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1. 发明授权

US06891191B2 Organic semiconductor devices and methods of fabrication 失效
标题翻译：有机半导体器件及其制造方法
公开(公告)号：US06891191B2
公开(公告)日：2005-05-10
申请号：US10652959
申请日：2003-09-02
申请人： Steven Xiao , Chunong Qiu , Cindy Xing Qiu
发明人： Steven Xiao , Chunong Qiu , Cindy Xing Qiu
IPC分类号： H01L35/24 , H01L51/00 , H01L51/30
CPC分类号： H01L51/0575 , H01L51/0037 , H01L51/0038 , H01L51/4246 , Y02E10/549
摘要： The present invention discloses a vertical junction structure with multi-PN channels, which provides a maximum interface between p-type and n-type materials in order to assist the charge separation, and offers continuous phases in both p- and n-type materials for charge transport in opposite directions.The present invention also provides methods for constructing the device structures. The main steps include 1) assembling a porous structure or a framework with semiconductor materials of one conduction type on a first electrode, 2) filling pores or coating the framework made from the materials in step 1 with semiconductors or precursors of conducting polymer of a opposite conduction type, 3) chemically and physically treating the system to form closed packed multi-PN channels.
摘要翻译：本发明公开了一种具有多PN通道的垂直结结构，其提供p型和n型材料之间的最大界面，以协助电荷分离，并且在p型和n型材料中提供连续相电荷运输在相反的方向。本发明还提供了构造装置结构的方法。主要步骤包括：1）在第一电极上组装一种导电类型的半导体材料的多孔结构或框架，2）用步骤1中的材料填充孔或涂覆由该材料制成的框架，导电类型，3）化学和物理处理系统以形成封闭多PN通道。

2. 发明授权

US08852755B2 Oxadiazole metallic complexes and their electronic and opto-electronic applications 有权
标题翻译：恶二唑金属络合物及其电子和光电应用
公开(公告)号：US08852755B2
公开(公告)日：2014-10-07
申请号：US10917474
申请日：2004-08-13
申请人： Chunong Qiu , Steven Xiao , Cindy Xing Qiu
发明人： Chunong Qiu , Steven Xiao , Cindy Xing Qiu
IPC分类号： C09K11/06 , H01L51/54 , H01L51/46 , C07D271/10 , C07F15/00 , H01L51/00 , H05B33/14 , H01L51/50
CPC分类号： C09K11/06 , C07D271/10 , C07F15/0033 , C09K2211/1029 , C09K2211/1048 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention relates to oxadiazole metallic complexes. More specifically it relates to the synthesis and electronic and opto-electronic applications of oxadiazole metallic complexes having a general Formula I, wherein each of variables is defined herein.
摘要翻译：本发明涉及恶二唑金属络合物。更具体地，本发明涉及具有通式I的恶二唑金属络合物的合成和电子和光电应用，其中每个变量在本文中定义。

3. 发明申请

US20050019976A1 Non-vacuum methods for the fabrication of organic semiconductor devices 失效
标题翻译：用于制造有机半导体器件的非真空方法
公开(公告)号：US20050019976A1
公开(公告)日：2005-01-27
申请号：US10624003
申请日：2003-07-22
申请人： Steven Xiao , Chunong Qiu , Cindy Qiu
发明人： Steven Xiao , Chunong Qiu , Cindy Qiu
IPC分类号： H01L51/30 , H01L51/40
CPC分类号： H01L51/0021 , H01L51/0006 , H01L51/0022 , H01L51/0024 , H01L51/0037 , H01L51/0038 , H01L51/424 , H01L51/441 , H01L51/442 , H01L51/5203 , Y02E10/549
摘要： This invention discloses methods for the fabrication of organic semiconductor material-based devices under non-vacuum environment. In one embodiment, electrodes are formed by electrodeposition from an electrolyte containing ions or complexes of the electrode materials to be deposited. In another embodiment, electrodes are formed by solution processing from a solution (or ink) containing nano-particle of the electrode materials or the precursor of electrode materials to be deposited. In addition, two different modes, either layer by layer or layer to layer, are disclosed for the fabrication of organic semiconductor material-based devices, wherein all semiconductor organic materials required by the function of the desired device are deposited under an non-vacuum environment.
摘要翻译：本发明公开了在非真空环境下制造基于有机半导体材料的器件的方法。在一个实施例中，电极通过从包含待沉积的电极材料的离子或络合物的电解质电沉积形成。在另一个实施方案中，通过溶液处理从含有电极材料的纳米颗粒或待沉积的电极材料的前体的溶液（或油墨）形成电极。另外，为了制造基于有机半导体材料的器件，公开了分层或层到层的两种不同的模式，其中所需器件功能所需的所有半导体有机材料在非真空环境下沉积。

