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1. 发明授权

US6156381A Ozone treatment of surface of membrane to improve permselectivity 有权
标题翻译：臭氧处理膜表面以提高选择性
公开(公告)号：US6156381A
公开(公告)日：2000-12-05
申请号：US226524
申请日：1998-12-30
申请人： Pamela J. Leong , Frederick L. Coan , John A. Jensvold , Thomas O. Jeanes
发明人： Pamela J. Leong , Frederick L. Coan , John A. Jensvold , Thomas O. Jeanes
IPC分类号： B01D67/00 , B05D5/00 , B05D3/02 , B05D7/22
CPC分类号： B01D67/0093
摘要： A method for preparing a surface modified gas separation membrane, wherein said membrane has improved permselective properties for separating a mixture of gases as compared to the unmodified membrane, is described. The method comprises coating a surface unmodified gas separation membrane with a solution of a coating material, wherein the coating material is an organic material having at least one site of unsaturation; heating the coated gas separation membrane; and contacting the heated coated gas separation membrane with at least one oxidizing agent for a time effective to surface modify the gas separation membrane to produce the surface modified gas separation membrane having improved permselectivity.
摘要翻译：描述了一种制备表面改性气体分离膜的方法，其中与未改性膜相比，所述膜具有改善的选择性选择性，用于分离气体混合物。该方法包括用涂覆材料的溶液涂覆表面未改性的气体分离膜，其中涂层材料是具有至少一个不饱和位点的有机材料; 加热涂层气体分离膜; 并使加热的涂覆的气体分离膜与至少一种氧化剂接触，以有效地表面改性气体分离膜，以产生具有改进的选择性的表面改性气体分离膜。

2. 发明授权

US5679133A Gas separations utilizing glassy polymer membranes at sub-ambient temperatures 失效
标题翻译：在低于环境温度下使用玻璃状聚合物膜的气体分离
公开(公告)号：US5679133A
公开(公告)日：1997-10-21
申请号：US292771
申请日：1994-08-18
申请人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Stephen E. Bales , Henry Nelson Beck , Thomas O. Jeanes , Bethanne L. Smith
发明人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Stephen E. Bales , Henry Nelson Beck , Thomas O. Jeanes , Bethanne L. Smith
IPC分类号： B01D53/22 , B01D53/26 , B01D63/00 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/02 , C01B21/04 , C08G64/10 , C08G75/06 , C08G75/26 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/12
CPC分类号： B01D71/48 , B01D53/22 , B01D53/228 , B01D53/268 , B01D69/02 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/0251 , C01B21/0444 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12 , C01B2210/0046 , C01B2210/0062 , Y02P20/129
摘要： This invention relates to a method of and apparatus for separating component gases in a gas mixture employing a glassy polymer membrane at temperatures of 5.degree. C. or less so as to achieve superior separation of gas components.
摘要翻译：本发明涉及一种在5℃或更低的温度下使用玻璃状聚合物膜分离气体混合物中的组分气体的方法和装置，以实现气体组分的优异分离。

3. 发明授权

US4874401A Gas separation membranes from bisphenol AF polycarbonates and polyestercarbonates 失效
标题翻译：来自双酚AF聚碳酸酯和聚酯碳酸酯的气体分离膜
公开(公告)号：US4874401A
公开(公告)日：1989-10-17
申请号：US123495
申请日：1987-11-20
申请人： Thomas O. Jeanes
发明人： Thomas O. Jeanes
IPC分类号： B01D71/48 , B01D71/50 , C08G63/64 , C08G64/10 , D01D5/24 , D01F6/64
CPC分类号： C08G63/64 , B01D71/48 , B01D71/50 , C08G64/10
摘要： The invention relates to a gas separation membrane comprsing a thin discriminating layer of bisphenol AF polycarbonate or polyestercarbonate.The invention further relates to a method of separating gases comprising(a) contacting with a feed gas mixture under pressure one side of a semi-permeable membrane comprising a thin discriminating layer of polycarbonate or polyestercarbonate, wherein the diphenolic residue in the polymer backbone is based on bisphenol AF;(b) maintaining a pressue differential across the membrane under conditions such that a component(s) of the feed gas selectively permeates through the membrane from the high pressure side to the low pressure side of the membrane;(c) removing the permeated gas which is enriched in the faster permeating component(s) from the low pressure side of the membrane;(d) removing the nonpermeated gas which is depleted in the faster permeating component(s) from the high pressure side of the membrane.

