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1. 发明授权

US4217309A Process for producing methacrolein 失效
标题翻译：生产异丁烯醛的方法
公开(公告)号：US4217309A
公开(公告)日：1980-08-12
申请号：US15903
申请日：1979-02-28
申请人： Sumio Umemura , Kyoji Ohdan , Kenichi Suzuki , Yasuo Bando , Terumi Hisayuki
发明人： Sumio Umemura , Kyoji Ohdan , Kenichi Suzuki , Yasuo Bando , Terumi Hisayuki
IPC分类号： B01J23/887 , B01J23/89 , C07C5/48 , C07C45/35 , C07C45/04
CPC分类号： C07C5/48 , B01J23/8877 , B01J23/8993 , C07C45/35 , B01J2523/00
摘要： Methacrolein is produced in a high yield by catalytically oxidizing isobutylene at a temperature of from 250.degree. to 500.degree. C. by using a catalyst represented by the formula:Mo.sub.a Co.sub.b Fe.sub.c Bi.sub.d Cs.sub.e X.sub.f Y.sub.g O.sub.hwherein X is either both vanadium and palladium, Y is at least one member selected from titanium, nickel, tin and zirconium, a=12, b=2-12, c=0.5-7, d=0.1-5, e=0.0005-0.5, f=0.01-2, g=0-5 and h is a positive number proportional to the number of oxygen atoms satisfying the average valency of the metal atoms stated in the formula, which catalyst has a high resistance to compression and abrasion and exhibits a high catalytic efficiency, mechanical strength and durability.
摘要翻译：通过使用由式MoaCobFecBidCseXfYgOh表示的催化剂，在250℃至500℃的温度下催化氧化异丁烯，以高产率生产甲基丙烯醛，其中X既是钒又是钯，Y是至少一种选自钛，镍，锡和锆，a = 12，b = 2-12，c = 0.5-7，d = 0.1-5，e = 0.0005-0.5，f = 0.01-2，g = 0-5，h为与氧原子数成比例的正数，其满足式中金属原子的平均价，该催化剂具有高抗压缩和耐磨性，并且具有高催化效率，机械强度和耐久性。

2. 发明授权

US4171328A Catalytic oxidation of isobutylene 失效
标题翻译：异丁烯的催化氧化
公开(公告)号：US4171328A
公开(公告)日：1979-10-16
申请号：US917793
申请日：1978-06-22
申请人： Sumio Umemura , Kyoji Ohdan , Kenichi Suzuki , Terumi Hisayuki
发明人： Sumio Umemura , Kyoji Ohdan , Kenichi Suzuki , Terumi Hisayuki
IPC分类号： C07C47/22 , B01J23/00 , B01J23/887 , C07B61/00 , C07C45/00 , C07C45/35 , C07C67/00 , C07C45/02
CPC分类号： B01J23/8876 , C07C45/35 , B01J2523/00
摘要： Isobutylene is catalytically oxidized in the vapor phase with molecular oxygen to form methacrolein. The catalyst used consists essentially of metal oxides and is represented by the formula:Mo.sub.a Bi.sub.b Fe.sub.c Co.sub.d Zr.sub.e X.sub.f Ti.sub.g O.sub.hwherein Mo=molybdenum, Bi=bismuth, Fe=iron, Co=cobalt, Zr=zirconium, X=calcium and/or zinc, Ti=titanium and O=oxygen, and the subscripts indicating the atomic ratios of the respective metals to bismuth are: a=5-20, b=1, c=0.2-5, d=1-10, e=0.01-2, f=0.01-2, and g=0.01-1. The catalyst exhibits little or no reduction in mechanical strength during the oxidation reaction and results in an enhanced yield of methacrolein.
摘要翻译：异丁烯在气相中用分子氧催化氧化形成甲基丙烯醛。所使用的催化剂基本上由金属氧化物组成，并由下式表示：MoaBibFecCodZreXfTigOh WHEREIN Mo =钼，Bi =铋，Fe =铁，Co =钴，Zr =锆，X =钙和/或锌，Ti =钛和O =氧，表示各金属与铋的原子比的下标为：a = 5-20，b = 1，c = 0.2-5，d = 1-10，e = 0.01-2，f = 2，g = 0.01-1。该催化剂在氧化反应期间几乎没有或没有降低机械强度，并导致甲基丙烯醛的收率提高。

