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1. 发明授权

US06440655B1 Silver halide element with improved high temperature storage and reduced thickness 失效
标题翻译：具有改善的高温储存和减小厚度的卤化银元件
公开(公告)号：US06440655B1
公开(公告)日：2002-08-27
申请号：US09593088
申请日：2000-06-13
申请人： Steven P. Szatynski , James H. Reynolds , Janet N. Younathan , George J. Burgmaier
发明人： Steven P. Szatynski , James H. Reynolds , Janet N. Younathan , George J. Burgmaier
IPC分类号： G03C7305
CPC分类号： G03C7/30511 , G03C7/30552 , G03C7/30558 , G03C7/30576 , G03C7/3924 , G03C2007/3027
摘要： A silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising a polyester support and an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.
摘要翻译：一种卤化银照相元件，其包含至少一种含有染料形成成色剂的卤化银乳剂层，其与氧化的彩色显影剂反应形成染料，所述卤化银元素还包含聚酯载体和式I的酰氨基化合物，其中INH为显影抑制剂; LINK是连接或定时基团，m是0,1或2; R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起代表必需的原子形成5或6元环或多环系统，或者R1和R2独立地为-C（= O）（LINK）m-INH基团，或被-NR3aC（= O） - （LINK）m- INH基团，其中R3a定义与R1或R2相同，并且其中式I化合物基本上不与氧化显影剂反应以释放INH。

2. 发明授权

US06472133B1 Silver halide element with improved high temperature storage 失效
标题翻译：具有改善的高温储存的卤化银元件
公开(公告)号：US06472133B1
公开(公告)日：2002-10-29
申请号：US09592705
申请日：2000-06-13
申请人： James H. Reynolds , Steven P. Szatynski , Stephen P. Singer , George J. Burgmaier , Janet N. Younathan , Lillian M. Kellogg
发明人： James H. Reynolds , Steven P. Szatynski , Stephen P. Singer , George J. Burgmaier , Janet N. Younathan , Lillian M. Kellogg
IPC分类号： G03C7305
CPC分类号： G03C7/30511 , G03C7/30552
摘要： This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and wherein INH is a development inhibitor; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.
摘要翻译：本发明涉及一种卤化银照相元件，其包含至少一种含有染料形成成色剂的卤化银乳剂层，其与氧化的彩色显影剂反应形成染料，所述卤化银元素还包含式I的酰氨基化合物，其中INH为显影抑制剂; LINK是连接或时序基团，m是0,1或2; 并且其中INH是开发抑制剂; R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起代表形成5或6元环或多环体系所必需的原子，或者R 1和R 2独立地为-C（= O）（LINK）m-INH基团，或被-NR 3 a C（= O） - （LINK）m-INH基团取代，其中R 3a定义与R 1或 R2，并且其中式I的化合物基本上不与氧化的显影剂反应以释放INH。

3. 发明授权

US06472134B1 Silver halide element with improved high temperature storage and sensitivity 失效
标题翻译：具有改善的高温储存和灵敏度的卤化银元件
公开(公告)号：US06472134B1
公开(公告)日：2002-10-29
申请号：US09593108
申请日：2000-06-13
申请人： Steven P. Szatynski , James H. Reynolds , Annabel A. Muenter , George J. Burgmaier
发明人： Steven P. Szatynski , James H. Reynolds , Annabel A. Muenter , George J. Burgmaier
IPC分类号： G03C7305
CPC分类号： G03C1/346 , G03C1/12 , G03C7/30511
摘要： A silver halide photographic element comprising at least one silver halide emulsion, said silver halide element further comprising an amido compound represented by Formula 1 wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and R1 and R2 independently represents an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system; or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH; and a fragmentable electron donor compound of the formula X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′, and optionally. 3) the radical X′ has an oxidation potential ≦−0.7V.
摘要翻译：包含至少一种卤化银乳剂的卤化银照相元件，所述卤化银元素还包含由式1表示的酰胺化合物，其中INH是显影抑制剂; LINK是连接或定时基团，m是0,1或2; 并且R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起代表形成5或6元环或多环体系所必需的原子; 或者R 1和R 2独立地为-C（= O）（LINK）m-INH基团，或被-NR 3 a C（= O） - （LINK）m-INH基团取代，其中R 3a定义与R 1或 R2，并且其中式I的化合物基本上不与氧化显影剂反应以释放INH; 和式X-Y'的可裂解电子给体化合物或含有式-X-Y'部分的化合物; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则碱，β - 与X直接或间接共价连接，并且其中：1 ）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'的氧化形式经历键断裂反应，得到基团X和离去片段Y'，并且任选地，3）基团X'具有<= -0.7V的氧化电位。

