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    • 1. 发明专利
    • Treatment of exhaust gas from vacuum degassing installation
    • 从真空脱盐装置处理排气
    • JPS6119727A
    • 1986-01-28
    • JP13862684
    • 1984-07-04
    • Sumitomo Metal Ind Ltd
    • TAKAHASHI TSUTOMUMARUKAWA YUUJIYOU
    • B22D11/10B22D11/106B22D11/112B22D11/113B22D11/116C21C7/10F27D17/00
    • C21C7/10Y02P10/122
    • PURPOSE:To synthetically reduce steel manufacturing cost, by separating the exhaust gaseous mixture of Ar and CO2 recovered from a vacuum degassing apparatus into Ar and CO2 and respectively using Ar and CO2 in a continuous casting tundish and the vacuum degassing apparatus. CONSTITUTION:The molten steel 4 in a ladle 3 decarburized under vacuum in a vacuum tank 1 having a sucking-up pipe 2-1 and a discharge pipe 2-2 and recirculated to the ladle 3 to perform vacuum decarburization refining. In this case, the gaseous mixture consisting of the Ar-gas used in the sucking-up pipe 2-1 and decarburized CO2-gas by O2 from an oxygen blow pipe 7 is supplied to a condenser 10 to remove air therein and introduced into an Ar separation apparatus 19 to be separated into Ar and CO2. The Ar-gas 35 is used in the tundish of a continuous casting apparatus through a gas holder 21. The separated CO2-gas 26 is recirculated to the vacuum degassing apparatus through a CO2-gas holder 24 and used as the seal gas of the top part and exhaust port part of the vacuum tank 1 and an alloy adding apparatus 6.
    • 目的:为了综合降低钢铁制造成本,将从真空脱气装置回收的Ar和二氧化碳的废气混合物分离成Ar和CO2,并分别在连续铸造中间包和真空脱气装置中分别使用Ar和CO2。 构成:在具有吸引管2-1和排出管2-2的真空槽1中真空脱碳的钢水包3中的钢水4,再循环到钢包3进行真空脱碳精炼。 在这种情况下,将由吸入管2-1中使用的Ar气体和来自氧气吹送管7的O2的脱碳的CO 2气体组成的气体混合物供给到冷凝器10,以将其中的空气导入到 Ar分离装置19分离成Ar和CO 2。 Ar气体35通过气体保持器21用于连续铸造设备的中间包中。分离的CO 2气体26通过CO 2气体保持器24再循环到真空脱气装置中并用作顶部的密封气体 真空槽1的一部分和排气口部分以及合金添加装置6。
    • 2. 发明专利
    • Treatment of waste gas from vacuum degassing equipment
    • 从真空脱水设备处理废气
    • JPS619513A
    • 1986-01-17
    • JP12952584
    • 1984-06-22
    • Kyodo Sanso KkSumitomo Metal Ind Ltd
    • TAKAHASHI TSUTOMUMARUKAWA YUUJIYOUDEN TAKAHIRO
    • C21C7/10F27D17/00
    • C21C7/10
    • PURPOSE:To recover Ar in high purity and at low cost and to reduce the cost of molten steel treatment by using water freed of dissolved air as the water for cooling a condenser of an evacuation apparatus wherein Ar is separated and recovered from the waste gas of the vacuum degasing equipment, and circulated and reused. CONSTITUTION:An inert gas 5' such as Ar is blown into suction pipe 2-1 at the lower part of a vacuum vessel 1, and molten steel 4 in a ladle 3 is successively sucked and continuously degasified. In this case, the inside of the vessel 1 is kept at 1-100mm.Hg, and the recovery of Ar is improved by reducing the N2 content in the waste gas from the vacuum degasing equipment. Namely, water freed of dissolved air in an evacuation apparatus is used as the water for cooling the condenser of the evacuation apparatus in order to reduce the N2 content in the waste gas. Besides, the waste gas condensed with the dissolved air-free water is stored temporarily in a storage tank, and then Ar is separated in an AR separator. The recovered Ar is circulated and reused as the gas for circulating molten steel, cooling the O2 lance, and sealing.
