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    • 6. 发明授权
    • Electroplating apparatus with vented electrolyte manifold
    • 带排气电解液歧管的电镀设备
    • US08475637B2
    • 2013-07-02
    • US12337147
    • 2008-12-17
    • Jingbin FengZhian HeRobert RashSteven T. Mayer
    • Jingbin FengZhian HeRobert RashSteven T. Mayer
    • C25D17/00C25D21/04
    • C25D7/123C25D17/001C25D17/002
    • Embodiments related to increasing a uniformity of an electroplated film are disclosed. For example, one disclosed embodiment provides an electroplating apparatus comprising a plating chamber, a work piece holder, a cathode contact configured to electrically contact a work piece, and an anode contact configured to electrically contact an anode disposed in the plating chamber. A diffusing barrier is disposed between the cathode contact and the anode contact to provide a uniform electrolyte flow to the work piece, and electrolyte delivery and return paths are provided for delivering electrolyte to and away from the plating chamber. Additionally, a vented electrolyte manifold is disposed in the electrolyte delivery path immediately upstream of the plating chamber, the vented electrolyte manifold comprising one or more electrolyte delivery openings that open to the plating chamber and one or more vents that open to a location other than the plating chamber.
    • 公开了与提高电镀膜的均匀性有关的实施例。 例如,一个公开的实施例提供了一种电镀设备,其包括电镀室,工件保持器,构造成电接触工件的阴极接触件和被配置为电接触设置在电镀室中的阳极的阳极接触件。 扩散阻挡层设置在阴极接触件和阳极接触件之间,以提供均匀的电解质流向工件,并且提供电解质输送和返回路径用于将电解质输送到电镀室和远离电镀室。 另外,排气的电解液歧管设置在紧邻镀室的上游的电解质输送路径中,排出的电解质歧管包括一个或多个向电镀室敞开的电解质输送开口,以及一个或多个通向出口 电镀室。
    • 8. 发明申请
    • THROUGH SILICON VIA FILLING USING AN ELECTROLYTE WITH A DUAL STATE INHIBITOR
    • 通过使用电解液与双态抑制剂进行填充的硅
    • US20110284386A1
    • 2011-11-24
    • US13110488
    • 2011-05-18
    • Mark J. WilleySteven T. Mayer
    • Mark J. WilleySteven T. Mayer
    • C25D5/02C25D19/00C25D3/38
    • C25D3/38C25D5/022C25D7/123C25D21/12H01L21/2885H01L21/76879H01L21/76898H01L23/53228H01L2924/0002H01L2924/00
    • A method for electrofilling large, high aspect ratio recessed features with copper without depositing substantial amounts of copper in the field region is provided. The method allows completely filling recessed features having aspect ratios of at least about 5:1 such as at least about 10:1, and widths of at least about 1 μm in a substantially void-free manner without depositing more than 5% of copper in the field region (relative to the thickness deposited in the recessed feature). The method involves contacting the substrate having one or more large, high aspect ratio recessed features (such as a TSVs) with an electrolyte comprising copper ions and an organic dual state inhibitor (DSI) configured for inhibiting copper deposition in the field region, and electrodepositing copper under potential-controlled conditions, where the potential is controlled not exceed the critical potential of the DSI.
    • 提供了一种用于电镀大量,高纵横比的凹陷特征与铜而不在现场区域中沉积大量铜的方法。 该方法允许以基本无空隙的方式完全填充具有至少约5:1的纵横比(例如至少约10:1)和至少约1μm的宽度的凹陷特征,而不沉积超过5%的铜 场区域(相对于沉积在凹陷特征中的厚度)。 该方法包括将具有一个或多个大的,高纵横比的凹陷特征(例如TSV)的基底与包含铜离子的电解质和被配置用于抑制场区中的铜沉积的有机双态抑制剂(DSI)接触,以及电沉积 在电势控制条件下,电位控制的铜不超过DSI的临界电位。