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1. 发明申请

US20070010394A1 Process for producing catalyst for methacrylic acid production 审中-公开
标题翻译：生产甲基丙烯酸催化剂的方法
公开(公告)号：US20070010394A1
公开(公告)日：2007-01-11
申请号：US10558501
申请日：2004-05-27
申请人： Sudo Atsushi , Yoshimasa Seo , Tatsuhiko Kurakami
发明人： Sudo Atsushi , Yoshimasa Seo , Tatsuhiko Kurakami
IPC分类号： B01J27/24
CPC分类号： C07C51/235 , B01J23/002 , B01J27/199 , B01J37/0219 , B01J37/0236 , B01J2523/00 , C07C51/252 , C07C51/377 , C07C57/04 , B01J2523/15 , B01J2523/50 , B01J2523/51 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/17
摘要： The object of the present invention is to provide a method for preparing a catalyst for producing methacrylic acid by subjecting methacrolein, isobutyl aldehyde or isobutyric acid to gas phase catalytic oxidation with high yield and high selectivity. A method for preparing a catalyst for producing methacrylic acid by subjecting methacrolein, isobutyl aldehyde or isobutyric acid to gas phase catalytic oxidation, the method comprising: (a) a step of blending compounds each containing any one of Mo, V, P, Cu, Cs or NH4 with water to prepare an aqueous solution or dispersion of the compounds (hereinafter referred to, both included, as a slurry); (b) a step of drying the slurry obtained in the step (a) to obtain a dried slurry; (c) a step of calcining the dried slurry obtained in..the step (b) to obtain a calcined body; (d) a step of filtering a mixture obtained by blending the calcined body obtained in the step (c) with water to separate an aqueous solution and water-insoluble matter; and (e) a step of drying the water-insoluble matter obtained in the step (d) to obtain a dried water-insoluble body.
摘要翻译：本发明的目的是提供一种通过以高产率和高选择性将甲基丙烯醛，异丁醛或异丁酸进行气相催化氧化来制备用于生产甲基丙烯酸的催化剂的方法。一种通过使甲基丙烯醛，异丁醛或异丁酸进行气相催化氧化来制备甲基丙烯酸的催化剂的方法，所述方法包括：（a）将各自含有Mo，V，P，Cu， Cs或NH 4与水反应以制备化合物的水溶液或分散体（以下称为两者，均为浆料）; （b）干燥步骤（a）中获得的浆料以获得干燥的浆料的步骤; （c）煅烧步骤（b）中获得的干燥浆料以获得煅烧体的步骤; （d）将通过将步骤（c）中获得的煅烧体与水混合而获得的混合物与水分离以分离水溶液和水不溶性物质的步骤; 和（e）干燥步骤（d）中获得的水不溶性物质以获得干燥的水不溶性体的步骤。

2. 发明申请

US20110137078A1 Catalyst And Method For Producing Unsaturated Aldehyde And Unsaturated Carboxylic Acid 审中-公开
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂和方法
公开(公告)号：US20110137078A1
公开(公告)日：2011-06-09
申请号：US12994206
申请日：2009-05-25
申请人： Masaki Nakahara , Hideki Sugi , Yoshimasa Seo , Tatsuhiko Kurakami , Hiroyuki Onoue
发明人： Masaki Nakahara , Hideki Sugi , Yoshimasa Seo , Tatsuhiko Kurakami , Hiroyuki Onoue
IPC分类号： C07C51/16 , B01J35/02 , B01J37/02
CPC分类号： C07C51/235 , B01J23/002 , B01J35/026 , B01J37/0215 , B01J37/0217 , B01J2523/00 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/17 , B01J2523/36 , B01J2523/44 , B01J2523/52 , B01J2523/55
摘要： Provided is a catalyst which can prevent a lowering in selectivity for a target product in a gas phase catalytic reaction and has an excellent frictional resistance. A catalyst which is a supported catalyst comprising an inert support that is coated with a catalyst powder, characterized in that the inert support is ring-shaped and has an outer periphery that is curved in the lengthwise direction of the support, and the catalyst is produced by granulation in a moisten environment. The above described catalyst is useful in the gas phase oxidation of propylene, isobutylene, tertiary-butyl alcohol or methyl tertiary-butyl ether to thereby produce an unsaturated aldehyde corresponding thereto, or in the gas phase oxidation of such an unsaturated aldehyde as described above to thereby produce an unsaturated carboxylic acid.
摘要翻译：本发明提供能够防止气相催化反应中的对象物的选择性降低且具有优异的摩擦阻力的催化剂。一种催化剂，其是包含涂覆有催化剂粉末的惰性载体的载体催化剂，其特征在于惰性载体是环状的，并且具有在载体的长度方向上弯曲的外周，并且产生催化剂通过在湿润的环境中制粒。上述催化剂可用于丙烯，异丁烯，叔丁醇或甲基叔丁基醚的气相氧化，从而产生与其对应的不饱和醛，或在如上所述的这种不饱和醛的气相氧化中从而产生不饱和羧酸。