    • 目的:以高纯度和低成本回收Ar,并通过使用除去溶解空气的水来降低钢水处理成本,作为用于冷却排气装置的冷凝器的水,其中Ar从废气中分离回收 真空脱气设备,循环利用。 构成:将惰性气体5'如“Ar”在真空容器1的下部吹入吸入管2-1中,钢包3中的钢水4被连续地吸入并连续脱气。 在这种情况下,容器1的内部保持在1-100mm.Hg,并且通过减少来自真空脱气设备的废气中的N 2含量来提高Ar的回收率。 也就是说,为了减少废气中的N 2含量,使用在排气装置中排出溶解空气的水作为用于冷却排气装置的冷凝器的水。 此外,与溶解的无空气水一起冷凝的废气临时储存在储罐中,然后在AR分离器中分离Ar。 回收的Ar循环和再利用作为用于循环钢水的气体,冷却O2喷枪和密封。
    • 3. 发明专利
    • Refining method in converter
    • 转换器中的精炼方法
    • JPS5763613A
    • 1982-04-17
    • JP13718180
    • 1980-09-30
    • Sumitomo Metal Ind Ltd
    • HIROKI NOBUYOSHIMARUKAWA YUUJIYOUUEKI HIROMITSUIKEMIYA HIROYUKISHIROTA YOSHIYASU
    • C21C5/28C21C5/30C21C5/32
    • C21C5/32
    • PURPOSE:To perform the accurate control of the final carbon content and to attain an accurate hit of the tapping temp. by adding a substance which generates heat by the reaction with oxygen to molten steel in a converter at a suitable time when pretreated molten iron is charged into the converter to carry out oxygen blowing. CONSTITUTION:Molten iron subjected to a pretreatment such as dephosphorization is charged into a converter 1, a lance 3 is put in the converter 1 from the uppper opening, and by spraying oxygen on the molten iron, oxygen blowing is carried out. A hopper 4 is supplied with a substance which generates heat by the reaction with oxygen, e.g. a heat compensating additive such as an Fe-Si alloy, metallic Al, coke or coal, and the substance is added to molten steel in the converter 1 at a suitable time after starting the blowing. This additive generates heat by the reaction with oxygen and raises the temp. of the molten steel.
    • 目的:要精确控制最终的碳含量,并获得精确的攻丝温度。 通过在将预处理的铁水装入转炉中以进行吹氧的适当时间,在转炉中加入通过与氧气的反应产生热量的钢液体转化为钢水的物质。 构成:将经过预处理如脱磷的熔融铁装入转炉1中,将喷枪3从上游开口放入转炉1中,并通过在铁水上喷氧,进行吹氧。 向料斗4供给通过与氧的反应产生热量的物质,例如, 诸如Fe-Si合金,金属Al,焦炭或煤的热补偿添加剂,并且在开始吹制之后的合适时间将该物质加入到转炉1中的钢水中。 该添加剂通过与氧的反应产生热量,并提高温度。 的钢水。
    • 4. 发明专利
    • Refining method for converter
    • 转换器精炼方法
    • JPS5757814A
    • 1982-04-07
    • JP13098380
    • 1980-09-20
    • Sumitomo Metal Ind Ltd
    • HIROKI NOBUYOSHIMARUKAWA YUUJIYOUUEKI HIROMITSUIKEMIYA HIROYUKISHIROTA YOSHIYASU
    • C21C5/28C21C5/35
    • C21C5/35
    • PURPOSE:To make the use of inexpensive ore possible by charging pretreated molten iron into aconverter, and adding materials contg. Mn, Cr or Ni during oxygen blowing without adding any slag making agent thereby controlling the component concn. thereof. CONSTITUTION:The molten iron which is beforehand subjected to desiliconization, dephosphorization, and desulfurization is charged into a composite blowing furnace 1, and a lance 3 is inserted vertically through the upper opening thereof to blow gaseous pure oxygen to the molten metal, whereby oxygen blowing is accomplished. Mn-contg. materials, Cr-contg. materials or Ni-contg. materials which are crushed to lumps are contained in a hopper 4, and a slag making agent such as quick lime is contained in a hopper 6. At the suitable point of time after the start of the oxygen blowing, Mn ore and the like are charged into the furnace 1. The slag making agent is not added or if necessary, a small amt. thereof is added. An inert gas is introduced through a tyere 2 to stir the steel bath. Thereby, the concns. of Mn, Cr, Ni components of the molten iron are controlled by using inexpensive ore.
