic acid salt, a metal acetylacetonato complex, and a metal alkoxide having an organic group with 6 or more carbon atoms) in a solvent to provide a state of solution, applying the solution onto a substrate, drying the solution, and subjecting the resultant substrate to irradiation with a laser light of a 400 nm or less wavelength, to form a metal oxide on the substrate. According to that method, a metal oxide can be produced without applying a heat treatment at a high temperature of the degree adopted in the conventionally known application thermal decomposition method.
摘要翻译：公开了一种金属氧化物的制造方法，该方法包括以下步骤：将金属有机化合物（例如金属有机酸盐，金属乙酰丙酮络合物和具有6个或更多个碳原子的有机基团的金属醇盐）在溶剂中以提供溶液状态，将溶液施加到基材上，干燥溶液，并使所得基板对波长为400nm以下的激光进行照射，以在基板上形成金属氧化物。根据该方法，可以在常规已知的应用热分解方法中采用的高温下进行金属氧化物而不进行热处理。

2. 发明授权

US06362453B1 Method of etching transparent solid material with laser beam 有权
标题翻译：用激光束蚀刻透明固体材料的方法
公开(公告)号：US06362453B1
公开(公告)日：2002-03-26
申请号：US09267683
申请日：1999-03-15
申请人： Jun Wang , Hiroyuki Niino , Akira Yabe
发明人： Jun Wang , Hiroyuki Niino , Akira Yabe
IPC分类号： B23K2612
CPC分类号： C03C23/0025 , B23K26/0624 , B23K26/066 , B23K26/1224 , B23K26/18 , B23K26/361 , B23K26/40 , B23K2103/50 , B28D1/221 , C03B33/0207 , C03B33/082 , C03C15/00
摘要： A method of etching a surface of a transparent solid material with a laser beam, wherein the surface is irradiated with the laser beam having a fluence of 0.01-100 J/cm2/pulse while maintaining a fluid capable of absorbing the laser beam in contact with an opposite surface of the solid material.
摘要翻译：一种用激光束蚀刻透明固体材料的表面的方法，其中用能量为0.01-100J / cm 2 /脉冲的激光束照射该表面，同时保持能够吸收激光束的流体与固体材料的相对表面。

3. 发明授权

US5580616A Method for surface modifying a fluorocarbonpolymer 失效
标题翻译：表面改性氟碳聚合物的方法
公开(公告)号：US5580616A
公开(公告)日：1996-12-03
申请号：US357136
申请日：1994-12-15
申请人： Hiroyuki Niino , Akira Yabe
发明人： Hiroyuki Niino , Akira Yabe
IPC分类号： C08J7/00 , B29C35/08 , B29C59/16 , C08J7/14 , C23C18/20 , H05K3/18 , B05D3/00
CPC分类号： H05K3/185 , B29C59/16 , C23C18/1641 , C23C18/2006 , C23C18/2033 , C23C18/204 , C23C18/208 , C23C18/285 , C23C18/30 , B29C2035/0827 , B29C2035/0838 , B29K2027/12
摘要： There is disclosed a method for surface-modifying a fluorocarbonpolymer-molded article and a method for chemical plating the surface. The method for surface-modifying comprises irradiating the fluorocarbonpolymer-molded article with an ultraviolet laser beam having a wavelength of 250 nm or less, in the presence of hydrazine compound, to make a surface of the said fluorocarbonpolymer-molded article hydrophilic. The surface made being hydrophilic is made lipophilic by chemical treating with an organic acid anhydride. The method for chemical plating comprises chemical plating the surface made being hydrophilic by the above method for surface-modifying, to deposit a metal film on a surface of the fluorocarbonpolymer-molded article.
摘要翻译：公开了一种氟碳聚合物成型体的表面改性方法和表面化学镀的方法。用于表面改性的方法包括在肼化合物的存在下，用波长为250nm以下的紫外线激光束照射氟碳聚合物模制品，以使所述氟碳聚合物模制品的表面亲水。通过用有机酸酐进行化学处理使亲水的表面变得亲油。化学镀方法包括通过上述用于表面改性的方法将由亲水的表面化学镀以在氟碳聚合物模塑制品的表面上沉积金属膜。