4. 发明授权

US06734279B2 Two step production of polycarbonates 有权
标题翻译：两步生产聚碳酸酯
公开(公告)号：US06734279B2
公开(公告)日：2004-05-11
申请号：US10289537
申请日：2002-11-05
申请人： Thomas O. Jeanes , John Osby
发明人： Thomas O. Jeanes , John Osby
IPC分类号： C08G6400
CPC分类号： B01J31/0237 , B01J31/0239 , B01J31/0244 , B01J2531/985 , C08G64/24 , C08G64/403
摘要： Methods of synthesizing high molecular weight polycarbonate polymers are described. Also described are polycarbonates produced by these methods.
摘要翻译：描述合成高分子量聚碳酸酯聚合物的方法。还描述了通过这些方法制备的聚碳酸酯。

5. 发明授权

US6136073A Boreside feed modules with permeate flow channels 有权
标题翻译：具有渗透流动通道的前端进料模块
公开(公告)号：US6136073A
公开(公告)日：2000-10-24
申请号：US184604
申请日：1998-11-02
申请人： Frederick Coan , Thomas O. Jeanes , John Arthur Jensvold
发明人： Frederick Coan , Thomas O. Jeanes , John Arthur Jensvold
IPC分类号： B01D53/22 , B01D63/02
CPC分类号： B01D63/02 , B01D53/22 , B01D2313/12 , B01D2319/02
摘要： A boreside feed gas separation membrane device containing primarily hollow fiber membranes with discrete flow channels incorporated into the bundle to allow for pressure removal of the permeate gas collected on the shellside of the device is described. The flow channels minimize pressure drop and/or the build-up of back pressure on the shellside of the device while maintaining proper counter-current flow patterns in the device. The incorporation of flow channels results in improved efficiency of the device, especially for feed streams or membrane types that lead to high permeate flow rate that result in excessive shellside pressure drops.
摘要翻译：描述了主要包含具有结合到束中的离散流动通道的中空纤维膜以允许压力去除收集在装置壳体上的渗透气体的内侧进料气体分离膜装置。流动通道使装置的壳体侧的压降和/或背压的积聚最小化，同时在装置中保持适当的逆流流动模式。流动通道的引入导致装置的效率提高，特别是对于导致高渗透流量的进料流或膜类型而导致过大的壳侧压降。

6. 发明授权

US06641643B2 Ceramic deoxygenation hybrid systems for the production of oxygen and nitrogen gases 有权
公开(公告)号：US06641643B2
公开(公告)日：2003-11-04
申请号：US09975753
申请日：2001-10-10
申请人： John A. Jensvold , Scott S. Campbell , Thomas O. Jeanes
发明人： John A. Jensvold , Scott S. Campbell , Thomas O. Jeanes
IPC分类号： B01D5322
CPC分类号： C01B13/0259 , B01D53/047 , B01D53/229 , B01D53/326 , B01D2256/10 , B01D2256/12 , B01D2257/102 , B01D2259/40007 , C01B13/0251 , C01B21/0438 , C01B2210/0045 , C01B2210/0046
摘要： A gas separation system comprising one or more ceramic membranes is described. The system, particularly, the arrangement of the ceramic membranes and/or other polymeric membranes or PSA systems, results in maximum durability of the ceramic membranes.

7. 发明授权

US5352272A Gas separations utilizing glassy polymer membranes at sub-ambient temperatures 失效
标题翻译：在低于环境温度下使用玻璃状聚合物膜的气体分离
公开(公告)号：US5352272A
公开(公告)日：1994-10-04
申请号：US930059
申请日：1992-08-13
申请人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Stephen E. Bales , Henry N. Beck , Thomas O. Jeanes , Bethanne L. Smith
发明人： David J. Moll , Alan F. Burmester , Thomas C. Young , Kent B. McReynolds , James E. Clark , Charles Z. Hotz , Ritchie A. Wessling , George J. Quarderer , Ronald M. Lacher , Stephen E. Bales , Henry N. Beck , Thomas O. Jeanes , Bethanne L. Smith
IPC分类号： B01D53/22 , B01D53/26 , B01D63/00 , B01D69/02 , B01D71/48 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/02 , C01B21/04 , C08G64/10 , C08G75/06 , C08G75/26 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/12
CPC分类号： B01D71/48 , B01D53/22 , B01D53/228 , B01D53/268 , B01D69/02 , B01D71/50 , B01D71/52 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/72 , C01B13/0251 , C01B21/0444 , C08G64/10 , C08G75/06 , C08G75/26 , C08L71/12 , C01B2210/0046 , C01B2210/0062 , Y02P20/129
摘要： This invention relates to a method of and apparatus for separating component gases in a gas mixture employing a glassy polymer membrane at temperatures of 5.degree. C. or less so as to achieve superior separation of gas components.
摘要翻译：本发明涉及一种在5℃或更低的温度下使用玻璃状聚合物膜分离气体混合物中的组分气体的方法和装置，以实现气体组分的优异分离。

