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1. 发明授权

US5516877A Crosslinkable carbonate polymers of dihydroxyaryl fluorene 失效
标题翻译：二羟基芳基芴的交联碳酸酯聚合物
公开(公告)号：US5516877A
公开(公告)日：1996-05-14
申请号：US291211
申请日：1994-08-16
申请人： Stephen E. Bales , James P. Godschalx , Philip C. Yang , Matthew T. Bishop , Maurice J. Marks
发明人： Stephen E. Bales , James P. Godschalx , Philip C. Yang , Matthew T. Bishop , Maurice J. Marks
IPC分类号： C08G64/14 , C08G64/00
CPC分类号： C08G64/14
摘要： There are disclosed carbonate polymers of dihydroxyaryl fluorene having crosslinkable moieties. There are also disclosed such polymers in the form of composites. The polymers of this invention are capable of being crosslinked by activation of the crosslinkable moieties. Once crosslinked, these polymers demonstrate an excellent combination of properties including resistance to melting at high temperatures, solvent resistance, optical clarity, impact resistance, and physical strength.
摘要翻译：公开了具有可交联部分的二羟基芳基芴的碳酸酯聚合物。还公开了复合材料形式的这种聚合物。本发明的聚合物能够通过可交联部分的活化而交联。一旦交联，这些聚合物表现出包括耐高温熔融性，耐溶剂性，光学透明度，耐冲击性和物理强度的优异的组合。

2. 发明授权

US5362838A Carbonate polymers containing ethenyl aryl moieties 失效
标题翻译：含有乙烯基芳基部分的碳酸酯聚合物
公开(公告)号：US5362838A
公开(公告)日：1994-11-08
申请号：US19950
申请日：1993-02-19
申请人： James E. McGrath , Stephen E. Bales , Daniel M. Knauss , Thomas A. Chamberlin , Michael J. Mullins , Maurice J. Marks
发明人： James E. McGrath , Stephen E. Bales , Daniel M. Knauss , Thomas A. Chamberlin , Michael J. Mullins , Maurice J. Marks
IPC分类号： C08G63/52 , C08G64/00 , C08G64/04 , C08G64/14 , C08G64/20 , C08L69/00
CPC分类号： C08G64/045 , C08L69/00
摘要： There are disclosed carbonate polymers having ethenyl aryl moieties. Such carbonate polymers are prepared from one or more multi-hydric compounds and have an average degree of polymerization of at least about 1 based on multi-hydric compound. These polymers, including blends thereof, can be easily processed and shaped into various forms and structures according to the known techniques. During or subsequent to the processing, the polymers can be crosslinked, by exposure to heat or radiation, for example, to provide crosslinked polymer compositions. These compositions have a good combination of properties, including for example, processability into shaped articles having unexpectedly good combinations of toughness, solvent resistance, ignition resistance, modulus and resistance to thermal linear expansion.
摘要翻译：公开了具有乙烯基芳基部分的碳酸酯聚合物。这种碳酸酯聚合物由一种或多种多水合化合物制备，并且基于多羟基化合物具有至少约1的平均聚合度。根据已知技术，这些聚合物，包括其共混物，可以容易地加工成各种形式和结构。在加工期间或之后，聚合物可以通过暴露于热或辐射而交联，例如提供交联的聚合物组合物。这些组合物具有良好的性能组合，包括例如具有出乎意料的良好的韧性，耐溶剂性，耐点火性，模量和耐热线性膨胀组合的成型制品的加工性能。