3. 发明授权

US4364844A Catalyst for production of unsaturated carboxylic acid, preparation thereof and production of unsaturated carboxylic acid 失效
标题翻译：用于生产不饱和羧酸的催化剂，其制备和不饱和羧酸的生产
公开(公告)号：US4364844A
公开(公告)日：1982-12-21
申请号：US184178
申请日：1980-09-04
申请人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Kenichi Suzuki , Yasuo Bando , Toshihiko Hogami , Masataka Fuginaga
发明人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Kenichi Suzuki , Yasuo Bando , Toshihiko Hogami , Masataka Fuginaga
IPC分类号： C07C51/235 , B01J21/04 , B01J23/28 , B01J27/198 , B01J27/199 , B01J27/224 , B01J35/10 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , B01J27/18 , B01J21/00
CPC分类号： C07C51/252 , B01J23/002 , B01J23/28 , B01J27/199 , B01J2523/00
摘要： An improved catalyst suitable for use in the production of an unsaturated carboxylic acid by the catalytic vapor phase oxidation of an unsaturated aldehyde is provided. In this catalyst, a heat-resistant inorganic substance, such as alumina, silica-alumina and silicon carbide, having a particle diameter of 3 through 10 mm, an apparent porosity of 35 through 60%, a water absorption of 20 through 50%, an average pore diameter of not less than 40 microns, a specific surface area of not more than 2 m.sup.2 /g and a bulk specific gravity of 1.5 through 2.0 is used for supporting a composition containing molybdenum, phosphorus, vanadium and the alkali metals. The use of the above-mentioned carrier results in the advantages that the unsaturated carboxylic acid, such as methacrylic acid, can be selectively produced from the unsaturated aldehyde at a high yield and that the mechanical strength of the catalyst is remarkably improved.
摘要翻译：提供了适用于通过不饱和醛的催化气相氧化生产不饱和羧酸的改进的催化剂。在该催化剂中，将粒径为3〜10mm，表观孔隙率为35〜60％，吸水率为20〜50％的耐热无机物质如氧化铝，二氧化硅 - 氧化铝和碳化硅，平均孔径不小于40微米，比表面积不超过2m 2 / g，堆积比重为1.5至2.0，用于支撑含有钼，磷，钒和碱金属的组合物。通过使用上述载体，可以得到不饱和羧酸（如甲基丙烯酸）可以高收率地从不饱和醛中选择性地制备的优点，催化剂的机械强度显着提高。

4. 发明授权

US4110350A Catalytic oxidative process for producing maleic anhydride 失效
标题翻译：用于生产马来酸酐的催化氧化方法
公开(公告)号：US4110350A
公开(公告)日：1978-08-29
申请号：US816916
申请日：1977-07-19
申请人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Harumi Ikezawa
发明人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Harumi Ikezawa
IPC分类号： B01J23/16 , B01J23/22 , B01J23/847 , B01J27/198 , C07C51/25 , C07D307/60
CPC分类号： C07C51/25 , B01J23/16 , B01J23/22 , B01J23/8472 , B01J27/198 , C07C51/252
摘要： Unsaturated hydrocarbons having 4 to 6 carbon atoms are catalytically oxidized into maleic anhydride by using a catalyst, which consists essentially of oxides of (A) vanadium, (B) phosphorus, (C) titanium and (D) optionally at least one element selected from sodium, calcium, magnesium, iron, zirconium, boron, manganese, silver and molybdenum in the atomic ratios defined by the following formulaVP.sub.a Ti.sub.b X.sub.c O.sub.dwherein X is the element (D) set forth above and a=1.0 to 5.0, b=2.0 to 12.0 and c=0 to 1.0, and which catalyst is prepared by calcining a mixture of a vanadium-containing compound and titanium dioxide at a temperature of 650.degree. C. to 1,500.degree. C., incorporating into the mixture a phosphorus-containing compound and optionally the element "X"-containing compound and, then, heating the resulting mixture.
摘要翻译：具有4-6个碳原子的不饱和烃通过使用催化剂催化氧化成马来酸酐，所述催化剂基本上由（A）钒，（B）磷，（C）钛和（D）的氧化物组成，任选地至少一种选自钠，钙，镁，铁，锆，硼，锰，银和钼，其原子比由下列化学式定义：VPaTibXcOd WHEREIN X是上述元素（D），a = 1.0至5.0，b = 2.0至12.0 并且c = 0至1.0，并且通过在650℃至1500℃的温度下煅烧含钒化合物和二氧化钛的混合物来制备该催化剂，将含磷化合物和任选地含有元素“X”的化合物，然后加热所得混合物。

