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    • 3. 发明授权
    • Photographic material having improved color reproduction
    • 具有改进的色彩再现的照相材料
    • US06140036A
    • 2000-10-31
    • US259992
    • 1999-03-01
    • Richard L. PartonSteven G. LinkJoan C. PotenzaLois A. Buitano
    • Richard L. PartonSteven G. LinkJoan C. PotenzaLois A. Buitano
    • G03C1/14G03C1/16G03C1/18
    • G03C1/16G03C1/18G03C1/14
    • This invention relates to a silver halide photographic material comprising at least one silver halide emulsion having associated therewith at least one dye of Formula I ##STR1## wherein: W and W' represent independently an O atom, a S atom, a Se atom or a NR' group wherein R' is a substituted or unsubstituted alkyl group,Z.sub.1 represents a substituted or unsubstituted aromatic group,Z.sub.1 ' independently represents a fused aromatic group or a substituted or unsubstituted aromatic group which may be appended directly to the dye or Z.sub.1 ' represents LZ.sub.2 where L represents a linking group and Z.sub.2 represents a substituted or unsubstituted aromatic group or substituted or unsubstituted alkyl group,L.sub.1, L.sub.2, and L.sub.3 independently represent methine groups bearing a hydrogen, substituted or unsubstituted alkyl group, or a halogen atom,n represents 0 or 1,the benzene rings shown can be further substituted or unsubstituted,R.sub.1 and R.sub.2 are both substituted or unsubstituted alkyl groups,R.sub.3 is hydrogen or a substituted or unsubstituted alkyl group,X is one or more ions as needed to balance the charge on the molecule.
    • 本发明涉及一种卤化银照相材料,其包含至少一种卤化银乳剂,其具有至少一种式I的染料,其中:W和W'独立地表示O原子,S原子,Se原子或NR'基团 其中R'为取代或未取代的烷基,Z1表示取代或未取代的芳基,Z1'独立地表示可以直接与染料偶联的稠合芳基或取代或未取代的芳基,或者Z1'表示LZ2,其中L 表示连接基团,Z 2表示取代或未取代的芳基或取代或未取代的烷基,L 1,L 2和L 3独立地表示带有氢,取代或未取代的烷基或卤素原子的次甲基,n表示0或1 所示的苯环可以被进一步取代或未取代,R 1和R 2都是取代或未取代的烷基,R 3是氢或取代基 有机或未取代的烷基,X是平衡分子上的电荷所需的一种或多种离子。
    • 5. 发明申请
    • MONOAZO COLORANTS FROM PYRAZOLOBENZODIAZINEDIOXIDES
    • 来自吡唑并二恶英酮的MONOAZO染料
    • US20090181170A1
    • 2009-07-16
    • US12015110
    • 2008-01-16
    • Steven G. LinkJoan C. PotenzaAnn L. Carroll-Lee
    • Steven G. LinkJoan C. PotenzaAnn L. Carroll-Lee
    • B05D5/00C09B62/35C09D11/02
    • B41M5/0023C09B29/3691C09D11/328
    • The invention relates to monoazo colorants derived from pyrazolobenzodiazinedioxides of Formula 1: wherein R1 and R2 are hydrogen or any non-metallic group, n is 0-4, R3 is hydrogen, acyl, aryl, alkenyl, alkynyl or alkyl, A represents an aromatic heterocyclic ring or an aromatic group of Formula 2: wherein R6 and R8 are hydrogen, alkyl, sulfonic acid, or 1-4 carbon alkoxy, R7 is any non-metallic group, m is 0-3, and R6 and R7, R7 and R8, or, when m>1, two R7 groups is can be joined to form a fused carbocyclic or heterocyclic aromatic or non-aromatic ring. The invention also relates to an aqueous ink that comprises at least one colorant of Formula 1: wherein A represents an aromatic or heteroaromatic ring, and A can be bonded to other rings that can be aromatic, aliphatic or heterocyclic, and an ink printing method using the colorant-containing ink.