8. 发明授权

US5209848A Xylylene based polyether membranes for gas separation 失效
标题翻译：用于气体分离的基于二甲苯的聚醚膜
公开(公告)号：US5209848A
公开(公告)日：1993-05-11
申请号：US748479
申请日：1991-08-22
申请人： Thomas O. Jeanes , Ritchie A. Wessling
发明人： Thomas O. Jeanes , Ritchie A. Wessling
IPC分类号： B01D53/22 , B01D53/26 , B01D71/52 , C01B3/50 , C08G63/64 , C08G63/672 , C08G64/18 , C08G65/40
CPC分类号： B01D71/52 , B01D53/228 , B01D53/268 , C01B3/503 , C08G63/64 , C08G63/672 , C08G64/183 , C08G65/4006 , C08G65/4018 , C01B2203/0405 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/0495
摘要： The invention relates to novel xylylene based polyether gas separation membranes and a method of separating gases using such membranes.
摘要翻译：本发明涉及新的基于二甲苯的聚醚气体分离膜和使用这种膜分离气体的方法。

9. 发明授权

US4851014A Gas separation membranes derived from polycarbonates, polyesters, and polyestercarbonates containing tetrafluorobisphenol F 失效
标题翻译：衍生自含有四氟双酚F的聚碳酸酯，聚酯和聚酯碳酸酯的气体分离膜
公开(公告)号：US4851014A
公开(公告)日：1989-07-25
申请号：US214563
申请日：1988-07-01
申请人： Thomas O. Jeanes
发明人： Thomas O. Jeanes
IPC分类号： B01D53/22 , B01D71/48 , B01D71/50 , C08G63/64 , C08G63/682 , C08G64/10
CPC分类号： B01D71/50 , B01D53/228 , B01D71/48 , C08G63/64 , C08G63/6826 , C08G64/10
摘要： The invention is a semi-permeable membrane consituting a thin discriminating layer of bisphenolic polycarbonate, polyester, or polyestercarbonate, with a significant portion of the bisphenolic residues in the polymer backbone being based on tetrafluorobisphenol F. The invention also includes a method of separating gases using the described membrane.
摘要翻译：本发明是一种半透膜，其包括双酚聚碳酸酯，聚酯或聚酯碳酸酯的薄识别层，聚合物主链中的大部分双酚残基基于四氟双酚F.本发明还包括使用所描述的膜。

10. 发明授权

US4840646A Tetrabromo bisphenol based polyestercarbonate membranes and method of using 失效
标题翻译：四溴双酚基聚碳酸酯膜及其使用方法
公开(公告)号：US4840646A
公开(公告)日：1989-06-20
申请号：US221483
申请日：1988-07-19
申请人： Joginder N. Anand , Stephen E. Bales , Darrell C. Feay , Thomas O. Jeanes
发明人： Joginder N. Anand , Stephen E. Bales , Darrell C. Feay , Thomas O. Jeanes
IPC分类号： B01D53/22 , B01D71/48 , B01D71/50 , C08G63/682
CPC分类号： C08G63/682 , B01D53/22 , B01D71/48 , B01D71/50
摘要： The invention is a membrane comprising a dense skin of a polyestercarbonate, wherein the diphenolic residue in the backbone of the polyestercarbonate is a tetrabromo diphenolic residue, wherein the membrane has a separation factor for oxygen and nitrogen of 6.5 or greater at about 24.degree. C. In another aspect, the invention is a method of separating oxygen from a mixture of gases comprising nitrogen and oxygen, wherein the method comprises (a) contacting the gas mixture with a thin, non-porous membrane comprising a polyestercarbonate described hereinbefore under conditions such that the oxygen selectively permeates through the membrane to the other side of the membrane; and (b) removing the permeated oxygen from the other side of the membrane, wherein separation factor for the oxygen and nitrogen is 6.5 or greater at about 24.degree. C. The membranes of this invention demonstrate surprisingly high separation factors for oxygen and nitrogen separations. The membranes of this invention have good mechanical properties and therefore are useful under more extreme conditions, for example temperature and pressure, than many commercially used membranes.
摘要翻译：本发明是一种包含聚酯碳酸酯致密表皮的膜，其中聚酯碳酸酯主链中的二酚残基是四溴二酚残基，其中该膜在约24℃下具有6.5或更高的氧和氮分离因子。在另一方面，本发明是从包含氮和氧的气体混合物中分离氧的方法，其中所述方法包括（a）使气体混合物与包含上述聚酯碳酸酯的薄的非多孔膜接触，条件是使得氧选择性地渗透膜到膜的另一侧; 和（b）从膜的另一侧除去渗透的氧气，其中在约24℃下氧和氮的分离因子为6.5或更大。本发明的膜表现出惊人的高分离因子用于氧气和氮气的分离。本发明的膜具有良好的机械性能，因此在许多商业使用的膜的更极端条件下，例如温度和压力下是有用的。

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