3. 发明授权

US08088947B2 Method for producing methacrolein and/or methacrylic acid 有权
标题翻译：甲基丙烯醛和/或甲基丙烯酸的制备方法
公开(公告)号：US08088947B2
公开(公告)日：2012-01-03
申请号：US12223494
申请日：2007-03-30
申请人： Tatsuhiko Kurakami , Toshitake Kojima , Yoshimasa Seo
发明人： Tatsuhiko Kurakami , Toshitake Kojima , Yoshimasa Seo
IPC分类号： C07C51/12 , C07C51/14 , C07C51/16 , C07C45/00
CPC分类号： C07C45/37 , B01J21/04 , B01J21/12 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J23/8885 , B01J35/0006 , B01J2523/00 , C07C51/23 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/15 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845
摘要： The present invention relates to a method for producing methacrolein and/or methacrylic acid characterized in that the catalyst filling length of a dehydration catalyst layer is 3 to 20% of the catalyst filling length of an oxidation catalyst layer in a method where raw material gas containing gaseous t-butanol is supplied to a fixed-bed multitubular reactor having a dehydration catalyst layer and an oxidation catalyst layer in this order, from the entrance for raw material gas toward the exit, to produce methacrolein and/or methacrylic acid by dehydration reaction and catalytic gas phase oxidation reaction, and the present invention can increase the conventional yield of approximately 80% to 81 to 82% even when a reaction bath temperature is relatively low (approximately 355° C.).
摘要翻译：本发明涉及甲基丙烯醛和/或甲基丙烯酸的制造方法，其特征在于，在含有原料气体的方法中，脱水催化剂层的催化剂填充长度为氧化催化剂层的催化剂填充长度的3〜20％将气态叔丁醇从原料气体入口向出口依次供给具有脱水催化剂层和氧化催化剂层的固定床多管反应器，通过脱水反应生成甲基丙烯醛和/或甲基丙烯酸，催化气相氧化反应，即使反应浴温度相对较低（约355℃），本发明也可将常规产率提高约80％至81％至82％。

4. 发明申请

US20090062564A1 Method for Producing Methacrolein and/or Methacrylic Acid 有权
标题翻译：生产甲基丙烯醛和/或甲基丙烯酸的方法
公开(公告)号：US20090062564A1
公开(公告)日：2009-03-05
申请号：US12223494
申请日：2007-03-30
申请人： Tatsuhiko Kurakami , Toshitake Kojima , Yoshimasa Seo
发明人： Tatsuhiko Kurakami , Toshitake Kojima , Yoshimasa Seo
IPC分类号： C07C51/16 , C07C45/29
CPC分类号： C07C45/37 , B01J21/04 , B01J21/12 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J23/8885 , B01J35/0006 , B01J2523/00 , C07C51/23 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/15 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845
摘要： The present invention relates to a method for producing methacrolein and/or methacrylic acid characterized in that the catalyst filling length of a dehydration catalyst layer is 3 to 20% of the catalyst filling length of an oxidation catalyst layer in a method where raw material gas containing gaseous t-butanol is supplied to a fixed-bed multitubular reactor having a dehydration catalyst layer and an oxidation catalyst layer in this order, from the entrance for raw material gas toward the exit, to produce methacrolein and/or methacrylic acid by dehydration reaction and catalytic gas phase oxidation reaction, and the present invention can increase the conventional yield of approximately 80% to 81 to 82% even when a reaction bath temperature is relatively low (approximately 355° C.).
摘要翻译：本发明涉及甲基丙烯醛和/或甲基丙烯酸的制造方法，其特征在于，在含有原料气体的方法中，脱水催化剂层的催化剂填充长度为氧化催化剂层的催化剂填充长度的3〜20％将气态叔丁醇从原料气体入口向出口依次供给具有脱水催化剂层和氧化催化剂层的固定床多管反应器，通过脱水反应生成甲基丙烯醛和/或甲基丙烯酸，催化气相氧化反应，即使反应浴温度相对较低（约355℃），本发明也可将常规产率提高约80％至81％至82％。