5. 发明授权

US4006167A Vapor phase oxidation of unsaturated aliphatic hydrocarbon to maleic anhydride using a catalyst consisting essentially of the oxides of vanadium, phosphorous, zirconium, and manganese 失效
标题翻译：使用基本上由钒，磷，锆和锰的氧化物组成的催化剂将不饱和脂族烃气相氧化成马来酸酐
公开(公告)号：US4006167A
公开(公告)日：1977-02-01
申请号：US589518
申请日：1975-06-23
申请人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Harumi Ikezawa
发明人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Harumi Ikezawa
IPC分类号： C07C51/25 , C07D307/60
CPC分类号： C07C51/252
摘要： Unsaturated hydrocarbons having 4 to 6 carbon atoms are catalytically oxidized into maleic anhydride at relatively low temperatures in the range of 300.degree. C to 450.degree. C. The catalyst used consists essentially of oxides of vanadium, phosphorus, zirconium, and at least one element selected from manganese, boron, cadmium, silver, bismuth and zinc.
摘要翻译：具有4-6个碳原子的不饱和烃在300℃至450℃的较低温度下被催化氧化成马来酸酐。所使用的催化剂基本上由钒，磷，锆和至少一种元素选择的氧化物组成来自锰，硼，镉，银，铋和锌。

6. 发明授权

US4177161A Catalytic oxidative process for producing maleic anhydride 失效
标题翻译：用于生产马来酸酐的催化氧化方法
公开(公告)号：US4177161A
公开(公告)日：1979-12-04
申请号：US902935
申请日：1978-05-05
申请人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Harumi Ikezawa
发明人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Harumi Ikezawa
IPC分类号： B01J23/16 , B01J23/22 , B01J23/847 , B01J27/198 , C07C51/25 , B01J27/14
CPC分类号： C07C51/25 , B01J23/16 , B01J23/22 , B01J23/8472 , B01J27/198 , C07C51/252
摘要： Unsaturated hydrocarbons having 4 to 6 carbon atoms are catalytically oxidized into maleic anhydride by using a catalyst, which consists essentially of oxides of (A) vanadium, (B) phosphorus, (C) titanium and (D) optionally at least one element selected from sodium, calcium, magnesium, iron, zirconium, boron, manganese, silver and molybdenum in the atomic ratios defined by the following formulaVP.sub.a Ti.sub.b X.sub.c O.sub.dwherein X is the element (D) set forth above and a=1.0 to 5.0, b=2.0 to 12.0 and c=0 to 1.0, and which catalyst is prepared by calcining a mixture of a vanadium-containing compound and titanium dioxide at a temperature of 650.degree. C. to 1,500.degree. C., incorporating into the mixture a phosphorus-containing compound and optionally the element "X"-containing compound and, then, heating the resulting mixture.
摘要翻译：具有4-6个碳原子的不饱和烃通过使用催化剂催化氧化成马来酸酐，所述催化剂基本上由（A）钒，（B）磷，（C）钛和（D）的氧化物组成，任选地至少一种选自钠，钙，镁，铁，锆，硼，锰，银和钼，其原子比由下式VPaTibXcOd定义，其中X是上述元素（D），a = 1.0至5.0，b = 2.0至12.0 并且c = 0至1.0，并且通过在650℃至1500℃的温度下煅烧含钒化合物和二氧化钛的混合物来制备该催化剂，将含磷化合物和任选地含有元素“X”的化合物，然后加热所得混合物。