4. 发明授权

US06472135B1 Silver halide element with improved high temperature storage and raw stock keeping 失效
标题翻译：具有改善的高温储存和原料储存的卤化银元件
公开(公告)号：US06472135B1
公开(公告)日：2002-10-29
申请号：US09593113
申请日：2000-06-13
申请人： Steven P. Szatynski , James H. Reynolds , Lillian M. Kellogg , George J. Burgmaier
发明人： Steven P. Szatynski , James H. Reynolds , Lillian M. Kellogg , George J. Burgmaier
IPC分类号： G03C7305
CPC分类号： G03C1/34 , G03C1/346 , G03C7/30511
摘要： This invention relates to a silver halide photographic element comprising at least one silver halide emulsion, said silver halide element further comprising an amido compound represented by Formula 1 wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and R1 and R2 independently represents an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2; and wherein the compound of Formula 1 does not substantially react with oxidized developer to release INH; and a reductone compound represented by Formula 2 wherein R7 and R8 are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or an alkyl group with a solubilizing group such as —OH, sulfonamide, sulfamoyl, or carbamoyl, R7 and R8 may be joined to complete a heterocyclic ring, R4 and R5 are H, OH, alkyl, aryl, cycloalkyl, or may together represent an alkylidene group, n is 1 or 2 and R3 is H, alkyl, aryl, or CO2R6 where R6 is alkyl.
摘要翻译：本发明涉及包含至少一种卤化银乳剂的卤化银照相元件，所述卤化银元素还包含由式1表示的酰胺化合物，其中INH是显影抑制剂; LINK是连接或定时基团，m是0,1或 2; 并且R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起表示形成5或6元环或多环体系所必需的原子，或者R 1和R 2独立地为 -C（= O）（LINK）m-INH基团，或被-NR 3 a C（= O） - （LINK）m-INH基团取代，其中R 3a定义与R 1或R 2相同; 并且其中式1的化合物基本上不与氧化的显影剂反应以释放INH; 和由式7表示的还原酮化合物，其中R 7和R 8相同或不同，并且可以表示H，烷基，环烷基，芳基或具有增溶基团如-OH，磺酰胺，氨磺酰基或氨基甲酰基的烷基，R7和 R8可以连接成杂环，R4和R5是H，OH，烷基，芳基，环烷基，或者可以一起代表亚烷基，n是1或2，R 3是H，烷基，芳基或CO 2 R 6，其中R 6 是烷基。

5. 发明授权

US07189502B1 Radiographic materials with antifoggant precursors 失效
标题翻译：具有防雾前体的射线照相材料
公开(公告)号：US07189502B1
公开(公告)日：2007-03-13
申请号：US11242340
申请日：2005-10-03
申请人： Robert E. Dickerson , George J. Burgmaier , Steven P. Szatynski , Stephen A. Hershey
发明人： Robert E. Dickerson , George J. Burgmaier , Steven P. Szatynski , Stephen A. Hershey
IPC分类号： G03C1/08 , G03C7/26 , G03C7/32 , G03C1/06 , G03C1/005
CPC分类号： G03C1/346 , G03C1/16 , G03C1/29 , G03C1/7614 , G03C1/85 , G03C5/16 , G03C5/17 , G03C7/30511 , G03C2001/0055 , G03C2001/03511 , G03C2001/7425 , G03C2001/7635 , G03C2007/3025 , G03C2200/27 , Y10S430/156
摘要： A radiographic material containing tabular silver halide grains also includes an amido compound as an antifoggant precursor that can slowly release an antifoggant over time. These compounds are present in reactive association with the silver halide in tabular silver halide emulsion layers, and are present in an amount of at least 0.5 mmol/mol of silver. The radiographic materials are protected from fog during storage particularly in high temperature environments.
摘要翻译：包含片状卤化银颗粒的射线照相材料还包括作为防灰雾剂前体的酰氨基化合物，其随时间缓慢释放防灰雾剂。这些化合物与片状卤化银乳剂层中的卤化银反应性地存在，并且以至少0.5mmol / mol的银的量存在。放射照相材料在储存期间特别是在高温环境中得到防雾。