4. 发明授权

US5266244A Method of forming a thin electroconductive film 失效
标题翻译：形成薄导电膜的方法
公开(公告)号：US5266244A
公开(公告)日：1993-11-30
申请号：US867202
申请日：1992-06-30
申请人： Akira Yabe , Hiroyuki Niino , Masashi Shimoyama
发明人： Akira Yabe , Hiroyuki Niino , Masashi Shimoyama
IPC分类号： B01J19/12 , B23K26/00 , B29C35/08 , B29C59/16 , B29C70/88 , C08J5/18 , C08J7/00 , H01B1/12 , H01B13/00
CPC分类号： B29C70/882 , B01J19/121 , B01J19/122 , B29C59/16 , H01B1/125 , B29C2035/0838 , B29K2027/06 , B29K2027/08 , B29K2995/0005
摘要： A thin electroconductive film is formed by irradiating a shaped article of chlorinated vinyl polymer with a pulsive light having a pulse duration of not greater than 100 nsec., a fluence of above about 15 mJ/cm.sup.2 /pulse and below that at which the polymer is subject to ablation, a laser wavelength of from about 190 to about 300 nm, and repetition frequency of above about 1 Hz and below that at which the polymer is subject to deformation and/or decomposition by a regenerative function of irradiation, under vacuum or in an oxygen-free atmosphere, thereby irradiating the article with total photon numbers of at least 1.times.10.sup.18 /cm.sup.2 without causing photocrosslinking, oxidation or cleavage of the backbone chain. The invention does not use materials other than the starting polymer such as solvents or strong bases that can contaminate the thin film during a dehydrochlorination, so there is no need to remove solvents after reaction and no residual salts will be formed in the dehydrochlorination.
摘要翻译： PCT No.PCT / JP91 / 00333 Sec。 371日期：1992年6月30日 102（e）日期1992年6月30日PCT 1991年3月12日PCT PCT。公开号WO91 / 13680 PCT 日期：1991年9月19日。薄导电膜通过用脉冲持续时间不超过100nsec的脉冲光照射氯化乙烯基聚合物的成形制品，高于约15mJ / cm 2 /脉冲的注量和聚合物可能在其下进行烧蚀，激光波长为约190至约300nm，重复频率高于约1Hz，低于聚合物通过再生功能变形和/或分解的频率的照射，在真空下或在无氧气氛中，从而以不小于1×10 18 / cm 2的总光子数照射物品，而不引起主链的光交联，氧化或裂解。本发明不使用起始聚合物以外的材料，例如在脱氯化氢中可能污染薄膜的溶剂或强碱，因此在反应后不需要除去溶剂，在脱氯化氢中不会形成残留的盐。

5. 发明授权

US5374291A Method of processing photosensitive glass 失效
标题翻译：感光玻璃的加工方法
公开(公告)号：US5374291A
公开(公告)日：1994-12-20
申请号：US66318
申请日：1993-05-21
申请人： Akira Yabe , Hiroyuki Niino , Nobuhiro Kondo , Hirokazu Ono , Tomoaki Takahashi , Yoshinaga Takahashi , Toshio Matsumura
发明人： Akira Yabe , Hiroyuki Niino , Nobuhiro Kondo , Hirokazu Ono , Tomoaki Takahashi , Yoshinaga Takahashi , Toshio Matsumura
IPC分类号： C03C15/00 , C03C23/00
CPC分类号： C03C23/0025 , C03C15/00 , Y10S65/04
摘要： A method of processing a photosensitive glass includes exposing. Photosensitive glass by radiation from a laser whose oscillation wavelength lies within the range of wavelengths of exposing light to which the glass responds. Then, the exposed portions 1c are thermally developed and etched. Since a laser beam propagates with a high rectilinearity, the front and rear surfaces of thick photosensitive glass can be exposed without producing dimensional errors. Therefore, the etching accuracy is improved. Especially, where the front and rear surfaces of photosensitive glass are etched, both surfaces can be processed so as to form the same shape in them accurately. In addition, because almost all the energy of the laser radiation is used for exposure of the photosensitive glass, the energy is not wasted and so the efficiency is high.
摘要翻译：一种处理感光玻璃的方法包括曝光。来自激光器的辐射的感光玻璃，其振荡波长在玻璃响应的曝光光的波长范围内。然后，暴露部分1c被热显影和蚀刻。由于激光束以高直线传播，因此可以暴露厚的感光玻璃的前表面和后表面而不产生尺寸误差。因此，蚀刻精度提高。特别是在感光玻璃的前表面和后表面被蚀刻的地方，可以对两个表面进行加工，以便在其中精确地形成相同的形状。此外，由于激光辐射的几乎所有的能量都用于感光玻璃的曝光，所以能量不被浪费，因此效率高。