4. 发明申请

US20050045874A1 ORGANIC SEMICONDUCTOR DEVICES AND METHODS OF FABRICATION 失效
标题翻译：有机半导体器件及其制造方法
公开(公告)号：US20050045874A1
公开(公告)日：2005-03-03
申请号：US10652959
申请日：2003-09-02
申请人： Steven Xiao , Chunong Qiu , Cindy Qiu
发明人： Steven Xiao , Chunong Qiu , Cindy Qiu
IPC分类号： H01L35/24 , H01L51/00 , H01L51/30 , H01L29/08
CPC分类号： H01L51/0575 , H01L51/0037 , H01L51/0038 , H01L51/4246 , Y02E10/549
摘要： The present invention discloses a vertical junction structure with multi-PN channels, which provides a maximum interface between p-type and n-type materials in order to assist the charge separation, and offers continuous phases in both p- and n-type materials for charge transport in opposite directions. The present invention also provides methods for constructing the device structures. The main steps include 1) assembling a porous structure or a framework with semiconductor materials of one conduction type on a first electrode, 2) filling pores or coating the framework made from the materials in step 1 with semiconductors or precursors of conducting polymer of a opposite conduction type, 3) chemically and physically treating the system to form closed packed multi-PN channels.
摘要翻译：本发明公开了一种具有多PN通道的垂直结结构，其提供p型和n型材料之间的最大界面，以协助电荷分离，并且在p型和n型材料中提供连续相电荷运输在相反的方向。本发明还提供了构造装置结构的方法。主要步骤包括：1）在第一电极上组装一种导电类型的半导体材料的多孔结构或框架，2）用步骤1中的材料填充孔或涂覆由该材料制成的框架，导电类型，3）化学和物理处理系统以形成封闭多PN通道。

5. 发明申请

US20060036065A1 Soluble aniline-thiophene copolymers 失效
标题翻译：苯胺 - 噻吩共聚物
公开(公告)号：US20060036065A1
公开(公告)日：2006-02-16
申请号：US10918804
申请日：2004-08-16
申请人： Steven Xiao , Chunong Qiu , Cindy Qiu
发明人： Steven Xiao , Chunong Qiu , Cindy Qiu
IPC分类号： C08G75/00 , C08L81/00
CPC分类号： C08G73/0273
摘要： The present invention discloses soluble copolymers of aniline and thiophene having a general formula I. Wherein: m and n each independently represents an integer, with m≧1 and n≧2. R1, R2, R3, R4, R5, R6 and R7 each independently represents, hydrogen atom, or a liner or branched or cyclo aliphatic group having from 1 to 20 carbon atoms, or an aromatic group having from 5 to 30 carbon atoms, or any other functional group, but at least one among R1, R2, R3, R4, R5, R6, and R7 is not a hydrogen atom. The present invention also teaches methods for the synthesis, characterization and application of the disclosed copolymers.
摘要翻译：本发明公开了具有通式I的苯胺和噻吩的可溶性共聚物。其中m和n各自独立地表示整数，其中m≥1且n> = 2。 R 1，R 2，R 3，R 4，R 5，R 6和R 7各自独立地表示氢原子或具有1至20个碳原子的直链或支链或环状脂族基团或具有5至30个碳原子的芳族基团，或任何其它官能团，但R 1，R 2，R 3，R 4，R 5，R 6和R 7中的至少一个不是氢原子。本发明还教导了所公开的共聚物的合成，表征和应用的方法。