3. 发明授权

US5045610A Blend of copolyestercarbonate polymer derived from diaryl dicarboxylic acid 失效
标题翻译：由二芳基二羧酸衍生的共聚酯碳酸酯聚合物的共混物
公开(公告)号：US5045610A
公开(公告)日：1991-09-03
申请号：US401213
申请日：1989-08-31
申请人： Stephen E. Bales , Kenneth A. Burdett , Guo-Shuh J. Lee
发明人： Stephen E. Bales , Kenneth A. Burdett , Guo-Shuh J. Lee
IPC分类号： C08G63/64 , C08L69/00 , C08L101/00
CPC分类号： C08L69/005 , C08G63/64 , C08L101/00
摘要： This invention relates to copolyestercarbonate polymers which are prepared with diaryl dicarboxylic acid compounds, particularly biphenyldicarboxylic acid compounds. Such copolyestercarbonate polymers show good physical properties including high glass transition temperatures and low ultraviolet radiation sensitivity. The thermoplastic copolymestercarbonates can be used to prepare films or molded articles or blended with other thermoplastic resins to give thermoplastic polymer blends for molding purposes.
摘要翻译：本发明涉及用二芳基二羧酸化合物，特别是联苯二羧酸化合物制备的共聚酯碳酸酯聚合物。这种共聚酯碳酸酯聚合物显示出良好的物理性质，包括高玻璃化转变温度和低紫外线辐射敏感性。热塑性共聚酯碳酸酯可用于制备膜或模塑制品或与其它热塑性树脂共混以得到用于模制目的的热塑性聚合物共混物。

4. 发明授权

US4388455A Process for preparing ester carbonate copolymers 失效
标题翻译：制备碳酸酯共聚物的方法
公开(公告)号：US4388455A
公开(公告)日：1983-06-14
申请号：US378693
申请日：1982-05-17
申请人： Stephen E. Bales
发明人： Stephen E. Bales
IPC分类号： C08G63/00 , C08G63/20 , C08G63/64 , C08G64/20
CPC分类号： C08G63/64
摘要： Ordered ester/carbonate copolymers having improved properties at higher solids are provided by (1) contacting a dihydric organic compound such as bisphenol-A with a diacid halide such as terephthaloyl chloride and a carbonate precursor such as phosgene under conditions sufficient to form an ester/carbonate oligomer and (2) contacting the oligomer with additional carbonate precursor to produce the desired ordered ester/carbonate copolymer.
摘要翻译：通过（1）在足以形成酯/酯的条件下使二羟基有机化合物如双酚A与二酰卤如对苯二甲酰氯和碳酸酯前体例如光气接触来提供在较高固体下具有改进性能的有序酯/碳酸酯共聚物，碳酸酯低聚物和（2）使低聚物与另外的碳酸酯前体接触以产生所需的有序酯/碳酸酯共聚物。

5. 发明授权

US5352272A Gas separations utilizing glassy polymer membranes at sub-ambient temperatures 失效
标题翻译：在低于环境温度下使用玻璃状聚合物膜的气体分离
公开(公告)号：US5352272A
公开(公告)日：1994-10-04
申请号：US930059
申请日：1992-08-13
申请人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Stephen E. Bales , Henry N. Beck , Thomas O. Jeanes , Bethanne L. Smith
发明人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Stephen E. Bales , Henry N. Beck , Thomas O. Jeanes , Bethanne L. Smith
IPC分类号： B01D53/22 , B01D53/26 , B01D63/00 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/02 , C01B21/04 , C08G64/10 , C08G75/06 , C08G75/26 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/12
CPC分类号： B01D71/48 , B01D53/22 , B01D53/228 , B01D53/268 , B01D69/02 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/0251 , C01B21/0444 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12 , C01B2210/0046 , C01B2210/0062 , Y02P20/129
摘要： This invention relates to a method of and apparatus for separating component gases in a gas mixture employing a glassy polymer membrane at temperatures of 5.degree. C. or less so as to achieve superior separation of gas components.
摘要翻译：本发明涉及一种在5℃或更低的温度下使用玻璃状聚合物膜分离气体混合物中的组分气体的方法和装置，以实现气体组分的优异分离。