7. 发明授权

US4154703A Process for the preparation of maleic anhydride catalyst 失效
标题翻译：马来酸酐催化剂的制备方法
公开(公告)号：US4154703A
公开(公告)日：1979-05-15
申请号：US820338
申请日：1977-07-29
申请人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Masataka Fuzinaga
发明人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Yasuo Bando , Masataka Fuzinaga
IPC分类号： C07D307/60 , B01J23/00 , B01J23/22 , B01J27/00 , B01J31/36 , C07B61/00 , C07C51/25 , B01J27/14 , C07D307/89
CPC分类号： B01J31/0258 , B01J23/22 , B01J31/0259 , B01J31/0267 , B01J31/36 , B01J31/38 , C07C51/252 , B01J2231/70 , B01J31/24
摘要： Maleic anhydride is prepared by the catalytic oxidation of unsaturated hydrocarbons having 4 to 6 carbon atoms, at a temperature of from 350.degree. to 500.degree. C., in the presence of a catalyst which is produced by a method wherein a mixture of a titanium oxide and a vanadium compound in an atomic ratio of from 1 to 15 is calcined at a temperature of from 630.degree. to 1000.degree. C. to prepare a precursory catalyst, and wherein a gas mixture containing an organic phosphorus compound and a carrier gas is brought into contact with a mass of the percursory catalyst at a supply rate of the phosphorus compound being from 0.01 to 10 millimoles/hr per 1 ml of the mass of the percursory catalyst and at a temperature of from 350.degree. to 600.degree. C. during when a total amount of from 0.3 to 30 millimoles of the phosphorus compound per 1 ml of the mass of the precursory catalyst passes through the mass of the precursory catalyst.
摘要翻译：马来酸酐通过催化氧化具有4-6个碳原子的不饱和烃，在350-500℃的温度下，在催化剂的存在下制备，所述催化剂是通过以下方法制备的，其中将氧化钛将原子比为1〜15的钒化合物在630〜1000℃的温度下煅烧，制备前体催化剂，将含有有机磷化合物和载气的气体混合物以每1毫升质量催化剂的磷化合物的供给速率为0.01至10毫摩尔/小时，并且在350℃至600℃的温度下，与一批质量的催化剂接触，总量为0.3至30毫摩尔的磷化合物/ 1毫升质量的前体催化剂通过前体催化剂的质量。

8. 发明授权

US4256914A Catalytic oxidation of methacrolein 失效
标题翻译：甲基丙烯醛的催化氧化
公开(公告)号：US4256914A
公开(公告)日：1981-03-17
申请号：US68198
申请日：1979-08-17
申请人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Kenichi Suzuki , Toshihiko Hogami , Masataka Fuginaga
发明人： Sumio Umemura , Kyoji Ohdan , Fumihiko Sakai , Kenichi Suzuki , Toshihiko Hogami , Masataka Fuginaga
IPC分类号： B01J27/00 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00
CPC分类号： C07C51/252
摘要： Methacrolein is catalytically oxidized into methacrylic acid in the vapor phase at a temperature of 200.degree. to 450.degree. C. The catalyst used is comprised of molybdenum, phosphorus, potassium and/or cesium, vanadium, silver and/or tellurium, and oxygen, and represented by the formula:Mo.sub.12 P.sub.a A.sub.b V.sub.c X.sub.d O.sub.ewherein A is K and/or Cs and X is Ag and/or Te, and a=0.5-5, b=0.1-4, c=0.05-3, d=0.001-2 and e is a positive number required by the valence states of the other elements present.
摘要翻译：所用的催化剂由钼，磷，钾和/或铯，钒，银和/或碲以及氧组成，并且气相中的甲基丙烯酸在气相中催化氧化成甲基丙烯酸。由式表示：Mo12PaAbVcXdOe其中A是K和/或Cs和X是Ag和/或Te，a = 0.5-5，b = 0.1-4，c = 0.05-3，d = 0.001-2，e是其他元素的价态所要求的正数。