5. 发明授权

US6028220A Producing acrolein and acrylic acid using a supported dual activity molybdenum, iron, and bismuth based catalyst in a fixed bed multitubular reactor 失效
标题翻译：在固定床多管反应器中使用支撑的双活性钼，铁和铋基催化剂生产丙烯醛和丙烯酸
公开(公告)号：US6028220A
公开(公告)日：2000-02-22
申请号：US117461
申请日：1998-07-28
申请人： Koichi Wada , Yoshimasa Seo , Akira Iwamoto , Atsushi Sudo , Fumio Sakai , Kazuo Shiraishi , Hiroyoshi Nowatari
发明人： Koichi Wada , Yoshimasa Seo , Akira Iwamoto , Atsushi Sudo , Fumio Sakai , Kazuo Shiraishi , Hiroyoshi Nowatari
IPC分类号： B01J23/88 , B01J8/06 , B01J23/31 , B01J23/887 , C07B61/00 , C07C27/14 , C07C45/35 , C07C47/22 , C07C51/25 , C07C57/05 , C07C205/00 , C07C51/16
CPC分类号： C07C45/35 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J8/06 , C07C51/252 , B01J2208/025 , B01J2523/00
摘要： The present invention concerns a method for producing acrolein and acrylic acid by carrying out vapor phase catalytic oxidation of propylene with molecular oxygen or a gas containing molecular oxygen using a oxidation catalysts comprising Mo, Bi and Fe as an essentially element and a fixed bed multitubular reactor, which comprisesa) using a plurality of supported catalysts having different activities, which was obtained, for example, by different calcination method in the production process of the supported catalysts,b) setting a catalyst layer in a reaction tube, which is formed by dividing it into plural portions in the tube axial direction, andc) arranging the aforementioned plural supported catalysts in such order that the activity becomes high toward the outlet from the inlet of the material gas in the reaction tube axial direction.According to the present invention, the generation of hot spot can be avoided and over oxidation reaction can be avoided and the acrolein and acrylic acid are produced constantly for a prolonged period of time.
摘要翻译： PCT No.PCT / JP97 / 04402 Sec。 371日期：1998年7月28日 102（e）日期1998年7月28日PCT 1997年12月2日PCT PCT。第WO98 / 24746号公报日期1998年6月11日本发明涉及通过使用包含Mo，Bi和Fe作为基本元素的氧化催化剂，通过用分子氧或含有分子氧的气体进行丙烯的气相催化氧化来生产丙烯醛和丙烯酸的方法，一种固定床多管反应器，其包括a）使用多种活性不同的负载催化剂，其通过例如在负载型催化剂的制备方法中通过不同的煅烧方法获得，b）将催化剂层设置在反应管通过在管轴方向上分成多个部分而形成，以及c）按照反应管轴向从原料气体的入口出口的活性变高的顺序排列上述多个负载型催化剂。根据本发明，可以避免产生热点，可以避免过度氧化反应，并且持续长时间地生产丙烯醛和丙烯酸。

6. 发明授权

US5959143A Catalysts and process for the preparation thereof 失效
标题翻译：催化剂及其制备方法
公开(公告)号：US5959143A
公开(公告)日：1999-09-28
申请号：US737028
申请日：1996-10-30
申请人： Hideki Sugi , Fumio Sakai , Koichi Wada , Kazuo Shiraishi , Toshitake Kojima , Atsushi Umejima , Yoshimasa Seo
发明人： Hideki Sugi , Fumio Sakai , Koichi Wada , Kazuo Shiraishi , Toshitake Kojima , Atsushi Umejima , Yoshimasa Seo
IPC分类号： B01J23/88 , B01J23/00 , B01J23/887 , B01J35/00 , B01J37/00 , B01J37/02 , C07B61/00 , C07C51/25 , C07C57/055 , C07C51/235 , B01J23/22
CPC分类号： B01J37/0045 , B01J23/002 , B01J23/8877 , B01J35/002 , B01J35/1009 , B01J35/108 , C07C51/252 , B01J2523/00 , B01J37/0236
摘要： A catalyst having a high activity and mechanical strength and a process for preparing it are provided. The catalyst comprises molybdenum, vanadium, copper and antimony as essential components. The peak in X-ray diffractometry of the catalytically active component with Cu--K.alpha. line is largest at 22.2.+-.0.30.degree. (2.theta.).
摘要翻译： PCT No.PCT / JP96 / 00506 Sec。 371日期1996年10月30日 102（e）1996年10月30日PCT PCT 1996年3月1日PCT公布。公开号WO96 / 27437 日本1996年9月12日提供具有高活性和机械强度的催化剂及其制备方法。催化剂包括钼，钒，铜和锑作为必需组分。具有Cu-Kα线的催化活性组分的X射线衍射峰值在22.2±0.30°（2θ）处最大。