6. 发明申请

US20060033098A1 Organic semiconductor devices having low contact resistance 失效
标题翻译：具有低接触电阻的有机半导体器件
公开(公告)号：US20060033098A1
公开(公告)日：2006-02-16
申请号：US10914676
申请日：2004-08-10
申请人： Ishiang Shih , Yi Chen , Chunong Qiu , Cindy Qiu , Steven Xiao
发明人： Ishiang Shih , Yi Chen , Chunong Qiu , Cindy Qiu , Steven Xiao
IPC分类号： H01L35/24
CPC分类号： H01L51/105 , H01L51/0021 , H01L51/0541 , H01L51/0545 , Y02E10/549
摘要： Organic semiconductor-based devices such as thin film transistors, organic light emitting devices and solar cells have potential in low cost electronic and optoelectronic applications. The performance of these organic semiconductor-based devices is often limited by the large resistance between the organic semiconductors and counter electrodes. This invention provides device structures and methods to reduce the unwanted resistance.
摘要翻译：有机半导体器件如薄膜晶体管，有机发光器件和太阳能电池具有低成本电子和光电子应用的潜力。这些基于有机半导体的器件的性能通常受到有机半导体和对电极之间的大电阻的限制。本发明提供了减少不需要的电阻的器件结构和方法。

7. 发明申请

US20060036097A1 Oxadiazole metallic complexes and their electronic and opto-electronic applications 有权
标题翻译：恶二唑金属络合物及其电子和光电应用
公开(公告)号：US20060036097A1
公开(公告)日：2006-02-16
申请号：US10917474
申请日：2004-08-13
申请人： Chunong Qiu , Steven Xiao , Cindy Qiu
发明人： Chunong Qiu , Steven Xiao , Cindy Qiu
IPC分类号： C07D271/10 , C09K11/06 , H05B33/14
CPC分类号： C09K11/06 , C07D271/10 , C07F15/0033 , C09K2211/1029 , C09K2211/1048 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： The present invention relates to oxadiazole metallic complexes. More specifically it relates to the synthesis and electronic and opto-electronic applications of oxadiazole metallic complexes having a general Formula I, wherein each of variables is defined herein.
摘要翻译：本发明涉及恶二唑金属络合物。更具体地，本发明涉及具有通式I的恶二唑金属络合物的合成和电子和光电应用，其中每个变量在本文中定义。

8. 发明申请

US20050009227A1 Organic semiconductor devices and methods of fabrication 有权
标题翻译：有机半导体器件及其制造方法
公开(公告)号：US20050009227A1
公开(公告)日：2005-01-13
申请号：US10617413
申请日：2003-07-11
申请人： Steven Xiao , Chunong Qiu , Cindy Qiu
发明人： Steven Xiao , Chunong Qiu , Cindy Qiu
IPC分类号： H01L21/00 , H01L35/24 , H01L51/00 , H01L51/30 , H01L51/40 , H01L51/56
CPC分类号： H01L51/4253 , B82Y10/00 , H01L51/0024 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/0046 , H01L51/424 , H01L51/56 , H01L2251/308 , Y02E10/549 , Y02P70/521
摘要： This invention discloses structures of organic materials-based semiconductor devices and methods for the fabrication of such devices. According to this invention, each of the devices has a first part and a second part. The first part has at least a first organic semiconductor material layer deposited on a first electrode and the second part has at least a second organic semiconductor material layer deposited on a second electrode. Said device is formed by assembling the two individual parts together. Each part maybe fabricated separately and consists of an electrode coated with semiconductor organic materials required by the function of the desired device. A schematic diagram in the FIG. 3 shows a first part (11) consisting of a first substrate (13), a first electrode (14) and at least one layer of organic materials (15); the second part (12) of the device consisting of the second substrate (16), a second electrode (17) with at least a layer of organic materials (18). The organic device (10) is finally obtained by combining the first part (11) with the second part (12) under controlled environment. This is preferably done by aligning the first part (11) onto the second part (12), and then by initiating a cross-link between organic material (15) and organic material (18) via heating, electron beam or light irradiation.
摘要翻译：本发明公开了基于有机材料的半导体器件的结构及其制造方法。根据本发明，每个装置具有第一部分和第二部分。第一部分至少具有沉积在第一电极上的第一有机半导体材料层，并且第二部分至少具有沉积在第二电极上的第二有机半导体材料层。所述装置通过将两个单独部件组装在一起而形成。每个部件可以单独制造，并且由涂覆有所需器件功能所需的半导体有机材料的电极组成。图中的示意图。图3示出了由第一基板（13），第一电极（14）和至少一层有机材料（15）组成的第一部分（11）。所述装置的第二部分（12）由第二基板（16），具有至少一层有机材料（18）的第二电极（17）组成。最终通过在受控环境下组合第一部分（11）和第二部分（12）来获得有机装置（10）。这优选通过将第一部分（11）对准第二部分（12），然后通过加热，电子束或光照射引发有机材料（15）和有机材料（18）之间的交联来完成。