6. 发明授权

US4840646A Tetrabromo bisphenol based polyestercarbonate membranes and method of using 失效
标题翻译：四溴双酚基聚碳酸酯膜及其使用方法
公开(公告)号：US4840646A
公开(公告)日：1989-06-20
申请号：US221483
申请日：1988-07-19
申请人： Joginder N. Anand , Stephen E. Bales , Darrell C. Feay , Thomas O. Jeanes
发明人： Joginder N. Anand , Stephen E. Bales , Darrell C. Feay , Thomas O. Jeanes
IPC分类号： B01D53/22 , B01D71/48 , B01D71/50 , C08G63/682
CPC分类号： C08G63/682 , B01D53/22 , B01D71/48 , B01D71/50
摘要： The invention is a membrane comprising a dense skin of a polyestercarbonate, wherein the diphenolic residue in the backbone of the polyestercarbonate is a tetrabromo diphenolic residue, wherein the membrane has a separation factor for oxygen and nitrogen of 6.5 or greater at about 24.degree. C. In another aspect, the invention is a method of separating oxygen from a mixture of gases comprising nitrogen and oxygen, wherein the method comprises (a) contacting the gas mixture with a thin, non-porous membrane comprising a polyestercarbonate described hereinbefore under conditions such that the oxygen selectively permeates through the membrane to the other side of the membrane; and (b) removing the permeated oxygen from the other side of the membrane, wherein separation factor for the oxygen and nitrogen is 6.5 or greater at about 24.degree. C. The membranes of this invention demonstrate surprisingly high separation factors for oxygen and nitrogen separations. The membranes of this invention have good mechanical properties and therefore are useful under more extreme conditions, for example temperature and pressure, than many commercially used membranes.
摘要翻译：本发明是一种包含聚酯碳酸酯致密表皮的膜，其中聚酯碳酸酯主链中的二酚残基是四溴二酚残基，其中该膜在约24℃下具有6.5或更高的氧和氮分离因子。在另一方面，本发明是从包含氮和氧的气体混合物中分离氧的方法，其中所述方法包括（a）使气体混合物与包含上述聚酯碳酸酯的薄的非多孔膜接触，条件是使得氧选择性地渗透膜到膜的另一侧; 和（b）从膜的另一侧除去渗透的氧气，其中在约24℃下氧和氮的分离因子为6.5或更大。本发明的膜表现出惊人的高分离因子用于氧气和氮气的分离。本发明的膜具有良好的机械性能，因此在许多商业使用的膜的更极端条件下，例如温度和压力下是有用的。

7. 发明授权

US4330662A Ordered copolyestercarbonate resins 失效
标题翻译：有序共聚酯碳酸酯树脂
公开(公告)号：US4330662A
公开(公告)日：1982-05-18
申请号：US200759
申请日：1980-10-27
申请人： Stephen E. Bales
发明人： Stephen E. Bales
IPC分类号： C08G63/00 , C08G63/64 , C08G63/12
CPC分类号： C08G63/64
摘要： Ordered copolyestercarbonate resins having repeating units of the formula: ##STR1## wherein a portion of R.sup.1 is meta-phenylene and a portion of R.sub.1 is para-phenylene and R is independently an aromatic hydrocarbylene or inertly substituted aromatic hydrocarbylene, e.g., ##STR2## exhibit physical properties such as heat resistance, clarity and impact strength that are superior to the comparable properties of corresponding random copolymers. They exhibit melt processability that is superior to the melt processability of corresponding copolyestercarbonates wherein R.sup.1 is entirely para-phenylene. They exhibit heat resistance, notch sensitivity and low temperature impact resistance that are superior to comparable properties of corresponding copolyestercarbonates wherein R.sup.1 is entirely meta-phenylene. Such resins are useful for making transparent tough films and molded articles having high heat resistance.
摘要翻译：具有下式重复单元的有序共聚酯碳酸酯树脂：其中R1的一部分是间亚苯基，R 1的一部分是对亚苯基，R独立地是芳族亚烃基或惰性取代的芳族亚烃基，例如，诸如耐热性，透明度和冲击强度的物理性能优于相应无规共聚物的可比性能。它们表现出优于相应的共聚酯碳酸酯的熔融加工性的熔融加工性，其中R1是完全对亚苯基。它们表现出耐热性，切口灵敏度和耐低温冲击性，其优于相应的共聚酯碳酸酯的性能，其中R1完全是间 - 亚苯基。这种树脂可用于制造具有高耐热性的透明韧性薄膜和模制品。