6. 发明授权

US07629112B1 Color photographic materials with yellow minimum density colorants 失效
标题翻译：具有黄色最小密度着色剂的彩色感光材料
公开(公告)号：US07629112B1
公开(公告)日：2009-12-08
申请号：US12129726
申请日：2008-05-30
申请人： Paul L. Zengerle , Drake M. Michno , James H. Reynolds , Steven P. Szatynski , John W. Harder
发明人： Paul L. Zengerle , Drake M. Michno , James H. Reynolds , Steven P. Szatynski , John W. Harder
IPC分类号： G03C1/46 , G03C1/06 , G03C7/46 , G03C1/815 , G03C7/26
CPC分类号： G03C1/832 , G03C7/3041 , G03C7/39292
摘要： Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed yellow colorant that is present in an amount to provide a status M blue density greater than 0.003 per mg/m2. This colorant provides minimum density at lower cost and can be incorporated with minimal or no organic solvents and thus enable a reduced organic load that may lead to improved film physical properties.
摘要翻译：具有多个彩色成像层的卤化银彩色照相元件含有永久的预形成的黄色着色剂，其量以提供大于0.003 / mg / m 2的状态M蓝色密度。该着色剂以较低的成本提供最小的密度，并且可以与最少的或没有有机溶剂结合，从而能够降低可能导致改进的膜物理性能的有机负载。

7. 发明申请

US20090297992A1 COLOR PHOTOGRAPHIC MATERIALS WITH YELLOW MINIMUM DENSITY COLORANTS 失效
标题翻译：彩色摄影材料与黄色最小密度色素
公开(公告)号：US20090297992A1
公开(公告)日：2009-12-03
申请号：US12129726
申请日：2008-05-30
申请人： Paul L. Zengerle , Drake M. Michno , James H. Reynolds , Steven P. Szatynski , John W. Harder
发明人： Paul L. Zengerle , Drake M. Michno , James H. Reynolds , Steven P. Szatynski , John W. Harder
IPC分类号： G03C5/29 , G03C1/10
CPC分类号： G03C1/832 , G03C7/3041 , G03C7/39292
摘要： Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed yellow colorant that is present in an amount to provide a status M blue density greater than 0.003 per mg/m2. This colorant provides minimum density at lower cost and can be incorporated with minimal or no organic solvents and thus enable a reduced organic load that may lead to improved film physical properties.
摘要翻译：具有多个彩色成像层的卤化银彩色照相元件含有永久的预形成的黄色着色剂，其量以提供大于0.003 / mg / m 2的状态M蓝色密度。该着色剂以较低的成本提供最小的密度，并且可以与最少的或没有有机溶剂结合，从而能够降低可能导致改进的膜物理性能的有机负载。

8. 发明申请

US20090325108A1 COLOR PHOTOGRAPHIC MATERIALS WITH MAGENTA MINIMUM DENSITY DYES 失效
标题翻译：彩色摄影材料与MAGENTA最小密度染色体
公开(公告)号：US20090325108A1
公开(公告)日：2009-12-31
申请号：US12147548
申请日：2008-06-27
申请人： Paul L. Zengerle , John W. Harder , Drake M. Michno , James H. Reynolds , Steven P. Szatynski
发明人： Paul L. Zengerle , John W. Harder , Drake M. Michno , James H. Reynolds , Steven P. Szatynski
IPC分类号： G03C7/26 , G03C1/46
CPC分类号： G03C7/3029 , G03C2200/22
摘要： Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed magenta dye that is present in an amount to provide a status M green density greater than 0.005 per mg/m2. This dye provides minimum density at lower cost and enables lower dye levels and a reduced organic load that may lead to improved film physical properties.
摘要翻译：具有多个彩色成像层的卤化银彩色照相元件含有永久的预形成的品红色染料，其量以提供大于0.005mg / m 2的状态M绿色密度。该染料以更低的成本提供最小的密度，并且能够降低染料水平和降低的有机负载，这可导致改进的膜物理性能。