9. 发明申请

US20130092878A1 Thermoplastic based electronic conductive inks and method of making the same 审中-公开
标题翻译：基于热塑性的电子导电油墨及其制造方法
公开(公告)号：US20130092878A1
公开(公告)日：2013-04-18
申请号：US13317331
申请日：2011-10-17
申请人： Steven Xiao
发明人： Steven Xiao
IPC分类号： C09D11/00 , H01B1/12
CPC分类号： C09D11/106 , C09D5/24 , C09D11/52
摘要： This invention discloses a composition of thermoplastic based electronic conductive inks, more specifically electronic conductive inks containing chemically functioned thermoplastic resins and poly(3,4-ethylenedioxythiophene). This invention also teaches the method of making the same and electronic devices making from the same.
摘要翻译：本发明公开了一种基于热塑性的电子导电油墨组合物，更具体地说是含有化学功能的热塑性树脂和聚（3,4-亚乙基二氧噻吩）的电子导电油墨。本发明还教导了制造它们的方法和由其制造的电子器件。

10. 发明授权

US06864329B2 Hybrid organic-inorganic light emitting polymers 失效
标题翻译：杂化有机 - 无机发光聚合物
公开(公告)号：US06864329B2
公开(公告)日：2005-03-08
申请号：US10233825
申请日：2002-09-03
申请人： Steven Xiao , My T. Nguyen
发明人： Steven Xiao , My T. Nguyen
IPC分类号： C08G77/42 , C08G77/442 , C08G77/452 , C09K11/02
CPC分类号： C08G77/452 , C08G77/42 , C08G77/442
摘要： Provided herein is an inorganic-organic hybrid conjugated polymer having opto-electronic function and a process to make the same. The disclosed polymer contains inorganic or organic bulky groups in the polymer backbone or as pedant groups and has a general formula: wherein: A is a bulk group, comprising at least one silsesquioxane, serving as a positional anchor for the polymer. S serving as a spacer includes alkyl, cycyloalkyl group of from 1 to 30 carbon atoms, or aryl or substituted aryl of from 6 to 50 carbon atoms, or herteroaryl or substituted heteroaryl of from 4 to 50 carbons. CP represents any conjugated polymer segment at least one portion thereof comprising an opto-electronic function, for example, polyacetylenes, polyphenylenes, polyphenylenevinylenes, polythiophenes, polypyrroles, polyanilines, polyfluorences, and any conjugated co-polymer segment. x, y and z are positive integers, where x and z is equal or greater than 1. These integers determine the configuration of such a hybrid polymer system as expressed in the above formula.
摘要翻译：本文提供了具有光电功能的无机 - 有机杂化共轭聚合物和制备其的方法。所公开的聚合物在聚合物主链中含有无机或有机大体积基团，或具有通式：其中：A为主体，包含至少一种倍半硅氧烷，用作聚合物的定位锚。作为间隔基的S包括1至30个碳原子的烷基，氰基烷基或6至50个碳原子的芳基或取代的芳基，或4至50个碳的杂芳基或取代的杂芳基。 CP代表任何共轭聚合物链段，其至少一部分包含光电子功能，例如聚乙烯，聚苯，聚亚苯基亚乙烯基，聚噻吩，聚吡咯，聚苯胺，聚芴和任何共轭共聚物链段。 x，y和z是正整数，其中x和z等于或大于1.这些整数决定了如上式所示的这种混合聚合物体系的构型。

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