    • 本发明涉及衍生自式1的吡唑并二氮杂二环氧化物的单偶氮染料:其中R 1和R 2是氢或任何非金属基团,n是0-4,R 3是氢,酰基,芳基,链烯基,炔基或烷基,A代表芳香族 杂环或式2的芳基:其中R 6和R 8是氢,烷基,磺酸或1-4碳烷氧基,R 7是任何非金属基团,m是0-3,并且R 6和R 7,R 7和 R8,或者当m> 1时,可以连接两个R 7基团以形成稠合的碳环或杂环芳族或非芳族环。 本发明还涉及包含至少一种式1的着色剂的水性油墨:其中A表示芳族或杂芳族环,并且A可以与可以是芳族,脂族或杂环的其它环结合,以及使用 含着色剂的油墨。
    • 6. 发明授权
    • Photographic film element with broad blue sensitivity
    • 具有宽蓝色灵敏度的摄影胶片元素
    • US06225037B1
    • 2001-05-01
    • US09129658
    • 1998-08-05
    • Lois A. BuitanoAllan F. SowinskiSteven G. Link
    • Lois A. BuitanoAllan F. SowinskiSteven G. Link
    • G03C116
    • G03C7/3041G03C1/0051G03C1/16G03C1/29G03C5/50G03C7/3022G03C2001/03558
    • This invention comprises a photographic element for accurately recording a scene as an image comprising a support and coated on the support a plurality of hydrophilic colloid layers comprising radiation-sensitive silver halide emulsion layers forming recording layer units for separately recording blue, green and red exposures wherein, (A) the blue recording layer unit comprises at least one blue sensitive emulsion having a peak dyed absorptance of between 435 and 465 nm and an absorptance at 480 nm≧50% of the maximum peak dyed absorptance; or (B) the blue sensitive recording unit comprises a blue sensitive emulsion layer having a peak dyed absorptance of between 435 and 465 nm, and the emulsion exhibits an overall half-peak dyed absorption bandwidth of at least 50 nm.
    • 本发明包括用于将场景精确地记录为包括载体的图像并将其涂覆在多个亲水胶体层上的照相元件,所述多个亲水胶体层包含形成用于分别记录蓝,绿和红曝光的记录层单元的辐射敏感卤化银乳剂层,其中 (A)蓝色记录层单元包括至少一种感光度高的乳剂,其峰值染料吸收率在435和465nm之间,吸光度在480nm> =最大峰值染色吸收率的50%。 或(B)蓝色敏感记录单元包括具有435和465nm之间的峰值染色吸收率的感蓝乳剂层,并且该乳液表现出至少50nm的总体半峰染色吸收带宽。
    • 7. 发明授权
    • Photographic film element containing an emulsion with broadened green
responsivity
    • 含有具有扩大的绿色响应度的乳液的摄影胶片元件
    • US06093526A
    • 2000-07-25
    • US259988
    • 1999-03-01
    • Lois A. BuitanoSteven G. LinkAllan F. Sowinski
    • Lois A. BuitanoSteven G. LinkAllan F. Sowinski
    • G03C7/20G03C1/16G03C1/18G03C7/30
    • G03C7/3041G03C1/16G03C1/18
    • This invention comprises a photographic element for accurately recording a scene as an image comprising a support and coated on the support a plurality of hydrophilic colloid layers comprising radiation-sensitive silver halide emulsion layers forming recording layer units for separately recording blue, green and red exposures wherein, the green recording layer unit comprises at least one green sensitive emulsion having:(i) a peak dyed absorptance of between 520 and 560 nm,(ii) an absorption bandwidth at 50% of the peak dyed absorptance greater than or equal to 50 nm,(iii) an absorption bandwidth at 80% of the peak dyed absorptance greater than or equal to 27 nm,(iv) a ratio of the absorptance at 560 nm to the peak dyed absorptance greater than or equal to 0.40,(v) a ratio of the absorptance at 550 nm to the peak dyed absorptance greater than or equal to 0.60, and(vi) a ratio of the absorptance at 520 nm to the peak dyed absorptance greater than or equal to 0.55.