7. 发明授权

US06762148B2 Catalyst process of making 有权
标题翻译：催化剂制备过程
公开(公告)号：US06762148B2
公开(公告)日：2004-07-13
申请号：US10321955
申请日：2002-12-17
申请人： Junzo Ohishi , Masahiro Senyo , Yoshimasa Seo , Hideki Sugi
发明人： Junzo Ohishi , Masahiro Senyo , Yoshimasa Seo , Hideki Sugi
IPC分类号： B01J2300
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8877 , B01J23/8885 , B01J37/0215 , B01J37/0223 , B01J2523/00 , C07C57/04 , B01J2523/17 , B01J2523/22 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/13 , B01J2523/842 , B01J2523/56
摘要： An object of the present invention is to provide a catalyst that is highly active and has a large mechanical strength. The catalyst of the present invention contains molybdenum, vanadium, copper and antimony as the essential components, being produced by using antimony acetate for an antimony source material and preferably used for producing acrylic acid by vapor-phase catalytic oxidation of acrolein.
摘要翻译：本发明的目的是提供一种高活性且机械强度大的催化剂。本发明的催化剂含有钼，钒，铜，锑作为必要成分，通过使用锑酸锑锑原料制造，优选通过气相催化氧化丙烯醛来生产丙烯酸。

8. 发明授权

US5929275A Catalyst and process for producing unsaturated aldehyde and unsaturated acid 失效
标题翻译：用于生产不饱和醛和不饱和酸的催化剂和方法
公开(公告)号：US5929275A
公开(公告)日：1999-07-27
申请号：US853215
申请日：1997-05-09
申请人： Koichi Wada , Akira Iwamoto , Yoshimasa Seo , Atsusi Sudo , Fumio Sakai , Kazuo Shiraishi , Hideaki Miki
发明人： Koichi Wada , Akira Iwamoto , Yoshimasa Seo , Atsusi Sudo , Fumio Sakai , Kazuo Shiraishi , Hideaki Miki
IPC分类号： B01J23/88 , B01J23/887 , B01J35/08 , B01J37/00 , B01J37/02 , C07B61/00 , C07C27/14 , C07C45/35 , C07C45/37 , C07C45/38 , C07C47/22 , C07C51/25 , C07C51/275 , C07C57/05 , C07C51/16 , B01J23/16 , C07C45/32
CPC分类号： C07C45/37 , B01J23/002 , B01J23/8876 , B01J37/0223 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： A catalyst for the production of unsaturated aldehyde and unsaturated acid, obtained by loading a catalytically active component on a carrier and calcining the loaded catalyst, characterized by an average particle diameter of the catalyst of 4 to 16 mm, an average particle diameter of the carrier of 3 to 12 mm, a calcining temperature of 520 to 600.degree. C. and an amount of the catalytically active component loaded on the carrier of 5 to 80% by weight �weight of the catalytically active component)/(weight of the catalytically active component+weight of the carrier+weight of a strength improver)!, and a process for producing unsaturated aldehyde and unsaturated acid with the catalyst.
摘要翻译：用于生产不饱和醛和不饱和酸的催化剂，其通过将催化活性组分负载在载体上并煅烧负载的催化剂而获得，其特征在于催化剂的平均粒径为4至16mm，载体的平均粒径 3至12mm，煅烧温度为520-600℃，负载在载体上的催化活性组分的量为5-80重量％[催化活性组分的重量] /（催化活性组分的重量）组分+载体重量+强度改进剂的重量）]以及用催化剂生产不饱和醛和不饱和酸的方法。