6. 发明授权

US5175043A Aromatic polymer molded article with modified surface condition and process for producing the same 失效
标题翻译：具有改性表面状态的芳族聚合物成型品及其制造方法
公开(公告)号：US5175043A
公开(公告)日：1992-12-29
申请号：US392929
申请日：1991-01-07
申请人： Akira Yabe , Hiroyuki Niino , Shozaburo Nagano , Masahiro Hosoi , Takatoshi Kuratsuji , Kazuaki Hotta , Masashi Nakano
发明人： Akira Yabe , Hiroyuki Niino , Shozaburo Nagano , Masahiro Hosoi , Takatoshi Kuratsuji , Kazuaki Hotta , Masashi Nakano
IPC分类号： B29C35/08 , B29C59/16 , B41M5/26 , B41M5/36 , G11B7/245 , G11B7/26
CPC分类号： B29C59/16 , B41M5/267 , G11B7/245 , G11B7/263 , B29C2035/0827 , B29C2035/0838 , B29C2791/009 , B29K2063/00 , B29K2067/00 , B29K2069/00 , B29K2071/00 , B29K2077/10 , B29K2079/08 , B29K2081/04 , B29K2081/06 , B29K2995/0021 , B41M5/262 , B41M5/36 , Y10T428/24479 , Y10T428/24942
摘要： The present invention lies in a process for modifying the surface of a molded article, which process comprises irradiating the surface of a molded article composed of an aromatic polymer or a polymer composition containing said aromatic polymer, with an ultraviolet laser beam having a wavelength of about 150 nm-380 nm at a fluence at least lower than the threshold to modify the surface as compared with the condition before the irradiation. The process makes it possible to modify the condition of the laser beam-irradiated surface portions of the molded article to, for example, a white color or black color, whereby the molded article can be endowed with functions and properties required in its use in various applications.
摘要翻译： PCT No.PCT / JP88 / 01252 Sec。 371日期1991年1月7日 102（e）日期1991年1月7日PCT提交1988年12月10日PCT公布。第WO89 / 05330号公报日本1982年6月15日。本发明在于改性成型体的表面的方法，该方法包括将由芳族聚合物或含有所述芳族聚合物的聚合物组合物组成的模塑制品的表面与紫外线与照射前的条件相比，以能量密度至少低于阈值的波长为约150nm-380nm的激光束来修饰表面。该方法使得可以将模制品的激光束照射的表面部分的状态改变为例如白色或黑色，由此模制品可以赋予其在各种使用中所需的功能和性能应用程序。

7. 发明授权

US6007876A Method for producing polymer articles with a modified surface 失效
标题翻译：具有改性表面的聚合物制品的制造方法
公开(公告)号：US6007876A
公开(公告)日：1999-12-28
申请号：US46632
申请日：1998-03-24
申请人： Hiroyuki Niino
发明人： Hiroyuki Niino
IPC分类号： A61L27/00 , A61L27/34 , C08F2/48 , C08J7/00 , C08J7/04 , C08J7/12
CPC分类号： C08J7/047 , A61L27/34 , C08J2400/14 , C08J2405/00 , C08J2489/00
摘要： There is disclosed a method for producing polymer articles having highly functionalized surfaces excellent in biocompatibility, by irradiating the surfaces of a polymer article with an ultraviolet laser beam in a solution containing a biopolymer. According to this method, a polymer article that has surfaces with biocompatibility, can be produced.
摘要翻译：公开了通过在含有生物聚合物的溶液中用紫外线激光束照射聚合物制品的表面，制造具有生物相容性优异的高官能化表面的聚合物制品的方法。根据该方法，可以制造具有生物相容性的表面的聚合物制品。

8. 发明授权

US5229715A Variable reluctance sensor for electromagnetically sensing the rate of movement of an object 失效
标题翻译：用于电磁感测物体运动速度的可变磁阻传感器
公开(公告)号：US5229715A
公开(公告)日：1993-07-20
申请号：US959493
申请日：1992-10-09
申请人： Hiroyuki Niino , Youichi Taniai
发明人： Hiroyuki Niino , Youichi Taniai
IPC分类号： G01P3/488
CPC分类号： G01P3/488
摘要： A variable reluctance sensor is disclosed as adapted for sensing the rate of revolution of a toothed wheel of magnetic material. The sensor has at least two magnets disposed side by side. One of the magnet has a first pole (e.g. S pole) disposed opposite the toothed wheel, and the other magnet has a second pole (e.g. N pole) disposed opposite the toothed wheel. The second pole of the first mentioned magnet and the first pole of the second magnet are both held against a magnetic core around which a coil is wound. As the teeth of the magnetic wheel successively travel past the magnets, they create magnetic fluxes oriented in opposite directions, which counteract each other in the core. Consequently, the total magnetic flux in the magnetic member varies more greatly than heretofore depending upon whether each magnet is opposed to any one tooth, or to the space between any two neighboring teeth, of the magnetic wheel. Such great variations in magnetic flux are translated into a correspondingly large amplitude signal as by the coil around the core.
摘要翻译：公开了可变磁阻传感器，用于感测磁性材料的齿轮的转速。传感器具有并排设置的至少两个磁体。一个磁体具有与齿轮相对设置的第一极（例如S极），另一个磁体具有与齿轮相对设置的第二极（例如，N极）。第一磁铁的第二极和第二磁体的第一极都被保持在磁芯上，线圈缠绕在磁芯上。当磁轮的齿相继行进通过磁体时，它们产生相反方向取向的磁通量，这在磁芯中相互抵消。因此，取决于磁体是否与任何一个齿相对或磁轮的任意两个相邻齿之间的空间相对，磁性部件中的总磁通量比以前更大程度地变化。磁通量的这种巨大的变化被转换成相当大的幅度信号，如通过芯周围的线圈。

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