    • 本发明包括用于将场景精确地记录为包括载体的图像并将其涂覆在多个亲水胶体层上的照相元件,所述多个亲水胶体层包含形成用于分别记录蓝,绿和红曝光的记录层单元的辐射敏感卤化银乳剂层,其中 ,绿色记录层单元包括至少一种感绿乳液,其具有:(i)520和560nm之间的峰值染料吸收率,(ii)在大于或等于50nm的峰值染料吸收率的50%处的吸收带宽 ,(iii)大于或等于27nm的峰值染料吸收率的80%处的吸收带宽,(iv)560nm处的吸收率与峰值染料吸收率之比大于或等于0.40,(v)a 550nm处的吸收率与峰值染料吸收率的比值大于或等于0.60,以及(vi)520nm处的吸收率与峰值染色吸收率之比大于或等于0.55。
    • 9. 发明授权
    • Color negative films intended for scanning having interleaved green and
red recording layer units
    • 用于具有交错的绿色和红色记录层单元的扫描的彩色底片
    • US6146818A
    • 2000-11-14
    • US223221
    • 1998-12-30
    • Maria J. GonzalezAllan F. SowinskiLois A. BuitanoSteven G. Link
    • Maria J. GonzalezAllan F. SowinskiLois A. BuitanoSteven G. Link
    • G03C7/20G03C1/00G03C1/035G03C7/00G03C7/26G03C7/30G03C1/08
    • G03C7/30G03C7/3022G03C7/3029G03C7/3041
    • A color negative film is disclosed capable of producing dye images suitable for digital scanning comprised of a support and, coated on the support, a series of hydrophilic colloid layers including at least two red recording emulsion layer units capable of forming a dye image of a first hue, at least two green recording emulsion layer units capable of forming a dye image of a second hue, and at least one blue recording emulsion layer unit capable of forming a dye image of a third hue, wherein, (1) the series of hydrophilic colloid layers include the following sequence, starting with the layer unit coated nearest the support: (a) a slower speed red recording layer unit, (b) a slower speed green recording layer unit, (c) a faster speed red recording layer unit, and (d) a faster speed green recording layer unit; (2) colored masking couplers are absent from the recording layer units; (3) tabular grain emulsions sensitized to the green and red are employed in the green and red recording layer units, respectively, and (4) spectral sensitizing dye in the red recording layer units exhibits an overall half-peak absorption bandwidth of at least 50 nm bridging the green and red regions of the spectrum, with absorption at 560 nm being in the range of from 80 to 95 percent of maximum absorption, which is located in the spectral region of from 570 to 710 nm. When the images produced by the red recording layer units are printed as red images, the human eye sees the red component image as an improved reproduction of the red component of the original image.
    • 公开了一种彩色底片,其能够产生适于数字扫描的染料图像,该染料图像由载体构成,并且涂覆在载体上,一系列亲水胶体层,其包括至少两个红色记录乳剂层单元,能够形成第一 能够形成第二色调的染料影像的至少两个绿色记录乳剂层单元和能够形成第三色调的染料影像的至少一个蓝色记录乳剂层单元,其中,(1)一系列亲水性 胶体层包括以下顺序,从最靠近载体的层单元开始:(a)较慢速度的红色记录层单元,(b)较慢速度的绿色记录层单元,(c)较快速度的红色记录层单元, 和(d)更快速的绿色记录层单元; (2)记录层单元中不存在彩色掩蔽成色剂; (3)在绿色和红色记录层单元中分别使用对绿色和红色敏化的片状颗粒乳剂,(4)红色记录层单元中的光谱增感染料显示总共半峰吸收带宽至少为50 nm桥接光谱的绿色和红色区域,560nm处的吸收在最大吸收的80%至95%的范围内,其位于570至710nm的光谱区域。 当红色记录层单元产生的图像被打印为红色图像时,人眼将红色分量图像视为原始图像的红色分量的改进的再现。