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1. 发明授权

US4460794A Process for continuous production of alkylbenzaldehydes 失效
标题翻译：连续生产烷基苯甲醛的方法
公开(公告)号：US4460794A
公开(公告)日：1984-07-17
申请号：US386588
申请日：1982-06-09
申请人： Susumu Fujiyama , Shunichi Matsumoto
发明人： Susumu Fujiyama , Shunichi Matsumoto
IPC分类号： B01J27/00 , C07B61/00 , C07C45/00 , C07C45/49 , C07C47/542 , C07C67/00
CPC分类号： C07C45/49
摘要： Alkylbenzaldehyde is continuously produced in high yield from alkylbenzene by formylation with carbon monoxide in the presence of HF--BF.sub.3, where the alkylbenzene, HF--BF.sub.3 and carbon monoxide under a carbon monoxide partial pressure of at least 5 kg/cm.sup.2 absolute are introduced into the reactor to continuously carry out complexing of the alkylbenzene with HF--BF.sub.3 and formylation with the carbon monoxide successively in one and same reactor.
摘要翻译：在HF-BF 3存在下，用一氧化碳进行甲酰化从烷基苯连续制备烷基苯甲醛，其中将烷基苯，HF-BF 3和一氧化碳分压为至少5kg / cm2绝对的一氧化碳引入到反应器中连续进行烷基苯与HF-BF 3的络合，并在一个反应器中依次用一氧化碳进行甲酰化反应。

2. 发明授权

US4368336A Process for formylating xylene mixture 失效
标题翻译：甲酰化二甲苯混合物的方法
公开(公告)号：US4368336A
公开(公告)日：1983-01-11
申请号：US233304
申请日：1981-02-11
申请人： Susumu Fujiyama , Shunichi Matsumoto , Yuji Takamizawa
发明人： Susumu Fujiyama , Shunichi Matsumoto , Yuji Takamizawa
IPC分类号： C07C49/76 , B01J27/00 , B01J27/12 , C07B61/00 , C07C45/00 , C07C45/49 , C07C47/542 , C07C67/00
CPC分类号： C07C45/49
摘要： A xylene mixture containing at least one of m-xylene and o-xylene is formylated by carbon monoxide in the presence of hydrogen fluoride and boron trifluoride at a molar ratio of boron trifluoride to sum total of m-xylene and o-xylene in the xylene mixture of not more than 1.5 to selectively and correspondingly produce at least one of 2,4-dimethylbenzaldehyde and 3,4-dimethylbenzaldehyde.
摘要翻译：包含间二甲苯和邻二甲苯中的至少一种的二甲苯混合物在氟化氢和三氟化硼存在下，通过一氧化碳以三氟化硼的摩尔比与二甲苯中的间二甲苯和邻二甲苯的总和相加来甲酰化不超过1.5的混合物选择性地并相应地产生2,4-二甲基苯甲醛和3,4-二甲基苯甲醛中的至少一种。

3. 发明授权

US3988424A Method for decomposing an aromatic aldehyde-hydrogen fluoride-boron trifluoride complex 失效
标题翻译：分解芳香醛 - 氟化氢 - 三氟化硼配合物的方法
公开(公告)号：US3988424A
公开(公告)日：1976-10-26
申请号：US639698
申请日：1975-12-11
申请人： Susumu Fujiyama , Takehiko Takahashi , Minoru Takagawa , Shigeki Ozao
发明人： Susumu Fujiyama , Takehiko Takahashi , Minoru Takagawa , Shigeki Ozao
IPC分类号： C07C47/52 , B01J27/32 , B01J38/56 , C01B7/19 , C01B35/06 , C07B61/00 , C07C45/00 , C07C45/49 , C07C45/83 , C07C45/85 , C07C67/00 , C07C45/14
CPC分类号： C07C45/85 , C01B35/06 , C01B35/061 , C01B7/191 , C07C45/00 , C07C45/49 , C07C45/83
摘要： A method for decomposing an aromatic aldehyde-hydrogen fluoride-boron trifluoride complex in the presence of a decomposing agent represented by the formula ##SPC1##Wherein n is integer of 1-6, inclusive, and m is integer of 0-5, inclusive, and a total of n and m is 6 or less, to obtain an aromatic aldehyde, hydrogen fluoride and boron trifluoride separately without causing any change in the quality of the aromatic aldehyde or without forming undesirable byproducts is disclosed.
摘要翻译：在由式WHEREIN N表示的分解剂的存在下分解芳族醛 - 氟化氢 - 三氟化硼配合物的方法是1-6，INCLUSIVE和M的整数是0-5，包含和总计的整数的N和M为6或更少，以独立的方式获得芳香醛，氢氟酸和硼三氟甲磺酸，不会导致芳香醛的质量发生任何变化或不形成不合乎生产条件的产品。