9. 发明授权

US4045478A Method for the preparation of methacrylic acid 失效
标题翻译：制备甲基丙烯酸的方法
公开(公告)号：US4045478A
公开(公告)日：1977-08-30
申请号：US658909
申请日：1976-02-18
申请人： Sumio Umemura , Kyoji Ohdan , Kenichi Suzuki , Fumio Adachi
发明人： Sumio Umemura , Kyoji Ohdan , Kenichi Suzuki , Fumio Adachi
IPC分类号： B01J23/28 , B01J27/186 , C07C51/25 , C07C57/055 , C07C51/32
CPC分类号： B01J27/186 , B01J23/28 , C07C51/252
摘要： Methacrylic acid can be produced from methacrolein with a high reaction percentage of methacrolein and a high selectivity percentage of methacrylic acid, by bringing a reaction feed containing methacrolein and molecular oxygen into contact with an oxidation catalyst at a temperature of 200 to 450.degree. C, the oxidation catalyst comprising oxides of molybdenum, phosphorus, calcium, at least one element selected from the group consisting of arsenic, bismuth, tin, titanium, tantalum and boron and, optionally, at least one element selected from the group consisting of antimony, niobium and magnesium.
摘要翻译：甲基丙烯酸可以通过甲基丙烯醛的高反应百分率和甲基丙烯酸的高选择性百分比通过使含有甲基丙烯醛和分子氧的反应进料与氧化催化剂在200至450℃的温度下接触来生产，氧化催化剂，其包含钼，磷，钙的氧化物，选自砷，铋，锡，钛，钽和硼中的至少一种元素，以及任选的至少一种选自锑，铌和镁。

10. 发明授权

US4290922A Ammoxidation catalyst for the production of acrylonitrile from propylene and process for producing the same 失效
标题翻译：用于从丙烯生产丙烯腈的氨氧化催化剂及其制备方法
公开(公告)号：US4290922A
公开(公告)日：1981-09-22
申请号：US134053
申请日：1980-03-26
申请人： Sumio Umemura , Kyoji Ohdan , Mikio Hidaka , Toshio Kurafuji
发明人： Sumio Umemura , Kyoji Ohdan , Mikio Hidaka , Toshio Kurafuji
IPC分类号： B01J23/88 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , B01J21/06 , B01J23/24
CPC分类号： B01J23/8872 , B01J23/8876 , B01J23/8877 , B01J23/8878 , C07C253/26 , Y02P20/52
摘要： A catalyst for the ammoxidation of propylene to prepare acrylonitrile with a high yield thereof comprising an oxide composition of the empirical formula (I)Mo.sub.a Co.sub.b Ni.sub.c Fe.sub.d Bi.sub.e V.sub.f Ca.sub.g K.sub.h X.sub.i Si.sub.j O.sub.k (I)wherein X is zirconium and/or chromium, the subscripts a, b, c, d, e, f, g, h, i and j respectively denote the number of the respective atoms of the elements, when a=10, b=0 to 8, c=0 to 8, (b+c)=2 to 10, d=0.3 to 7, e=0.01 to 3, f=0.01 to 2, g=0.01 to 5, h=0.05 to 0.5, i=0 to 2, j=10 to 50, and the subscript k denotes the number of oxygen atoms which satisfies the average valency of the elements other than oxygen and the ratio a:k being in a range of 10:30 to 80, which catalyst is prepared by preparing an aqueous slurry containing respective element-containing compounds, by spray drying the aqueous slurry to prepare a dried solid precursory catalyst and, finally, by calcining the precursory catalyst as a temperature of from 500.degree. to 750.degree. C. to provide an activated catalyst.
摘要翻译：用于丙烯氨氧化以制备丙烯腈的高产率的催化剂，其包含经验式（I）的氧化物组合物，其中X是锆和/或铬，下标a，b，c，d，e的MoaCobNicFedBieVfCagKhXiSijOk（I）当a = 10，b = 0〜8，c = 0〜8，（b + c）= 2〜10时，f，g，h，i，j分别表示各元素的原子数，d = 0.3〜7，e = 0.01〜3，f = 0.01〜2，g = 0.01〜5，h = 0.05〜0.5，i = 0〜2，j = 10〜50，下标k表示氧数原子，其满足除氧之外的元素的平均化合价，a:k的比例在10:30至80的范围内，该催化剂通过制备含有各含元素化合物的含水浆料，通过喷雾干燥水溶液浆料以制备干燥的固体前体催化剂，最后通过在500℃至750℃的温度下煅烧前体催化剂以提供活化的催化剂。

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