8. 发明授权

US6051294A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US6051294A
公开(公告)日：2000-04-18
申请号：US21058
申请日：1998-02-09
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08L71/00 , B65B55/00
CPC分类号： C08L71/00 , Y10T428/1352
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one dtglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophillo moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能的聚醚通过使至少一种双亲性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种dt缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使双亲单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

9. 发明授权

US5837032A Gas separations utilizing glassy polymer membranes at sub-ambient temperatures 失效
标题翻译：在低于环境温度下使用玻璃状聚合物膜的气体分离
公开(公告)号：US5837032A
公开(公告)日：1998-11-17
申请号：US382032
申请日：1995-02-10
申请人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Thomas O. Jeanes , Henry N. Beck , Stephen E. Bales , Bethanne L. Smith
发明人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Thomas O. Jeanes , Henry N. Beck , Stephen E. Bales , Bethanne L. Smith
IPC分类号： B01D53/22 , B01D53/26 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/02 , C01B21/04 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12
CPC分类号： C01B13/0251 , B01D53/22 , B01D53/228 , B01D53/268 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B21/0444 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12 , C01B2210/0046 , C01B2210/0062
摘要： This invention relates to a method of an apparatus and method for separating component gases in a gas mixture employing a glassy polymer membrane at temperatures at or slightly above the freezing point of any liquid present so as to achieve superior separator of gas components. The composition of certain monomers and polymers are claimed.
摘要翻译： PCT No.PCT / US93 / 07696 Sec。 371日期1995年2月10日 102（e）1995年2月10日PCT PCT 1993年8月13日PCT公布。出版物WO94 / 04250 日本特开1994年3月3日本发明涉及一种使用玻璃状聚合物膜在气体混合物中分离组分气体的装置和方法的方法，所述气体混合物在存在的任何液体的冰点处或稍高于所存在的任何液体的冰点处，以便获得优异的气体分离器组件。要求某些单体和聚合物的组成。

10. 发明授权

US5532331A Thiodiphenol copolycarbonates and their use as components of multilayered polymeric reflective bodies 失效
标题翻译：硫代二苯酚共聚碳酸酯及其作为多层聚合物反射体的组分的用途
公开(公告)号：US5532331A
公开(公告)日：1996-07-02
申请号：US351436
申请日：1994-12-14
申请人： Stephen E. Bales , Charles A. Langhoff , John A. Wheatley
发明人： Stephen E. Bales , Charles A. Langhoff , John A. Wheatley
IPC分类号： C08G64/08 , C08G64/00
CPC分类号： C08G64/081 , Y10T428/31507
摘要： This invention provides novel copolycarbonates that exhibit improvements in glass transition temperature, refractive index, and limiting oxygen index compared to prior art thiodiphenol/bisphenol A copolycarbonates. The copolycarbonates of this invention comprise the reaction products of 4,4'-thiodiphenol and compounds such as 9,9-bis (4-hydroxyphenyl) fluorene with phosgene. They are useful as components of multilayered polymeric reflective bodies.
摘要翻译： PCT No.PCT / US93 / 06074 Sec。 371日期1994年12月15日 102（e）1994年12月15日日期PCT提交1993年6月24日PCT公布。出版物WO94 / 02533 日本1994年2月3日。本发明提供与现有技术的硫代二酚/双酚A共聚碳酸酯相比，显示玻璃化转变温度，折射率和极限氧指数的改进的新型共聚碳酸酯。本发明的共聚碳酸酯包括4,4'-硫代二酚和诸如9,9-双（4-羟基苯基）芴和光气的化合物的反应产物。它们可用作多层聚合物反射体的组分。

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