4. 发明授权

US3956394A Process for purifying p-tolualdehyde 失效
标题翻译：对甲苯甲醛纯化方法
公开(公告)号：US3956394A
公开(公告)日：1976-05-11
申请号：US510610
申请日：1974-09-30
申请人： Susumu Fujiyama , Minoru Takagawa
发明人： Susumu Fujiyama , Minoru Takagawa
IPC分类号： C07C47/542 , C07C45/00 , C07C45/46 , C07C47/52 , C07C67/00 , C07C45/24
CPC分类号： C07C45/81
摘要： P-Tolualdehyde is separated with a high purify from a mixture of tolualdehyde isomers having a mole fraction of p-tolualdehyde of at least 0.27, on the basis of total tolualdehyde isomers by cooling the mixture to a crystallization temperature of -6.degree. to -60.degree.C, thereby crystallizing p-tolualdehyde, and separating the resulting p-tolualdehyde crystals from mother liquor. A solvent such as an aliphatic hydrocarbon having 1 to 9 carbon atoms or an alicyclic hydrocarbon having 3 to 9 carbon atoms can be added to the mixture before cooling to improve the crystallization conditions. The resulting crystals can be washed with a washing agent, such as said solvent, to remove the other isomers adhering to the crystals.
摘要翻译：通过将混合物冷却至-6℃至-60℃的结晶温度，从甲苯甲醛的摩尔分数至少为0.27的甲苯甲醛异构体的混合物中，以总甲苯甲醛异构体为基准，将P-甲醛从高纯度中分离出来 DEG，从而使对甲苯甲醛结晶，并将所得的对甲苯甲醛晶体与母液分离。可以在冷却之前向混合物中加入溶剂如具有1至9个碳原子的脂族烃或具有3至9个碳原子的脂环族烃以改善结晶条件。所得晶体可以用诸如所述溶剂的洗涤剂洗涤以除去附着在晶体上的其它异构体。

5. 发明授权

US3948998A Process for producing p-tolualdehyde 失效
标题翻译：对甲苯甲醛生产方法
公开(公告)号：US3948998A
公开(公告)日：1976-04-06
申请号：US530006
申请日：1974-12-05
申请人： Susumu Fujiyama , Takehiko Takahashi , Shigeki Kozao , Toyomi Kasahara
发明人： Susumu Fujiyama , Takehiko Takahashi , Shigeki Kozao , Toyomi Kasahara
IPC分类号： C07C47/542 , B01J27/00 , C07B61/00 , C07C45/00 , C07C45/49 , C07C47/52 , C07C67/00 , C07C45/14
CPC分类号： C07C45/49
摘要： This invention relates to a two step process for producing p-tolualdehyde which comprises reacting toluene with carbon monoxide in the presence of hydrogen fluoride and boron trifluoride, characterized by mixing all of the toluene, all of the hydrogen fluoride and only part of the boron trifluoride necessary to convert a substantial amount of toluene to p-tolualdehyde, thereby forming a toluene-hydrogen fluoride-boron trifluoride complex and reacting the toluene in the reaction system with carbon monoxide, thereby converting a portion of the toluene to p-tolualdehyde, and then adding the remainder of the boron trifluoride to the reaction product and reacting the remainder of the toluene with carbon oxide.
摘要翻译：本发明涉及生产对甲苯甲醛的两步法，该方法包括在氟化氢和三氟化硼的存在下使甲苯与一氧化碳反应，其特征在于将所有甲苯，全氟化氢和仅一部分三氟化硼将大量甲苯转化成对甲苯甲醛，从而形成甲苯 - 氟化氢 - 三氟化硼配合物，并使反应体系中的甲苯与一氧化碳反应，从而将甲苯的一部分转化为对甲苯甲醛，然后将剩余的三氟化硼加入到反应产物中，并使余下的甲苯与碳氧化物反应。