9. 发明授权

US07632632B1 Color photographic materials with magenta minimum density dyes 失效
标题翻译：彩色照相材料，品红色最小密度染料
公开(公告)号：US07632632B1
公开(公告)日：2009-12-15
申请号：US12147548
申请日：2008-06-27
申请人： Paul L. Zengerle , John W. Harder , Drake M. Michno , James H. Reynolds , Steven P. Szatynski
发明人： Paul L. Zengerle , John W. Harder , Drake M. Michno , James H. Reynolds , Steven P. Szatynski
IPC分类号： G03C7/46 , G03C7/32 , G03C5/26 , G03C1/08 , G03C1/005
CPC分类号： G03C7/3029 , G03C2200/22
摘要： Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed magenta dye that is present in an amount to provide a status M green density greater than 0.005 per mg/m2. This dye provides minimum density at lower cost and enables lower dye levels and a reduced organic load that may lead to improved film physical properties.
摘要翻译：具有多个彩色成像层的卤化银彩色照相元件含有永久的预形成的品红色染料，其量以提供大于0.005mg / m 2的状态M绿色密度。该染料以更低的成本提供最小的密度，并且能够降低染料水平和降低的有机负载，这可导致改进的膜物理性能。

10. 发明授权

US5763146A Photographic materials containing water soluble amino hexose reductones 失效
标题翻译：含有水溶性氨基己糖还原剂的摄影材料
公开(公告)号：US5763146A
公开(公告)日：1998-06-09
申请号：US814517
申请日：1997-03-10
申请人： James H. Reynolds , Steven P. Szatynski , Jeffrey L. Hall , Norma B. Platt
发明人： James H. Reynolds , Steven P. Szatynski , Jeffrey L. Hall , Norma B. Platt
IPC分类号： G03C1/005 , G03C1/34 , G03C7/392 , G03C7/46
CPC分类号： G03C7/39236 , G03C1/34 , G03C1/005 , G03C1/0051
摘要： The invention relates to a silver halide photographic emulsion comprising silver halide grains and the reductone of Formula I ##STR1## wherein R.sub.1 and R.sub.2 are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or an alkyl group with a solubilizing group such as --OH, sulfonamide, sulfamoyl, or carbamoyl, R.sub.1 and R.sub.2 may be joined to complete a heterocyclic ring such as aziridinyl, azetidinyl, pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl, or pyridinyl, R.sub.4 and R.sub.5 are H, OH, alkyl, aryl, cycloalkyl, or may together represent an alkylidene group, n is 1 or 2 and R.sub.3 is H, alkyl, aryl, or CO.sub.2 R.sub.6 where R.sub.6 is alkyl, and wherein the logarithm of the partition coefficient for the reductone when equilibrated as a solute between n-octanol and water (logP) is less than 0.293.
摘要翻译：本发明涉及包含卤化银颗粒和式I的还原酮的卤化银照相乳剂，其中R1和R2相同或不同，并且可以代表H，烷基，环烷基，芳基或烷基，其中可以连接增溶基团如-OH，磺酰胺，氨磺酰基或氨基甲酰基，R 1和R 2可以连接成杂环，例如氮丙啶基，氮杂环丁烷基，吡咯烷基，哌啶基，吗啉基，哌嗪基或吡啶基，R 4和R 5是H，OH，烷基，芳基，环烷基，或可以一起表示亚烷基，n为1或2，R 3为H，烷基，芳基或CO 2 R 6，其中R 6为烷基，并且其中当平衡时为还原体的分配系数的对数为正辛醇和水之间的溶质（logP）小于0.293。

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