    • 目的:为了通过将预处理的铁水装入逆变器来使用廉价的矿石,并添加材料。 Mn,Cr或Ni,而不添加任何造渣剂,从而控制组分浓度。 其中。 构成:将预先进行脱硅,脱磷,脱硫的铁水装入复合式吹风炉1中,将喷枪3的上部开口垂直地插入,将气态纯氧吹向熔融金属,由此吹入氧气 完成了 Mn-contg 材料,Cr-contg。 材料或Ni-contg。 粉碎成块的材料被包含在料斗4中,并且渣斗6中包含诸如生石灰的造渣剂。在开始吹氧之后的合适时间点,向Mn矿石等加料 进入炉子1.不添加造渣剂,或者如果需要,添加小量的。 添加。 将惰性气体通过搅拌器2引入搅拌器中。 因此, 通过使用廉价的矿石来控制铁水的Mn,Cr,Ni成分。
    • 5. 发明专利
    • Discharging method of slag from mixer car
    • 从混合器汽车排出的排渣方法
    • JPS59208008A
    • 1984-11-26
    • JP8394283
    • 1983-05-12
    • Sumitomo Metal Ind Ltd
    • MARUKAWA YUUJIYOUKATOU HIROKATSUYOSHIDA SHIYUUJI
    • C21C1/06
    • C21C1/06
    • PURPOSE:To discharge surely the slag from the inside of a mixer car by knowing the approach of the level of a molten iron to the aperture of the mixer car from the signal of a magnetic flux type molten iron detector provided alongside the aperture and to stop tilting of the mixer car. CONSTITUTION:A magnetic flux type molten iron detector is provided alongside the aperture 2 of a mixer car and an AC power source 8 is applied to a signal transmitting coil 3 to generate a magnetic flux 9. An induced voltage is generated in a signal receiving coil 4 by the flux 9. While the level of a molten iron 7 is measured with the detector, the mixer car 1 is tilted to discharge slag therefrom. The approach of the level of the molten iron 7 to the aperture 2 is known from the increase in the output voltage of the coil 4 and the tilting of the car 1 is stopped just before the molten iron 7 flows out from the aperture 2. The slag in the car 1 is surely discharged by the above-mentioned method.
    • 目的:为了从混合器车内部排出炉渣,必须从围绕孔径的磁通式铁水检测器的信号中知道将铁水平接近混合器车厢的孔口并停止 搅拌车倾斜。 构成:在混合器轿厢的孔2旁边设置磁通式铁水检测器,并且将AC电源8施加到信号传输线圈3以产生磁通量9.在信号接收线圈中产生感应电压 当用检测器测量铁水7的水平时,搅拌车1倾斜以从其中排出炉渣。 由于线圈4的输出电压的增加,铁水7向孔2的高度的接近是已知的,并且在铁水7从孔2流出之前轿厢1的倾斜停止。 通过上述方法可靠地排出轿厢1中的渣。
    • 6. 发明专利
    • Separating and recovering method for zn component from substance containing zn
    • 来自含有ZN的物质的ZN组分的分离和回收方法
    • JPS57120630A
    • 1982-07-27
    • JP605681
    • 1981-01-19
    • Sumitomo Metal Ind LtdTaenaka Kogyo Kk
    • HASHIMOTO TAKAOMARUKAWA YUUJIYOUTSUTSUMI MASAKATSUHIDAKA CHIKARA
    • C22B19/20C01G9/00C22B19/32C25C1/16
    • Y02P10/234
    • PURPOSE: To separate and recover Zn at a low cost by adding an aqueous ammonium thiocyanate soln. to wet separate Zn as a Zn(SCN)
      2 soln., crystallizing Zn(SCN)
      2 by cooling, and carrying out solid-liq. separation.