9. 发明申请

US20070004584A1 Catalyst for oxidation of alkane, process for preparing thereof and process for producing unsaturated oxygen-containing compound 失效
标题翻译：烷烃氧化催化剂，其制备方法和不饱和含氧化合物的制备方法
公开(公告)号：US20070004584A1
公开(公告)日：2007-01-04
申请号：US11494846
申请日：2006-07-28
申请人： Tomoaki Kobayashi , Yoshimasa Seo
发明人： Tomoaki Kobayashi , Yoshimasa Seo
IPC分类号： B01J29/04
CPC分类号： B01J23/002 , B01J23/28 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J2523/00 , C07C45/33 , C07C51/215 , C07C47/22 , C07C47/21 , C07C57/04 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/48 , B01J2523/64 , B01J2523/13 , B01J2523/69 , B01J2523/14 , B01J2523/15
摘要： An object of the present invention is to provide a highly active catalyst for producing an unsaturated oxygen-containing compound from an alkane and the catalyst comprising Mo, V, Ti and Sb or Te as the indispensable active components. The preferable catalyst is represented by formula (1) or (2) as shown below, Mo1.0VaTibXcYdOe (1) Mo1.0VaTibXcYdZfOe (2) wherein X represents Sb or Te; Y represents Nb, W or Zr; Z represents Li, Na, K, Rb, Cs, Mg, Ca or Sr; a, b, c, d, e and f represent atomic ratios of their respective elements, with 0
摘要翻译：本发明的目的是提供一种用于从烷烃生产不饱和含氧化合物的高活性催化剂和包含Mo，V，Ti和Sb或Te作为不可缺少的活性组分的催化剂。优选的催化剂由如下所示的式（1）或（2）表示：<？in-line-formula description =“In-line formula”end =“lead”？> Mo 1.0 （1） -line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> Mo V>> X X X e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e （2）<？in-line-formula description =“In-line formula”end =“tail”？>其中X表示Sb或Te; Y表示Nb，W或Zr; Z表示Li，Na，K，Rb，Cs，Mg，Ca或Sr; a，b，c，d，e和f表示它们各自元素的原子比，其中0

10. 发明授权

US4925980A Process for producing methacrylic acid and a catalyst 失效
标题翻译：生产甲基丙烯酸和催化剂的方法
公开(公告)号：US4925980A
公开(公告)日：1990-05-15
申请号：US697685
申请日：1985-02-01
申请人： Mutsumi Matsumoto , Yoshimasa Seo
发明人： Mutsumi Matsumoto , Yoshimasa Seo
IPC分类号： B01J23/28 , B01J23/68 , B01J23/887 , B01J27/00 , B01J27/199 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C57/055 , C07C67/00
CPC分类号： B01J23/002 , B01J23/28 , B01J23/686 , B01J23/8877 , B01J27/199 , C07C51/252 , B01J2523/00
摘要： The present invention relates to a process for producing methacrylic acid by oxidizing methacrolein in vapor phase with molecular oxygen or a gas containing molecular oxygen, characterized in that the oxidation is carried out in the presence of a catalyst having a composition shown by the following formula:Mo.sub.a V.sub.b P.sub.c X.sub.d Y.sub.e O.sub.fwherein Mo, V, P and O respectively represent molybdenum, vanadium, phosphorus and oxygen; X represents at least one element selected from the group consisting of potassium, rubidium, cesium, and thallium; Y represents at least one element selected from the group consisting of copper, silver, tin, thorium, germanium, nickel, iron, cobalt, titanium, rhenium, chromium, cerium, antimony and magnesium; and a, b, c, d, e and f denote the atomic ratio of respective elements where, a is 10, b is a number of 6 or less than 6 excluding 0, preferably 0.5 to 3, c is a number of 0.5 to 6, preferably 0.5 to 3, d is a number of 0.5 or less than 0.5 excluding 0, preferably 0.01 to 0.3, e is a number of 5 or less than 5 exclusing 0, preferably 0.01 to 1 and f is a number determined by the valence and atomic ratio of the other elements and usually is a number of 35 to 80, and comprising heteropolyacid having the elements above-mentioned as its components and X-metal salt of the heteropolyacid both of which are present in a mixed state, and relates also to the above-mentioned catalyst.
摘要翻译：本发明涉及通过用分子氧或含有分子氧的气体在气相中氧化异丁烯醛来生产甲基丙烯酸的方法，其特征在于氧化是在具有下式所示组成的催化剂的存在下进行的： MoaVbPcXdYeOf其中Mo，V，P和O分别代表钼，钒，磷和氧; X表示选自钾，铷，铯和铊中的至少一种元素; Y表示选自铜，银，锡，钍，锗，镍，铁，钴，钛，铼，铬，铈，锑和镁中的至少一种元素; a，b，c，d，e和f表示各元素的原子比，a为10，b为6以下，6以下的数，不包括0，优选为0.5〜3，c为0.5〜 6，优选为0.5〜3，d为除0以外的0.5以下的数，优选为0.01〜0.3，e为5以下，5以下的数，不超过0，优选为0.01〜1，f为化合价和其他元素的原子比，通常为35〜80，包含上述元素的杂多酸作为其成分，杂多酸的X金属盐都以混合状态存在，并且涉及还涉及上述催化剂。

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