6. 发明授权

US5436374A Process for producing 4-formyl-4'-methylbiphenyl from biphenyl 失效
标题翻译：从联苯生产4-甲酰基-4'-甲基联苯的方法
公开(公告)号：US5436374A
公开(公告)日：1995-07-25
申请号：US281126
申请日：1994-07-28
申请人： Makoto Komatsu , Susumu Fujiyama , Koichi Kida , Mitsuharu Kitamura
发明人： Makoto Komatsu , Susumu Fujiyama , Koichi Kida , Mitsuharu Kitamura
IPC分类号： B01J27/12 , C07B61/00 , C07C45/49 , C07C47/546
CPC分类号： C07C45/49
摘要： A process for producing a 4-formyl-4'-methylbiphenyl from a biphenyl which comprises conducting the carbonylation of the biphenyl with carbon monoxide in the presence of a HF-BF.sub.3 catalyst in a carbonylation reactor to obtain the resulting reaction product solution containing a 4-formylbiphenyl, separating the 4-formylbiphenyl from the reaction product solution, hydrogenating the separated 4-formylbiphenyl to obtain a 4-methylbiphenyl, recycling the 4-methylbiphenyl to the carbonylation reactor, and then conducting both the carbonylation of the biphenyl with carbon monoxide to obtain a formylbiphenyl and the carbonylation of the 4-methylbiphenyl with carbon monoxide to obtain a 4-formyl-4'-methylbiphenyl simultaneously in the presence of the HF-BF.sub.3 catalyst in the carbonylation reactor.
摘要翻译：一种由联苯生产4-甲酰基-4'-甲基联苯的方法，其包括在羰基化反应器中，在HF-BF 3催化剂存在下，用一氧化碳进行联苯的羰基化，得到所得到的含有4 - 甲酰基联苯，从反应产物溶液中分离4-甲酰基联苯，氢化分离的4-甲酰基联苯，得到4-甲基联苯，将4-甲基联苯循环到羰基化反应器中，然后进行联苯与一氧化碳的羰基化反应在羰基化反应器中，在HF-BF 3催化剂的存在下，用一氧化碳得到甲酰基联苯和4-甲基联苯羰基化，得到4-甲酰基-4'-甲基联苯。

7. 发明授权

US4789455A Process for producing pitch used as starting material for the making of carbon materials 失效
标题翻译：制造用作碳材料制造原料的沥青的方法
公开(公告)号：US4789455A
公开(公告)日：1988-12-06
申请号：US77211
申请日：1987-07-24
申请人： Isao Mochida , Susumu Fujiyama , Yukio Sakai , Hiroyuki Otsuka
发明人： Isao Mochida , Susumu Fujiyama , Yukio Sakai , Hiroyuki Otsuka
IPC分类号： C10C1/19 , C10C3/00
CPC分类号： C10C1/19 , C10C3/002
摘要： A process for producing pitch useful as a starting material for the manufacture of a carbon material is provided. The pitch is produced by polymerizing a condensed nuclear aromatic compound or a material containing the same. The polymerization is carried out in the presence of a hydrogen fluoride/boron trifluoride catalyst system. The condensed nuclear aromatic compounds which may be used in this process are naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, pyrene and mixtures thereof.

8. 发明授权

US4036885A Method for decomposing an aromatic aldehyde-hydrogen fluoride-boron fluoride complex 失效
标题翻译：分解芳香醛 - 氟化氢 - 氟化硼配合物的方法
公开(公告)号：US4036885A
公开(公告)日：1977-07-19
申请号：US654625
申请日：1976-02-02
申请人： Susumu Fujiyama , Minoru Takagawa , Shiro Kajiyama
发明人： Susumu Fujiyama , Minoru Takagawa , Shiro Kajiyama
IPC分类号： C07C45/83 , C07C45/85 , C07C45/24
CPC分类号： C07C45/83 , C07C45/85
摘要： This invention relates to a two-step method for decomposing an aromatic aldehyde-hydrogen fluoride-boron trifluoride complex in the presence of benzene as a diluent to obtain an aromatic aldehyde, hydrogen fluoride and boron trifluoride separately without causing any change in the quality of the aromatic aldehyde or without forming undesirable byproducts.
摘要翻译：本发明涉及一种在苯作为稀释剂存在下分解芳族醛 - 氟化氢 - 三氟化硼配合物的二步法，以分别得到芳族醛，氟化氢和三氟化硼，而不会导致任何质量变化芳香醛或不形成不期望的副产物。

9. 发明授权

US3962343A Method for decomposing an aromatic aldehyde-hydrogen fluoride-boron fluoride complex 失效
标题翻译：分解芳香醛 - 氟化氢 - 氟化硼配合物的方法
公开(公告)号：US3962343A
公开(公告)日：1976-06-08
申请号：US468025
申请日：1974-05-08
申请人： Susumu Fujiyama , Minoru Takagawa , Shiro Kajiyama
发明人： Susumu Fujiyama , Minoru Takagawa , Shiro Kajiyama
IPC分类号： C07C45/51 , B01J27/32 , B01J38/56 , C01B7/19 , C01B35/06 , C07C45/00 , C07C45/49 , C07C45/83 , C07C45/85 , C07C47/52 , C07C67/00 , C07C45/24
CPC分类号： C07C45/85 , C07C45/00 , C07C45/49 , C07C45/83
摘要： This invention relates to a two-step method for decomposing an aromatic aldehyde-hydrogen fluoride-boron trifluoride complex in the presence of benzene as a diluent to obtain an aromatic aldehyde, hydrogen fluoride and boron trifluoride separately without causing any change in the quality of the aromatic aldehyde or without forming undesirable byproducts.
摘要翻译：本发明涉及一种在苯作为稀释剂存在下分解芳族醛 - 氟化氢 - 三氟化硼配合物的二步法，以分别得到芳族醛，氟化氢和三氟化硼，而不会导致任何质量变化芳香醛或不形成不期望的副产物。

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