      CONSTITUTION: To a substance contg. Zn such as blast furnace dust or converter dust produced in an iron mill is added an aqueous ammonium thiocyanate soln. such as rhodane waste water discharged from a process for desulfurizing waste gas from a coke oven. They are agitated with an agitator and filtered to extract Zn as a Zn(SCN)
      2 soln. By cooling this extacted soln., Zn(SCN)
      2 is crystallized and separated. The crystallized Zn(SCN)
      2 is oxidized to ZnO, the ZnO is dissolved in an org. acid, and the resulting soln. is electrolyzed to recover Zn.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:通过添加硫氰酸铵水溶液,以低成本分离和回收Zn。 将Zn作为Zn(SCN)2溶液进行湿式分离,通过冷却使Zn(SCN)2结晶,并进行固体锂离子电池。 分离 构成:对物质的限制 在铁厂生产的高炉粉尘或转炉粉尘等Zn中加入硫氰酸铵水溶液。 例如从焦炉的废气脱硫方法排出的丁烷废水。 用搅拌器搅拌,过滤以Zn(SCN)2溶液萃取Zn。 通过冷却该溶液,使Zn(SCN)2结晶并分离。 将结晶的Zn(SCN)2氧化成ZnO,将ZnO溶解在有机溶剂中。 酸和所得的溶胶。 电解回收锌。
    • 7. 发明专利
    • Desiliconization treatment of molten iron
    • 硬化铁的脱硫处理
    • JPS5763610A
    • 1982-04-17
    • JP13718280
    • 1980-09-30
    • Sumitomo Metal Ind Ltd
    • HIROKI NOBUYOSHIMARUKAWA YUUJIYOUUEKI HIROMITSUIKEMIYA HIROYUKISHIROTA YOSHIYASU
    • C21C1/04
    • PURPOSE: To reduce the content of Si of the molten iron to be subjected to dephosphorization treatment as far as possible by blowing a desiliconizer of iron oxide type together with a carrier gas into the molten iron through a lance inserted therein through a receiving port of a torpedo car in pretreatment of molten iron.
      CONSTITUTION: After a torpedo car 1 is stopped in a prescribed position, a lance 2 is inserted through a receiving port 3, and is immersed to suitable depth in molten iron 10. Thence, a desiliconizer is blown together with gaseous N
      2 or the like as a carrier gas into the molten iron 10 through the lance 2, whereby the molten iron is desiliconized. This desiliconizer is preferably the one of iron oxide type of 60W70% Fe
      2 O
      3 and 15W20% CaO. As a result, the content of Si in the molten iron 10 decreases considerably, the original unit of using the dephosphorizer in dephosphorization treatment is reduced, and the dephosphorization treatment and further the converter refining of post stage are accomplished surely.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:为了尽可能减少要进行脱磷处理的铁水的Si含量,通过将穿过其中的氧化铁类型的脱硅剂与载气一起吹入通过其中的 鱼雷车预处理铁水。 构成:在鱼雷车1停止在规定位置后,将喷枪2插入通过接收口3,并浸入铁水10中适当的深度。然后,脱气剂与气态N 2等一起吹送 载气通过喷枪2进入铁水10,由此使铁水脱硅。 该脱硅剂优选为氧化铁类型为60〜70%的Fe 2 O 3和15〜20%的CaO。 结果,铁水中的Si含量显着降低,脱磷处理中使用脱磷剂的原始单元减少,并且可靠地实现脱磷处理和后期转化器精制。
    • 8. 发明专利
    • Converter refining method
    • 转换器精炼方法
    • JPS5760004A
    • 1982-04-10
    • JP13479780
    • 1980-09-26
    • Sumitomo Metal Ind Ltd
    • HIROKI NOBUYOSHIMARUKAWA YUUJIYOUUEKI HIROMITSUIKEMIYA HIROYUKISHIROTA YOSHIYASU
    • C21C5/32C21C5/35
    • C21C5/35
    • PURPOSE:To decrease watt loss and to improve iron yield by charging molten iron which is beforehand subjected to desiliconization, dephosphorization and desulfurization treatments into a converter, and controlling the ratio between the intrusion depth of the jet of oxygen in the steel bath and the depth of the steel bath at below specific values without adding any slag making agent or with addition of a small amt. thereof. CONSTITUTION:Molten iron which is subjected to pretreatments of desiliconization, dephosphorization and desulfurization is charged into a composite blowing furnace 1t, and without addition of any slag making agent or after a small amt. of the slag making agent of about
    • 目的:通过将预先进行脱硅,脱磷和脱硫处理的铁水装入转炉,降低瓦特损耗并提高铁产量,并控制钢浴中氧气射流入侵深度与深度之比 的钢液在低于特定值的情况下,不添加任何造渣剂或加入少量。 其中。 构成:将进行脱硅,脱磷,脱硫预处理的熔融铁装入复合式吹风炉1t中,不添加任何造渣剂,或小型之后。 的添加量为每公斤铁水约<= 20kg的造渣剂,喷枪3垂直穿过转炉顶部,氧气通过喷枪3吹入铁水中,由此吹氧 完成了 此时,将来自喷枪3的氧喷射入钢浴的侵入深度L与钢槽的深度Lo的比率控制为<= 0.2。
    • 9. 发明专利
    • Recovering method for vanadium from molten pig iron
    • 从硬脂酸铁中回收钒的方法
    • JPS5739109A
    • 1982-03-04
    • JP11508880
    • 1980-08-20
    • Sumitomo Metal Ind Ltd
    • HIROKI NOBUYOSHIMARUKAWA YUUJIYOUUEKI HIROMITSUIKEMIYA HIROYUKISHIROTA YOSHIYASU
    • C22B7/04C01D7/00C21C1/00C21C1/02C21C1/04C22B34/22
    • C21C1/025Y02P10/212
    • PURPOSE:To recover valuable vanadium in a high yield, by adding a slag forming agent with an alkali metal carbonate base to pig iron after removal of slag from the pig iron due to the desiliconization and dephosphorization treatments of it and by recovering vanadium from the formed slag. CONSTITUTION:The slag obtained by the secondarty dephosphorization treatment of pig iron after the desiliconization and primary dephosphorization treatments, is cooled to solidify and then crushed into lumps. The lamps are eluted with hot water. After removal of the residue such SiO2 and Fe, Fe ions such as ferric sulfate are added to the extrate to remove S as FeS and then the extrate is further concentrated to remove Na2CO3 as crystal. Subsequently, a Ca compound such as CaO is added to the extrate to separate P as Ca3(PO4)2 and hen an ammonium compound such as (NH4)2SO4 is added to the extrate to precipitate NH4VO3, which is heated and decomposed to form V2O5. The V2O5 is reduced by Al and pure vanadium is recovered.
    • 目的:为了从高产量中回收有价值的钒,通过在生铁中去除炉渣后,将生成的碱金属碳酸盐底渣添加到生铁中,由于其脱硅和脱磷处理,并从形成的钒中回收钒 矿渣。 构成:通过脱硅和初次脱磷处理后的生铁二次脱磷处理得到的炉渣冷却固化,然后粉碎成块状。 灯用热水洗脱。 在除去残余物如SiO 2和Fe之后,将Fe离子如硫酸铁加入到萃取物中以除去S作为FeS,然后进一步浓缩以除去作为晶体的Na 2 CO 3。 随后,将钙化合物如CaO加入到Ca(PO 4)2中,并将铵化合物如(NH 4)2 SO 4加入到该萃取物中以沉淀出NH4VO3,将其加热分解形成V 2 O 5 。 V2O5被Al还原,回收纯钒。
    • 10. 发明专利
    • Sand material for sand blast use
    • SAND BLAST使用的材料
    • JPS54146096A
    • 1979-11-14
    • JP5481978
    • 1978-05-08
    • Sumitomo Metal Ind Ltd
    • MARUKAWA YUUJIYOUKANBAYASHI TAKAYUKI
    • C21C5/28B24C11/00C21C5/00F27D15/00
    • PURPOSE: To improve problems of environmental sanitation and at the same time to make magnetic recovery possible and increase efficiency, by using as sand material for sand blast use the pulverized converter slag, which is obtained by pulverizing converter slag, which is produced as a by-product in steel making by a converter.
      CONSTITUTION: Melted converter slag produced in a converter is contained in a tundish. Then, it is discharged from an outlet provided in the lower part of a tundish. At this time, from the nozzle provided at the end in the lower part near the tundish, oxygen-rich compressed air is blown to the flowing melted slag, and then the slag is cooled suddenly and is made to scatter; and thereby pulverized converter slag is obtained. The specific gravity of this pulverized slag is 2 to 3. By this, the time for sand blast processing can be shortened. Since FeO, etc. are properly oxidized, it is easy to recover them with a magnet.
      COPYRIGHT: (C)1979,JPO&Japio
    • 目的:为了改善环境卫生问题,同时要进行磁力恢复,提高效率,通过使用沙尘作为沙尘,使用通过粉碎转炉炉渣获得的粉碎的转炉渣,其是以 - 转炉炼钢产品。 构成:转炉中生产的熔融转炉炉渣包含在中间包中。 然后,从设置在中间包下部的出口排出。 此时,从位于中间包附近的下部的端部的喷嘴,向流动的熔融炉渣吹入富氧压缩空气,然后使炉渣突然冷却并使其散开; 从而获得粉碎的转炉渣。 该粉碎渣的比重为2比3,可以缩短喷砂处理的时间。 由于FeO等被适当氧化,所以很容易用磁铁回收它们。